KR102675517B1 - High performance deodorant compositions using natural caster oil derivatives - Google Patents
High performance deodorant compositions using natural caster oil derivatives Download PDFInfo
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- KR102675517B1 KR102675517B1 KR1020220002453A KR20220002453A KR102675517B1 KR 102675517 B1 KR102675517 B1 KR 102675517B1 KR 1020220002453 A KR1020220002453 A KR 1020220002453A KR 20220002453 A KR20220002453 A KR 20220002453A KR 102675517 B1 KR102675517 B1 KR 102675517B1
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- ricinoleic acid
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- oil derivative
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- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 239000002781 deodorant agent Substances 0.000 title abstract description 18
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical class CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 claims abstract description 37
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 23
- 239000004359 castor oil Substances 0.000 claims abstract description 17
- 235000019438 castor oil Nutrition 0.000 claims abstract description 17
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 17
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011701 zinc Substances 0.000 claims abstract description 16
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 16
- 229960003656 ricinoleic acid Drugs 0.000 claims abstract description 14
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003205 fragrance Substances 0.000 claims abstract description 8
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 5
- 229930195729 fatty acid Natural products 0.000 claims abstract description 5
- 239000000194 fatty acid Substances 0.000 claims abstract description 5
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 4
- 239000003463 adsorbent Substances 0.000 claims abstract description 4
- 239000003054 catalyst Substances 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims abstract description 4
- 150000007524 organic acids Chemical class 0.000 claims abstract description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 4
- 229950008882 polysorbate Drugs 0.000 claims abstract description 4
- 229920000136 polysorbate Polymers 0.000 claims abstract description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000230 xanthan gum Substances 0.000 claims abstract description 4
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 4
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 4
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- 235000004443 Ricinus communis Nutrition 0.000 claims abstract description 3
- 239000003921 oil Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 13
- 238000004332 deodorization Methods 0.000 abstract description 11
- 239000000499 gel Substances 0.000 abstract description 10
- 239000002245 particle Substances 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 238000002474 experimental method Methods 0.000 abstract description 3
- 239000002075 main ingredient Substances 0.000 abstract description 2
- 235000019645 odor Nutrition 0.000 description 23
- 239000000126 substance Substances 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- -1 acetic acid Chemical class 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 210000002345 respiratory system Anatomy 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 231100000597 Sick building syndrome Toxicity 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 208000008842 sick building syndrome Diseases 0.000 description 1
- ZFRKQXVRDFCRJG-UHFFFAOYSA-N skatole Chemical compound C1=CC=C2C(C)=CNC2=C1 ZFRKQXVRDFCRJG-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- ODLHGICHYURWBS-LKONHMLTSA-N trappsol cyclo Chemical compound CC(O)COC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COCC(O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1COCC(C)O ODLHGICHYURWBS-LKONHMLTSA-N 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/32—Organic compounds
- A61L2101/36—Carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Botany (AREA)
- Zoology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
본 발명은 탈취제 조성물에 관한 것으로서, 보다 상세하게는 천연 피마자오일 유도체인 리시놀레익산으로 부터 얻어진 수소화된 리시놀레익산의 아연착체가 주성분으로 함유된 것으로 기존의 탈취방법이 가지고 있는 장시간의 탈취 소요시간 및 한정된 탈취공간의 단점을 개선하여 넓은 공간에 퍼져있는 냄새 성분 입자들을 짧은 시간 내에 제거할 수 있는 탈취성능을 지닌 분말형, 액상이나 겔상 형태의 새로운 다양한 유형으로 제조가 가능한 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물에 관한 것으로서,
상기 본 발명의 해결적 수단은,
“고압반응기에 에탄올, 리시놀레익산, 란타늄옥사이드 촉매를 중량비로 10 : 2~1 : 0.02의 비율로 혼합하여 넣고 밀폐된 상태에서 2~5기압이 유지될 수 있는 양의 수소 가스를 가하면서 40~70℃에서 3~6시간 동안 수소화 반응을 진행한 후에 혼합물에서 에탄올을 증발시켜 제거하여 수소화된 리시놀레익산을 제조하고,
상기 제조된 수소화된 리시놀레익산과 산화아연을 중량비로 8 : 1의 비율로 혼합하고 상압, 80-100℃에서 3~6시간 교반하면서 반응시킨 후에 혼합물을 에탄올로 세척하고 건조시켜 제조되는 수소화된 리시놀레익산의 아연착체에 흡착체 역할을 하는 소듐폴리아크릴레이트, 잔탄검 또는 카보폴 중 어느 하나 이상을 중량비로 1 : 5~30의 비율로 혼합하여 제조되는 것을 포함하는 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물과,
상기 수소화된 리시놀레익산의 아연착체와 물, 프로필렌글라이콜, 폴리소르베이트, 유기산, 지방산소다, 향료 중 어느 하나 이상을 중량비로 1 : 10~100 비율로 혼합하여 제조되는 것을 포함하는 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물과.
