CN106433928A - Environment-friendly aluminum and aluminum alloy cutting fluid composition - Google Patents

Environment-friendly aluminum and aluminum alloy cutting fluid composition Download PDF

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Publication number
CN106433928A
CN106433928A CN201610841031.9A CN201610841031A CN106433928A CN 106433928 A CN106433928 A CN 106433928A CN 201610841031 A CN201610841031 A CN 201610841031A CN 106433928 A CN106433928 A CN 106433928A
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CN
China
Prior art keywords
aluminum
cutting fluid
aluminum alloy
agent
alloy cutting
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610841031.9A
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Chinese (zh)
Inventor
黄福川
张姗姗
潘发存
胡雄风
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Guangxi University
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Guangxi University
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Priority to CN201610841031.9A priority Critical patent/CN106433928A/en
Publication of CN106433928A publication Critical patent/CN106433928A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/14—Metal deactivation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18—Anti-foaming property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/34—Fragrance or deodorizing properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/76—Reduction of noise, shudder, or vibrations
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses environment-friendly aluminum and aluminum alloy cutting fluid composition which is characterized by adopting No. 15 total-loss system oil as base oil, being matched with various compound additives and comprising an antioxidant, a metal deactivator, an oiliness agent, a friction modifier, an anti-foaming agent, an extreme pressure agent, an anti-wear agent, an antirust agent, a cooling accelerant, a surfactant, a coupling agent, a bactericide and an assistant emulsifier. The composition disclosed by the invention has the advantages of being environment-friendly, high in bearing capacity, easy to diffuse, large in heat capacity, good in antirust property, good in cleaning property, low in foam, long in service life and difficult to stink, and waste liquid meets the standard to be discharged after treatment.

