CN106520302A - Lubricant composite for niobium alloy cutting process technology - Google Patents

Lubricant composite for niobium alloy cutting process technology Download PDF

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Publication number
CN106520302A
CN106520302A CN201610962490.2A CN201610962490A CN106520302A CN 106520302 A CN106520302 A CN 106520302A CN 201610962490 A CN201610962490 A CN 201610962490A CN 106520302 A CN106520302 A CN 106520302A
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niobium alloy
alloy cutting
lubricant compositions
cutting technology
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CN201610962490.2A
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Chinese (zh)
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黄福川
唐弓斌
肖锋
张姗姗
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Guangxi University
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Guangxi University
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085Phosphorus oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
    • C10M2207/1233Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic used as base material
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a lubricant composite for a niobium alloy cutting process technology. According to the lubricant composite, 50% of 10 total loss system oil and 50% of adipic acid ester are compounded to serve as a base oil, and a variety of composite additives are added. The composite additives comprise an antioxidant, a metal deactivator, an oiliness agent, a friction modifier, an extreme pressure agent, an antiwear agent, an antirust agent, an anti-foaming agent, a dispersing agent, an anticreaming agent, a cooling accelerant, an oxidation and corrosion inhibitor and the like. The lubricant composite is good in cooling performance, lubricating property, carrying capacity, antifriction-damping property, leanability, chip removal effect, antirust property, oxidation and corrosion property, antifoaming property and putrefaction resistance, low in odor and nonirritating.

Description

A kind of niobium alloy cutting technology lubricant compositions
Technical field
A kind of niobium alloy cutting technology lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Niobium is greyish white non-ferrous metal, 2468 DEG C of fusing point, 4742 DEG C of boiling point, 8.57 grams/cc of density.Under room temperature, niobium is in sky It is stable in gas, be not also fully oxidized during red heat in oxygen, with sulphur, nitrogen, the direct chemical combination of carbon under high temperature, can with titanium, zirconium, hafnium, Tungsten forms alloy.Do not act on inorganic acid or alkali, be also insoluble in chloroazotic acid, but dissolve in hydrofluoric acid.Pure niobium is used in electron tube Residual gas is removed, niobium is mixed in steel and can be improved non-oxidizability of the steel in high temperature, improve the welding performance of steel.Niobium is additionally operable to manufacture High-temperature metal ceramics.
The processing method of metal is various, but machining is most common, most widely used one kind all the time.Metal cutting is Important mechanical processing toolses, as used by which, cutting element type can be divided into two big class;One class is that the cutting carried out with cutter adds Work;Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of using the cutting element (knife with cutting edge Tool or emery wheel) excess metal of workpiece is cut on stock-removing machine, so as to be that workpiece obtains regular geometry, size is smart The processing method of degree and surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and in time removing. The two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion that this friction is consumed is heat, it Working (machining) efficiency and workpiece quality can be affected.As serious friction produces substantial amounts of heat, make cutter and workpiece overheated, reduce cutter In the life-span, affect Product Precision.In order to cool down and lubricate cutter and workpiece, it is necessary to produced with taking away cutting in time using cutting lubricant Raw heat, reduces the temperature of cutter and workpiece and plays lubrication;Workpiece surface finish is improved, and extends making for cutter Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be in the constant rubbing surface that moves repeatedly it Between, despite pressure it is very big, but easily form lubricating oil film.And cut the fresh table that oil is then that constantly contact cutting is formed Face, machined surface recur elastic deformation, thus the pressure born between cutter and machined surface is bigger than general lubricating status Much.Niobium alloy cutting technology lubricant is that high intensity, the cutting of heat-resisting alloy material, shaping efficiency is improved, and is improved Cutting-tool's used life and workpiece quality;Ensure chip, the industry security of tapping process and protection simultaneously.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, bearing capacity, antifriction Damping, cleaning and chip removal effect, rust-preventing characteristic, antioxygen anticorrosive property, defoaming, anti-corruptibility, it is low smell, nonirritant Niobium alloy cutting technology lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of niobium alloy cutting technology lubricant compositions, using No. 10 total loss system oils of mass ratio 50% Based on compound with 50% hexanedioic acid ester, oil, coordinates various compound additives, its each mass percent into being grouped into:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.03%~0.2%
Metal deactivator 0.05%~0.1%
Oiliness improver 4.0%~8.0%
Friction improver 0.5%~1.5%
Extreme pressure agent 4.0%~6.0%
Antiwear additive 4.0%~6.0%
Antirust agent 0.05%~0.2%
Anti-foaming agent 10~30ppm
Dispersant 1.0%~4.0%
Anti emulsifier 0.05%~0.15%
Urge cryogen 0.5%~2.0%
Oxidation and corrosion inhibitor 0.8%~1.5%
The mass percent summation of above each component is 100%.
Antioxidant is that dialkyl diphenylamine T561 of the 2,6 di-t-butyl mixed phenol T502 and 50% of mass ratio 50% is multiple Close;
Metal deactivator is that the thiadiazoles derivative of the benzotriazole derivative T551 and 50% of mass ratio 50% is combined.
Oiliness improver is sulfurized lard;Friction improver is sulphur molybdenum phosphate T461.
Extreme pressure agent is tricresol phosphate fat T306;Antiwear additive is sulfide isobutene T321.
Antirust agent is that the lanolin of the BTA T706 and 50% of mass ratio 50% is combined;Anti-foaming agent is methyl silicon Oil.
Dispersant is polyisobutylene-bis-succinimide T161;Anti emulsifier is polyethers macromolecular compound DL-32.
Urge the petroleum sodium sulfonate T702 that cryogen is mass ratio 50%.
Oxidation and corrosion inhibitor is double octyl group basic zinc salts T203 of sulphur phosphorus.
It is an advantage of the current invention that:
The composition of the present invention has good cooling, lubricity, bearing capacity, damping antifriction, cleaning and row Bits effect, rust-preventing characteristic, antioxygen anticorrosive property, defoaming, anti-corruptibility, it is low smell, nonirritant;High intensity, heat-resisting can be improved The cutting of alloy material, shaping efficiency, improve cutting-tool's used life and workpiece quality;Ensure chip, tapping process simultaneously Industry security and protection.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
The key technical indexes of 3 product of embodiment:
The key technical indexes of 2 product of embodiment:
The key technical indexes of 1 product of embodiment:

Claims (7)

1. a kind of niobium alloy cutting technology lubricant compositions, it is characterised in that:Using No. 10 total loss of mass ratio 50% Consumption system oil and 50% hexanedioic acid ester it is compound based on oil, coordinate various compound additives, its respective mass percent Into being grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.03%~0.2% Metal deactivator 0.05%~0.1% Oiliness improver 4.0%~8.0% Friction improver 0.5%~1.5% Extreme pressure agent 4.0%~6.0% Antiwear additive 4.0%~6.0% Antirust agent 0.05%~0.2% Anti-foaming agent 10~30ppm Dispersant 1.0%~4.0% Anti emulsifier 0.05%~0.15% Urge cryogen 0.5%~2.0% Oxidation and corrosion inhibitor 0.8%~1.5%
The mass percent summation of above each component is 100%.
2. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antioxidant Be mass ratio 50% 2,6 di-t-butyl mixed phenol T502 and 50% dialkyl diphenylamine T561 be combined;Metal deactivator is The thiadiazoles derivative of the benzotriazole derivative T551 and 50% of mass ratio 50% is combined.
3. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver is Sulfurized lard;Friction improver is sulphur molybdenum phosphate T461.
4. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is Tricresol phosphate fat T306;Antiwear additive is sulfide isobutene T321.
5. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is The lanolin of the BTA T706 and 50% of mass ratio 50% is combined;Anti-foaming agent is methyl-silicone oil.
6. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that dispersant is Polyisobutylene-bis-succinimide T161;Anti emulsifier is polyethers macromolecular compound DL-32.
7. a kind of niobium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that urge the cryogen to be The petroleum sodium sulfonate T702 of mass ratio 50%.Oxidation and corrosion inhibitor is double octyl group basic zinc salts T203 of sulphur phosphorus.
CN201610962490.2A 2016-11-04 2016-11-04 Lubricant composite for niobium alloy cutting process technology Withdrawn CN106520302A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109401811A (en) * 2018-11-13 2019-03-01 西安航天发动机有限公司 A kind of cutting fluid and its preparation method and application

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104694221A (en) * 2013-12-06 2015-06-10 北京有色金属研究总院 A lubricating and cooling liquid used for tantalum alloy machining and a preparing method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104694221A (en) * 2013-12-06 2015-06-10 北京有色金属研究总院 A lubricating and cooling liquid used for tantalum alloy machining and a preparing method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
牛茹轩等: "《废有机溶剂与废矿物油污染防治知识问答》", 31 May 2016, 冶金工业出版社 *
马贤智等: "《实用机械加工手册》", 28 February 2015, 辽宁科学技术出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109401811A (en) * 2018-11-13 2019-03-01 西安航天发动机有限公司 A kind of cutting fluid and its preparation method and application

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