상기 조성물은 분말형, 액상형, 겔형 중 어느 하나인 것을 포함하는 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물"을 그 구성적 특징으로 함으로서,
본 발명은 천연 피마자오일 유도체인 리시놀레익산으로부터 얻어진 수소화된 리시놀레익산의 아연착체는 실험결과 탈취제로써 유용한 효능이 있는 것으로 확인되었으며 따라서 이런 화합물을 탈취제의 성분으로 사용하면 기존의 문제점들을 해소할 수 있는 효과를 발휘하며,
다음, 본 발명은 기존의 탈취방법이 가지고 있는 장시간의 탈취 소요시간 및 한정된 탈취공간의 단점을 개선하여 넓은 공간에 퍼져있는 냄새 성분 입자들을 짧은 시간 내에 제거할 수 있는 탈취성능을 지닌 분말형, 액상이나 겔상 형태의 새로운 다양한 유형으로 조성가능하여 다양한 장소에 사용 가능한 것이다.The present invention relates to a deodorant composition, and more specifically, to a deodorizing composition containing as its main ingredient a zinc complex of hydrogenated ricinoleic acid obtained from ricinoleic acid, a natural castor oil derivative. and a natural castor oil derivative that can be manufactured in a variety of new types in powder, liquid or gel form with deodorizing performance that can remove odorous particles spread in a wide space within a short period of time by improving the disadvantages of limited deodorizing space. Pertaining to a composition of a high-performance odor remover,
The solution of the present invention is,
“Into the high pressure reactor, mix ethanol, ricinoleic acid, and lanthanum oxide catalyst in a weight ratio of 10:2~1:0.02 and add hydrogen gas in an amount that can maintain 2~5 atm in a sealed state, After the hydrogenation reaction was performed at ~70°C for 3 to 6 hours, ethanol was evaporated and removed from the mixture to prepare hydrogenated ricinoleic acid.
The hydrogenated ricinoleic acid and zinc oxide prepared above were mixed at a weight ratio of 8:1 and reacted with stirring at 80-100°C at normal pressure for 3 to 6 hours, followed by washing the mixture with ethanol and drying. A product using a natural castor oil derivative that is prepared by mixing a zinc complex of ricinoleic acid with at least one of sodium polyacrylate, xanthan gum, or carbopol, which acts as an adsorbent, in a weight ratio of 1:5 to 30. A composition of a high-performance odor remover,
Natural castor, which is prepared by mixing the zinc complex of the hydrogenated ricinoleic acid with any one or more of water, propylene glycol, polysorbate, organic acid, fatty acid soda, and fragrance in a weight ratio of 1:10 to 100. A composition of a high-performance odor remover using an oil derivative.
The composition is characterized as "a composition of a high-performance deodorant using a natural castor oil derivative, which includes any of powder, liquid, and gel forms,"
In the present invention, the zinc complex of hydrogenated ricinoleic acid obtained from ricinoleic acid, a natural castor oil derivative, was confirmed to have useful efficacy as a deodorant as a result of experiments. Therefore, using this compound as a deodorant component can solve the existing problems. It is effective,
Next, the present invention improves the shortcomings of the long deodorization time and limited deodorization space of the existing deodorization method, and provides a powder-type and liquid form with deodorizing performance that can remove odor component particles spread over a large space in a short period of time. It can be formulated into various new types such as gel or gel form, so it can be used in various places.
