CN108324983A - A kind of air freshener and preparation method thereof - Google Patents

A kind of air freshener and preparation method thereof Download PDF

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Publication number
CN108324983A
CN108324983A CN201810162244.8A CN201810162244A CN108324983A CN 108324983 A CN108324983 A CN 108324983A CN 201810162244 A CN201810162244 A CN 201810162244A CN 108324983 A CN108324983 A CN 108324983A
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China
Prior art keywords
air freshener
mass fraction
present
smell
active component
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CN201810162244.8A
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Chinese (zh)
Inventor
李宗厚
朱恩光
成号
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Daily Chemical (jiangsu) Ltd By Share Ltd
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Daily Chemical (jiangsu) Ltd By Share Ltd
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Priority to CN201810162244.8A priority Critical patent/CN108324983A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02Acyclic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/28Myrtaceae [Myrtle family], e.g. teatree or clove
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/21Use of chemical compounds for treating air or the like

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Botany (AREA)
  • Biotechnology (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The present invention relates to a kind of air freshener, main active component and its mass fraction are:1 15 parts of disinfectant, 1 20 parts of eliminating smell agent, 0.1 5 parts of solubilizer, 0.1 2 parts of additive, 0.01 1 parts of preservative.The invention further relates to the preparation methods of the air freshener.The air freshener of the present invention can be combined with peculiar smell, achieved the effect that really to go to eliminate the unusual smell, gone peculiar smell ability strong, and health environment-friendly, disinfection.

