CN106520338A - White alloy grinding process lubricant composition - Google Patents

White alloy grinding process lubricant composition Download PDF

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Publication number
CN106520338A
CN106520338A CN201610966134.8A CN201610966134A CN106520338A CN 106520338 A CN106520338 A CN 106520338A CN 201610966134 A CN201610966134 A CN 201610966134A CN 106520338 A CN106520338 A CN 106520338A
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China
Prior art keywords
lubricant compositions
agent
grinding technique
metal grinding
technique lubricant
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CN201610966134.8A
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Chinese (zh)
Inventor
黄福川
唐弓斌
陈帆
陈一帆
胡雄风
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Guangxi University
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Guangxi University
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Priority to CN201610966134.8A priority Critical patent/CN106520338A/en
Publication of CN106520338A publication Critical patent/CN106520338A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/288—Partial esters containing free carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/041—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving a condensation reaction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a white alloy grinding process lubricant composition. 22# total-loss system oil is adopted as base oil, and the base oil is matched with multiple composite additives. The white alloy grinding process lubricant composition is prepared from antioxidant, metal passivator, an oiliness agent, friction improver, an extreme pressure agent, an antiwear agent, an antirust agent, an anti-foaming agent, a demulsifying compound, a cooling accelerant, an oxidation and corrosion inhibitor, dispersant and the like. The white alloy grinding process lubricant composition is directly used in the lubricating course of the white alloy grinding process. The composition has good cooling performance, lubricity, anti-oxidation stability, diffusivity, cleaning performance, corrosion resistance, chip removal performance, low volatility, low oil mist performance, inhibition to scratches, bruises and solubility to paint and high thermal capacity.