Description
본 발명은 탈취제 조성물에 관한 것으로서, 보다 상세하게는 천연 피마자오일 유도체인 리시놀레익산으로 부터 얻어진 수소화된 리시놀레익산의 아연착체가 주성분으로 함유된 것으로 기존의 탈취방법이 가지고 있는 장시간의 탈취 소요시간 및 한정된 탈취공간의 단점을 개선하여 넓은 공간에 퍼져있는 냄새 성분 입자들을 짧은 시간 내에 제거할 수 있는 탈취성능을 지닌 분말형, 액상이나 겔상 형태의 새로운 다양한 유형으로 제조가 가능한 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물에 관한 것이다.The present invention relates to a deodorant composition, and more specifically, to a deodorizing composition containing as its main ingredient a zinc complex of hydrogenated ricinoleic acid obtained from ricinoleic acid, a natural castor oil derivative. and a natural castor oil derivative that can be manufactured in a variety of new types in powder, liquid or gel form with deodorizing performance that can remove odorous particles spread in a wide space within a short period of time by improving the disadvantages of limited deodorizing space. It relates to a composition of a high-performance odor remover.
우리 생활 주변에서는 암모니아를 비롯한 악취 발산 물질이 그 종류를 셀 수 없을 정도로 많이 존재하며 통상적으로 인체에서 발생하는 악취만 하더라도 황화수소ㆍ메르캅탄 등의 황화합물, 암모니아ㆍ스카톨ㆍ아민 등의 질소화합물 그리고 포름산, 아세트산 등의 지방산 등이 포함된다. There are countless types of odor-emitting substances, including ammonia, in our daily lives. The odors commonly generated by the human body include sulfur compounds such as hydrogen sulfide and mercaptan, nitrogen compounds such as ammonia, skatol, and amine, and formic acid. , fatty acids such as acetic acid, etc.
최근 들어서는 생활수준의 향상으로 냄새에 더욱 민감해짐에 따라 생활의 불쾌감을 주는 악취를 공해로 규정하여 관련 법규에 의한 규제가 강화되는 실정이다. Recently, as living standards have improved and people have become more sensitive to odors, odors that cause discomfort in daily life are defined as pollution, and regulations by related laws are being strengthened.
이와 같은 악취를 제거하기 위해서 다양한 방법들이 사용되고 있는데 현재 사용되고 있는 탈취 방법들은 크게 3가지로 나누어진다.Various methods are used to remove such bad odors, and the deodorizing methods currently in use are largely divided into three types.
첫 번째는 감각적인 방법으로 향료를 이용하는 것으로서, 화장실이나 방안에 좋지 않은 냄새가 나면 이들보다 더 강한 향료를 사용해 사람이 나쁜 냄새를 맡지 못하도록 만드는 경우로서, 이 방법은 근본적으로 냄새 나는 물질을 제거하는 것은 아니며, 또한 대부분의 이러한 탈취제는 첨가된 향료는 그 자체 성분 및 향 탈취제의 첨가물이 호흡기를 통해 계속 축적되어 장기간 사용시 인체에 유해할 수 있는 단점을 갖고 있는 것이다. The first is to use fragrances in a sensory way. If there is an unpleasant odor in the bathroom or room, stronger fragrances are used to prevent people from smelling the bad smell. This method essentially removes odorous substances. In addition, most of these deodorants have the disadvantage that the added fragrances themselves and the additives of the fragrance deodorants continue to accumulate through the respiratory tract, which can be harmful to the human body when used for a long period of time.
두 번째는 물리적인 방법으로 흡착원리를 이용하는 것으로서, 이를 이용한 대표적인 탈취제로는 숯이 있는데. 숯은 1g의 표면적이 약 300m²나 되는 다공성 물질로 냄새 나는 물질을 흡착하는 기능이 있어 냄새 분자가 숯의 구멍에 모두 흡착되면 더 이상 흡착을 못하므로 효과에 한계가 있어 냄새 탈취제로 쓰인 숯을 정기적으로 바꿔주어야 하는 문제점과 더불어 탈취하는데 시간이 오래 걸린다는 단점이 있다.The second is a physical method that uses the principle of adsorption, and a representative deodorant using this is charcoal. Charcoal is a porous material with a surface area of about 300 m² per gram, and has the function of adsorbing odorous substances. Once all odor molecules are absorbed into the pores of the charcoal, they can no longer be adsorbed, so the effectiveness is limited, so charcoal used as an odor deodorizer should be used regularly. In addition to the problem of having to replace it, there is a disadvantage that it takes a long time to deodorize.