Description

A kind of air freshener and preparation method thereof
Technical field
The present invention relates to a kind of air freshener more particularly to a kind of air freshener for going to eliminate the unusual smell and its preparation sides Method.
Background technology
Air freshener is household and industrial circle one of market with fastest developing speed.We live or work place, If there is niff, it will usually which selection uses air freshener, can feel more comfortable with let us.With people's life water Flat continuous improvement, people are higher and higher to the air pleasant degree requirement of ambient enviroment, therefore increasingly using air freshener Frequently, the usage amount of air freshener is also increasing.
Although having many different types of air freshener products in the market, it is most of be all cover peculiar smell rather than Peculiar smell is eliminated, these peculiar smell still exist in around us in fact, some poisonous and harmful peculiar smell even can threaten our health. With the continuous social and economic development, requirement of the consumer for product is also higher and higher, and this simple smell covers not Be that we want, can not really meet consumer demand, it is intended that be to completely remove peculiar smell, rather than it is simple It covers.
Therefore, it can be effectively removed more there is an urgent need to develop a kind of air freshener that really can go to eliminate the unusual smell in the market The various peculiar smell of kind, rather than simple covering, this is air freshener field one of the technical problems that are urgent to solve.
Invention content
The problem of simply covering peculiar smell present invention aim to address existing air freshener, providing one kind can really go Air freshener to eliminate the unusual smell and preparation method thereof, product of the invention can be combined with peculiar smell, reached and really gone the effect to eliminate the unusual smell Fruit, health environment-friendly, disinfection.
The present invention provides a kind of air freshener, main active component and its mass fraction are:
One according to the present invention specific but non-limiting embodiment, the main active component of the air freshener And its mass fraction is:
One according to the present invention specific but non-limiting embodiment, the main active component of the air freshener And its mass fraction is:
One according to the present invention specific but non-limiting embodiment, the air freshener also contain deionized water 72.3-83.15 parts.
One according to the present invention specific but non-limiting embodiment, wherein the eliminating smell agent is soybean ethyl sulphur Acetoacetic ester morpholine (FORESTALL).
One according to the present invention specific but non-limiting embodiment, wherein the disinfectant is selected from ethyl alcohol At least one of with the chloro- phenol of 3,5- dimethyl -4- (PCMX).
One according to the present invention specific but non-limiting embodiment, wherein the solubilizer is selected from polysorbate At least one of ester -20 (polysorbas20) and Cremophor RH40 (CO 40).
One according to the present invention specific but non-limiting embodiment, wherein it is white that the additive is selected from alternate leaf At least one of thousand layers of leaf oil (tea tree ethereal oil), menthyl lactate and peppermint extracting solution;The preservative is selected from 2- methyl -4- At least one of isothiazoline -3- ketone (MIT), DMDM hydantoin (DMDMH) and Phenoxyethanol.
One according to the present invention specific but non-limiting embodiment, the air freshener also contain deionized water And/or pigment.
One according to the present invention specific but non-limiting embodiment, wherein the quality of eliminating smell agent accounts for the total matter of formula The 12-17% of amount;The quality of tea tree ethereal oil accounts for the 0.3-0.7% of formula gross mass.
On the other hand, the present invention also provides a kind of preparation method of air freshener, include the following steps:
Deionized water is put into agitated kettle, unlatching stirring, disinfectant, eliminating smell agent, stirring to dissolving is added;
Solubilizer is heated to 40-50 DEG C, under stirring in another agitated kettle, additive is added, water is mixed into after dissolving Xiang Zhong adds preservative, pigment, is uniformly dissolved up to air freshener.
The beneficial effects are mainly as follows:
1. the present invention adds a kind of very unique cationic surfactant-soybean second in air freshener for the first time Base ethyl-sulfate morpholine (FORESTALL) can really remove diversified peculiar smell, suitably increase dosage, can reach fine Go peculiar smell ability.Relative to conventional products, air freshener of the invention can be combined with peculiar smell, reached and really gone to eliminate the unusual smell Effect.
2. the air freshener of the present invention also added ethyl alcohol and tea tree ethereal oil, both there is preferable sterilizing Effect, especially tea tree ethereal oil, natural plant essential oils are environmentally protective, also have the fragrance of unique tea tree ethereal oil during use, Without adding essence, distinctive fragrance is provided while sterilization, has saved the required cost of addition essence.
