CN106520318A - Lubricant composition for zircaloy cutting treatment technology - Google Patents
Lubricant composition for zircaloy cutting treatment technology Download PDFInfo
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- CN106520318A CN106520318A CN201610963554.0A CN201610963554A CN106520318A CN 106520318 A CN106520318 A CN 106520318A CN 201610963554 A CN201610963554 A CN 201610963554A CN 106520318 A CN106520318 A CN 106520318A
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/2805—Esters used as base material
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/283—Esters of polyhydroxy compounds
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C10M2215/086—Imides
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/09—Complexes with metals
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- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/72—Extended drain
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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Abstract
The invention discloses a lubricant composition for a zircaloy cutting treatment technology. The 50% of poly alpha-alkene and 50% of ester oil Radia7543 are composited as base oil according to the mass ratio, and the base oil is cooperated with a plurality of composite additives which comprise an anti-oxidant, a metal passivator, an oiliness agent, a friction improver, an extreme pressure agent, an anti-grinding agent, an anti-foaming agent, an emulsion inhibitor, a dispersant, a cooling accelerant, and an oxidation and corrosion inhibitor. The composition has good cooling performance, lubricity, bearing capability, antifriction and vibration damping, cleaning and chip removal effects, and has the characteristics of rust removal, antioxidant anticorrosion, defoaming performance, anti-corrosion, low smell, and no irritation.
Description
Technical field
A kind of zircaloy cutting technology lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Zircaloy can be with resistance to very high temperature, as the ground floor containment vessel for making nuclear reaction.The thermal capture of zirconium cuts
Face is little, has prominent nuclearity energy, is the indispensable material of development atomic energy industry, adds other elements composition by base of zirconium
Alloy, is refractory metal material that a class is widely used in nuclear reactor.Zirconium powder easy firing in atmosphere, can make detonating primer and nothing
Pyrotechnic composition.Zirconium is a kind of rare metal, with spies such as surprising corrosion resistance, high fusing point, the hardness of superelevation and intensity
Property, it is widely used in Aero-Space, military project, nuclear reaction, atomic energy field.The plasticity of zirconium is good, it is easy to be processed into plate, silk etc..
Zirconium can absorb the gases such as oxygen, hydrogen, nitrogen in large quantities in heating, can be used as hydrogen storage material.
The processing method of metal is various, but machining is most common, most widely used one kind all the time.Metal cutting is
Important mechanical processing toolses, as used by which, cutting element type can be divided into two big class;One class is that the cutting carried out with cutter adds
Work;Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of using the cutting element (knife with cutting edge
Tool or emery wheel) excess metal of workpiece is cut on stock-removing machine, so as to be that workpiece obtains regular geometry, size is smart
The processing method of degree and surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and in time removing.
The two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion that this friction is consumed is heat, it
Working (machining) efficiency and workpiece quality can be affected.As serious friction produces substantial amounts of heat, make cutter and workpiece overheated, reduce cutter
In the life-span, affect Product Precision.In order to cool down and lubricate cutter and workpiece, it is necessary to produced with taking away cutting in time using cutting lubricant
Raw heat, reduces the temperature of cutter and workpiece and plays lubrication;Workpiece surface finish is improved, and extends making for cutter
Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be in the constant rubbing surface that moves repeatedly it
Between, despite pressure it is very big, but easily form lubricating oil film.And cut the fresh table that oil is then that constantly contact cutting is formed
Face, machined surface recur elastic deformation, thus the pressure born between cutter and machined surface is bigger than general lubricating status
Much.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, bearing capacity, antifriction
Vibration damping, cleaning and chip removal effect, antirust, antioxygen anticorrosion, defoaming, anti-corrupt, low smell, nonirritant zircaloy cutting
Processing technology lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of zircaloy cutting technology lubricant compositions, using mass ratio 50% poly alpha olefin and 50% ester
Oil based on class oil (Radia7543) is compound, coordinates various compound additives, its each mass percent into being grouped into:
Component | Mass percentage content |
Base oil | Surplus |
Antioxidant | 0.05%~0.2% |
Metal deactivator | 0.1%~0.3% |
Oiliness improver | 4.0%~8.0% |
Friction improver | 0.5%~2.0% |
Extreme pressure agent | 3.0%~5.0% |
Antiwear additive | 4.0%~6.0% |
Anti-foaming agent | 10~30ppm |
Anti emulsifier | 0.05%~0.2% |
Dispersant | 1.0%~4.0% |
Urge cryogen | 1.0%~2.0% |
Oxidation and corrosion inhibitor | 0.8%~1.2% |
The mass percent summation of above each component is 100%.
