CN106565201A - 一种防紫外线瓷器及其制作工艺 - Google Patents
一种防紫外线瓷器及其制作工艺 Download PDFInfo
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- CN106565201A CN106565201A CN201610921382.0A CN201610921382A CN106565201A CN 106565201 A CN106565201 A CN 106565201A CN 201610921382 A CN201610921382 A CN 201610921382A CN 106565201 A CN106565201 A CN 106565201A
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- parts
- porcelain
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- kaolin
- stove
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- 229910052573 porcelain Inorganic materials 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical class O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000002994 raw material Substances 0.000 claims abstract description 31
- 239000000843 powder Substances 0.000 claims abstract description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004927 clay Substances 0.000 claims abstract description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 239000010451 perlite Substances 0.000 claims abstract description 6
- 235000019362 perlite Nutrition 0.000 claims abstract description 6
- 239000000454 talc Substances 0.000 claims abstract description 6
- 229910052623 talc Inorganic materials 0.000 claims abstract description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010457 zeolite Substances 0.000 claims abstract description 5
- 108010001441 Phosphopeptides Proteins 0.000 claims abstract description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 28
- 235000012211 aluminium silicate Nutrition 0.000 claims description 28
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- 235000015895 biscuits Nutrition 0.000 claims description 17
- 238000005245 sintering Methods 0.000 claims description 17
- 238000005516 engineering process Methods 0.000 claims description 13
- 238000012545 processing Methods 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 5
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 5
- 244000025254 Cannabis sativa Species 0.000 claims description 5
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 5
- 244000124853 Perilla frutescens Species 0.000 claims description 5
- 235000004348 Perilla frutescens Nutrition 0.000 claims description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 5
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
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- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 5
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 5
- 235000019991 rice wine Nutrition 0.000 claims description 5