3. the eliminating smell agent soybean ethyl sulfuric acid ethyl ester morpholine (FORESTALL) in air freshener of the present invention and disinfection When agent ethyl alcohol is used cooperatively, there is synergistic function to going to eliminate the unusual smell, can effectively enhance peculiar smell ability, can preferably capture different Taste molecule also can be contacted preferably, permeate sources of odor, neutralized to peculiar smell.
4. the air freshener of the present invention, preservative selects preferable Phenoxyethanol, non-formaldehyde releaser safe and healthy.
Specific implementation mode
Provided hereinafter specific embodiments to further illustrate the present invention, but the present invention is not limited only to implementation below Mode.
The present inventor has found in studying for a long period of time, and soybean ethyl sulfuric acid ethyl ester morpholine (FORESTALL) is used for Air freshener, can obtain it is extraordinary go the effect that eliminates the unusual smell, because of soybean ethyl sulfuric acid ethyl ester morpholine (FORESTALL) energy Odor molecules are captured well, can also be contacted well, be permeated sources of odor, peculiar smell is neutralized, really remove varied Peculiar smell, rather than go to eliminate the unusual smell by simple covering.Especially when soybean ethyl sulfuric acid ethyl ester morpholine (FORESTALL) and disinfection When fungicide ethyl alcohol is used in compounding, synergistic function is produced to going to eliminate the unusual smell, can effectively enhance peculiar smell ability.And it will be big Beans ethyl sulfuric acid ethyl ester morpholine (FORESTALL) is used for air freshener, still belongs to the first time, has no document report in the past, in the market Also without the air freshener products of the ethyl ester morpholine of ethyl sulfuric acid containing soybean (FORESTALL).In addition, present invention adds natural Plants essential oil provides unique tea tree ethereal oil fragrance while with good sterilizing effect.And the present invention selects Preservative without Form aldehyde release body gives the health care of more safety and sanitation.
During being compounded to numerous components, with the difference of formulation ratio, product go peculiar smell ability, smell and at This etc. has larger difference.We pass through a large amount of experimental study and improvement, have obtained following formula.
A kind of air freshener, main active component and its mass fraction are:
The air freshener of the present invention can also contain any decentralized medium commonly used in the art, preferably comprise deionization Water.57-97.79 parts of deionized water can also be contained in above-mentioned formula.
Preferably, a kind of air freshener, main active component and its mass fraction are:
65-93.75 parts of deionized water can also be contained in above-mentioned agent prescription with fresh air.
It is furthermore preferred that a kind of air freshener, main active component and its mass fraction are:
72.3-83.15 parts of deionized water can also be contained in above-mentioned agent prescription with fresh air.
In above-mentioned formula, the eliminating smell agent selects soybean ethyl sulfuric acid ethyl ester morpholine (FORESTALL).It is it is a kind of very Unique cationic surfactant can capture odor molecules well, also can preferably contact, permeate sources of odor, to peculiar smell It is neutralized, can really remove diversified peculiar smell.
The disinfectant is selected from ethyl alcohol and 3, at least one of chloro- phenol of 5- dimethyl -4- (PCMX), preferably second Alcohol.It is better using ethyl alcohol, because ethyl alcohol has synergistic function with soybean ethyl sulfuric acid ethyl ester morpholine (FORESTALL), Product can be significantly increased goes peculiar smell ability, and the irritation of ethyl alcohol relative to the chloro- phenol of 3,5- dimethyl -4- (PCMX) compared with It is small, while also there is good sterilizing effect.
The solubilizer is selected from polysorbate -20 (polysorbas20) and Cremophor RH40 (CO 40) at least It is a kind of.Wherein, polysorbate -20 (polysorbas20) while with preferable solubilization also there is preferable emulsification to make With;Cremophor RH40 (CO 40) also has preferable solubilization, and the two can be used in compounding, so that natural plants are smart Oily Melaleuca alternifolia leaf oil (tea tree ethereal oil) is preferably dissolved in system.
The additive is selected from Melaleuca alternifolia leaf oil (tea tree ethereal oil), menthyl lactate and peppermint extracting solution extremely Few one kind.Wherein, Melaleuca alternifolia leaf oil (tea tree ethereal oil) has preferable bactericidal effect and has special fragrance;Work as summer When can also be properly added mint ingredient, to increase refrigerant effect.
The preservative is selected from 2-methyl-4-isothiazolin-3-one (MIT), DMDM hydantoin (DMDMH) and benzene oxygen second At least one of alcohol, preferably Phenoxyethanol.The anti-corrosion effect of Phenoxyethanol is preferably and without Form aldehyde release body.
As needed, air freshener of the invention also contains various auxiliary materials commonly used in the art, such as pigment.