세 번째는 화학적인 방법중 한 방법으로는 냄새 분자를 산화시키는 것이며 이 방법에 주로 사용되는 물질인 이산화염소는 강한 산화력을 지니고 있어 주위의 냄새 분자를 산화시켜 냄새 원인을 제거하며, 다른 방법으로는 냄새 분자를 분해하는 것으로 후라보노이드 성분 같은 물질은 특정한 냄새 분자를 분해시켜 탈취 효과를 낼 수 있으며 또 다른 방법으로는 냄새 분자를 감싸서 증발시키는 것과 같은 효과를 내는 방법이 있는데 수산화프로필 베타 사이클로덱스트린, 염화아연과 같은 물질들이 이 방법에 이용되며, 경우에 따라서는 위의 방법들이 복합적으로 이용되고 있다. Thirdly, one of the chemical methods is to oxidize odor molecules. Chlorine dioxide, a substance mainly used in this method, has strong oxidizing power and oxidizes surrounding odor molecules to remove the cause of the odor. Another method is to oxidize odor molecules. By decomposing odor molecules, substances such as flavonoids can produce a deodorizing effect by decomposing specific odor molecules. Another method is to produce the same effect by wrapping odor molecules and evaporating them, such as hydroxypropyl beta cyclodextrin and zinc chloride. Substances such as are used in this method, and in some cases, the above methods are used in combination.
이와 같이 많은 탈취 제품들이 화학적인 방법을 선호하나 원료를 희석시키거나 분산시킨 형태로 사용되어지기 때문에 탈취성능의 저하, 짧은 탈취 지속력, 냄새를 유발하는 원인 물질들 중 일부 물질만 탈취하는 제한된 탈취범위의 한계성을 가지고 있고 이러한 물질들을 희석시키거나 분산시키기 위해 적당한 용매로 액상화한 후에 스프레이를 이용하여 분무하여 탈취하는데 탈취 주성분이 호흡기를 통해 몸 안에 축적되어 장기간 사용시 인체에 유해한 문제점이 있다.Like this, many deodorizing products prefer chemical methods, but because they are used in a diluted or dispersed form of raw materials, deodorizing performance is reduced, deodorizing performance is short, and deodorizing only some of the substances that cause odor are limited. It has limitations, and in order to dilute or disperse these substances, they are liquefied with an appropriate solvent and then sprayed using a spray to deodorize. However, there is a problem that the main deodorizing ingredient accumulates in the body through the respiratory tract and is harmful to the human body when used for a long period of time.
본 발명은 상기의 문제점을 해소하기 위한 것으로서,The present invention is intended to solve the above problems,
첫째, 천연 피마자오일 유도체인 리시놀레익산으로부터 얻어진 수소화된 리시놀레익산의 아연착체는 실험결과 탈취제로써 유용한 효능이 있는 것으로 확인되었으며 따라서 이런 화합물을 탈취제의 성분으로 사용하면 상기의 문제점들을 해소할 수 있는 효능을 지닌 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물를 제공함에 그 목적이 있고,First, the zinc complex of hydrogenated ricinoleic acid obtained from ricinoleic acid, a natural castor oil derivative, was confirmed to be useful as a deodorant as a result of experiments. Therefore, using this compound as a deodorant ingredient can solve the above problems. The purpose is to provide a composition of high-performance deodorant using effective natural castor oil derivatives,
다음, 본 발명에서는 기존의 탈취방법이 가지고 있는 장시간의 탈취 소요시간 및 한정된 탈취공간의 단점을 개선하여 넓은 공간에 퍼져있는 냄새 성분 입자들을 짧은 시간 내에 제거할 수 있는 탈취성능을 지닌 분말형, 액상이나 겔상 형태의 새로운 유형의 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물을 제공함에 그 목적이 있고,Next, the present invention improves the shortcomings of the long deodorization time and limited deodorization space of the existing deodorization method, and provides a powder-type and liquid form with deodorizing performance that can remove odorous particles spread over a large space in a short period of time. The purpose is to provide a high-performance odor remover composition using a new type of natural castor oil derivative in gel form,
또한, 이를 위하여 본 발명은 우수한 탈취능력을 가능케 할 수 있는 탈취 시스템을 지니고 있으며, In addition, for this purpose, the present invention has a deodorizing system that enables excellent deodorizing ability,
또한 다양한 방법으로 가공하면 여러 형태로의 성형이 가능한 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물를 제공함에 그 목적이 있는 것이다. In addition, the purpose is to provide a high-performance deodorant composition using a natural castor oil derivative that can be molded into various shapes by processing in various ways.
