CN109821384A - A kind of peculiar smell neutralizer and preparation method thereof - Google Patents
A kind of peculiar smell neutralizer and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to daily use chemicals cleaning supplies technical fields, propose a kind of peculiar smell neutralizer, it is grouped as by the group of following parts by weight: 1~5 part of tea polyphenols, 5~20 parts of terpinol, 5~17 parts of light-coloured vinegar, 3~15 parts of chitosan, 0.5~15 part of morpholine of -4- soybean-based ethyl-sulfate of 4- ethyl, 0.5~10 part of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.2~0.8 part of zinc ricinate ester, 0.5~2 part of phellandrene, the chloro- 2- (2 of 5-, 4- dichlorophenoxy) 0.1~1 part of phenol, 80~130 parts of deionized water, preparation method uses substep mixing method, it is first that light-coloured vinegar is soluble in water, chitosan is added, terpinol and tea polyphenols etc., obtain just mixed liquid one, again successively by 4- ethyl -4- soybean-based ethyl-sulfate morpholine, soybean ethyl sulfuric acid ethyl ester morpholine, castor-oil plant Zinc oleate ester is added in deionized water, obtains just mixed liquid two, and phellandrene, the chloro- 2- of 5- (2,4- dichlorophenoxy) phenol is added after mixing with first mixed liquid one, is uniformly mixed, obtains peculiar smell neutralizer.The present invention solves the problems, such as that peculiar smell neutralizer odor removal efficient is low in the prior art, safety is poor.
Description
Technical field
The invention belongs to daily use chemicals cleaning supplies technical field, it is related to a kind of peculiar smell neutralizer and preparation method thereof.
Background technique
In nature, human habitat, the article of some special odors or workplace can give out irritating peculiar smell,
Make people there is an urgent need to use air freshening product to improve the air quality of living environment and working environment, to improve life product
Matter.Part with fresh air is household and industrial circle one of market with fastest developing speed, and many similar-type products, most of in the market
It is to cover peculiar smell rather than go to eliminate it.Specific aspect is such as: 1, in terms of life household nursing: carpet deodorant, finishing material, kitchen
Room and bathroom surfaces eliminating smell agent, clothing eliminating smell agent and pet care product etc.；2, in terms of industrial production: the control of sewer peculiar smell,
The control of food service industry taste, medical manufacture, sewage water discharge processing, the peculiar smell control of public lavatory and rubbish filling plant.
The peculiar smell of various concentration can bring different degrees of influence to human lives, and low concentration peculiar smell can result in human body and exhale
Inhale unsmooth, dysphoria.High concentration peculiar smell will lead to human body and occur in gross stress reaction, such as nausea and vomiting, or even generation
Toxication shape makes one to be choked to death.
In the modern life, the method for handling peculiar smell includes flavouring agent masking, activated carbon adsorption, solvent adsorption, chemical substance
It covers, the technologies such as the catalysis of UV photocatalyst, ozone deodorizing, biological enzyme deodorization after centralized collection.Ideal peculiar smell eutralising means is to the greatest extent
Possible removing odorant, cuts off root, but the above method or can not be eradicated using taste masking or complex process, investment
Cost is excessively high or the deodorization period is longer, inefficiency.The means of peculiar odor treatment are inappropriate to be likely to cause the secondary of natural environment
Pollution, increases burden to natural environment, to increase other adverse effects to human lives.High efficiency, inanimate object toxic, nothing
How safely and effectively the peculiar smell neutralization method of environmental hazard is in the peculiar smell and new development direction of class air freshening product instantly,
Solution peculiar smell control problem, be important topic instantly urgently to be resolved.
Summary of the invention
The present invention proposes a kind of peculiar smell neutralizer and preparation method thereof, solves the effect of peculiar smell neutralizer deodorization in the prior art
The problem that rate is low, safety is poor.
The technical scheme of the present invention is realized as follows:
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
1~5 part of tea polyphenols, 5~20 parts of terpinol, 5~17 parts of light-coloured vinegar, 3~15 parts of chitosan, 4- ethyl -4- soybean-based
0.5~15 part of ethyl-sulfate morpholine, 0.5~10 part of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.2~0.8 part of zinc ricinate ester, water
0.5~2 part of celery alkene, 0.1~1 part of phenol, 80~130 parts of deionized water of the chloro- 2- of 5- (2,4- dichlorophenoxy).