Description

A kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss
Technical field
The invention belongs to cutting fluid field, particularly to a kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss.
Background technology
Aluminium alloy density is low, but intensity is higher, and near or above high-quality steel, plasticity is good, can be processed into various section bars, tool Have excellent electric conductivity, heat conductivity and a corrosion stability, industrial widely use, usage amount is only second to steel.Some aluminium alloys can be adopted Obtain good mechanical performance, physical property and corrosion resistance with heat treatment.In Aeronautics and Astronautics, automobile, machine-building, ship Widely apply in oceangoing ship and chemical industry.
With the extensive application of aluminum and aluminium alloy, its processing capacity also quickly increases, aluminum and aluminum alloy cutting fluid consumption Increasing.The enhancing to environmental protection consciousness for the people, proposes higher requirement to the feature of environmental protection of the working fluid after using.Simultaneously because The health requirements of working space and safety standard carry mark and also propose new requirement to cutting fluid.
It has environmental friendliness, bearing capacity is high, be easy to diffusion, thermal capacity is big, rust-preventing characteristic is good, cleaning is good, low bubble, length Life-span, be difficult smelly, waste liquid in process qualified discharge.
The processing method of metal is various, but machining is most common all the time, most widely used one kind.Metal cutting is Important mechanical processing toolses, as used by it, cutting element type can be divided into two big class；One class is to be added with the cutting that cutter is carried out Work；Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of using the cutting element (knife with cutting edge Tool or emery wheel) on stock-removing machine, the excess metal of workpiece is cut, from but workpiece obtain rule geometry, size essence Degree and the processing method of surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and timely removing. This two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion that this friction consumes is heat, it Working (machining) efficiency and workpiece quality can be affected.Because serious friction produces substantial amounts of heat, make cutter and workpiece overheated, reduce cutter In the life-span, affect Product Precision.In order to cool down and lubricating cutter and workpiece it is necessary to produce to take away cutting in time using cutting lubricant Raw heat, reduces the temperature of cutter and workpiece and plays lubrication；Improve workpiece surface finish, and extend making of cutter Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be at the constant rubbing surface that moves repeatedly it Between, despite pressure very big, but easily formed lubricating oil film.And cut the fresh table that oil is then that constantly contact cutting is formed Face, machined surface recurs elastic deformation, thus the pressure being born between cutter and machined surface is bigger than general lubricating status Much.Lubricating oil is required to have good cooling, lubricity, bearing capacity, antifriction vibration damping, cleaning and chip removal effect, and Antirust, antioxygen anticorrosion, defoaming, anti-corrupt, low abnormal smells from the patient, nonirritant.
Content of the invention
The technical problem to be solved in the present invention is to provide a kind of environmental friendliness, bearing capacity height, be easy to diffusion, thermal capacity Greatly, rust-preventing characteristic is good, cleaning is good, low bubble, long-life, be difficult smelly, and waste liquid is in processing the environmental friendliness aluminum of qualified discharge and aluminum Alloy cutting fluid composite.
The present invention adopts the following technical scheme that solution above-mentioned technical problem：
A kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss, using oil based on No. 15 total loss system oil, Coordinate multiple compound additives, the one-tenth of its respective mass percent is grouped into：
Component Mass percentage content
Base oil Surplus
Antioxidant 0.03%～0.2%
Metal deactivator 0.03%～0.1%
Oiliness improver 2%～3%
Friction improver 4%～6%
Anti-foaming property 20～60ppm
Extreme pressure agent 2%～8%
Antiwear additive 3%～5%
Antirust agent 0.05%～0.2%
Urge cryogen 0.08%～0.3%
Surfactant 10%～18%
Coupling agent 1%～2%
Antibacterial 0.02%～0.1%
Co-emulsifier 0.5%～2%
Each constituent mass percentage ratio summation is 100% above.
Antioxidant is butyl octyl diphenylamines T557；Metal deactivator be mass ratio 50% benzotriazole derivant T551 with 50% DBPC 2,6 ditertiary butyl p cresol T501 is combined.
Oiliness improver is oleic acid glycol ester T403A；Friction improver is ethyl oleate.
Anti-foaming property is methyl-silicone oil；Extreme pressure agent is sulfuration cottonseed oil T405.
Antiwear additive is the sulfide isobutene T321 of mass ratio 50% and 50% high base number calcium mahogany sulfonate T103 is combined；Anti- Rust agent is the BTA T706 and 50% of mass ratio 50% is that heptadecenyl imidazolidene succinate T703 is combined.
Cryogen is urged to be petroleum sodium sulfonate；Surfactant is the tall oil diglycollic amide of mass ratio 33% and 67% mistake Water sorbitan oleate class is combined；Coupling agent is poly- propanol；
Antibacterial is the 1,4- morpholine of mass ratio 50% and 50% triazine Starcide BK is combined；Help breast Agent is alcohol ether carboxylate Staradd HW35.
The advantage of the present composition is：There is environmental friendliness, bearing capacity is high, be easy to diffusion, thermal capacity is big, antirust Property good, cleaning is good, low bubble, long-life, be difficult smelly, waste liquid in process qualified discharge.
Specific embodiment
Embodiment 1：
Following component is in harmonious proportion by mass percentage and forms：
Each constituent mass percentage ratio summation is 100% above.
Embodiment 2：
Following component is in harmonious proportion by mass percentage and forms：
Each constituent mass percentage ratio summation is 100% above.
Embodiment 3：
Following component is in harmonious proportion by mass percentage and forms：
Each constituent mass percentage ratio summation is 100% above.
The main physical and chemical index of embodiment 3 product：

Claims (8)

