CN106635300A - Environment-friendly titanium alloy Ti6A14V cutting fluid composition - Google Patents

Environment-friendly titanium alloy Ti6A14V cutting fluid composition Download PDF

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CN106635300A
CN106635300A CN201610840980.5A CN201610840980A CN106635300A CN 106635300 A CN106635300 A CN 106635300A CN 201610840980 A CN201610840980 A CN 201610840980A CN 106635300 A CN106635300 A CN 106635300A
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titanium alloy
composition
i6a14v
agent
oil
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黄福川
肖锋
黄军
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Guangxi University
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Guangxi University
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024Propene
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
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    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
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    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
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    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64Environmental friendly compositions
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
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    • C10N2040/244Metal working of specific metals

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  • Oil, Petroleum & Natural Gas (AREA)
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  • Lubricants (AREA)

Abstract

The invention discloses an environment-friendly titanium alloy Ti6A14V cutting fluid composition. 75% of 5# total loss system oil and 25% of castor-based dioctyl sebacate are compounded to serve as base oil and matched with various compound additives including antioxidants, metal deactivators, oiliness agents, friction modifiers, extreme pressure agents, anti-wear agents, anti-foaming agents, anti-fogging agents, cooling accelerants, reinforcing agents, antioxidant preservatives and the like. The composition has good cooling property, lubricating property, bearing capacity, antifriction vibration damping property, cleaning and chip removal functions, rust protection property and antioxidant corrosion protection property, good defoaming property, rot resistance, low smell and no irritation.

Description

A kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids
Technical field
The invention belongs to metal working lubricant field, more particularly to a kind of environmental friendliness titanium alloy T i6A14V cutting fluids Composition.
Background technology
Because titanium alloy T i6A14V has superior mechanical performance characteristic, it is widely used in ocean engineering and aviation boat The manufacture of its industrial construction package.It has a good specific strength, and the energy of high intensity is kept under stronger corrosion resistance and high temperature Power.But titanium alloy T i6A14V is not only a kind of material for being difficult and being machined, and can cause knife in process The Fast Wearing of tool.Abrasion is that the presence due to rubbing causes to produce loss or the surface material of energy in relative movement The abrasion condition of material.If only macroscopically seeing, its contact surface is smooth, but from from thin sight, really between numerous micro-bulges Interaction.
Titanium alloy T i6A14V materials have thermal conductivity factor low.At high temperature, the intensity and firmness change of material are little.Cause This cutting resistance is big.Further, since its toughness is high, cutting is easily sticked, therefore is adding man-hour, cutter quick abrasion easily to collapse knife, workpiece Surface quality is poor, the flaw such as crackle and the residual coefficient of built-up edge easily occurs.
The processing method of metal is various, but machining is most common, most widely used one kind all the time.Metal cutting is Important mechanical processing toolses, by its cutting element type used two big class can be divided into;One class is that the cutting carried out with cutter adds Work;Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of using the cutting element (knife with cutting edge Tool or emery wheel) excess metal of workpiece is cut on stock-removing machine, so as to be that workpiece obtains regular geometry, size is smart The processing method of degree and surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and in time removing. The two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion that this friction is consumed is heat, it Working (machining) efficiency and workpiece quality can be affected.Because serious friction produces substantial amounts of heat, make cutter and workpiece overheated, reduce cutter In the life-span, affect Product Precision.In order to cool down and lubricating cutter and workpiece, it is necessary to produced with taking away cutting in time using cutting lubricant Raw heat, reduces the temperature of cutter and workpiece and plays lubrication;Workpiece surface finish is improved, and extends making for cutter Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be in the constant rubbing surface that moves repeatedly it Between, despite pressure it is very big, but easily form lubricating oil film.And cut the fresh table that oil is then that constantly contact cutting is formed Face, machined surface recurs elastic deformation, thus the pressure born between cutter and machined surface is bigger than general lubricating status Much.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, bearing capacity, antifriction Damping, cleaning and chip removal effect, antirust, antioxygen anticorrosion, good defoaming, anti-corrupt, low smell, nonirritant environment friend The composition of good titanium alloy T i6A14V cutting fluids.
The present invention adopts the following technical scheme that solution above-mentioned technical problem:
A kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids, using No. 5 total loss systems of mass ratio 75% With castor-oil plant base di-n-octyl sebacate of the oil with 25% it is compound based on oil, coordinate various compound additives, its respective quality hundred Fraction into being grouped into:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.1%~0.6%
Metal deactivator 0.2%~1%
Oiliness improver 4%~6%
Friction improver 1%~3%
Extreme pressure agent 2%~5%
Antiwear additive 4%~6%
Anti-foaming agent 10~50ppm
Antifoggant 3%~4%
Urge cryogen 1%~6%
Reinforcing agent 3%~4%
Antioxidant preservative 0.5%~1.5%
Above each component mass percent summation is 100%.
Antioxidant is that the conjunction copper antioxidant T541 and 2,6- di-t-butyl mixed phenols T502A of mass ratio 67% are combined;Metal Passivator is benzotriazole derivative T551.
Oiliness improver is sulfurized olefin cotton oil T405;Friction improver is dialkyl dithiophosphoric acid oxygen molybdenum T462.
Extreme pressure agent is acid dibutyl phosphite T304;Antiwear additive is three polybutene of sulfuration;Anti-foaming agent is methyl-silicone oil T901。
Antifoggant is ethylene-propylene copolymer T612;Cryogen is urged to be petroleum sodium sulfonate T702.
Reinforcing agent is chlorinated paraffin T302;Antioxidant preservative is dialkyl dithio amino formate.
The present invention composition advantage be:It is damping, clear with good cooling, lubricity, bearing capacity, antifriction Wash and chip removal effect, it is antirust, antioxygen anticorrosion, good defoaming, anti-corrupt, low smell, nonirritant.
Specific embodiment
Embodiment 1:
Following each component is reconciled by mass percentage and is formed:
Component Mass percentage content
No. 5 total loss system oils of mass ratio 75% are combined with 25% castor-oil plant base di-n-octyl sebacate Surplus
Conjunction copper antioxidant (T541) of mass ratio 67% is combined with 2,6- di-t-butyl mixed phenols (T502A) 0.1%
Benzotriazole derivative (T551) 1%
Sulfurized olefin cotton oil (T405) 4%
Dialkyl dithiophosphoric acid oxygen molybdenum (T462) 3%
Acid dibutyl phosphite (T304) 5%
Vulcanize three polybutene 5%
Methyl-silicone oil (T901) 50ppm
Ethylene-propylene copolymer (T612) 3%
Petroleum sodium sulfonate (T702) 4%
Chlorinated paraffin (T302) 4%
Dialkyl dithio amino formate 1%
Above each component mass percent summation is 100%.
Embodiment 2:
Following each component is reconciled by mass percentage and is formed:
Component Mass percentage content
No. 5 total loss system oils of mass ratio 75% are combined with 25% castor-oil plant base di-n-octyl sebacate 69.5%
Conjunction copper antioxidant (T541) of mass ratio 67% is combined with 2,6- di-t-butyl mixed phenols (T502A) 0.5%
Benzotriazole derivative (T551) 1%
Sulfurized olefin cotton oil (T405) 6%
Dialkyl dithiophosphoric acid oxygen molybdenum (T462) 1%
Acid dibutyl phosphite (T304) 5%
Vulcanize three polybutene 5%
Methyl-silicone oil (T901) 50ppm
Ethylene-propylene copolymer (T612) 4%
Petroleum sodium sulfonate (T702) 4%
Chlorinated paraffin (T302) 3%
Dialkyl dithio amino formate 1%
Above each component mass percent summation is 100%.
Embodiment 3:
Following each component is reconciled by mass percentage and is formed:
Component Mass percentage content
No. 5 total loss system oils of mass ratio 75% are combined with 25% castor-oil plant base di-n-octyl sebacate 70.4%
Conjunction copper antioxidant (T541) of mass ratio 67% is combined with 2,6- di-t-butyl mixed phenols (T502A) 0.6%
Benzotriazole derivative (T551) 1%
Sulfurized olefin cotton oil (T405) 5%
Dialkyl dithiophosphoric acid oxygen molybdenum (T462) 1%
Acid dibutyl phosphite (T304) 3%
Vulcanize three polybutene 6%
Methyl-silicone oil (T901) 50ppm
Ethylene-propylene copolymer (T612) 4%
Petroleum sodium sulfonate (T702) 5%
Chlorinated paraffin (T302) 3%
Dialkyl dithio amino formate 1%
Above each component mass percent summation is 100%.
The main physical and chemical index of the product of embodiment 3:

Claims (7)

1. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids, it is characterised in that:Using No. 5 of mass ratio 75% Oil based on castor-oil plant base di-n-octyl sebacate of the total loss system oil with 25% is compound, coordinates various compound additives, its Each mass percent into being grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.1%~0.6% Metal deactivator 0.2%~1% Oiliness improver 4%~6% Friction improver 1%~3% Extreme pressure agent 2%~5% Antiwear additive 4%~6% Anti-foaming agent 10~50ppm Antifoggant 3%~4% Urge cryogen 1%~6% Reinforcing agent 3%~4% Antioxidant preservative 0.5%~1.5%
Above each component mass percent summation is 100%.
2. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that antioxygen Agent is that the conjunction copper antioxidant T541 and 2,6- di-t-butyl mixed phenols T502A of mass ratio 67% are combined.
3. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that metal Passivator is benzotriazole derivative T551.
4. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that oiliness Agent is sulfurized olefin cotton oil T405;Friction improver is dialkyl dithiophosphoric acid oxygen molybdenum T462.
5. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that extreme pressure Agent is acid dibutyl phosphite T304;Antiwear additive is three polybutene of sulfuration;Anti-foaming agent is methyl-silicone oil T901.
6. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that antifog Agent is ethylene-propylene copolymer T612;Cryogen is urged to be petroleum sodium sulfonate T702.
7. a kind of composition of environmental friendliness titanium alloy T i6A14V cutting fluids as claimed in claim 1, it is characterised in that reinforcement Agent is chlorinated paraffin T302;Antioxidant preservative is dialkyl dithio amino formate.
CN201610840980.5A 2016-09-21 2016-09-21 Environment-friendly titanium alloy Ti6A14V cutting fluid composition Pending CN106635300A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110982601A (en) * 2019-11-05 2020-04-10 上海樱花化研化工科技有限公司 Titanium alloy cutting fluid composition and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1235971A (en) * 1999-05-12 1999-11-24 项品然 Method for producing oil-soluble metal deactivator-benzothiazole derivative
CN102031190A (en) * 2010-12-28 2011-04-27 东莞太平洋博高润滑油有限公司 Cutting oil and preparation method thereof
CN104152228A (en) * 2014-08-30 2014-11-19 广西大学 Composition of castor-based EC-2 hardened gear face cutting oil
CN104194897A (en) * 2014-08-30 2014-12-10 广西大学 Composition of castor-based depth drilling and cutting fluid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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Application publication date: 20170510