상기의 목적을 달성하기 위한 해결적 수단은, The solution to achieve the above purpose is,
“고압반응기에 에탄올, 리시놀레익산, 란타늄옥사이드 촉매를 중량비로 10 : 2~1 : 0.02의 비율로 혼합하여 넣고 밀폐된 상태에서 2~5기압이 유지될 수 있는 양의 수소 가스를 가하면서 40~70℃에서 3~6시간 동안 수소화 반응을 진행한 후에 혼합물에서 에탄올을 증발시켜 제거하여 수소화된 리시놀레익산을 제조하고,
상기 제조된 수소화된 리시놀레익산과 산화아연을 중량비로 8 : 1의 비율로 혼합하고 상압, 80-100℃에서 3~6시간 교반하면서 반응시킨 후에 혼합물을 에탄올로 세척하고 건조시켜 제조되는 수소화된 리시놀레익산의 아연착체에 흡착체 역할을 하는 소듐폴리아크릴레이트, 잔탄검 또는 카보폴 중 어느 하나 이상을 중량비로 1 : 5~30의 비율로 혼합하여 제조되는 것을 포함하는 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물과,“Into the high pressure reactor, mix ethanol, ricinoleic acid, and lanthanum oxide catalyst in a weight ratio of 10:2~1:0.02 and add hydrogen gas in an amount sufficient to maintain a pressure of 2~5 atmospheres in a sealed state while adding 40 After the hydrogenation reaction was performed at ~70°C for 3 to 6 hours, ethanol was evaporated and removed from the mixture to prepare hydrogenated ricinoleic acid.
The hydrogenated ricinoleic acid and zinc oxide prepared above were mixed at a weight ratio of 8:1 and reacted with stirring at 80-100°C at normal pressure for 3 to 6 hours, followed by washing the mixture with ethanol and drying. A product using a natural castor oil derivative that is prepared by mixing a zinc complex of ricinoleic acid with at least one of sodium polyacrylate, xanthan gum, or carbopol, which acts as an adsorbent, in a weight ratio of 1:5 to 30. A composition of a high-performance odor remover,
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상기 수소화된 리시놀레익산의 아연착체와 물, 프로필렌글라이콜, 폴리소르베이트, 유기산, 지방산소다, 향료 중 어느 하나 이상을 중량비로 1 : 10~100 비율로 혼합하여 제조되는 것을 포함하는 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물과,Natural castor, which is prepared by mixing the zinc complex of the hydrogenated ricinoleic acid with any one or more of water, propylene glycol, polysorbate, organic acid, fatty acid soda, and fragrance in a weight ratio of 1:10 to 100. A composition of a high-performance odor remover using an oil derivative,
상기 조성물은 분말형, 액상형, 겔형 중 어느 하나인 것을 포함하는 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물"을 구성적 특징으로 함으로서 상기의 목적을 달성할 수 있다.The above-mentioned purpose can be achieved by the composition being characterized as “a composition of a high-performance deodorant using a natural castor oil derivative, which is in any one of powder form, liquid form, and gel form.”
본 발명은 천연 피마자오일 유도체인 리시놀레익산으로부터 얻어진 수소화된 리시놀레익산의 아연착체는 실험결과 탈취제로써 유용한 효능이 있는 것으로 확인되었으며 따라서 이런 화합물을 탈취제의 성분으로 사용하면 기존의 문제점들을 해소할 수 있는 효과를 발휘하며,In the present invention, the zinc complex of hydrogenated ricinoleic acid obtained from ricinoleic acid, a natural castor oil derivative, was confirmed to have useful efficacy as a deodorant as a result of experiments. Therefore, using this compound as a deodorant component can solve the existing problems. It is effective,
다음, 본 발명은 기존의 탈취방법이 가지고 있는 장시간의 탈취 소요시간 및 한정된 탈취공간의 단점을 개선하여 넓은 공간에 퍼져있는 냄새 성분 입자들을 짧은 시간 내에 제거할 수 있는 탈취성능을 지닌 분말형, 액상이나 겔상 형태의 새로운 다양한 유형으로 조성가능하여 다양한 장소에 사용 가능한 것이다.Next, the present invention improves the shortcomings of the long deodorization time and limited deodorization space of the existing deodorization method, and provides a powder-type and liquid form with deodorizing performance that can remove odor component particles spread over a large space in a short period of time. It can be formulated into a variety of new types such as gel or gel form, so it can be used in various places.