1. a kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss it is characterised in that：Made using No. 15 total loss system oil Based on oil, coordinate multiple compound additives, the one-tenth of its respective mass percent is grouped into：
Component Mass percentage content Base oil Surplus Antioxidant 0.03%～0.2% Metal deactivator 0.03%～0.1% Oiliness improver 2%～3% Friction improver 4%～6% Anti-foaming property 20～60ppm Extreme pressure agent 2%～8% Antiwear additive 3%～5% Antirust agent 0.05%～0.2% Urge cryogen 0.08%～0.3% Surfactant 10%～18% Coupling agent 1%～2% Antibacterial 0.02%～0.1% Co-emulsifier 0.5%～2%
Each constituent mass percentage ratio summation is 100% above.
2. as claimed in claim 1 a kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss it is characterised in that antioxidant is Butyl octyl diphenylamines T557.
3. as claimed in claim 1 a kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss it is characterised in that metal deactivating Agent is benzotriazole derivant T551 of mass ratio 50% and 50% DBPC 2,6 ditertiary butyl p cresol T501 is combined.
4. as claimed in claim 1 a kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss it is characterised in that oiliness improver is Oleic acid glycol ester T403A；Friction improver is ethyl oleate.
5. as claimed in claim 1 a kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss it is characterised in that anti-foaming property is Methyl-silicone oil；Extreme pressure agent is sulfuration cottonseed oil T405.
6. as claimed in claim 1 a kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss it is characterised in that antiwear additive is The sulfide isobutene T321 of mass ratio 50% and 50% high base number calcium mahogany sulfonate T103 be combined；Antirust agent is mass ratio 50% BTA T706 and 50% be heptadecenyl imidazolidene succinate T703 be combined.
7. as claimed in claim 1 a kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss it is characterised in that urging the cryogen to be Petroleum sodium sulfonate；Surfactant is the tall oil diglycollic amide of mass ratio 33% and 67% sorbitan monooleate class Compound；Coupling agent is poly- propanol.
8. as claimed in claim 1 a kind of environmental friendliness aluminum and aluminum alloy cutting fluid compositionss it is characterised in that antibacterial is The 1,4- morpholine of mass ratio 50% and 50% triazine Starcide BK be combined；Co-emulsifier is alcohol ether carboxylate Staradd HW35.
CN201610841031.9A 2016-09-21 2016-09-21 Environment-friendly aluminum and aluminum alloy cutting fluid composition Pending CN106433928A (en)

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CN106433928A true CN106433928A (en) 2017-02-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108998176A (en) * 2018-07-20 2018-12-14 广东顺德中海源富环保科技有限公司 A kind of aluminum alloy cutting fluid and preparation method thereof
CN110699157A (en) * 2019-10-18 2020-01-17 中科孚迪科技发展有限公司 Cutting oil for titanium alloy processing and preparation method thereof
CN112646644A (en) * 2019-10-10 2021-04-13 中国石油化工股份有限公司 Long-life hard water resistant cutting oil composition, preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102311864A (en) * 2011-08-05 2012-01-11 安庆市中天石油化工有限公司 Cutting fluid special for NC machine tools
CN104046484A (en) * 2014-06-29 2014-09-17 青岛国强环保科技有限公司 Special cutting fluid for machine tools
CN104694221A (en) * 2013-12-06 2015-06-10 北京有色金属研究总院 A lubricating and cooling liquid used for tantalum alloy machining and a preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102311864A (en) * 2011-08-05 2012-01-11 安庆市中天石油化工有限公司 Cutting fluid special for NC machine tools
CN104694221A (en) * 2013-12-06 2015-06-10 北京有色金属研究总院 A lubricating and cooling liquid used for tantalum alloy machining and a preparing method thereof
CN104046484A (en) * 2014-06-29 2014-09-17 青岛国强环保科技有限公司 Special cutting fluid for machine tools

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108998176A (en) * 2018-07-20 2018-12-14 广东顺德中海源富环保科技有限公司 A kind of aluminum alloy cutting fluid and preparation method thereof
CN112646644A (en) * 2019-10-10 2021-04-13 中国石油化工股份有限公司 Long-life hard water resistant cutting oil composition, preparation method and application thereof
CN110699157A (en) * 2019-10-18 2020-01-17 中科孚迪科技发展有限公司 Cutting oil for titanium alloy processing and preparation method thereof
CN110699157B (en) * 2019-10-18 2021-09-21 中科孚迪科技发展有限公司 Cutting oil for titanium alloy processing and preparation method thereof

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Application publication date: 20170222