As further technical solution, it is grouped as by the group of following parts by weight:
2~4 parts of tea polyphenols, 8~17 parts of terpinol, 10~15 parts of light-coloured vinegar, 5~11 parts of chitosan, 4- ethyl -4- soybean-based
3~10 parts of ethyl-sulfate morpholine, 2~8 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.4~0.7 part of zinc ricinate ester, phellandrene 1
~1.7 parts, 0.2~0.8 part of phenol, 90~120 parts of deionized water of the chloro- 2- of 5- (2,4- dichlorophenoxy).
As further technical solution, it is grouped as by the group of following parts by weight:
3 parts of tea polyphenols, 13 parts of terpinol, 12 parts of light-coloured vinegar, 7 parts of chitosan, 4- ethyl -4- soybean-based ethyl-sulfate morpholine 7
Part, 6 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.5 part of zinc ricinate ester, 1.4 parts of phellandrene, 5- chloro- 2- (2,4- Dichlorophenoxies
Base) 0.6 part of phenol, 100 parts of deionized water.
As further technical solution, the deacetylating degree of chitosan is 70%~85%.
The invention also provides a kind of preparation methods of peculiar smell neutralizer, comprising the following steps:
S1, according to a kind of formula of above-mentioned peculiar smell neutralizer, it is spare to weigh each component；
S2, light-coloured vinegar is dissolved into formula in the deionized water of half volume, obtains light-coloured vinegar solution；
S3, chitosan, terpinol and tea polyphenols are added into the light-coloured vinegar solution that step S2 is obtained, are obtained after stirring and dissolving just
Mixed liquid one；
S4, successively by 4- ethyl -4- soybean-based ethyl-sulfate morpholine, soybean ethyl sulfuric acid ethyl ester morpholine, zinc ricinate
Ester is added in formula in the deionized water of the other half volume, obtains just mixed liquid two after mixing,
S5, the first mixed liquid one that step S3 is obtained is mixed with the first mixed liquid two that step S4 is obtained, obtains mixed solution；
Phellandrene, the chloro- 2- of 5- (2,4- dichlorophenoxy) phenol are added in S6, the mixed solution obtained to step S5, mixes
Peculiar smell neutralizer is obtained after closing uniformly.
As further technical solution, mixing speed is 200~260r/min in step S3, mixing time is 20~
30min。
The present invention is using principle and has the beneficial effect that
In the present invention, pure plant soybean protein and castor oil are selected on formula, while tea polyphenols, terpinol, white are added
Vinegar, chitosan, the chloro- 2- of phellandrene, 5- (2,4- dichlorophenoxy) phenol etc., can sufficiently dissolve in water, can be with peculiar smell
In foul smell molecule reaction, in air formaldehyde, benzene, ammonia, amyl hydrosulfide and to smoking place in nicotine, tar, phenol,
Carbon monoxide etc. has preferable removal effect, can safely and efficiently remove peculiar smell present in household, industry and public environment,
Meanwhile fungistatic effect is also fine, can effectively solve the problem that the problem that peculiar smell neutralizer odor removal efficient is low in the prior art.The original of selection
Expect that safety and environmental protection, biodegradable are good, to human skin, respiratory mucosa is non-stimulated, and it is highly-safe, while with deionized water
As decentralized medium, avoids using a large amount of organic solvents, reduce to the destruction of environment and the injury of human body, therefore, the feature of environmental protection
More preferably, it is suitble to promote the use of.
In the present invention, the components such as tea polyphenols, terpinol, light-coloured vinegar, chitosan are mutually cooperateed in formula, can effectively be adsorbed
Pernicious gas in air carries out absorption degradation, 4- ethyl -4- soybean-based ethyl-sulfate to formaldehyde, benzene, the ammonia etc. in air
Quinoline and soybean ethyl sulfuric acid ethyl ester morpholine, zinc ricinate ester cooperate, accurately capturing, by way of molecule package, with
The reaction of foul smell molecule is at salt, permanent, irreversibility by odor molecules to thoroughly remove, phellandrene and the chloro- 2- of 5- (2,4- dichloro-benzenes
Oxygroup) phenol cooperation, so that the peculiar smell neutralizer of preparation has good fungistatic effect, various ingredients are synergistic, so that system
Standby peculiar smell neutralizer in air formaldehyde, benzene, ammonia, amyl hydrosulfide and to smoking place in nicotine, tar, phenol, one
Carbonoxide etc. has preferable removal effect, meanwhile, fungistatic effect is also fine, meets consumer demand.
