CN101455849B - Air purification agent - Google Patents

Air purification agent Download PDF

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Publication number
CN101455849B
CN101455849B CN 200710094437 CN200710094437A CN101455849B CN 101455849 B CN101455849 B CN 101455849B CN 200710094437 CN200710094437 CN 200710094437 CN 200710094437 A CN200710094437 A CN 200710094437A CN 101455849 B CN101455849 B CN 101455849B
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Prior art keywords
component
air
gel
product
chlorine dioxide
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CN 200710094437
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Chinese (zh)
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CN101455849A (en
Inventor
刘青松
张蕾
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SHANGHAI WHITECAT SHAREHOLDING CO Ltd
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SHANGHAI WHITECAT SHAREHOLDING CO Ltd
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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention relates to the field of daily-use chemical industry, in particular to a deodorization, sterilization and air purification product in home care, which is mainly technically characterized in that the deodorization, sterilization and air purification product utilizes strong oxidation of chlorine dioxide and sterilization of broad spectrum to perform sterilization and deodorization on air in a room. The product has two compositions which are A and B respectively, wherein the A is a stable chlorine dioxide solution, a surfactant and flavoring essence, and the B is gel, an activator and a sustained release agent. When the product is used, the B is poured into a container for holding the A, and uniform gel is quickly formed without stirring. When the product is placed in the room, the chlorine dioxide and the flavoring essence can be naturally and slowly released in the air from the gel, kill harmful bacteria and viruses in the air, and oxidize and decompose harmful compositions with peculiar smell in the air, so that the product has the function of purifying the air in the room and can continuously act for two months. The air purificant has the characteristics of simple and convenient use and operation, long effect, safety and nonirritant.