We have found that the dosage of eliminating smell agent soybean ethyl sulfuric acid ethyl ester morpholine is to production after many experiments and further investigation The effect of going to eliminate the unusual smell of product has a significant impact, when the quality of eliminating smell agent soybean ethyl sulfuric acid ethyl ester morpholine accounts for formula gross mass When 12-17%, going to eliminate the unusual smell, effect is fine and cost is relatively low.And the quality of tea tree ethereal oil accounts for the 0.3- of formula gross mass When 0.7%, have the effect of better increase particularity smell, it is nonirritant.
The air freshener of the present invention can be prepared by the following method (half cold match):
(1) deionized water is put into agitated kettle, unlatching stirring, disinfectant, eliminating smell agent, stirring to dissolving is added;
(2) solubilizer is heated to 40-50 DEG C, under stirring in another agitated kettle, additive is added, is mixed into after dissolving In water phase, preservative, pigment are added, is uniformly dissolved up to air freshener.The mixing speed is 40rpm/min or so.
The proportion relation of the proportion relation of each component and each component in above-mentioned agent prescription with fresh air in above-mentioned preparation process Unanimously.
Relative to conventional products in the market, air freshener of the invention can be combined with peculiar smell, reach really remove it is different It is good to de-taste effect for the effect of taste.
With reference to specific embodiment, the present invention is further elaborated, but the present invention is not limited to following embodiments.
Experimental method used in above and following embodiments is conventional method unless otherwise specified.
Above and the materials, reagents and the like used in the following examples, is commercially available unless otherwise specified.
Embodiment 1
A kind of air freshener, component and its mass fraction are:
This formulation product de-tastes scarce capacity, and tea tree ethereal oil fragrance is thin.
5g this products are taken, are sprayed in lavatory (fixed lavatory is by access times), actual effect is as follows:
The time required to de-tasting:5 minutes
Duration:2 days.
Embodiment 2
A kind of air freshener, component and its mass fraction are:
This formulation product de-tastes scarce capacity, and tea tree ethereal oil fragrance is thin.
5g this products are taken, are sprayed in lavatory (fixed lavatory is by access times), actual effect is as follows:
The time required to de-tasting:5 minutes
Duration:2 days
Embodiment 3
A kind of air freshener, component and its mass fraction are:
This formulation product, which de-tastes ability, to manage it, and tea tree ethereal oil fragrance is moderate.
5g this products are taken, are sprayed in lavatory (fixed lavatory is by access times), actual effect is as follows:
The time required to de-tasting:3 minutes
Duration:4 days
Embodiment 4
A kind of air freshener, component and its mass fraction are:
This formulation product de-tastes that ability is preferable, and tea tree ethereal oil fragrance is also moderate.
5g this products are taken, are sprayed in lavatory (fixed lavatory is by access times), actual effect is as follows:
The time required to de-tasting:2 minutes
Duration:6 days
Embodiment 5
A kind of air freshener, component and its mass fraction are:
This formulation product de-tastes that ability is preferable, and tea tree ethereal oil fragrance is heavier.
5g this products are taken, are sprayed in lavatory (fixed lavatory is by access times), actual effect is as follows:
The time required to de-tasting:1 minute
7 days duration
Embodiment 6
A kind of air freshener, component and its mass fraction are:
It is preferable that this formulation product de-tastes ability, and tea tree ethereal oil fragrance relatively stimulates.
5g this products are taken, are sprayed in lavatory (fixed lavatory is by access times), actual effect is as follows:
The time required to de-tasting:1 minute
Duration:7 days
It can see from the test experience that de-tastes of above-described embodiment 1-6, it is universal that air freshener of the invention de-tastes effect Very well.Wherein, when soybean ethyl sulfuric acid ethyl ester morpholine dosage is relatively low, when being formulated 12% or less gross mass, ability is de-tasted slightly There are deficiency, duration shorter (Examples 1 and 2);When soybean ethyl sulfuric acid ethyl ester morpholine dosage is in the 12- of formula gross mass When 17%, can reach it is required go to eliminate the unusual smell effect and cost it is relatively low (embodiment 3-5);When soybean ethyl sulfuric acid ethyl ester morpholine When being formulated 17% or more of gross mass, go to eliminate the unusual smell effect and is not improved but cost increases (embodiment 6) dosage.Separately Outside, the dosage of tea tree ethereal oil is when being formulated the 0.3-0.7% of gross mass, the effect with better increase particularity smell Fruit.
Because that on the market currently without the air freshener of the ethyl ester morpholine of ethyl sulfuric acid containing soybean, can not be done with product of the present invention Contrast test.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can be readily occurred in, It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection of claims Subject to range.

