CN101711883A - Aerosol air purification freshener and preparation method thereof - Google Patents
Aerosol air purification freshener and preparation method thereof Download PDFInfo
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- CN101711883A CN101711883A CN200910191301A CN200910191301A CN101711883A CN 101711883 A CN101711883 A CN 101711883A CN 200910191301 A CN200910191301 A CN 200910191301A CN 200910191301 A CN200910191301 A CN 200910191301A CN 101711883 A CN101711883 A CN 101711883A
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Abstract
The invention discloses aerosol air purification freshener and preparation method thereof. The air purification freshener comprises an emulsion and a propellent, wherein the emulsion comprises camphor wood oil, essence, alcohol, a surface active agent and deionized water; the deionized water is used for replacing various organic solvents, and the camphor wood oil is used as a main active matter for removing off-flavors; the camphor wood oil is diffused into a space in the form of aerosol and reacts with molecules of ammonia, formaldehyde, and the like to generate hydrogen bonds and covalent bonds so as to catch off-flavor molecules in air; and the odor of the camphor wood oil and the odor of spices cannot have conflicts so as to give fragrance to environment. The aerosol air purification freshener upgrades traditional air freshener products and becomes safer and more environmental-friendly, and meanwhile, the aerosol air purification freshener also has the effect of expelling vermins and is specially suitable for spaces such as toilets, automobiles, rooms, hotels, offices, and the like. The preparation method has simple process, safe and easy operation and good ruggedness and can provide reliable guarantees for the scale production of products.
Description
Technical field
The present invention relates to the air purifying preparation field, particularly a kind of aerosol air purification freshener and preparation method thereof.
Background technology
The aerosol-type air freshener also is faced with problems and pressure when China develops rapidly.Such as: 1, the problem of effect, air freshener is to reach the pure and fresh purpose of surrounding air with the abnormal flavour of covering in the environment basically in the market, even some product can reach the function of removing abnormal flavour, also be to use some strong oxidizing property materials (as chlorine dioxide) to reach the purpose of decomposing abnormal flavour, when decomposing abnormal flavour, also inevitably brought secondary pollution, also can remove simultaneously the fragrance of the air freshener in the environment to surrounding air; 2, the pressure of cost, air freshener adopts organic solvent and third butane mixture gase compositions such as ethanol, refining white mineral oil mostly for a long time, degree of dependence to oil product is bigger, and the unstability of oil, gas price lattice brings big pressure also for the production cost of air freshener; 3, An Quan pressure is propellant with third butane mixture gase, and Organic substances such as ethanol, refining white mineral oil are the air freshener of solvent, if consumer in use do not note, security incidents such as combustion explosion take place easily, exist serious potential safety hazard; 4, the pressure of environmental protection, more and more Yan Ge environmental requirement proposes to all trades and professions.Because photochemical reaction can take place in most of VOCs (VOC), cause destruction, the face of land air quality of atmospheric ozone layer to descend, make and live in the probability that this spatial people suffers from diseases of respiratory system and heighten, therefore, after the U.S. took the lead in limiting the VOC discharging, restriction VOC discharging was also played in administrative area, China Hong Kong in 2009.
In view of this, need a kind of air freshener, the various abnormal flavour in can purifying air can be given environment pure and fresh taste again simultaneously, and can not cause secondary pollution to air, and are simultaneously with low cost, safe in utilization.
Summary of the invention
In view of this, one of purpose of the present invention provides a kind of aerosol air purification freshener, the various abnormal flavour in not only purifying air, and give environment pure and fresh taste, and can not cause secondary pollution to air, simultaneously with low cost, safe in utilization.
Aerosol air purification freshener of the present invention comprises emulsion and propellant, and described emulsion comprises by own wt percentage ratio: camphor oil 2.2-2.7%, essence 0.5-1.5%, ethanol 1-3% and surfactant 0.6-1.5%, and surplus is a deionized water;
Described surfactant comprises 5 parts of sorbitan sesquioleate and 1 part of fatty alcohol-polyoxyethylene ether by weight, and described camphor oil comprises linalool 28-34%, Camphora 27-35% and cineole 13-17% by own wt percentage ratio;
Described alcoholic acid mass concentration is 95%, and the pH value of described emulsion is 7-8.
As further improvement, described emulsion comprises by own wt percentage ratio: camphor oil 2.5%, essence 1.1%, and ethanol 3% and surfactant 1.1%, surplus is a deionized water;
As further improvement, described propellant is one or both in propane, normal butane, iso-butane and the dimethyl ether, and described propellant weight is the 22-45% of emulsion weight;
As further improvement, described propellant is third butane mixture gase, and described third butane mixture gase comprises propane 20-40% and butane 60-80% by the own wt ratio, and the weight of described third butane mixture gase is the 22-30% of emulsion weight.
