CN106635300A - Environment-friendly titanium alloy Ti6A14V cutting fluid composition - Google Patents
Environment-friendly titanium alloy Ti6A14V cutting fluid composition Download PDFInfo
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
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- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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Abstract
The invention discloses an environment-friendly titanium alloy Ti6A14V cutting fluid composition. 75% of 5# total loss system oil and 25% of castor-based dioctyl sebacate are compounded to serve as base oil and matched with various compound additives including antioxidants, metal deactivators, oiliness agents, friction modifiers, extreme pressure agents, anti-wear agents, anti-foaming agents, anti-fogging agents, cooling accelerants, reinforcing agents, antioxidant preservatives and the like. The composition has good cooling property, lubricating property, bearing capacity, antifriction vibration damping property, cleaning and chip removal functions, rust protection property and antioxidant corrosion protection property, good defoaming property, rot resistance, low smell and no irritation.
Description
Technical field
The invention belongs to metal working lubricant field, more particularly to a kind of environmental friendliness titanium alloy T i6A14V cutting fluids
Composition.
Background technology
Because titanium alloy T i6A14V has superior mechanical performance characteristic, it is widely used in ocean engineering and aviation boat
The manufacture of its industrial construction package.It has a good specific strength, and the energy of high intensity is kept under stronger corrosion resistance and high temperature
Power.But titanium alloy T i6A14V is not only a kind of material for being difficult and being machined, and can cause knife in process
The Fast Wearing of tool.Abrasion is that the presence due to rubbing causes to produce loss or the surface material of energy in relative movement
The abrasion condition of material.If only macroscopically seeing, its contact surface is smooth, but from from thin sight, really between numerous micro-bulges
Interaction.
Titanium alloy T i6A14V materials have thermal conductivity factor low.At high temperature, the intensity and firmness change of material are little.Cause
This cutting resistance is big.Further, since its toughness is high, cutting is easily sticked, therefore is adding man-hour, cutter quick abrasion easily to collapse knife, workpiece
Surface quality is poor, the flaw such as crackle and the residual coefficient of built-up edge easily occurs.
The processing method of metal is various, but machining is most common, most widely used one kind all the time.Metal cutting is
Important mechanical processing toolses, by its cutting element type used two big class can be divided into;One class is that the cutting carried out with cutter adds
Work;Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of using the cutting element (knife with cutting edge
Tool or emery wheel) excess metal of workpiece is cut on stock-removing machine, so as to be that workpiece obtains regular geometry, size is smart
The processing method of degree and surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and in time removing.
The two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion that this friction is consumed is heat, it
Working (machining) efficiency and workpiece quality can be affected.Because serious friction produces substantial amounts of heat, make cutter and workpiece overheated, reduce cutter
In the life-span, affect Product Precision.In order to cool down and lubricating cutter and workpiece, it is necessary to produced with taking away cutting in time using cutting lubricant
Raw heat, reduces the temperature of cutter and workpiece and plays lubrication;Workpiece surface finish is improved, and extends making for cutter
Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be in the constant rubbing surface that moves repeatedly it
Between, despite pressure it is very big, but easily form lubricating oil film.And cut the fresh table that oil is then that constantly contact cutting is formed
Face, machined surface recurs elastic deformation, thus the pressure born between cutter and machined surface is bigger than general lubricating status
Much.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, bearing capacity, antifriction
Damping, cleaning and chip removal effect, antirust, antioxygen anticorrosion, good defoaming, anti-corrupt, low smell, nonirritant environment friend
The composition of good titanium alloy T i6A14V cutting fluids.
The present invention adopts the following technical scheme that solution above-mentioned technical problem:
A kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids, using No. 5 total loss systems of mass ratio 75%
With castor-oil plant base di-n-octyl sebacate of the oil with 25% it is compound based on oil, coordinate various compound additives, its respective quality hundred
Fraction into being grouped into:
Component | Mass percentage content |
Base oil | Surplus |
Antioxidant | 0.1%~0.6% |
Metal deactivator | 0.2%~1% |
Oiliness improver | 4%~6% |
Friction improver | 1%~3% |
Extreme pressure agent | 2%~5% |
Antiwear additive | 4%~6% |
Anti-foaming agent | 10~50ppm |
Antifoggant | 3%~4% |
Urge cryogen | 1%~6% |
Reinforcing agent | 3%~4% |
Antioxidant preservative | 0.5%~1.5% |
Above each component mass percent summation is 100%.
Antioxidant is that the conjunction copper antioxidant T541 and 2,6- di-t-butyl mixed phenols T502A of mass ratio 67% are combined;Metal
Passivator is benzotriazole derivative T551.
Oiliness improver is sulfurized olefin cotton oil T405;Friction improver is dialkyl dithiophosphoric acid oxygen molybdenum T462.
Extreme pressure agent is acid dibutyl phosphite T304;Antiwear additive is three polybutene of sulfuration;Anti-foaming agent is methyl-silicone oil
T901。
Antifoggant is ethylene-propylene copolymer T612;Cryogen is urged to be petroleum sodium sulfonate T702.
Reinforcing agent is chlorinated paraffin T302;Antioxidant preservative is dialkyl dithio amino formate.