Claims (11)

1. a kind of air freshener, main active component and its mass fraction are:
2. air freshener according to claim 1, main active component and its mass fraction are:
3. air freshener according to claim 2, main active component and its mass fraction are:
4. air freshener according to claim 3 also contains 72.3-83.15 parts of deionized water.
5. according to air freshener any in claim 1-4, wherein the eliminating smell agent is soybean ethyl sulfuric acid ethyl ester morpholine (FORESTALL)。
6. according to air freshener any in claim 1-4, wherein the disinfectant is selected from ethyl alcohol and 3,5- diformazans At least one of chloro- phenol of base -4- (PCMX).
7. according to air freshener any in claim 1-4, wherein the solubilizer is selected from the (tween of polysorbate -20 And at least one of Cremophor RH40 (CO 40) 20).
8. according to air freshener any in claim 1-4, wherein the additive is selected from Melaleuca alternifolia leaf oil At least one of (tea tree ethereal oil), menthyl lactate and peppermint extracting solution;The preservative is selected from 2- methyl -4- isothiazole At least one of quinoline -3- ketone (MIT), DMDM hydantoin (DMDMH) and Phenoxyethanol.
9. according to air freshener any in claim 1-4, also contain deionized water and/or pigment.
10. air freshener according to claim 8, wherein the quality of eliminating smell agent accounts for the 12-17% of formula gross mass;Tea tree The quality of essential oil accounts for the 0.3-0.7% of formula gross mass.
11. the preparation method of air freshener, includes the following steps as described in any in claim 1-10:
Deionized water is put into agitated kettle, unlatching stirring, disinfectant, eliminating smell agent, stirring to dissolving is added;
Solubilizer is heated to 40-50 DEG C, under stirring in another agitated kettle, additive is added, is mixed into water phase after dissolving, Preservative, pigment are added, is uniformly dissolved up to air freshener.
CN201810162244.8A 2018-02-27 2018-02-27 A kind of air freshener and preparation method thereof Pending CN108324983A (en)

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CN109289070A (en) * 2018-10-19 2019-02-01 德乐满香精香料(广州)有限公司 A kind of volatile-type liquid air freshener of suspension goldleaf particle and preparation method thereof
CN109821384A (en) * 2019-02-27 2019-05-31 石家庄多美斯日化用品有限公司 A kind of peculiar smell neutralizer and preparation method thereof
CN110252115A (en) * 2019-06-20 2019-09-20 深圳市中拓智森环保科技有限公司 Multifunctional air cleaning agent
CN110665355A (en) * 2019-08-22 2020-01-10 苏州市易柯露环保科技有限公司 Deodorant composition containing woody plant essential oil and preparation method thereof
CN111670904A (en) * 2020-06-12 2020-09-18 中山百科清洁用品制造有限公司 Air freshening and degerming agent and preparation method thereof
CN113142240A (en) * 2021-04-26 2021-07-23 贵州扬生医用器材有限公司 Environment disinfectant and preparation method thereof
CN114182526A (en) * 2021-12-27 2022-03-15 广东好顺欧迪斯科技股份有限公司 Clothing cooling spray and preparation method thereof

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CN107583087A (en) * 2017-09-07 2018-01-16 中山富士化工有限公司 A kind of deodorizing composition and spray for refreshing air

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109289070A (en) * 2018-10-19 2019-02-01 德乐满香精香料(广州)有限公司 A kind of volatile-type liquid air freshener of suspension goldleaf particle and preparation method thereof
CN109289070B (en) * 2018-10-19 2021-06-04 德乐满香精香料(广州)有限公司 Volatile liquid air freshener with suspended gold foil particles and preparation method thereof
CN109821384A (en) * 2019-02-27 2019-05-31 石家庄多美斯日化用品有限公司 A kind of peculiar smell neutralizer and preparation method thereof
CN110252115A (en) * 2019-06-20 2019-09-20 深圳市中拓智森环保科技有限公司 Multifunctional air cleaning agent
CN110665355A (en) * 2019-08-22 2020-01-10 苏州市易柯露环保科技有限公司 Deodorant composition containing woody plant essential oil and preparation method thereof
CN111670904A (en) * 2020-06-12 2020-09-18 中山百科清洁用品制造有限公司 Air freshening and degerming agent and preparation method thereof
CN113142240A (en) * 2021-04-26 2021-07-23 贵州扬生医用器材有限公司 Environment disinfectant and preparation method thereof
CN114182526A (en) * 2021-12-27 2022-03-15 广东好顺欧迪斯科技股份有限公司 Clothing cooling spray and preparation method thereof
CN114182526B (en) * 2021-12-27 2024-05-10 广东好顺欧迪斯科技股份有限公司 Clothing cool spray and preparation method thereof

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