CN106520302A - Lubricant composite for niobium alloy cutting process technology - Google Patents
Lubricant composite for niobium alloy cutting process technology Download PDFInfo
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- CN106520302A CN106520302A CN201610962490.2A CN201610962490A CN106520302A CN 106520302 A CN106520302 A CN 106520302A CN 201610962490 A CN201610962490 A CN 201610962490A CN 106520302 A CN106520302 A CN 106520302A
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- niobium alloy
- alloy cutting
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
- C10M2207/1233—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a lubricant composite for a niobium alloy cutting process technology. According to the lubricant composite, 50% of 10 total loss system oil and 50% of adipic acid ester are compounded to serve as a base oil, and a variety of composite additives are added. The composite additives comprise an antioxidant, a metal deactivator, an oiliness agent, a friction modifier, an extreme pressure agent, an antiwear agent, an antirust agent, an anti-foaming agent, a dispersing agent, an anticreaming agent, a cooling accelerant, an oxidation and corrosion inhibitor and the like. The lubricant composite is good in cooling performance, lubricating property, carrying capacity, antifriction-damping property, leanability, chip removal effect, antirust property, oxidation and corrosion property, antifoaming property and putrefaction resistance, low in odor and nonirritating.
Description
Technical field
A kind of niobium alloy cutting technology lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Niobium is greyish white non-ferrous metal, 2468 DEG C of fusing point, 4742 DEG C of boiling point, 8.57 grams/cc of density.Under room temperature, niobium is in sky
It is stable in gas, be not also fully oxidized during red heat in oxygen, with sulphur, nitrogen, the direct chemical combination of carbon under high temperature, can with titanium, zirconium, hafnium,
Tungsten forms alloy.Do not act on inorganic acid or alkali, be also insoluble in chloroazotic acid, but dissolve in hydrofluoric acid.Pure niobium is used in electron tube
Residual gas is removed, niobium is mixed in steel and can be improved non-oxidizability of the steel in high temperature, improve the welding performance of steel.Niobium is additionally operable to manufacture
High-temperature metal ceramics.
The processing method of metal is various, but machining is most common, most widely used one kind all the time.Metal cutting is
Important mechanical processing toolses, as used by which, cutting element type can be divided into two big class;One class is that the cutting carried out with cutter adds
Work;Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of using the cutting element (knife with cutting edge
Tool or emery wheel) excess metal of workpiece is cut on stock-removing machine, so as to be that workpiece obtains regular geometry, size is smart
The processing method of degree and surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and in time removing.
The two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion that this friction is consumed is heat, it
Working (machining) efficiency and workpiece quality can be affected.As serious friction produces substantial amounts of heat, make cutter and workpiece overheated, reduce cutter
In the life-span, affect Product Precision.In order to cool down and lubricate cutter and workpiece, it is necessary to produced with taking away cutting in time using cutting lubricant
Raw heat, reduces the temperature of cutter and workpiece and plays lubrication;Workpiece surface finish is improved, and extends making for cutter
Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be in the constant rubbing surface that moves repeatedly it
Between, despite pressure it is very big, but easily form lubricating oil film.And cut the fresh table that oil is then that constantly contact cutting is formed
Face, machined surface recur elastic deformation, thus the pressure born between cutter and machined surface is bigger than general lubricating status
Much.Niobium alloy cutting technology lubricant is that high intensity, the cutting of heat-resisting alloy material, shaping efficiency is improved, and is improved
Cutting-tool's used life and workpiece quality;Ensure chip, the industry security of tapping process and protection simultaneously.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, bearing capacity, antifriction
Damping, cleaning and chip removal effect, rust-preventing characteristic, antioxygen anticorrosive property, defoaming, anti-corruptibility, it is low smell, nonirritant
Niobium alloy cutting technology lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of niobium alloy cutting technology lubricant compositions, using No. 10 total loss system oils of mass ratio 50%
Based on compound with 50% hexanedioic acid ester, oil, coordinates various compound additives, its each mass percent into being grouped into:
Component | Mass percentage content |
Base oil | Surplus |
Antioxidant | 0.03%~0.2% |
Metal deactivator | 0.05%~0.1% |
Oiliness improver | 4.0%~8.0% |
Friction improver | 0.5%~1.5% |
Extreme pressure agent | 4.0%~6.0% |
Antiwear additive | 4.0%~6.0% |
Antirust agent | 0.05%~0.2% |
Anti-foaming agent | 10~30ppm |
Dispersant | 1.0%~4.0% |
Anti emulsifier | 0.05%~0.15% |
Urge cryogen | 0.5%~2.0% |
Oxidation and corrosion inhibitor | 0.8%~1.5% |
The mass percent summation of above each component is 100%.