In the present invention, light-coloured vinegar is added in formula, so that with agent solution in acidity in the peculiar smell of preparation, so that chitosan, tea
Polyphenol etc. is able to maintain stabilization in the solution, so that whole stability is improved, moreover, chitosan has under acidic environment
The property of cationic polyelectrolytes can effectively adsorb the gas with foreign flavor in air, and the acetic acid in light-coloured vinegar can be with
The alkaline gas such as the ammonia in air reaction, so that the removal rate of the alkaline gas such as ammonia is improved, in addition, acetic acid can also be with terpinol
It reacts and generates a small amount of terpinyl acetate, there is good deodorizing effect.
In the present invention, first light-coloured vinegar is dissolved in deionized water is made into light-coloured vinegar solution during the preparation process, add chitosan,
Terpinol and tea polyphenols etc. obtain just mixed liquid one, effectively increase the dissolubility of chitosan in water, then successively by 4- ethyl-
4- soybean-based ethyl-sulfate morpholine, soybean ethyl sulfuric acid ethyl ester morpholine, zinc ricinate ester are added in deionized water, obtain just mixed
Liquid two, just phellandrene is added after mixing in mixed liquid one and first mixed liquid two, the chloro- 2- of 5- (2,4- dichlorophenoxy) phenol is uniformly mixed,
Make each component in formula have the function that synergy by the preparation method that substep is added, effectively increases peculiar smell neutralizer
Deodorizing effect and fungistatic effect.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
1 part of tea polyphenols, 5 parts of terpinol, 5 parts of light-coloured vinegar, 3 parts of chitosan, 4- ethyl -4- soybean-based ethyl-sulfate morpholine 0.5
Part, 0.5 part of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.2 part of zinc ricinate ester, 0.5 part of phellandrene, 5- chloro- 2- (2,4- dichloro-benzenes
Oxygroup) 0.1 part of phenol, 80 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%,
Preparation method includes the following steps:
S1, according to above-mentioned formula, it is spare to weigh each component；
S2, light-coloured vinegar is dissolved into formula in the deionized water of half volume, obtains light-coloured vinegar solution；
S3, chitosan, terpinol and tea polyphenols are added into the light-coloured vinegar solution that step S2 is obtained, in 200~260r/min
Speed under stir 20~30min, dissolve chitosan, obtain just mixed liquid one；
S4, successively by 4- ethyl -4- soybean-based ethyl-sulfate morpholine, soybean ethyl sulfuric acid ethyl ester morpholine, zinc ricinate
Ester is added in formula in the deionized water of the other half volume, obtains just mixed liquid two after mixing,
S5, the first mixed liquid one that step S3 is obtained is mixed with the first mixed liquid two that step S4 is obtained, obtains mixed solution；
Phellandrene, the chloro- 2- of 5- (2,4- dichlorophenoxy) phenol are added in S6, the mixed solution obtained to step S5, mixes
Peculiar smell neutralizer is obtained after closing uniformly.
Embodiment 2
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
5 parts of tea polyphenols, 20 parts of terpinol, 17 parts of light-coloured vinegar, 15 parts of chitosan, 4- ethyl -4- soybean-based ethyl-sulfate morpholine
15 parts, 10 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.8 part of zinc ricinate ester, 2 parts of phellandrene, 5- chloro- 2- (2,4- dichloro-benzenes
Oxygroup) 1 part of phenol, 130 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%,
Preparation method is the same as embodiment one.
Embodiment 3
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
2 parts of tea polyphenols, 8 parts of terpinol, 10 parts of light-coloured vinegar, 5 parts of chitosan, 4- ethyl -4- soybean-based ethyl-sulfate morpholine 3
Part, 2 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.4 part of zinc ricinate ester, 1 part of phellandrene, 5- chloro- 2- (2,4- Dichlorophenoxies
Base) 0.2 part of phenol, 90 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%.