본 명세서에 개시되어 있는 본 발명의 개념에 따른 실시 예들에 대해서 특정한 구조적 또는 기능적 설명들은 단지 본 발명의 개념에 따른 실시 예들을 설명하기 위한 목적으로 예시된 것으로서, 본 발명의 개념에 따른 실시 예들은 다양한 변경들을 가할 수 있고 여러 가지 형태들을 가질 수 있으므로 본 발명의 사상 및 기술 범위에 포함되는 모든 변경, 균등물, 또는 대체물을 포함하며, 명세서 및 청구범위에 사용되는 용어나 단어는 통상적이거나 사전적인 의미로 한정 해석되지 않음은 물론, 발명자는 그 자신의 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 점에 입각하여, 본 발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야 한다. 따라서, 본 발명의 명세서에 기재된 실시예와 도면에 도시된 구성은 본 발명의 가장 바람직한 일 실시예에 불과할 뿐이고 본 발명의 기술적 사상을 모두 대변하는 것은 아닌바, 본 발명의 출원 시점에 있어서 이를 대체할 수 있는 다양한 균등물과 변형예들이 가능하거나 존재할 수 있음을 이해하여야 할 것이다.Specific structural or functional descriptions of the embodiments according to the concept of the present invention disclosed in this specification are merely illustrative for the purpose of explaining the embodiments according to the concept of the present invention, and the embodiments according to the concept of the present invention are Since various changes can be made and various forms can be taken, all changes, equivalents, or substitutes included in the spirit and technical scope of the present invention are included, and the terms and words used in the specification and claims are conventional or dictionary definitions. It is not limited to meaning, and the meaning and concept that corresponds to the technical idea of the present invention are based on the fact that the inventor can appropriately define the concept of the term to explain the invention in the best way. It should be interpreted as Accordingly, the embodiments described in the specification of the present invention and the configuration shown in the drawings are only one of the most preferred embodiments of the present invention and do not represent the entire technical idea of the present invention, and can be replaced at the time of filing of the present invention. It should be understood that various equivalents and modifications are possible or may exist.
또한, 본 발명의 명세서에서 다르게 정의되지 않는 한, 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 모든 용어들은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미를 가진다. 일반적으로 사용되는 사전에 정의되어 있는 것과 같은 용어들은 관련 기술의 문맥상 가지는 의미와 일치하는 의미를 갖는 것으로 해석되어야 하며, 본 명세서에서 명백하게 정의하지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다.In addition, unless otherwise defined in the specification of the present invention, all terms used herein, including technical or scientific terms, have the same meaning as generally understood by a person of ordinary skill in the technical field to which the present invention pertains. have Terms as defined in commonly used dictionaries should be interpreted as having meanings consistent with the meanings they have in the context of the related technology, and unless clearly defined in this specification, should not be interpreted in an idealized or overly formal sense. No.
우선, 본 발명의 제조는 크게 세 단계로 나눠지는데 첫 번째 단계는 천연 피마자오일 유도체인 리시놀레익산의 수소화 반응을 통해서 수소화된 리시놀레익산(12-하이드록시스테아릭산)을 제조하는 것이며, 두 번째 단계는 수소화된 리시놀레익산에서 본 발명의 핵심 구성 성분인 수소화된 리시놀레익의 아연착체를 얻는 것이며, 세 번째 단계는 수소화된 리시놀레익산의 아연착체와 나머지 구성 성분을 배합하여 본 발명을 만드는 것이다.First, the production of the present invention is largely divided into three steps. The first step is to produce hydrogenated ricinoleic acid (12-hydroxystearic acid) through the hydrogenation reaction of ricinoleic acid, a natural castor oil derivative, and the second step is to produce hydrogenated ricinoleic acid (12-hydroxystearic acid). The step is to obtain a zinc complex of hydrogenated ricinoleic acid, which is a key component of the present invention, from hydrogenated ricinoleic acid, and the third step is to prepare the present invention by combining the zinc complex of hydrogenated ricinoleic acid with the remaining components. will be.
