CN106520298A - A lubricant composition for a cupronickel grinding process - Google Patents

A lubricant composition for a cupronickel grinding process Download PDF

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Publication number
CN106520298A
CN106520298A CN201610962483.2A CN201610962483A CN106520298A CN 106520298 A CN106520298 A CN 106520298A CN 201610962483 A CN201610962483 A CN 201610962483A CN 106520298 A CN106520298 A CN 106520298A
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China
Prior art keywords
good
lubricant compositions
brass alloy
agent
grinding technique
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CN201610962483.2A
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Chinese (zh)
Inventor
黄福川
黄显昆
赵金城
胡雄风
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Guangxi University
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Guangxi University
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Publication of CN106520298A publication Critical patent/CN106520298A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/30—Anti-misting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A lubricant composition for a cupronickel grinding process is disclosed. Number 15 oil for total-loss systems is adopted as base oil and a plurality of composite additives are also added. The composition includes an antioxidant, a metal passivator, an oiliness agent, a friction improver, an antiwear agent, an anti-rust agent, an anti-foaming agent, an anti-emulsification agent, a dispersant, a filler, and the like. The composition is directly used for a lubrication process in the cupronickel grinding process, and has characteristics of a good cooling property, capability of eliminating heat generated by high-temperature deformation and friction, good high-temperature lubricity, good extreme pressure antiwear carrying capacity, good permeability, good diffusivity, a good cleaning property, a good chip removing property, good rust resistance, low oil mist, intermiscibility to paint, capability of inhibiting scratches and bruises, and high heat capacity.

Description

A kind of White brass alloy grinding technique lubricant compositions
Technical field
A kind of White brass alloy grinding technique lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Copper-nickel alloy is the acid bronze alloy with nickel as main adding elements, is silvery white in color, and has metallic luster, therefore named copper-nickel alloy.Cupro-nickel Between each other can infinitely solid solution, so as to form continuous solid solution, no matter that is, mutual ratio is how many, and it is permanent be α-single-phase alloy. When nickel is fused in rose copper, when content is more than more than 16%, the alloy color and luster of generation just becomes pure white such as silver, and nickel content is higher, Color is whiter.In copper-nickel alloy, the content of nickel is generally 25%.Pure copper plus nickel can significantly improve intensity, corrosion resistance, hardness, resistance and heat Electrically, and it is easy to plastotype, processing and welding[6], and reduce temperature coefficient of resistivity.Therefore copper-nickel alloy is compared with the machinery of other copper alloys Performance, physical property are all abnormal good, ductility is good, hardness is high, color and luster is attractive in appearance, it is corrosion-resistant, be rich in deep drawability, extensively made For fields such as shipbuilding, petrochemical industry, electrical equipment, instrument, medical apparatus and instruments, building, electric power, article of everyday use, musical instrument making, artwares, And also be important resistance and thermocouple metal.
Grinding fluid is that one kind is used in the metal removal course of processing, industrial with workpiece for cooling down and lubricating cutter Liquid.Metal cutting is important mechanical processing toolses, and as used by which, cutting element type can be divided into two big class.One class is to use knife Tool carries out machining, and such as turning, drilling, boring, milling, wound is cut and broached；Another kind of is that the grinding carried out with abrasive material adds Work, such as grinding, the top gem of a girdle-pendant are cut, grinding and superfinishing etc..By processing severe arrangement, machining can be divided into 16 kinds, wherein Grinding ranks the first.Cutting lubricant is divided into two big class so as to use, that is, cut lubricant and grinding lubricant, be required for good Good cooling and lubricant effect, but two kinds of processing modes have basic difference.In grinding, grinding speed is up to More than 1000r/min, temperature is more than 1100 DEG C, therefore it is required that there is higher cooling performance；In addition, grinding tool (such as emery wheel) hole holds Easily block, also therefore need higher detergency.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling effect, elimination high temperature deformation and friction The heat of generation；Good high temperature lubricating, extreme-pressure anti-wear bearing capacity；Good permeability, diffusibility, cleaning, chip removal Property, rust-preventing characteristic, low mist of oil and to paint intermiscibility, cut, scratch, the big White brass alloy grinding of thermal capacity can be suppressed Technology lubricant compositionss.
The present invention solves above-mentioned technical problem by following technical solution：
A kind of White brass alloy grinding technique lubricant compositions, using oil based on No. 15 total loss system oils, Coordinate various compound additives, its each mass percent into being grouped into：
Component Mass percentage content
Base oil Surplus
Antioxidant 0.1%～0.2%
Metal deactivator 0.05%～0.5%
Oiliness improver 4%～8%
Friction improver 1%～3%
Antiwear additive 3%～7%
Antirust agent 0.05%～0.2%
Anti-foaming agent 10ppm～30ppm
Anti emulsifier 0.05%～0.2%
Dispersant 1%～3%
Filler 1%～4%
The mass percent summation of above each component is 100%.
Antioxidant is that the fourth octyl diphenylamine T537 of the phenolic ester antioxidant T508 and 50% of mass ratio 50% is combined.
Metal deactivator is benzotriazole derivant T551.
Oiliness improver is Oleum Brassicae campestriss.
Friction improver is butyl borate.
Antiwear additive is chlorinated paraffin T301.
Antirust agent is BTA T706.
Anti-foaming agent is methyl-silicone oil.
Anti emulsifier is polyether high molecular compound DL32.
Dispersant is diene base succimide T152.
Filler is paraffin wax fully refined 68#.
It is an advantage of the current invention that：The compositionss of the present invention have good cooling effect, eliminate high temperature deformation and friction The heat of generation；Good high temperature lubricating, extreme-pressure anti-wear bearing capacity；Good permeability, diffusibility, cleaning, chip removal Property, rust-preventing characteristic, low mist of oil and to paint intermiscibility, cut, scratch can be suppressed, thermal capacity is big.
Specific embodiment
Embodiment 1：
Following each component is pressed the mediation of row mass percent to form：
Component Mass percentage content
No. 15 total loss system oils Surplus
The phenolic ester antioxidant (T508) of mass ratio 50% is combined with 50% fourth octyl diphenylamine (T537) 0.1%
Benzotriazole derivant (T551) 0.05%
Oleum Brassicae campestriss 4%
Butyl borate 1%
Chlorinated paraffin (T301) 3%
BTA (T706) 0.05%
Methyl-silicone oil 10ppm
Polyether high molecular compound (DL32) 0.05%
Diene base succimide (T152) 1%
Paraffin wax fully refined 68# 1%
Above each component mass percentage content summation is 100%.
Embodiment 2：
Following each component is pressed the mediation of row mass percent to form：
Component Mass percentage content
No. 15 total loss system oils Surplus
The phenolic ester antioxidant (T508) of mass ratio 50% is combined with 50% fourth octyl diphenylamine (T537) 0.15%
Benzotriazole derivant (T551) 0.3%
Oleum Brassicae campestriss 6%
Butyl borate 2%
Chlorinated paraffin (T301) 5%
BTA (T706) 0.15%
Methyl-silicone oil 20ppm
Polyether high molecular compound (DL32) 0.15%
Diene base succimide (T152) 2%
Paraffin wax fully refined 68# 3%
Above each component mass percentage content summation is 100%.
Embodiment 3：
Following each component is pressed the mediation of row mass percent to form：
Component Mass percentage content
No. 15 total loss system oils Surplus
The phenolic ester antioxidant (T508) of mass ratio 50% is combined with 50% fourth octyl diphenylamine (T537) 0.2%
Benzotriazole derivant (T551) 0.5%
Oleum Brassicae campestriss 8%
Butyl borate 3%
Chlorinated paraffin (T301) 7%
BTA (T706) 0.2%
Methyl-silicone oil 30ppm
Polyether high molecular compound (DL32) 0.2%
Diene base succimide (T152) 3%
Paraffin wax fully refined 68# 4%
Above each component mass percentage content summation is 100%.
The typical physiochemical techniques index of 1 product of embodiment：
The typical physiochemical techniques index of 2 product of embodiment：
The typical physiochemical techniques index of 3 product of embodiment：