Preparation method is the same as embodiment one.
Embodiment 4
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
4 parts of tea polyphenols, 17 parts of terpinol, 15 parts of light-coloured vinegar, 11 parts of chitosan, 4- ethyl -4- soybean-based ethyl-sulfate morpholine
10 parts, 8 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.7 part of zinc ricinate ester, 1.7 parts of phellandrene, 5- chloro- 2- (2,4- dichloro-benzenes
Oxygroup) 0.8 part of phenol, 120 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%,
Preparation method is the same as embodiment one.
Embodiment 5
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
2.5 parts of tea polyphenols, 10 parts of terpinol, 11 parts of light-coloured vinegar, 6 parts of chitosan, 4- ethyl -4- soybean-based ethyl-sulfate morpholine
5 parts, 5 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.5 part of zinc ricinate ester, 1.2 parts of phellandrene, 5- chloro- 2- (2,4- dichloro-benzenes
Oxygroup) 0.5 part of phenol, 95 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%,
Preparation method is the same as embodiment one.
Embodiment 6
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
3.5 parts of tea polyphenols, 15 parts of terpinol, 13 parts of light-coloured vinegar, 9 parts of chitosan, 4- ethyl -4- soybean-based ethyl-sulfate morpholine
8 parts, 7 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.6 part of zinc ricinate ester, 1.5 parts of phellandrene, 5- chloro- 2- (2,4- dichloro-benzenes
Oxygroup) 0.7 part of phenol, 105 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%,
Preparation method is the same as embodiment one.
Embodiment 7
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
3 parts of tea polyphenols, 13 parts of terpinol, 12 parts of light-coloured vinegar, 7 parts of chitosan, 4- ethyl -4- soybean-based ethyl-sulfate morpholine 7
Part, 6 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.5 part of zinc ricinate ester, 1.4 parts of phellandrene, 5- chloro- 2- (2,4- Dichlorophenoxies
Base) 0.6 part of phenol, 100 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%,
Preparation method is the same as embodiment one.
Comparative example 1
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
7 parts of morpholine of -4- soybean-based ethyl-sulfate of 4- ethyl, 6 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, zinc ricinate ester
0.5 part, 1.4 parts of phellandrene, 0.6 part of phenol of the chloro- 2- of 5- (2,4- dichlorophenoxy), 100 parts of deionized water,
Preparation method includes the following steps:
S1, according to above-mentioned formula, it is spare to weigh each component；
S2, successively by 4- ethyl -4- soybean-based ethyl-sulfate morpholine, soybean ethyl sulfuric acid ethyl ester morpholine, zinc ricinate
Ester is added in deionized water, obtains just mixed liquid after mixing,
S3, phellandrene, the chloro- 2- of 5- (2,4- dichlorophenoxy) phenol, mixing are added into the first mixed liquid that step S2 is obtained
Peculiar smell neutralizer is obtained after uniformly.
Comparative example 2
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
3 parts of tea polyphenols, 13 parts of terpinol, 12 parts of light-coloured vinegar, 7 parts of chitosan, 1.4 parts of phellandrene, 5- chloro- 2- (2,4- dichloros
Phenoxy group) 0.6 part of phenol, 100 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%,
Preparation method includes the following steps:
S1, according to above-mentioned formula, it is spare to weigh each component；
S2, light-coloured vinegar is dissolved into deionized water, obtains light-coloured vinegar solution；
S3, chitosan, terpinol and tea polyphenols are added into the light-coloured vinegar solution that step S2 is obtained, in 200~260r/min
Speed under stir 20~30min, dissolve chitosan, obtain just mixed liquid；
Phellandrene, the chloro- 2- of 5- (2,4- dichlorophenoxy) phenol, mixing are added in S4, the first mixed liquid for obtaining step S3
Peculiar smell neutralizer is obtained after uniformly.
Comparative example 3
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
3 parts of tea polyphenols, 13 parts of terpinol, 7 parts of chitosan, 7 parts of morpholine of -4- soybean-based ethyl-sulfate of 4- ethyl, soybean second
6 parts of base ethyl-sulfate morpholine, 0.5 part of zinc ricinate ester, 1.4 parts of phellandrene, the chloro- 2- of 5- (2,4- dichlorophenoxy) phenol
0.6 part, 100 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%,
It is corresponding in preparation method to delete step S2, it is corresponding that light-coloured vinegar solution in step S3 is changed to half in formula
The deionized water of volume, remaining step is the same as embodiment one.