Antioxidant be dialkyl diphenylamine T534 of mass ratio 50% and 50% sulfenyl phenolate T504 be combined;
Metal deactivator is thiadiazole.
Oiliness improver is oleic acid binaryglycol ester T403B;Friction improver is benzotriazole aliphatic acid amine salt T406.
Extreme pressure agent is acid dibutyl phosphite T304;Antiwear additive is sulfide isobutene T321.
Anti-foaming agent is ethyl silicon oil;Anti emulsifier is polyether high molecular compound DL32.
Dispersant is polyisobutene succinimide T155;Cryogen is urged to be petroleum sodium sulfonate.
Oxidation and corrosion inhibitor is dialkyldithiocarbamacompositions sulfuration oxygen molybdenum MoPTC.
It is an advantage of the current invention that:
There is the composition of the present invention good cooling, lubricity, bearing capacity, antifriction vibration damping, cleaning and chip removal to make
With, antirust, antioxygen anticorrosion, defoaming, anti-corrupt, low smell, nonirritant;High intensity, heat-resisting alloy material can be improved
Cutting, shaping efficiency, improve cutting-tool's used life and workpiece quality;Ensure chip, the industry security of tapping process simultaneously
And protection.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
The poly alpha olefin of mass ratio 50% and 50% Esters oil (Radia7543) be combined | Surplus |
The dialkyl diphenylamine (T534) of mass ratio 50% and 50% sulfenyl phenolate (T504) are compound | 0.06% |
Thiadiazole | 0.12% |
Oleic acid binaryglycol ester (T403B) | 4.05% |
Benzotriazole aliphatic acid amine salt (T406) | 0.65% |
Acid dibutyl phosphite (T304) | 3.29% |
Sulfide isobutene (T321) | 4.2% |
Ethyl silicon oil | 20ppm |
Polyether high molecular compound (DL32) | 0.06% |
Polyisobutene succinimide (T155) | 1.15% |
Petroleum sodium sulfonate | 1.16% |
Dialkyldithiocarbamacompositions vulcanize oxygen molybdenum MoPTC | 0.96% |
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
The poly alpha olefin of mass ratio 50% and 50% Esters oil (Radia7543) be combined | Surplus |
The dialkyl diphenylamine (T534) of mass ratio 50% and 50% sulfenyl phenolate (T504) are compound | 0.12% |
Thiadiazole | 0.18% |
Oleic acid binaryglycol ester (T403B) | 5.05% |
Benzotriazole aliphatic acid amine salt (T406) | 0.95% |
Acid dibutyl phosphite (T304) | 4.29% |
Sulfide isobutene (T321) | 5.2% |
Ethyl silicon oil | 25ppm |
Polyether high molecular compound (DL32) | 0.16% |
Polyisobutene succinimide (T155) | 2.15% |
Petroleum sodium sulfonate | 1.0% |
Dialkyldithiocarbamacompositions vulcanize oxygen molybdenum MoPTC | 1.0% |
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
The key technical indexes of 3 product of embodiment:
The key technical indexes of 2 product of embodiment:
The key technical indexes of 1 product of embodiment:
Claims (7)
1. a kind of zircaloy cutting technology lubricant compositions, it is characterised in that:Using the poly alpha olefin of mass ratio 50%
Based on compound with 50% Esters oil Radia7543, oil, coordinates various compound additives, its each mass percent into
It is grouped into:
The mass percent summation of above each component is 100%.
2. a kind of zircaloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antioxidant is
Dialkyl diphenylamine T534 of mass ratio 50% and 50% sulfenyl phenolate T504 be combined;Metal deactivator is thiadiazole.
3. a kind of zircaloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver is
Oleic acid binaryglycol ester T403B;Friction improver is benzotriazole fatty acid ammonium salt T406.
4. a kind of zircaloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is
Acid dibutyl phosphite T304;Antiwear additive is sulfide isobutene T321.
5. a kind of zircaloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that anti-foaming agent is
Ethyl silicon oil;Anti emulsifier is polyether high molecular compound DL32.
6. a kind of zircaloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that;Dispersant is
Polyisobutene succinimide T155;Cryogen is urged to be petroleum sodium sulfonate.
7. a kind of zircaloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that the anti-corruption of antioxygen
Agent is dialkyldithiocarbamacompositions sulfuration oxygen molybdenum MoPTC.
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CN109504506A (en) * | 2018-12-06 | 2019-03-22 | 汎宇化学(昆山)有限公司 | Water insoluble cutting oil and preparation method thereof |
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