The present invention composition advantage be:It is damping, clear with good cooling, lubricity, bearing capacity, antifriction
Wash and chip removal effect, it is antirust, antioxygen anticorrosion, good defoaming, anti-corrupt, low smell, nonirritant.
Specific embodiment
Embodiment 1:
Following each component is reconciled by mass percentage and is formed:
Component | Mass percentage content |
No. 5 total loss system oils of mass ratio 75% are combined with 25% castor-oil plant base di-n-octyl sebacate | Surplus |
Conjunction copper antioxidant (T541) of mass ratio 67% is combined with 2,6- di-t-butyl mixed phenols (T502A) | 0.1% |
Benzotriazole derivative (T551) | 1% |
Sulfurized olefin cotton oil (T405) | 4% |
Dialkyl dithiophosphoric acid oxygen molybdenum (T462) | 3% |
Acid dibutyl phosphite (T304) | 5% |
Vulcanize three polybutene | 5% |
Methyl-silicone oil (T901) | 50ppm |
Ethylene-propylene copolymer (T612) | 3% |
Petroleum sodium sulfonate (T702) | 4% |
Chlorinated paraffin (T302) | 4% |
Dialkyl dithio amino formate | 1% |
Above each component mass percent summation is 100%.
Embodiment 2:
Following each component is reconciled by mass percentage and is formed:
Component | Mass percentage content |
No. 5 total loss system oils of mass ratio 75% are combined with 25% castor-oil plant base di-n-octyl sebacate | 69.5% |
Conjunction copper antioxidant (T541) of mass ratio 67% is combined with 2,6- di-t-butyl mixed phenols (T502A) | 0.5% |
Benzotriazole derivative (T551) | 1% |
Sulfurized olefin cotton oil (T405) | 6% |
Dialkyl dithiophosphoric acid oxygen molybdenum (T462) | 1% |
Acid dibutyl phosphite (T304) | 5% |
Vulcanize three polybutene | 5% |
Methyl-silicone oil (T901) | 50ppm |
Ethylene-propylene copolymer (T612) | 4% |
Petroleum sodium sulfonate (T702) | 4% |
Chlorinated paraffin (T302) | 3% |
Dialkyl dithio amino formate | 1% |
Above each component mass percent summation is 100%.
Embodiment 3:
Following each component is reconciled by mass percentage and is formed:
Component | Mass percentage content |
No. 5 total loss system oils of mass ratio 75% are combined with 25% castor-oil plant base di-n-octyl sebacate | 70.4% |
Conjunction copper antioxidant (T541) of mass ratio 67% is combined with 2,6- di-t-butyl mixed phenols (T502A) | 0.6% |
Benzotriazole derivative (T551) | 1% |
Sulfurized olefin cotton oil (T405) | 5% |
Dialkyl dithiophosphoric acid oxygen molybdenum (T462) | 1% |
Acid dibutyl phosphite (T304) | 3% |
Vulcanize three polybutene | 6% |
Methyl-silicone oil (T901) | 50ppm |
Ethylene-propylene copolymer (T612) | 4% |
Petroleum sodium sulfonate (T702) | 5% |
Chlorinated paraffin (T302) | 3% |
Dialkyl dithio amino formate | 1% |
Above each component mass percent summation is 100%.
The main physical and chemical index of the product of embodiment 3:
Claims (7)
1. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids, it is characterised in that:Using No. 5 of mass ratio 75%
Oil based on castor-oil plant base di-n-octyl sebacate of the total loss system oil with 25% is compound, coordinates various compound additives, its
Each mass percent into being grouped into:
Above each component mass percent summation is 100%.
2. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that antioxygen
Agent is that the conjunction copper antioxidant T541 and 2,6- di-t-butyl mixed phenols T502A of mass ratio 67% are combined.
3. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that metal
Passivator is benzotriazole derivative T551.
4. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that oiliness
Agent is sulfurized olefin cotton oil T405;Friction improver is dialkyl dithiophosphoric acid oxygen molybdenum T462.
5. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that extreme pressure
Agent is acid dibutyl phosphite T304;Antiwear additive is three polybutene of sulfuration;Anti-foaming agent is methyl-silicone oil T901.
6. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that antifog
Agent is ethylene-propylene copolymer T612;Cryogen is urged to be petroleum sodium sulfonate T702.
7. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that reinforcement
Agent is chlorinated paraffin T302;Antioxidant preservative is dialkyl dithio amino formate.
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CN110982601A (en) * | 2019-11-05 | 2020-04-10 | 上海樱花化研化工科技有限公司 | Titanium alloy cutting fluid composition and preparation method thereof |
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CN102031190A (en) * | 2010-12-28 | 2011-04-27 | 东莞太平洋博高润滑油有限公司 | Cutting oil and preparation method thereof |
CN104152228A (en) * | 2014-08-30 | 2014-11-19 | 广西大学 | Composition of castor-based EC-2 hardened gear face cutting oil |
CN104194897A (en) * | 2014-08-30 | 2014-12-10 | 广西大学 | Composition of castor-based depth drilling and cutting fluid |
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Patent Citations (4)
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CN1235971A (en) * | 1999-05-12 | 1999-11-24 | 项品然 | Method for producing oil-soluble metal deactivator-benzothiazole derivative |
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