Comparative example 4
A kind of peculiar smell neutralizer, is grouped as by the group of following parts by weight:
3 parts of tea polyphenols, 12 parts of light-coloured vinegar, 7 parts of chitosan, 7 parts of morpholine of -4- soybean-based ethyl-sulfate of 4- ethyl, soybean ethyl
6 parts of ethyl-sulfate morpholine, 0.5 part of zinc ricinate ester, 1.4 parts of phellandrene, the chloro- 2- of 5- (2,4- dichlorophenoxy) phenol 0.6
Part, 100 parts of deionized water, wherein the deacetylation of chitosan is 70%~85%,
Corresponding in preparation method to delete terpinol in step S3, remaining step is the same as embodiment one.
Comparative example 5
With embodiment 7, preparation method is one-step method, and all components in formula are mixed for a kind of formula of peculiar smell neutralizer
Afterwards, it stirs evenly, obtains peculiar smell neutralizer.
Each component parts by weight are shown in Table 1 in Examples 1 to 7 and the formula of comparative example 1~5:
Each component parts by weight in 1 Examples 1 to 7 of table and the formula of comparative example 1~5
Note :-indicate no this item.
It is respectively sample with peculiar smell neutralizer prepared by Examples 1 to 7 and comparative example 1~5, performs the following performance tests:
1, the removal effect test of the pernicious gases such as PARA FORMALDEHYDE PRILLS(91,95): in 1m3Experiment bin in, the pure first of injection certain volume chemistry
Aldehyde (or benzene or ammonia or amyl hydrosulfide) opens storehouse internal fan, and gas concentration in the storehouse of sampling test immediately, is denoted as initial dense after 30min
Sample, is then put into the storehouse by degree, and gas concentration in collecting test storehouse immediately after 60min is denoted as ultimate density, calculates removal
Rate, removal rate=(initial concentration-ultimate density)/initial concentration × 100%, test result are shown in Table 2；
2, to smoking place smoke removal effect: in 1m3Experiment bin in, 10 perfume (or spice) are lighted simultaneously by experimenter
Cigarette opens storehouse internal fan, and gas (nicotine, tar, phenol, carbon monoxide) concentration in the storehouse of sampling test immediately, is denoted as after 30min
Then sample is put into the storehouse by initial concentration, gas concentration in collecting test storehouse immediately after 60min is denoted as ultimate density, counts
Removal rate, removal rate=(initial concentration-ultimate density)/initial concentration × 100% are calculated, test result is shown in Table 3；
3, fungistatic effect: experiment before confined space sample, by nutrient medium be placed in confined space quadrangle and in
Centre, after sampling, is placed in 37 DEG C of biochemical cultivation case cultures for 24 hours for culture plate, records clump count, is denoted as initial bacterium colony
Number, after having acquired the microorganism in air, is placed in 30min in this confined space for sample, it is allowed to volatilize naturally, with above-mentioned side
Method carries out template sampling, and template is placed in 37 DEG C of biochemical cultivation case cultures for 24 hours after sampling, records clump count, is denoted as most
Whole clump count, record places the clump count under different time air freshener environment, and calculates its bacteriostasis rate, and bacteriostasis rate=(just
Beginning clump count/- final clump count/degree)/initial clump count/× 100%, test result is shown in Table 4.