Two of purpose of the present invention is to provide the preparation method of described aerosol air purification freshener, comprises the steps:
A. in described ratio camphor oil, surfactant, essence, ethanol, surfactant are mixed and stir and obtain mixture;
B. more required deionized water is added under stirring condition in the mixture of step a gained slowly, to be mixedly can obtain required emulsion after evenly;
C. the emulsion of step b gained is carried out cannedly under stirring condition, fit on aerosol valve also seals, and the filling propellant gets final product then.
Beneficial effect of the present invention:
The beneficial effect of product of the present invention is: replace various organic solvents with deionized water, and scientific and reasonable employing camphor oil is as the main active matter of removing abnormal flavour in the air, characteristics in conjunction with the aerosol atomizing, make camphor oil be diffused into each corner of environment space fast with aerocolloidal kenel, the camphor oil that is concavity and the ammonia of spray pattern, sulfide, the reaction of formaldehyde equimolecular generates hydrogen bond, covalent bond, and accurate chelation, thereby free formaldehyde in the seizure air, ammonia, sulfide etc. produce the molecule of abnormal flavour, the result generates than weight molecule, the complex of more weak vapour pressure, thus it is no longer active that the stink molecular change is got; And the abnormal smells from the patient of camphor oil can not produce with the abnormal smells from the patient of spice and conflicts, make and give environment different fragrance when purifying air, make traditional air freshener product obtain upgrading, the better effects if of become safer, more environmental protection, removing abnormal flavour, this product also has the effect of driving sanitary insect pest simultaneously, is suitable for very much the air cleaning of occasions such as toilet, automobile, room, hotel, office space.
As further improvement, more preferably camphor oil 2.5%, essence 1.1% of the content of each composition in the emulsion among the present invention, ethanol 3% and surfactant 1.1%, surplus is a deionized water, makes emulsion stability better, the product longer service life.
As further improvement, propellant of the present invention is one or both in propane, normal butane, iso-butane and the dimethyl ether, and described propellant weight is the 22-45% of emulsion weight, and these several propellant raw materials are easy to get, with low cost, consumption is less and can effectively ensure the atomizing effect of product.
As further improvement, propellant of the present invention is third butane mixture gase more preferably, large usage quantity when its advantage is dimethyl ether as propellant, and be inflammable and explosive Class A Hazardous Chemical Substances, in fill, give birth to and careless slightlyly in tight, storage and the transit link very easily to have an accident, select for use the third butane mixture gase consumption littler, use safer, environmentally friendly when realizing better spray effect.
The beneficial effect of preparation method of the present invention is: technology is simple, handling safety is easy and favorable reproducibility, and reliable guarantee can be provided for the large-scale production of product.
The specific embodiment
Embodiment 1:
The aerosol air purification freshener of present embodiment, comprise emulsion and propellant, described emulsion comprises by own wt percentage ratio: camphor oil 2.2%, essence 0.5%, mass concentration is 95% ethanol 1%, surfactant 0.6%, surplus is a deionized water, in the present embodiment, camphor oil comprises linalool 28% by own wt percentage ratio, Camphora 32% and cineole 17%, surfactant comprises 5 parts of sorbitan sesquioleate and 1 part of fatty alcohol-polyoxyethylene ether by weight, the pH value of emulsion is 7, propellant is selected dimethyl ether for use, and the weight of dimethyl ether is 45% of emulsion weight; Need to prove: in the present embodiment propellant select for use in propane, butane, iso-butane and the dimethyl ether one or more all can, propellant selects for use Compressed Gas such as N2, CO2 etc. can realize purpose of the present invention equally.
The aerosol air purification freshener of preparation present embodiment specifically comprises the steps:
A. in described ratio camphor oil, surfactant, essence, ethanol, surfactant are mixed and stir and obtain mixture;
B. more required deionized water is slowly added under stirring condition in the mixture of step a gained, to be mixedly can obtain required emulsion after evenly;
C. the emulsion of step b gained is carried out cannedly under stirring condition, fit on aerosol valve also seals, and the filling propellant gets final product then.