Description

A kind of bidery metal grinding technique lubricant compositions
Technical field
A kind of bidery metal grinding technique lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Bidery metal is invented and gained the name by American's Babbitt, because of its existing white, is also called babbit.Including tin-base bearing Alloy and lead-base bearing alloy, are widely used.It has friction reduction characteristics, is unique material for being adapted to and rotating relative to soft axle Material, compared with other bearing materials, with more preferable adaptability and embedability, be widely used in big marine diesel engine, turbine, Alternating current generator, and other mining machineries and large rotating machinery etc..Its primary alloy constituent is stannum, lead, antimony, copper.Antimony, Copper, to improve alloy strength and hardness.
The tissue characteristic of babbit is that hard phase particle is uniform-distribution with soft phase matrix, and soft phase matrix has alloy Have extraordinary embedding Tibetan property, compliance and seizure resistance, and after break-in, soft matrix indent, Hard Inclusion evagination, make sliding surface it Between form minim gap, become store oil space and grease channel, beneficial to antifriction；Convex Hard Inclusion play supporting role, favorably In carrying.
According to GB：Babbit is divided to two kinds of tinbase and lead-containing alloy.The intensity and hardness of lead-containing alloy compares kamash alloy Low, corrosion resistance is also poor.Therefore, generally when using babbit, generally from kamash alloy.Lead-containing alloy is using comparing It is economical.
Grinding fluid is that one kind is used in the metal removal course of processing, industrial with workpiece for cooling down and lubricating cutter Liquid.Metal cutting is important mechanical processing toolses, and as used by which, cutting element type can be divided into two big class.One class is to use knife Tool carries out machining, and such as turning, drilling, boring, milling, wound is cut and broached；Another kind of is that the grinding carried out with abrasive material adds Work, such as grinding, the top gem of a girdle-pendant are cut, grinding and superfinishing etc..By processing severe arrangement, machining can be divided into 16 kinds, wherein Grinding ranks the first.Cutting lubricant is divided into two big class so as to use, that is, cut lubricant, be required for good cooling and profit Sliding effect, but two kinds of processing modes have basic difference.In grinding, grinding speed is up to more than 1000r/min, Temperature is more than 1100 DEG C, therefore it is required that there is higher cooling performance；In addition, grinding tool (such as emery wheel) hole is easily blocked, also therefore Need higher detergency.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of has that greasy property is excellent, dispersion cleansing power is strong, surface Highly polished, the anticorrosive cycle is long, easy to operate, cheap bidery metal grinding technique lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution：
A kind of bidery metal grinding technique lubricant compositions, using oil based on No. 22 total loss system oils, match somebody with somebody Close various compound additives, its each mass percent into being grouped into：
Component Mass percentage content
Base oil Surplus
Antioxidant 0.03%～0.2%
Metal deactivator 0.03%～0.2%
Oiliness improver 4%～8%
Friction improver 1%～3%
Extreme pressure agent 2%～4%
Antiwear additive 3%～5%
Antirust agent 0.08%～0.3%
Anti-foaming agent 10ppm～30ppm
Anti emulsifier 0.05%～0.3%
Urge cryogen 1%～2%
Oxidation and corrosion inhibitor 0.8%～1.5%
Dispersant 1%～4%
The mass percent summation of above each component is 100%.
Antioxidant is that the molybdenum naphthenate of 2, the 6- di-t-butyl mixed phenol T502 and 50% of mass ratio 50% is combined.
Metal deactivator is benzotriazole derivant T551.
Oiliness improver is Petiolus Trachycarpi oil.
Friction improver is two polyethers T402.
Extreme pressure agent is boronation phosphate ester T3011.
Antiwear additive is chlorinated paraffin T301.
Antirust agent be the methylbenzotrazole of mass ratio 50% and 50% alkenyl succinic acid half ester T747 be combined.
Anti-foaming agent is methyl-silicone oil T901.
Anti emulsifier is amine and epoxide condensation substance T1001.
Cryogen is urged to be petroleum sodium sulfonate T701.
Oxidation and corrosion inhibitor is double octyl group basic zinc salts T203 of sulfur phosphorus.
Dispersant is polyisobutylene succinamide T154A.
It is an advantage of the current invention that：The compositionss of the present invention have that greasy property is excellent, dispersion cleansing power is strong, surface light Cleanliness is high, the anticorrosive cycle is long, easy to operate, cheap.
Specific embodiment
Embodiment 1：
Following each component is pressed the mediation of row mass percent to form：
Component Mass percentage content
No. 22 total loss system oils Surplus
2,6- di-t-butyl mixed phenols (T502) of mass ratio 50% is combined with 50% molybdenum naphthenate 0.03%
Benzotriazole derivant (T551) 0.03%
Petiolus Trachycarpi oil 4%
Two polyethers (T402) 1%
Boronation phosphate ester (T3011) 2%
Chlorinated paraffin (T301) 3%
The methylbenzotrazole of mass ratio 50% and 50% alkenyl succinic acid half ester (T747) be combined 0.08%
Methyl-silicone oil (T901) 10ppm
Amine and epoxide condensation substance (T1001) 0.05%
Petroleum sodium sulfonate (T701) 1%
Double octyl groups basic zinc salt (T203) of sulfur phosphorus 0.8%
Polyisobutylene succinamide (T154A) 1%
Above each component mass percentage content summation is 100%.
Embodiment 2：
Following each component is pressed the mediation of row mass percent to form：
Component Mass percentage content
No. 22 total loss system oils Surplus
2,6- di-t-butyl mixed phenols (T502) of mass ratio 50% is combined with 50% molybdenum naphthenate 0.1%
Benzotriazole derivant (T551) 0.1%
Petiolus Trachycarpi oil 6%
Two polyethers (T402) 2%
Boronation phosphate ester (T3011) 3%
Chlorinated paraffin (T301) 4%
The methylbenzotrazole of mass ratio 50% and 50% alkenyl succinic acid half ester (T747) be combined 0.2%
Methyl-silicone oil (T901) 20ppm
Amine and epoxide condensation substance (T1001) 0.2%
Petroleum sodium sulfonate (T701) 1.5%
Double octyl groups basic zinc salt (T203) of sulfur phosphorus 1.2%
Polyisobutylene succinamide (T154A) 2%
Above each component mass percentage content summation is 100%.
Embodiment 3：
Following each component is pressed the mediation of row mass percent to form：
Component Mass percentage content
No. 22 total loss system oils Surplus
2,6- di-t-butyl mixed phenols (T502) of mass ratio 50% is combined with 50% molybdenum naphthenate 0.2%
Benzotriazole derivant (T551) 0.2%
Petiolus Trachycarpi oil 8%
Two polyethers (T402) 3%
Boronation phosphate ester (T3011) 4%
Chlorinated paraffin (T301) 5%
The methylbenzotrazole of mass ratio 50% and 50% alkenyl succinic acid half ester (T747) be combined 0.3%
Methyl-silicone oil (T901) 30ppm
Amine and epoxide condensation substance (T1001) 0.3%
Petroleum sodium sulfonate (T701) 2%
Double octyl groups basic zinc salt (T203) of sulfur phosphorus 1.5%
Polyisobutylene succinamide (T154A) 4%
Above each component mass percentage content summation is 100%.
The typical physiochemical techniques index of 1 product of embodiment：
The typical physiochemical techniques index of 2 product of embodiment：
The typical physiochemical techniques index of 3 product of embodiment：