The removal rate of the pernicious gases such as peculiar smell neutralizer PARA FORMALDEHYDE PRILLS(91,95) prepared by 2 Examples 1 to 7 of table and comparative example 1~5
| Detection project | Formaldehyde removal rate (%) | Benzene removal rate (%) | Ammonia removal rate (%) | Amyl hydrosulfide removal rate (%) |
| Embodiment 1 | 93.69 | 92.76 | 93.16 | 95.35 |
| Embodiment 2 | 94.53 | 92.29 | 93.65 | 95.49 |
| Embodiment 3 | 96.78 | 94.81 | 95.28 | 96.67 |
| Embodiment 4 | 96.92 | 94.74 | 94.96 | 96.51 |
| Embodiment 5 | 97.85 | 95.59 | 96.17 | 98.23 |
| Embodiment 6 | 98.27 | 95.46 | 96.42 | 98.75 |
| Embodiment 7 | 99.83 | 96.51 | 98.46 | 99.29 |
| Comparative example 1 | 75.28 | 71.63 | 68.31 | 67.48 |
| Comparative example 2 | 74.92 | 73.45 | 75.68 | 75.54 |
| Comparative example 3 | 83.49 | 83.29 | 81.75 | 81.06 |
| Comparative example 4 | 88.56 | 87.63 | 88.57 | 88.91 |
| Comparative example 5 | 85.43 | 84.68 | 84.85 | 84.09 |
It can be seen from the data in Table 2 that the embodiment of the present invention 1~7 prepare peculiar smell neutralizer to formaldehyde in air, benzene,
Ammonia and amyl hydrosulfide all have preferable removal effect, wherein the removal rate of PARA FORMALDEHYDE PRILLS(91,95) removes benzene 93.69%~99.83%
Except rate is 92.76%~96.51%, to the removal rate of ammonia 93.16%~98.46%, exist to the removal rate of amyl hydrosulfide
95.35%~99.29%, the formula and preparation method of embodiment 7 are the present invention preferably embodiments relatively, in the peculiar smell of preparation
It is best with removal effect of the agent to pernicious gases such as formaldehyde in air.
The removal rate of peculiar smell neutralizer prepared by 3 Examples 1 to 7 of table and comparative example 1~5 to the smoke in smoking place
| Detection project | Nicotine removal rate (%) | Tar removal rate (%) | Phenol removal rate (%) | Carbon monoxide removal rate (%) |
| Embodiment 1 | 90.15 | 90.62 | 91.37 | 90.56 |
| Embodiment 2 | 91.28 | 91.53 | 91.76 | 91.27 |
| Embodiment 3 | 92.35 | 91.87 | 93.01 | 92.42 |
| Embodiment 4 | 92.07 | 92.62 | 93.24 | 92.63 |
| Embodiment 5 | 92.46 | 92.93 | 94.18 | 93.38 |
| Embodiment 6 | 92.58 | 93.10 | 94.35 | 93.16 |
| Embodiment 7 | 93.61 | 93.75 | 94.67 | 94.08 |
| Comparative example 1 | 75.48 | 76.83 | 73.26 | 74.67 |
| Comparative example 2 | 78.09 | 79.26 | 78.51 | 77.49 |
| Comparative example 3 | 82.67 | 85.38 | 83.09 | 84.92 |
| Comparative example 4 | 85.61 | 84.96 | 85.30 | 85.85 |
| Comparative example 5 | 84.57 | 85.32 | 85.94 | 84.73 |
It can be seen from the data in Table 3 that smoke of the peculiar smell neutralizer of the preparation of the embodiment of the present invention 1~7 to smoking place
With preferable removal effect, wherein to the removal rate of nicotine 90.15%~93.61%, exist to the removal rate of tar
90.62%~93.75%, the removal rate of Pyrogentisinic Acid is 91.37%~94.67%, to the removal rate of carbon monoxide 90.56%
~94.08%, the formula and preparation method of embodiment 7 are the present invention preferably embodiment relatively, the peculiar smell neutralizer pair of preparation
The removal effect of the pernicious gas generated when smoking is best.
The bacteriostasis rate of peculiar smell neutralizer prepared by 4 Examples 1 to 7 of table and comparative example 1~5
It can be seen from the data in Table 4 that peculiar smell neutralizer prepared by the embodiment of the present invention 1~7 has good antibacterial effect
Fruit, bacteriostasis rate is 98.45%~99.48%, wherein the formula and preparation method of embodiment 7 are that the present invention is relatively preferably real
Apply example, bacteriostasis rate highest.