- 229960004889 salicylic acid Drugs 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- 238000009966 trimming Methods 0.000 claims description 5
- 239000000052 vinegar Substances 0.000 claims description 5
- 235000021419 vinegar Nutrition 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000811 xylitol Substances 0.000 claims description 5
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 5
- 229960002675 xylitol Drugs 0.000 claims description 5
- 235000010447 xylitol Nutrition 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229930014669 anthocyanidin Natural products 0.000 claims description 2
- 150000001452 anthocyanidin derivatives Chemical class 0.000 claims description 2
- 235000008758 anthocyanidins Nutrition 0.000 claims description 2
- 229940071162 caseinate Drugs 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 238000003763 carbonization Methods 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 241001474374 Blennius Species 0.000 abstract 1
- 239000000378 calcium silicate Substances 0.000 abstract 1
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract 1
- 239000005018 casein Substances 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- 239000003610 charcoal Substances 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 description 12
- 238000011161 development Methods 0.000 description 5
- YEDFEBOUHSBQBT-UHFFFAOYSA-N 2,3-dihydroflavon-3-ol Chemical compound O1C2=CC=CC=C2C(=O)C(O)C1C1=CC=CC=C1 YEDFEBOUHSBQBT-UHFFFAOYSA-N 0.000 description 4
- 229930003939 flavanonol Natural products 0.000 description 4
- 108700019535 Phosphoprotein Phosphatases Proteins 0.000 description 3
- 235000013351 cheese Nutrition 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 3
- 238000010304 firing Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052572 stoneware Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
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Abstract
本发明涉及陶瓷领域，具体涉及一种防紫外线瓷器，按重量份计，含有以下原料组分：黏土40‑45份、改性高岭土16‑20份、改性海藻炭16‑20份、黑滑石6‑8份、紫金土6‑8份、绢云母12‑16份、沸石6‑8份、珍珠岩4‑8份、酪蛋白磷酸肽螯合铁1‑2份、纳米硅酸钙1‑2份、氧化钛粉1‑2份、碳化硅粉1‑2份。本发明瓷器质地坚硬，表面光滑耐磨，抗紫外线和高温辐照，使用10年都不会出现裂痕与暗黄色斑块，瓷器在‑40℃低温下不会变脆。
Description
技术领域
本发明涉及陶瓷领域，具体涉及一种防紫外线瓷器及其制作工艺。
背景技术
用陶土烧制的器皿叫陶器，用瓷土烧制的器皿叫瓷器。陶瓷则是陶器，炻器和瓷器的总称。凡是用陶土和瓷土这两种不同性质的粘土为原料，经过配料、成型、干燥、焙烧等工艺流程制成的器物都可以叫陶瓷。
陶瓷的发展史是中华文明史的一个重要的组成部分，中国作为四大文明古国之一，为人类社会的进步和发展做出了卓越的贡献，其中陶瓷的发明和发展更具有独特的意义，中国历史上各朝各代有着不同艺术风格和不同技术特点。英文中的“china”既有中国的意思，又有陶瓷的意思，清楚地表明了中国就是“陶瓷的故乡”。早在欧洲人掌握瓷器制造技术一千多年前，汉族就已经制造出很精美的陶瓷器。中国是世界上最早应用陶器的国家之一，而中国瓷器因其极高的实用性和艺术性而备受世人的推崇。