Description

Air purifying preparation
Technical field
The present invention relates to filed of daily-use chemical industry, deodorization in especially a kind of household care, sterilization, air clearing product.
Technical background
Along with growth in the living standard, people are more and more higher to the requirement of bettering people's living environment, improving air quality.People need the living environment of pure and fresh, clean and tidy a, health.Room air pollution day by day becomes the problem that people pay close attention to.These pollutant have: formaldehyde, benzene, ammonia, radon, aromatic hydrocarbon, tetrachloroethylene, paracide, chlorine, carbon monoxide, hydrogen sulfide, organic amine, mercaptan, thioether.These come from, and abnormal flavour not only influences people's mood in life and the finishing material, and is threatening people's health, also exists various pathological form microorganisms in the air simultaneously.The air freshener of Xiao Shouing is general in the market only comes covering smell with fragrant, can not purify air, and can not kill airborne antibacterial.A kind of good air purifying preparation then not only will possess the characteristics of killing various harmful microorganisms and eliminating noxious substance, but also should possess safety, efficient, wide spectrum, has no side effect, and strong point such as stores and easy to use.Chlorine dioxide possesses above-mentioned every requirement and various characteristics fully, uses slow-releasing low concentration chlorine dioxide can effectively eliminate stink and the sterilization of room air, and is harmless.It is particularly suitable for the air cleaning that room, hotel, ward, meeting room, waiting room, car, telephone booth, Internet bar, refrigerator, freezer, storeroom, lavatory etc. are located.Develop a kind of chlorine dioxide air cleanser product, to reach the purpose of sterilization, sterilization, deodorization, will be subjected to the favor in market.Because the chlorine dioxide chemical property is active, in case the activation back will be decomposed in a couple of days.Generally chlorine dioxide is made the solid slow-release product at present.The described solid chlorine dioxide air purifying preparation of existing market and patent product is in the convenience of using with the slow release uniformity of chlorine dioxide is difficult to satisfy the daily demand of consumer.As patent CN 1470301A, adopt starch as carrier, be difficult to the uniformity of the rate of release of chlorine dioxide is effectively controlled; Patent CN 1704126A adopts polyvinyl alcohol as slow releasing agent, this composition is limited to the slow releasing function effect of chlorine dioxide, and because its strongly hydrophilic is unfavorable to the volatilization of moisture behind the gel formation, make colloid through a period of time after strain, forfeiture is to effective release property of chlorine dioxide.
Summary of the invention
The objective of the invention is to overcome the shortcoming of existing product, provide a kind of chlorine dioxide gel agent product of the release low concentration that can effectively evenly continue, the purpose that play deodorization, sterilize, purifies the air of a room.Easy to use, satisfactory for result.Owing to add essence, covered the abnormal smells from the patient of chlorine dioxide itself, be more conducive to consumer and accept.
The objective of the invention is to be realized by following technical scheme.
Air purifying preparation is made up of two kinds of components of A, B.
The weight percent concentration of A component is:
Stable ClO 2 solution 60-90%
Surfactant 0.1-8%
Essence 0.5-10%
The weight percent concentration of B component is:
Gel 0.5-15%
Activator 2-10%
Slow releasing agent 1-8%
A component and B component weight percent concentration be that summation is 100%.
A component and B component are packed respectively.During use, unpack, the B component is dropped in the A component, need not to stir, form uniform gel rapidly, placement is statically placed in indoor, the effect that can bring into play deodorization, sterilize, purifies air.Sustainable use two months.
A kind of preparation technology of air purifying preparation is characterized in that: stable ClO 2 solution is placed reactor, and 40-60 ℃ of stirring slowly drips surfactant and the essence that is pre-mixed.Fill after stirring gets component A; Gel, activator, slow releasing agent are put into the batch mixer mix homogeneously, and bag distribution packaging gets B component.
The concentration of described stable ClO 2 solution is 1-10%
Described slow releasing agent is phosphate or citrate.
Described gel is TYLOSE 30000.
Described activator is citric acid or tartaric acid or sodium bisulfate.
Described surfactant is the sulfonate of alkyl amine oxide or aliphatic alcohol.
The mechanism of action of this air purifying preparation is: under the effect of activator and slow releasing agent, slowly release hydrion, stability chlorine dioxide in gel is activated gradually, discharge the chlorine dioxide molecule uniformly, with airborne toxic and harmful generation oxidation reaction, harmful substance is transformed harmless material; Its strong oxidation decomposes the amino-acid oxidase of synthesized micro-organism cell protein simultaneously, cause amino acid whose carbochain fracture, protein loses function, thereby makes microbial death, experimental results show that it can effectively kill antibacterials such as airborne gold-coloured staphylococci, escherichia coli, purify air.
The invention effect
It is gel that effect of the present invention is to have adopted TYLOSE 30000, and the ClO 2 solution of strong oxidizing property can be under its effect, and it is rapid to form gel, need not stirring, heating process, forms uniform solid gel agent product.Therefore very convenient, be beneficial to consumer and use.
Effect of the present invention also is to have adopted phosphate or citrate as the rate of release of the chlorine dioxide in the gel of slow releasing agent control under the activator effect.The rate of release of chlorine dioxide molecule on gel surface can be controlled at 50-140ug/cm 2H works the mischief to human body to prevent the aerial excessive concentration of chlorine dioxide.
The abnormal smells from the patient of the chlorine dioxide that effect of the present invention also is to have adopted essence to cover and volatilizes itself makes it to be beneficial to consumer and accepts.
The embodiment of the invention
Embodiment 1:
The weight percent concentration of A component is:
Stable ClO 2 solution 82%
Surfactant 2.5%
Essence 1%
The weight percent concentration of B component is:
Gel 9%
Activator 4%
Slow releasing agent 1.5%.
The B component is dropped in the A component, need not to stir, form uniform gel rapidly.The rate of volatilization of chlorine dioxide is 139ug/cm in the test gel 2H.
Embodiment 2:
The weight percent concentration of A component is:
Stable ClO 2 solution 78%
Surfactant 3%
Essence 1%
The weight percent concentration of B component is:
Gel 9%
Activator 4%
Slow releasing agent 5%.
The B component is dropped in the A component, need not to stir, form uniform gel rapidly.The rate of volatilization of chlorine dioxide is 101ug/cm in the test gel 2H.
The deodorizing effect of each embodiment sees Table 1.
Prepare 850ppm ammonia, 1000ppm stink damp, 200ppm benzene, 1500mg/m respectively in airtight space 3Acetic acid gas is tested the deodorizing effect of above embodiment; Measure the deodorizing effect of the fishlike smell of each embodiment, kitchen, toilet simultaneously, the results are shown in Table 1.
The deodorizing effect of table 1 prescription
Deodorizing effect Ammonia Hydrogen sulfide Benzene Acetic acid Fishlike smell The kitchen Toilet
Example 1 100% 100% 90% 99% Good Good Good
Example 2 100% 100% 81% 93% Good Good Good
By example 1 preparation deodorizer, carry out the user and try out, send out 15 parts in sample.Table 2 has shown user's trial state.
Table 2 user trial state
The user is on probation to be estimated Toilet Garbage
Good 11 12
Generally 4 3
Difference 0 0

Claims (5)

1. an air purifying preparation comprises A component and B component, it is characterized in that:
The weight percent concentration of A component is:
Stable ClO 2 solution 60-90%
Surfactant 0.1-8%
Essence 0.5-10%
The weight percent concentration of B component is:
Gel 0.5-15%
Activator 2-10%
Slow releasing agent 1-8%
The weight percent concentration summation of A component and B component is 100%;
A component and B component are packed respectively,
Wherein slow releasing agent is phosphate or citrate.
2. air purifying preparation according to claim 1, it is characterized in that: described surfactant is the sulfonate of alkyl amine oxide or aliphatic alcohol.
3. air purifying preparation according to claim 1, it is characterized in that: described gel is hydroxy methocel ether.
4. air purifying preparation according to claim 1, it is characterized in that: described activator is citric acid or tartaric acid or sodium bisulfate.
5. the preparation technology of a kind of air purifying preparation according to claim 1, it is characterized in that: stable ClO 2 solution is placed reactor, and 35-60 ℃ of stirring slowly drips surfactant and the essence that is pre-mixed, canned after stirring, get component A; Gel, activator, slow releasing agent are put into the batch mixer mix homogeneously, and bag distribution packaging gets B component.
CN 200710094437 2007-12-11 2007-12-11 Air purification agent Active CN101455849B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN101455849A CN101455849A (en) 2009-06-17
CN101455849B true CN101455849B (en) 2013-08-14