Data comparison can be seen that the peculiar smell neutralizer of the preparation of the embodiment of the present invention 1~7 to harmful gas from table 2~4
All be significantly higher than comparative example 1~5 in the removal of body and fungistatic effect, wherein in comparative example 1 without plus tea polyphenols, terpinol,
Light-coloured vinegar, chitosan, in comparative example 2 without plus 4- ethyl -4- soybean-based ethyl-sulfate morpholine, soybean ethyl sulfuric acid ethyl ester morpholine,
Zinc ricinate ester, in comparative example 3 without plus light-coloured vinegar, in comparative example 4 without plus terpinol, the preparation method in comparative example 5 be
Each component mixes in being directly formulated, and illustrates that composition of raw materials, dosage and preparation method of the present invention are passes of the invention
Key technology is obtained by repetition test, is reduced any component or is saved any one step, is all not up to of the invention
Effect.Each component is synergistic in formula of the invention, cooperates specific preparation method, so that the peculiar smell neutralizer of preparation is to sky
Formaldehyde, benzene, ammonia, amyl hydrosulfide in gas and have to nicotine, tar, phenol, the carbon monoxide etc. in smoking place preferable
Removal effect, meanwhile, fungistatic effect is also fine, plays unexpected effect.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (6)
1. a kind of peculiar smell neutralizer, which is characterized in that be grouped as by the group of following parts by weight:
1~5 part of tea polyphenols, 5~20 parts of terpinol, 5~17 parts of light-coloured vinegar, 3~15 parts of chitosan, 4- ethyl -4- soybean-based sulfuric acid
0.5~15 part of ethyl ester morpholine, 0.5~10 part of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.2~0.8 part of zinc ricinate ester, phellandrene
0.5~2 part, 0.1~1 part of phenol, 80~130 parts of deionized water of the chloro- 2- of 5- (2,4- dichlorophenoxy).
2. a kind of peculiar smell neutralizer according to claim 1, which is characterized in that be grouped as by the group of following parts by weight:
2~4 parts of tea polyphenols, 8~17 parts of terpinol, 10~15 parts of light-coloured vinegar, 5~11 parts of chitosan, 4- ethyl -4- soybean-based sulfuric acid
3~10 parts of ethyl ester morpholine, 2~8 parts of morpholine of soybean ethyl sulfuric acid ethyl ester, 0.4~0.7 part of zinc ricinate ester, phellandrene 1~
1.7 parts, 0.2~0.8 part of phenol, 90~120 parts of deionized water of the chloro- 2- of 5- (2,4- dichlorophenoxy).
3. a kind of peculiar smell neutralizer according to claim 2, which is characterized in that be grouped as by the group of following parts by weight:
3 parts of tea polyphenols, 13 parts of terpinol, 12 parts of light-coloured vinegar, 7 parts of chitosan, 7 parts of morpholine of -4- soybean-based ethyl-sulfate of 4- ethyl, greatly
6 parts of morpholine of beans ethyl sulfuric acid ethyl ester, 0.5 part of zinc ricinate ester, 1.4 parts of phellandrene, the chloro- 2- of 5- (2,4- dichlorophenoxy) benzene
0.6 part of phenol, 100 parts of deionized water.
4. a kind of peculiar smell neutralizer according to claim 3, which is characterized in that the deacetylating degree of chitosan be 70%~
85%.
5. a kind of preparation method of peculiar smell neutralizer, which comprises the following steps:
S1, according to a kind of formula of peculiar smell neutralizer described in Claims 1 to 4 any one, it is spare to weigh each component；
S2, light-coloured vinegar is dissolved into formula in the deionized water of half volume, obtains light-coloured vinegar solution；
S3, chitosan, terpinol and tea polyphenols are added into the light-coloured vinegar solution that step S2 is obtained, just mixed liquid is obtained after stirring and dissolving
One；
S4, successively 4- ethyl -4- soybean-based ethyl-sulfate morpholine, soybean ethyl sulfuric acid ethyl ester morpholine, zinc ricinate ester added
Enter in formula in the deionized water of the other half volume, mixed liquid two at the beginning of obtaining after mixing,
S5, the first mixed liquid one that step S3 is obtained is mixed with the first mixed liquid two that step S4 is obtained, obtains mixed solution；
Phellandrene, the chloro- 2- of 5- (2,4- dichlorophenoxy) phenol are added in S6, the mixed solution obtained to step S5, mixing is equal
Peculiar smell neutralizer is obtained after even.
6. a kind of preparation method of peculiar smell neutralizer according to claim 5, which is characterized in that mixing speed in step S3
For 200~260r/min, mixing time is 20~30min.
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