Antioxidant is that dialkyl diphenylamine T561 of the 2,6 di-t-butyl mixed phenol T502 and 50% of mass ratio 50% is multiple
Close;
Metal deactivator is that the thiadiazoles derivative of the benzotriazole derivative T551 and 50% of mass ratio 50% is combined.
Oiliness improver is sulfurized lard;Friction improver is sulphur molybdenum phosphate T461.
Extreme pressure agent is tricresol phosphate fat T306;Antiwear additive is sulfide isobutene T321.
Antirust agent is that the lanolin of the BTA T706 and 50% of mass ratio 50% is combined;Anti-foaming agent is methyl silicon
Oil.
Dispersant is polyisobutylene-bis-succinimide T161;Anti emulsifier is polyethers macromolecular compound DL-32.
Urge the petroleum sodium sulfonate T702 that cryogen is mass ratio 50%.
Oxidation and corrosion inhibitor is double octyl group basic zinc salts T203 of sulphur phosphorus.
It is an advantage of the current invention that:
The composition of the present invention has good cooling, lubricity, bearing capacity, damping antifriction, cleaning and row
Bits effect, rust-preventing characteristic, antioxygen anticorrosive property, defoaming, anti-corruptibility, it is low smell, nonirritant;High intensity, heat-resisting can be improved
The cutting of alloy material, shaping efficiency, improve cutting-tool's used life and workpiece quality;Ensure chip, tapping process simultaneously
Industry security and protection.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
The key technical indexes of 3 product of embodiment:
The key technical indexes of 2 product of embodiment:
The key technical indexes of 1 product of embodiment:
Claims (7)
1. a kind of niobium alloy cutting technology lubricant compositions, it is characterised in that:Using No. 10 total loss of mass ratio 50%
Consumption system oil and 50% hexanedioic acid ester it is compound based on oil, coordinate various compound additives, its respective mass percent
Into being grouped into:
The mass percent summation of above each component is 100%.
2. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antioxidant
Be mass ratio 50% 2,6 di-t-butyl mixed phenol T502 and 50% dialkyl diphenylamine T561 be combined;Metal deactivator is
The thiadiazoles derivative of the benzotriazole derivative T551 and 50% of mass ratio 50% is combined.
3. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver is
Sulfurized lard;Friction improver is sulphur molybdenum phosphate T461.
4. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is
Tricresol phosphate fat T306;Antiwear additive is sulfide isobutene T321.
5. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is
The lanolin of the BTA T706 and 50% of mass ratio 50% is combined;Anti-foaming agent is methyl-silicone oil.
6. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that dispersant is
Polyisobutylene-bis-succinimide T161;Anti emulsifier is polyethers macromolecular compound DL-32.
7. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that urge the cryogen to be
The petroleum sodium sulfonate T702 of mass ratio 50%.Oxidation and corrosion inhibitor is double octyl group basic zinc salts T203 of sulphur phosphorus.
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CN201610962490.2A CN106520302A (en) | 2016-11-04 | 2016-11-04 | Lubricant composite for niobium alloy cutting process technology |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109401811A (en) * | 2018-11-13 | 2019-03-01 | 西安航天发动机有限公司 | A kind of cutting fluid and its preparation method and application |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104694221A (en) * | 2013-12-06 | 2015-06-10 | 北京有色金属研究总院 | A lubricating and cooling liquid used for tantalum alloy machining and a preparing method thereof |
-
2016
- 2016-11-04 CN CN201610962490.2A patent/CN106520302A/en not_active Withdrawn
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104694221A (en) * | 2013-12-06 | 2015-06-10 | 北京有色金属研究总院 | A lubricating and cooling liquid used for tantalum alloy machining and a preparing method thereof |
Non-Patent Citations (2)
Title |
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牛茹轩等: "《废有机溶剂与废矿物油污染防治知识问答》", 31 May 2016, 冶金工业出版社 * |
马贤智等: "《实用机械加工手册》", 28 February 2015, 辽宁科学技术出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109401811A (en) * | 2018-11-13 | 2019-03-01 | 西安航天发动机有限公司 | A kind of cutting fluid and its preparation method and application |
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