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021097119A1 (en) * 2019-11-11 2021-05-20 ProKure Solutions, LLC Methods of treatment of volatile organic compounds using chlorine dioxide

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CN103055337B (en) * 2013-01-07 2015-05-13 北京洛娃日化有限公司 Concentrated efficient deodorant
CN103949346A (en) * 2014-05-15 2014-07-30 无锡同春新能源科技有限公司 Telephone booth capable of purifying air and powered by photovoltaic power generation
CN104174266A (en) * 2014-08-29 2014-12-03 成都顺发消洗科技有限公司 Preparation method of slow-release chlorine dioxide air purifying agent
CN104437889A (en) * 2014-12-09 2015-03-25 鞍钢集团矿业公司 Hematite anti-floatation depressor
CN105145626B (en) * 2015-07-30 2019-03-26 竹安(北京)生物科技发展有限公司 A kind of immobilized gel chlorine dioxide air cleanser of aroma type
CN105600228A (en) * 2016-02-02 2016-05-25 耿春茂 Garbage bin with functions of removing odor and compressing garbage
CN105688661A (en) * 2016-02-02 2016-06-22 耿春茂 Photocatalytic deodorization plate
CN105730929A (en) * 2016-02-02 2016-07-06 耿春茂 Dustbin with photocatalysis deodorization function
CN105999349A (en) * 2016-06-21 2016-10-12 苏州格兰斯柯光电科技有限公司 Air purifying device
CN106111076A (en) * 2016-06-27 2016-11-16 马鞍山市顺达环保设备有限公司 A kind of formula of air purifying preparation
CN106386849A (en) * 2016-08-31 2017-02-15 南京尚易环保科技有限公司 Slow release type solid chlorine dioxide formaldegyde scavenging agent and preparing method thereof
CN106620781A (en) * 2016-12-29 2017-05-10 江阴天鸿环境科技有限公司 Freshener having rose fragrance
CN106729882A (en) * 2016-12-29 2017-05-31 江阴天鸿环境科技有限公司 A kind of sterilization freshener for alleviating headache
CN106853257A (en) * 2016-12-29 2017-06-16 江阴天鸿环境科技有限公司 Inducing resuscitation solid freshener
CN106822966A (en) * 2016-12-30 2017-06-13 江阴天鸿环境科技有限公司 A kind of pure and fresh ball of the solid of rose scent
CN106729887A (en) * 2016-12-30 2017-05-31 江阴天鸿环境科技有限公司 A kind of pure and fresh ball of fast cooling rose
CN106853259A (en) * 2016-12-30 2017-06-16 江阴天鸿环境科技有限公司 Containing rosewater fast cooling freshener
CN106729884A (en) * 2016-12-30 2017-05-31 江阴天鸿环境科技有限公司 Contain stearic fast cooling freshener
CN106620786A (en) * 2016-12-30 2017-05-10 江阴天鸿环境科技有限公司 Linalool-containing refreshing agent for reliving headache
CN107029269A (en) * 2017-05-23 2017-08-11 南宁市钱隆汽车租赁有限公司 Automobile-used solid freshener
CN108261901A (en) * 2018-02-05 2018-07-10 段宝荣 A kind of air purifying preparation and preparation method thereof
CN108057328A (en) * 2018-02-05 2018-05-22 段宝荣 Remove cleanser of formaldehyde in indoor air and preparation method thereof
CN111543426A (en) * 2020-05-11 2020-08-18 赵琦 Preparation method of slow-release chlorine dioxide gel
CN112136827A (en) * 2020-09-29 2020-12-29 黄俊雄 Slow-release chlorine dioxide solid gel and preparation method and application thereof
CN115090225A (en) * 2022-05-12 2022-09-23 重庆中科力泰高分子材料股份有限公司 Novel efficient aldehyde-removing transparent gel and preparation method thereof

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CN101011595A (en) * 2007-02-02 2007-08-08 河北科技大学 Wet towel disinfected by chlorine dioxide and its preparing process

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CN1266017A (en) * 2000-03-30 2000-09-13 周成威 Slow released water solution for stabilizing chlorine dioxide and making method thereof
CN1748508A (en) * 2004-09-17 2006-03-22 湖南省湘潭市洙津渡化工厂 Aromatic degerming agent
CN2841013Y (en) * 2005-10-28 2006-11-29 河北科技大学 Air-disinfecting clearing box for slow-release chlorinedioxide gas
CN101011595A (en) * 2007-02-02 2007-08-08 河北科技大学 Wet towel disinfected by chlorine dioxide and its preparing process

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021097119A1 (en) * 2019-11-11 2021-05-20 ProKure Solutions, LLC Methods of treatment of volatile organic compounds using chlorine dioxide

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Inventor after: Wang Xiaochun

Inventor after: Shi Rongying

Inventor before: Liu Qingsong

Inventor before: Zhang Lei