Claims (10)

1. a kind of bidery metal grinding technique lubricant compositions, it is characterised in that：Adopt No. 22 total loss system oils for Base oil, coordinates various compound additives, its each mass percent into being grouped into：
Component Mass percentage content Base oil Surplus Antioxidant 0.03%～0.2% Metal deactivator 0.03%～0.2% Oiliness improver 4%～8% Friction improver 1%～3% Extreme pressure agent 2%～4% Antiwear additive 3%～5% Antirust agent 0.08%～0.3% Anti-foaming agent 10ppm～30ppm Anti emulsifier 0.05%～0.3% Urge cryogen 1%～2% Oxidation and corrosion inhibitor 0.8%～1.5% Dispersant 1%～4%
The mass percent summation of above each component is 100%.
2. a kind of bidery metal grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antioxidant is The molybdenum naphthenate of 2, the 6- di-t-butyl mixed phenol T502 and 50% of mass ratio 50% is combined.
3. a kind of bidery metal grinding technique lubricant compositions as claimed in claim 1, it is characterised in that metal deactivating Agent is benzotriazole derivant T551.
4. a kind of bidery metal grinding technique lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver is Petiolus Trachycarpi oil；Friction improver is two polyethers T402.
5. a kind of bidery metal grinding technique lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is Boronation phosphate ester T3011；Antiwear additive is chlorinated paraffin T301.
6. a kind of bidery metal grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is The methylbenzotrazole of mass ratio 50% and 50% alkenyl succinic acid half ester T747 be combined.
7. a kind of bidery metal grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti-foaming agent is Methyl-silicone oil T901；Anti emulsifier is amine and epoxide condensation substance T1001.
8. a kind of bidery metal grinding technique lubricant compositions as claimed in claim 1, it is characterised in that urge the cryogen to be Petroleum sodium sulfonate T701.
9. a kind of bidery metal grinding technique lubricant compositions as claimed in claim 1, it is characterised in that the anti-corruption of antioxygen Agent is double octyl group basic zinc salts T203 of sulfur phosphorus.
10. a kind of bidery metal grinding technique lubricant compositions as claimed in claim 1, it is characterised in that dispersant is Polyisobutylene succinamide T154A.
CN201610966134.8A 2016-11-04 2016-11-04 White alloy grinding process lubricant composition Withdrawn CN106520338A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103409205A (en) * 2013-08-26 2013-11-27 广西大学 Hot rolling lubricant for vanadium/vanadium alloy plate strip
CN103409204A (en) * 2013-08-26 2013-11-27 广西大学 Lubricant for cold-rolling of chromium/chromium alloy plate strip

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103409205A (en) * 2013-08-26 2013-11-27 广西大学 Hot rolling lubricant for vanadium/vanadium alloy plate strip
CN103409204A (en) * 2013-08-26 2013-11-27 广西大学 Lubricant for cold-rolling of chromium/chromium alloy plate strip

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
牛茹轩等: "《废有机溶剂与废矿物油污染防治知识问答》", 31 May 2016, 冶金工业出版社 *

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