이하 본 발명의 조성물들을 보다 구체적으로 살펴보면, Looking at the compositions of the present invention in more detail below,
“고압반응기에 에탄올, 리시놀레익산, 란타늄옥사이드 촉매를 중량비로 10 : 2~1 : 0.02의 비율로 혼합하여 넣고 밀폐된 상태에서 2~5기압이 유지될 수 있는 양의 수소 가스를 가하면서 40~70℃에서 3~6시간 동안 수소화 반응을 진행한 후에 혼합물에서 에탄올을 증발시켜 제거하여 수소화된 리시놀레익산을 제조하고, “Into the high pressure reactor, mix ethanol, ricinoleic acid, and lanthanum oxide catalyst in a weight ratio of 10:2~1:0.02 and add hydrogen gas in an amount that can maintain 2~5 atm in a sealed state, After the hydrogenation reaction was performed at ~70°C for 3 to 6 hours, ethanol was evaporated and removed from the mixture to prepare hydrogenated ricinoleic acid.
상기 제조된 수소화된 리시놀레익산과 산화아연을 중량비로 8 : 1의 비율로 혼합하고 상압, 80-100℃에서 3~6시간 교반하면서 반응시킨 후에 혼합물을 에탄올로 세척하고 건조시켜 제조되는 수소화된 리시놀레익산의 아연착체를 포함하는 것이며, The hydrogenated ricinoleic acid and zinc oxide prepared above were mixed at a weight ratio of 8:1 and reacted with stirring at 80-100°C at normal pressure for 3 to 6 hours, followed by washing the mixture with ethanol and drying. It contains a zinc complex of ricinoleic acid,
바람직하게는, 상기 수소화된 리시놀레익산의 아연착체에 흡착체 역할을 하는 소듐폴리아크릴레이트, 잔탄검 또는 카보폴 중 어느 하나 이상을 중량비로 1 : 5~30의 비율로 혼합하여 제조되는 것을 포함하며,Preferably, it is prepared by mixing the zinc complex of the hydrogenated ricinoleic acid with at least one of sodium polyacrylate, xanthan gum, or carbopol, which acts as an adsorbent, in a weight ratio of 1:5 to 30. And
더욱 바람직하게는, 상기 수소화된 리시놀레익산의 아연착체와 물, 프로필렌글라이콜, 폴리소르베이트, 유기산, 지방산소다, 향료 중 어느 하나 이상을 중량비로 1 : 10~100 비율로 혼합하여 제조되는 것을 포함 것으로,More preferably, it is prepared by mixing the zinc complex of the hydrogenated ricinoleic acid with one or more of water, propylene glycol, polysorbate, organic acid, fatty acid soda, and fragrance in a weight ratio of 1:10 to 100. Including that,
상기 조성물은 분말형, 액상형, 겔형 중 어느 하나인 것을 포함하는 것이 바람직하다.The composition is preferably in any one of powder form, liquid form, and gel form.
본 발명의 냄새제거제의 성능을 확인하기 위한 한 예로, 냄새의 주요 원인 물질인 암모니아, 트리메틸아민, 황화수소와 새집증후군의 주요 원인 물질인 포름알데히드에 대해 상기의 분말형 냄새제거제를 가지고 탈취 성능시험을 실시하였다.As an example to confirm the performance of the deodorant of the present invention, a deodorizing performance test was conducted using the powder-type deodorizer above for ammonia, trimethylamine, and hydrogen sulfide, which are the main causes of odor, and formaldehyde, the main cause of sick building syndrome. It was carried out.