Embodiment 2:
The aerosol air purification freshener of present embodiment, comprise emulsion and propellant, described emulsion comprises following composition by own wt percentage ratio: camphor oil 2.5%, essence 1.1%, concentration is 95% ethanol 3%, surfactant 1.1%, surplus is a deionized water, in the present embodiment, camphor oil comprises linalool 30% by own wt percentage ratio, Camphora 30% and cineole 15%, surfactant comprises 5 parts of sorbitan sesquioleate and 1 part of fatty alcohol-polyoxyethylene ether by weight, the pH value of emulsion is 8, propellant is selected third butane mixture gase for use, described weight with propellant is 22% of emulsion weight, in the present embodiment, used propellant is third butane mixture gase, price is lower, atomisation pressure is moderate and viscosity is low, and described third butane mixture gase comprises 30% propane and 70% butane by own wt percentage ratio, improved when guaranteeing the product atomization quality product store and transportation in safety.
The aerosol air purification freshener of preparation present embodiment specifically comprises the steps:
A. in described ratio camphor oil, surfactant, essence, ethanol, surfactant are mixed and stir and obtain mixture;
B. more required deionized water is added under stirring condition in the mixture of step a gained slowly, to be mixedly can obtain required emulsion after evenly;
C. the emulsion of step b gained is carried out cannedly under stirring condition, fit on aerosol valve also seals, and the filling propellant gets final product then.
Embodiment 3:
The aerosol air purification freshener of present embodiment, comprise emulsion and propellant, described emulsion comprises by own wt percentage ratio: camphor oil 2.5%, essence 1.4%, concentration is 95% ethanol 3%, surfactant 1.3%, surplus is a deionized water, in the present embodiment, camphor oil comprises linalool 34% by own wt percentage ratio, Camphora 27% and cineole 13%, surfactant comprises 5 parts of sorbitan sesquioleate and 1 part of fatty alcohol-polyoxyethylene ether by weight, the pH value of emulsion is 7, propellant is selected third butane mixture gase for use, third butane mixture gase comprises 40% propane and 60% butane by own wt percentage ratio, and the weight of third butane mixture gase is 30% of emulsion weight.
The aerosol air purification freshener of preparation present embodiment specifically comprises the steps:
A. in described ratio camphor oil, surfactant, essence, ethanol, surfactant are mixed and stir and obtain mixture;
B. again with required deionized water under constantly fast stirring, add slowly in the mixture of step a gained, to be mixedly can obtain required emulsion after evenly;
C. the emulsion of step b gained is carried out cannedly under stirring condition, fit on aerosol valve also seals, and the filling propellant gets final product then.
Embodiment 4:
The aerosol air purification freshener of present embodiment, comprise emulsion and propellant, described emulsion comprises by own wt percentage ratio: camphor oil 2.7%, essence 1.5%, concentration is 95% ethanol 3%, surfactant 1.5%, surplus is a deionized water, in the present embodiment, camphor oil comprises linalool 32% by own wt percentage ratio, Camphora 29% and cineole 14%, surfactant comprises 5 parts of sorbitan sesquioleate and 1 part of fatty alcohol-polyoxyethylene ether by weight, the pH value of emulsion is 8, propellant is selected iso-butane for use, and the weight of iso-butane is 30% of emulsion weight.
The aerosol air purification freshener of preparation present embodiment specifically comprises the steps:
A. in described ratio camphor oil, surfactant, essence, ethanol, surfactant are mixed and stir and obtain mixture;
B. more required deionized water is added under stirring condition in the mixture of step a gained slowly, to be mixedly can obtain required emulsion after evenly;
C. the emulsion of step b gained is carried out cannedly under stirring condition, fit on aerosol valve also seals, and the filling propellant gets final product then.
Embodiment 5:
The aerosol air purification freshener of present embodiment, comprise emulsion and propellant, described emulsion comprises following composition by own wt percentage ratio: camphor oil 2.2%, essence 1.5%, concentration is 95% ethanol 3%, surfactant 0.6%, surplus is a deionized water, in the present embodiment, camphor oil comprises linalool 30% by own wt percentage ratio, Camphora 28% and cineole 17%, surfactant comprises 5 parts of sorbitan sesquioleate and 1 part of fatty alcohol-polyoxyethylene ether by weight, the pH value of emulsion is 7, propellant is selected third butane mixture gase for use, third butane mixture gase comprises 20% propane and 80% butane by own wt percentage ratio, and the weight of third butane mixture gase is 30% of emulsion weight.
The aerosol air purification freshener of preparation present embodiment specifically comprises the steps:
A. in described ratio camphor oil, surfactant, essence, ethanol, surfactant are mixed and stir and obtain mixture;
B. more required deionized water is added under stirring condition in the mixture of step a gained slowly, to be mixedly can obtain required emulsion after evenly;
C. the emulsion of step b gained is carried out cannedly under stirring condition, fit on aerosol valve also seals, and the filling propellant gets final product then.