随着近代科学技术的发展，近百年来又出现了许多新的陶瓷品种。它们不再使用或很少使用粘土、长石、石英等传统陶瓷原料，而是使用其他特殊原料，甚至扩大到非硅酸盐，非氧化物的范围，并且出现了许多新的工艺。美国和欧洲一些国家的文献已将“Ceramic”一词理解为各种无机非金属固体材料的通称。因此陶瓷的含义实际上已远远超越过去狭窄的传统观念了。
我国的陶瓷工业源远流长，历史悠久。陶、瓷器所用的原料绝大部分是天然的无机非金属矿物，这些原料通过加工精制、配合、成形、高温物理化学反应，才形成一种与原来组成物质截然不同的新的物质，即是陶瓷。我国陶到瓷发展经过了三个阶段：陶器—原始陶器—瓷器。目前瓷器原料各异，工艺各异，然而瓷器在原料和工艺上总存在一些问题，导致瓷器使用寿命短。
发明内容
本发明所要解决的技术问题在于提供一种防紫外线瓷器及其制作工艺，瓷器质地坚硬，表面光滑耐磨，抗紫外线和高温辐照，使用10年都不会出现裂痕与暗黄色斑块，瓷器在-40℃低温下不会变脆。
本发明所要解决的技术问题采用以下技术方案来实现：
一种防紫外线瓷器，其特征在于，按重量份计，含有以下原料组分：黏土40-45份、改性高岭土16-20份、改性海藻炭16-20份、黑滑石6-8份、紫金土6-8份、绢云母12-16份、沸石6-8份、珍珠岩4-8份、酪蛋白磷酸肽螯合铁1-2份、纳米硅酸钙1-2份、氧化钛粉1-2份、碳化硅粉1-2份。
所述改性高岭土由以下方法制备：向高岭土内加入白醋然后烧至150-200℃，再将高岭土浸泡于15°的绍兴黄酒中，将高岭土捞出沥干使其含水率维持在8％-10％，然后在5-5.2MPa压力下处理1小时，取出高岭土并烧至180-220℃，再将其放入浸泡液中浸泡1小时，捞出高岭土后继续煅烧至180-220℃，然后在1分钟内冷却至常温即可。
所述浸泡液由以下重量份原料制成：水杨酸20-30份、苹果酸14-18份、肉桂酸14-18份、花青素5-10份、木糖醇5-10份、黄烷酮醇5-10份、四乙氧基硅烷5-10份，将各原料混合加入它们重量份20倍清水搅拌均匀即可。
所述改性海藻炭由以下方法制备：将海藻炭加热至80-100℃，将其浸泡于50-60℃的双氧水，捞出海藻炭并加热至260-300℃使双氧水完全去除，然后在1分钟内冷却至常温即可。
一种防紫外线瓷器的制作工艺，包括以下步骤：
(1)按重量份秤取各原料，将各原料混合磨碎至500-600目的细粉；
(2)根据设计需求使细粉成型，修坯，将修整好的坯体在1000-1100℃炉窑中素烧，素烧30分钟后，将素烧坯打磨光滑；
(3)素烧坯施釉加入苏麻离青，将炉窑温度升至1250-1300℃，继续烧结30分钟，然后利用液氮对炉窑降温至1000-1100℃，接着将炉窑温度升至1250-1300℃，继续烧结30分钟，然后出炉窑。
烧结过程中每隔10分钟向炉窑中通入纯氧，使炉窑内氧气浓度维持在25.5-30.5％。
素烧坯继续烧结温度为1260-1280℃。
本发明的有益效果是：本发明瓷器质地坚硬，表面光滑耐磨，抗紫外线和高温辐照，使用10年都不会出现裂痕与暗黄色斑块，瓷器在-40℃低温下不会变脆。
具体实施方式
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例，进一步阐述本发明。
实施例1
一种防紫外线瓷器，其特征在于，按重量份计，含有以下原料组分：黏土42份、改性高岭土18份、改性海藻炭18份、黑滑石7份、紫金土7份、绢云母14份、沸石7份、珍珠岩6份、酪蛋白磷酸肽螯合铁1.5份、纳米硅酸钙1.5份、氧化钛粉1.5份、碳化硅粉1.5份。
所述改性高岭土由以下方法制备：向高岭土内加入白醋然后烧至150-200℃，再将高岭土浸泡于15°的绍兴黄酒中，将高岭土捞出沥干使其含水率维持在8％-10％，然后在5-5.2MPa压力下处理1小时，取出高岭土并烧至180-220℃，再将其放入浸泡液中浸泡1小时，捞出高岭土后继续煅烧至180-220℃，然后在1分钟内冷却至常温即可。
所述浸泡液由以下重量份原料制成：水杨酸25份、苹果酸16份、肉桂酸16份、花青素8份、木糖醇8份、黄烷酮醇8份、四乙氧基硅烷8份，将各原料混合加入它们重量份20倍清水搅拌均匀即可。
所述改性海藻炭由以下方法制备：将海藻炭加热至80-100℃，将其浸泡于50-60℃的双氧水，捞出海藻炭并加热至260-300℃使双氧水完全去除，然后在1分钟内冷却至常温即可。
一种防紫外线瓷器的制作工艺，包括以下步骤：
(1)按重量份秤取各原料，将各原料混合磨碎至550目的细粉；
(2)根据设计需求使细粉成型，修坯，将修整好的坯体在1050℃炉窑中素烧，素烧30分钟后，将素烧坯打磨光滑；
(3)素烧坯施釉加入苏麻离青，将炉窑温度升至1270℃，继续烧结30分钟，然后利用液氮对炉窑降温至1050℃，接着将炉窑温度升至1270℃，继续烧结30分钟，然后出炉窑。
烧结过程中每隔10分钟向炉窑中通入纯氧，使炉窑内氧气浓度维持在28.5％。
实施例2
一种防紫外线瓷器，其特征在于，按重量份计，含有以下原料组分：黏土40份、改性高岭土16份、改性海藻炭16份、黑滑石6份、紫金土6份、绢云母12份、沸石6份、珍珠岩4份、酪蛋白磷酸肽螯合铁1份、纳米硅酸钙1份、氧化钛粉1份、碳化硅粉1份。
所述改性高岭土由以下方法制备：向高岭土内加入白醋然后烧至150-200℃，再将高岭土浸泡于15°的绍兴黄酒中，将高岭土捞出沥干使其含水率维持在8％-10％，然后在5-5.2MPa压力下处理1小时，取出高岭土并烧至180-220℃，再将其放入浸泡液中浸泡1小时，捞出高岭土后继续煅烧至180-220℃，然后在1分钟内冷却至常温即可。
所述浸泡液由以下重量份原料制成：水杨酸20份、苹果酸14份、肉桂酸14份、花青素5份、木糖醇5份、黄烷酮醇5份、四乙氧基硅烷5份，将各原料混合加入它们重量份20倍清水搅拌均匀即可。
所述改性海藻炭由以下方法制备：将海藻炭加热至80-100℃，将其浸泡于50-60℃的双氧水，捞出海藻炭并加热至260-300℃使双氧水完全去除，然后在1分钟内冷却至常温即可。