Claims (9)

1. a kind of White brass alloy grinding technique lubricant compositions, it is characterised in that：Using No. 15 total loss system oils Based on oil, coordinate various compound additives, its each mass percent into being grouped into：
Component Mass percentage content Base oil Surplus Antioxidant 0.1%～0.2% Metal deactivator 0.05%～0.5% Oiliness improver 4%～8% Friction improver 1%～3% Antiwear additive 3%～7% Antirust agent 0.05%～0.2% Anti-foaming agent 10ppm～30ppm Anti emulsifier 0.05%～0.2% Dispersant 1%～3% Filler 1%～4%
The mass percent summation of above each component is 100%.
2. a kind of White brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antioxidant Be mass ratio 50% phenolic ester antioxidant T508 and 50% fourth octyl diphenylamine T537 be combined.
3. a kind of White brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that metal subtracts Agent living is benzotriazole derivant T551.
4. a kind of White brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver It is Oleum Brassicae campestriss.
5. a kind of White brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that friction changes It is butyl borate to enter agent；Antiwear additive is chlorinated paraffin T301.
6. a kind of White brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antirust agent It is BTA T706.
7. a kind of White brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti-foaming agent It is methyl-silicone oil；Anti emulsifier is polyether high molecular compound DL32.
8. a kind of White brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that dispersant It is diene base succimide T152.
9. a kind of White brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that filler It is paraffin wax fully refined 68#.
CN201610962483.2A 2016-11-04 2016-11-04 A lubricant composition for a cupronickel grinding process Withdrawn CN106520298A (en)

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Application Number Priority Date Filing Date Title
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103436333A (en) * 2013-08-26 2013-12-11 广西大学 Lubricating agent for cold rolling of vanadium and vanadium-alloy sheets
CN103468359A (en) * 2013-09-12 2013-12-25 广西大学 Cold rolling lubricating agent for lead and lead alloy sheet strip

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103436333A (en) * 2013-08-26 2013-12-11 广西大学 Lubricating agent for cold rolling of vanadium and vanadium-alloy sheets
CN103468359A (en) * 2013-09-12 2013-12-25 广西大学 Cold rolling lubricating agent for lead and lead alloy sheet strip

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
牛茹轩等: "《废有机溶剂与废矿物油污染防治知识问答》", 31 May 2016, 冶金工业出版社 *

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