Embodiment 6:
The aerosol air purification freshener of present embodiment, comprise emulsion and propellant, described emulsion comprises following composition by own wt percentage ratio: camphor oil 2.7%, essence 0.5%, concentration is 95% ethanol 1%, surfactant 1.5%, surplus is a deionized water, in the present embodiment, camphor oil comprises linalool 34% by own wt percentage ratio, Camphora 30% and cineole 13%, surfactant comprises 5 parts of sorbitan sesquioleate and 1 part of fatty alcohol-polyoxyethylene ether by weight, the pH value of emulsion is 8, propellant is selected the mixture of iso-butane and dimethyl ether for use and is comprised 30% iso-butane and 70% dimethyl ether by own wt percentage ratio, and the weight of propellant is 35% of emulsion weight.
The aerosol air purification freshener of preparation present embodiment specifically comprises the steps:
A. in described ratio camphor oil, surfactant, essence, ethanol, surfactant are mixed and stir and obtain mixture;
B. again with required deionized water under constantly fast stirring, add slowly in the mixture of step a gained, to be mixedly can obtain required emulsion after evenly;
C. the emulsion of step b gained is carried out cannedly under stirring condition, fit on aerosol valve also seals, and the filling propellant gets final product then.
The air purification effect of the product of each embodiment and atomizing effect such as following table:
| Sample | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Formaldehyde clearance/% | ??26 | ??33 | ??30 | ??26 | ??27 | ??26 |
| Ammonia clearance/% | ??83 | ??94 | ??89 | ??84 | ??83 | ??86 |
| Internal pressure, (25 ℃)/MPa | ??0.51 | ??0.43 | ??0.48 | ??0.47 | ??0.52 | ??0.44 |
| Atomizing particle size/micron | ??36 | ??54 | ??49 | ??45 | ??42 | ??47 |
Need to prove that in the various embodiments described above, used alcoholic acid methanol content meets the national standard of medical ethanol or edible ethanol, the size of enclosed space and air conditions are all identical in the foregoing description, and the consumption of air purification agent is identical.
Explanation is at last, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, although the present invention is had been described in detail with reference to preferred embodiment, those of ordinary skill in the art is to be understood that, can make amendment or be equal to replacement technical scheme of the present invention, and not breaking away from the aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of the claim scope of the present invention.
Claims (5)
1. an aerosol air purification freshener comprises emulsion and propellant, it is characterized in that:
Described emulsion comprises by own wt percentage ratio: camphor oil 2.2-2.7%, essence 0.5-1.5%, ethanol 1-3% and surfactant 0.6-1.5%, and surplus is a deionized water;
Described surfactant comprises 5 parts of sorbitan sesquioleate and 1 part of fatty alcohol-polyoxyethylene ether by weight, and described camphor oil comprises linalool 28-34%, Camphora 27-32% and cineole 13-17% by own wt percentage ratio;
Described alcoholic acid mass concentration is 95%, and the pH value of described emulsion is 7-8.
2. aerosol air purification freshener according to claim 1 is characterized in that: described emulsion comprises by own wt percentage ratio: camphor oil 2.5%, essence 1.1%, and ethanol 3% and surfactant 1.1%, surplus is a deionized water.
3. aerosol air purification freshener according to claim 1 and 2 is characterized in that: described propellant is one or both in propane, normal butane, iso-butane and the dimethyl ether, and described propellant weight is the 22-45% of emulsion weight.
4. aerosol air purification freshener according to claim 3, it is characterized in that: described propellant is third butane mixture gase, described third butane mixture gase comprises propane 20-40% and butane 60-80% by own wt percentage ratio, and the weight of described third butane mixture gase is the 22-30% of emulsion weight.
5. prepare the method for the described aerosol air purification freshener of claim 1, it is characterized in that: comprise the steps:
A. in described ratio camphor oil, surfactant, essence, ethanol, surfactant are mixed and stir and obtain mixture;
B. more required deionized water is added under stirring condition in the mixture of step a gained slowly, to be mixedly can obtain required emulsion after evenly;
C. the emulsion of step b gained is carried out cannedly under stirring condition, fit on aerosol valve also seals, and the filling propellant gets final product then.
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| CN 200910191301 CN101711883B (en) | 2009-10-30 | 2009-10-30 | Aerosol air purification freshener and preparation method thereof |
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| CN 200910191301 CN101711883B (en) | 2009-10-30 | 2009-10-30 | Aerosol air purification freshener and preparation method thereof |
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| CN101711883A true CN101711883A (en) | 2010-05-26 |
| CN101711883B CN101711883B (en) | 2013-01-23 |
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