一种防紫外线瓷器的制作工艺，包括以下步骤：
(1)按重量份秤取各原料，将各原料混合磨碎至500目的细粉；
(2)根据设计需求使细粉成型，修坯，将修整好的坯体在1000℃炉窑中素烧，素烧30分钟后，将素烧坯打磨光滑；
(3)素烧坯施釉加入苏麻离青，将炉窑温度升至1250℃，继续烧结30分钟，然后利用液氮对炉窑降温至1000℃，接着将炉窑温度升至1250℃，继续烧结30分钟，然后出炉窑。
烧结过程中每隔10分钟向炉窑中通入纯氧，使炉窑内氧气浓度维持在25.5％。
实施例3
一种防紫外线瓷器，其特征在于，按重量份计，含有以下原料组分：黏土45份、改性高岭土20份、改性海藻炭20份、黑滑石8份、紫金土8份、绢云母16份、沸石8份、珍珠岩8份、酪蛋白磷酸肽螯合铁2份、纳米硅酸钙2份、氧化钛粉2份、碳化硅粉2份。
所述改性高岭土由以下方法制备：向高岭土内加入白醋然后烧至150-200℃，再将高岭土浸泡于15°的绍兴黄酒中，将高岭土捞出沥干使其含水率维持在8％-10％，然后在5-5.2MPa压力下处理1小时，取出高岭土并烧至180-220℃，再将其放入浸泡液中浸泡1小时，捞出高岭土后继续煅烧至180-220℃，然后在1分钟内冷却至常温即可。
所述浸泡液由以下重量份原料制成：水杨酸30份、苹果酸18份、肉桂酸18份、花青素10份、木糖醇10份、黄烷酮醇10份、四乙氧基硅烷10份，将各原料混合加入它们重量份20倍清水搅拌均匀即可。
所述改性海藻炭由以下方法制备：将海藻炭加热至80-100℃，将其浸泡于50-60℃的双氧水，捞出海藻炭并加热至260-300℃使双氧水完全去除，然后在1分钟内冷却至常温即可。
一种防紫外线瓷器的制作工艺，包括以下步骤：
(1)按重量份秤取各原料，将各原料混合磨碎至600目的细粉；
(2)根据设计需求使细粉成型，修坯，将修整好的坯体在1100℃炉窑中素烧，素烧30分钟后，将素烧坯打磨光滑；
(3)素烧坯施釉加入苏麻离青，将炉窑温度升至1300℃，继续烧结30分钟，然后利用液氮对炉窑降温至1100℃，接着将炉窑温度升至1300℃，继续烧结30分钟，然后出炉窑。
烧结过程中每隔10分钟向炉窑中通入纯氧，使炉窑内氧气浓度维持在30.5％。
实验
本实施例1、2、3制成的瓷器与普通瓷器相比性能如下表：
由上表可知，本发明的瓷器性能明显优于普通瓷器。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。
Claims (7)
1.一种防紫外线瓷器，其特征在于，按重量份计，含有以下原料组分：黏土40-45份、改性高岭土16-20份、改性海藻炭16-20份、黑滑石6-8份、紫金土6-8份、绢云母12-16份、沸石6-8份、珍珠岩4-8份、酪蛋白磷酸肽螯合铁1-2份、纳米硅酸钙1-2份、氧化钛粉1-2份、碳化硅粉1-2份。
2.根据权利要求1所述的一种防紫外线瓷器，其特征在于，所述改性高岭土由以下方法制备：向高岭土内加入白醋然后烧至150-200℃，再将高岭土浸泡于15°的绍兴黄酒中，将高岭土捞出沥干使其含水率维持在8％-10％，然后在5-5.2MPa压力下处理1小时，取出高岭土并烧至180-220℃，再将其放入浸泡液中浸泡1小时，捞出高岭土后继续煅烧至180-220℃，然后在1分钟内冷却至常温即可。
3.根据权利要求2所述的一种防紫外线瓷器，其特征在于，所述浸泡液由以下重量份原料制成：水杨酸20-30份、苹果酸14-18份、肉桂酸14-18份、花青素5-10份、木糖醇5-10份、黄烷酮醇5-10份、四乙氧基硅烷5-10份，将各原料混合加入它们重量份20倍清水搅拌均匀即可。
4.根据权利要求1所述的一种防紫外线瓷器，其特征在于，所述改性海藻炭由以下方法制备：将海藻炭加热至80-100℃，将其浸泡于50-60℃的双氧水，捞出海藻炭并加热至260-300℃使双氧水完全去除，然后在1分钟内冷却至常温即可。
5.制作权利要求1-4任一项所述的一种防紫外线瓷器的制作工艺，其特征在于，包括以下步骤：
(1)按重量份秤取各原料，将各原料混合磨碎至500-600目的细粉；
(2)根据设计需求使细粉成型，修坯，将修整好的坯体在1000-1100℃炉窑中素烧，素烧30分钟后，将素烧坯打磨光滑；
(3)素烧坯施釉加入苏麻离青，将炉窑温度升至1250-1300℃，继续烧结30分钟，然后利用液氮对炉窑降温至1000-1100℃，接着将炉窑温度升至1250-1300℃，继续烧结30分钟，然后出炉窑。
6.根据权利要求5所述的一种防紫外线瓷器的制作工艺，其特征在于，烧结过程中每隔10分钟向炉窑中通入纯氧，使炉窑内氧气浓度维持在25.5-30.5％。
7.根据权利要求5所述的一种防紫外线瓷器的制作工艺，其特征在于，素烧坯继续烧结温度为1260-1280℃。
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| CN104072084A (zh) * | 2014-06-30 | 2014-10-01 | 南通蛇类治疗研究所 | 纳米矿石粉多效弹性陶瓷器皿 |
| CN104387016A (zh) * | 2014-10-13 | 2015-03-04 | 合肥庭索环保材料有限公司 | 防辐射墙板及其制作方法 |
| CN105060856A (zh) * | 2015-08-11 | 2015-11-18 | 长沙秋点兵信息科技有限公司 | 瓷器的配方及制作工艺 |
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| CN110264863A (zh) * | 2019-07-13 | 2019-09-20 | 广州彩邦印刷有限公司 | 耐磨标签 |
| CN112358278A (zh) * | 2020-10-28 | 2021-02-12 | 钦州市文承陶业文化有限公司 | 一种适合干压成型的坭兴陶快速制作工艺 |
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