구체적인 실험방법으로는 5L 부피의 챔버에 상기의 분말형 냄새제거제 20g을 넣고 각각의 가스를 개별 강제 주입하여 초기 농도를 50umol/mol로 한 후, 시험 측정시간을 2시간으로 하여 시편이 들어 있는 챔버 내의 잔여 가스 농도를 측정함으로써 각각의 가스에 대한 탈취성능을 측정하였다. The specific test method is to put 20g of the above powdery deodorant into a chamber with a volume of 5L, forcibly inject each gas individually to set the initial concentration to 50umol/mol, and then set the test measurement time to 2 hours and place the sample in the chamber containing the specimen. The deodorizing performance of each gas was measured by measuring the remaining gas concentration.
아래의 [표 1], [표 2], [표 3], [표 4]는 각각의 탈취시험에 대한 시험결과이다.[Table 1], [Table 2], [Table 3], and [Table 4] below show the test results for each deodorization test.
삭제delete
[표 1] [Table 1]
[표 2] [Table 2]
[표 3] [Table 3]
[표 4][Table 4]
상기 실험결과에서 알 수 있듯이 시간경과에 따른 Sample 농도가 현저히 감소함을 확인할 수 있으며 이로써 본 발명의 우수한 탈취성능을 확인할 수 있다. 특히 초기 탈취율에 있어서 기존의 탈취제와는 달리 냄새 발생 초기 30분 내에 대부분의 냄새를 제거하는 고성능의 탈취효과를 나타낸다.As can be seen from the above experimental results, it can be seen that the sample concentration decreases significantly over time, which confirms the excellent deodorizing performance of the present invention. In particular, in terms of initial deodorization rate, unlike existing deodorizers, it shows a high-performance deodorizing effect that removes most odors within the first 30 minutes of odor generation.
Claims (4)
상기 제조된 수소화된 리시놀레익산과 산화아연을 중량비로 8 : 1의 비율로 혼합하고 상압, 80-100℃에서 3~6시간 교반하면서 반응시킨 후에 혼합물을 에탄올로 세척하고 건조시켜 제조되는 수소화된 리시놀레익산의 아연착체에 흡착체 역할을 하는 소듐폴리아크릴레이트, 잔탄검 또는 카보폴 중 어느 하나 이상을 중량비로 1 : 5~30의 비율로 혼합하여 제조되는 것을 포함하는 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물.
Add ethanol, ricinoleic acid, and lanthanum oxide catalyst to a high-pressure reactor mixed at a weight ratio of 10:2~1:0.02, and add hydrogen gas in an amount sufficient to maintain a pressure of 2~5 atmospheres in a closed state. After the hydrogenation reaction was performed at 70°C for 3 to 6 hours, ethanol was evaporated and removed from the mixture to prepare hydrogenated ricinoleic acid.
The hydrogenated ricinoleic acid and zinc oxide prepared above were mixed at a weight ratio of 8:1 and reacted with stirring at 80-100°C at normal pressure for 3 to 6 hours, followed by washing the mixture with ethanol and drying. A product using a natural castor oil derivative that is prepared by mixing a zinc complex of ricinoleic acid with at least one of sodium polyacrylate, xanthan gum, or carbopol, which acts as an adsorbent, in a weight ratio of 1:5 to 30. Composition of high-performance odor remover.
상기 수소화된 리시놀레익산의 아연착체와 물, 프로필렌글라이콜, 폴리소르베이트, 유기산, 지방산소다, 향료 중 어느 하나 이상을 중량비로 1 : 10~100 비율로 혼합하여 제조되는 것을 포함하는 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물.
According to claim 1,
Natural castor, which is prepared by mixing the zinc complex of the hydrogenated ricinoleic acid with any one or more of water, propylene glycol, polysorbate, organic acid, fatty acid soda, and fragrance in a weight ratio of 1:10 to 100. A composition of a high-performance odor remover using an oil derivative.
상기 조성물은 분말형, 액상형, 겔형 중 어느 하나인 것을 포함하는 천연 피마자오일 유도체를 이용한 고성능 냄새제거제의 조성물.According to claim 1,
The composition is a high-performance deodorizing agent using a natural castor oil derivative, including one of powder form, liquid form, and gel form.
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| JP2004512839A (en) * | 2000-11-03 | 2004-04-30 | コグニス・ドイッチュランド・ゲゼルシヤフト・ミト・ベシュレンクテル・ハフツング・ウント・コンパニー・コマンデイトゲゼルシヤフト | Method for isolating 12-hydroxystearic acid |
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