CN106544125A - A kind of White brass alloy cutting technology lubricant compositions - Google Patents

A kind of White brass alloy cutting technology lubricant compositions Download PDF

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Publication number
CN106544125A
CN106544125A CN201610963527.3A CN201610963527A CN106544125A CN 106544125 A CN106544125 A CN 106544125A CN 201610963527 A CN201610963527 A CN 201610963527A CN 106544125 A CN106544125 A CN 106544125A
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brass alloy
cutting technology
lubricant compositions
alloy cutting
white brass
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CN201610963527.3A
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黄福川
黄显昆
赵金城
胡雄风
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Guangxi University
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Guangxi University
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/16Naphthenic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/50Emission or smoke controlling properties
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/74Noack Volatility
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of White brass alloy cutting technology lubricant compositions, using oil based on HVIS150 base oils, coordinate various compound additives.Including:Antioxidant, metal deactivator, oiliness improver, friction improver, extreme pressure agent, antiwear additive, antirust agent, anti-foaming agent, anti emulsifier, filler etc..It is directly used in the greasing of White brass alloy cutting technology.The composition of the present invention has good cooling, lubricity, wellability, diffusivity, cleaning, anti-corrosive properties, rust-preventing characteristic, chip resistance, low volatility, low oil fume; be conducive to cutter protection and improve stock-removing efficiency; thermal capacity is big; the good intermiscibility to paint; surface smoothness is high; anticorrosive, usage cycles are long.

Description

A kind of White brass alloy cutting technology lubricant compositions
Technical field
A kind of White brass alloy cutting technology lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Copper-nickel alloy is the acid bronze alloy with nickel as main adding elements, is silvery white in color, and has metallic luster, therefore named copper-nickel alloy.Cupro-nickel Between each other can infinitely solid solution, so as to form continuous solid solution, no matter that is, mutual ratio is how many, and it is permanent be α-single-phase alloy. When nickel is fused in red metal, when content is more than more than 16%, the alloy color and luster of generation just becomes pure white such as silver, and nickel content is higher, Color is whiter.In copper-nickel alloy, the content of nickel is generally 25%.Pure copper plus nickel can significantly improve intensity, corrosion resistance, hardness, resistance and heat Electrically, and be easy to plastotype, processing and weld[6], and reduce temperature coefficient of resistivity.Therefore copper-nickel alloy is compared with the machinery of other copper alloys Performance, physical property are all abnormal good, ductility is good, hardness is high, color and luster is attractive in appearance, it is corrosion-resistant, be rich in deep drawability, extensively made For fields such as shipbuilding, petrochemical industry, electrical equipment, instrument, medicine equipment, building, electric power, commodity, musical instrument making, handicrafts, And or important resistance and thermocouple metal.
The processing method of metal is various, but machining is most common, most widely used one kind all the time.Metal cutting is Important mechanical processing toolses, as used by which, cutting element type can be divided into two big class;One class is that the cutting carried out with cutter adds Work;Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of using the cutting element (knife with cutting edge Tool or emery wheel) excess metal of workpiece is cut on stock-removing machine, so as to be that workpiece obtains regular geometry, size is smart The processing method of degree and surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and in time removing. The two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion that this friction is consumed is heat, it Working (machining) efficiency and workpiece quality can be affected.As serious friction produces substantial amounts of heat, make cutter and workpiece overheated, reduce cutter In the life-span, affect Product Precision.In order to cool down and lubricate cutter and workpiece, it is necessary to produced with taking away cutting in time using cutting lubricant Raw heat, reduces the temperature of cutter and workpiece and plays lubrication;Workpiece surface finish is improved, and extends making for cutter Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be in the constant rubbing surface that moves repeatedly it Between, despite pressure it is very big, but easily form lubricating oil film.And cut the fresh table that oil is then that constantly contact cutting is formed Face, machined surface recur elastic deformation, thus the pressure born between cutter and machined surface is bigger than general lubricating status Much.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, wellability, diffusion Property, cleaning, anti-corrosive properties, rust-preventing characteristic, chip resistance, low volatility, low oil fume, be conducive to cutter protection and improve cutting effect Rate, thermal capacity are big, and the good intermiscibility to paint, surface smoothness are high, anticorrosive, the White brass alloy cutting of usage cycles length Processing technology lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of White brass alloy cutting technology lubricant compositions, using oil based on HVIS150 base oils, coordinate many Kind of compound additive, its each mass percent into being grouped into:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.02%~0.3%
Metal deactivator 0.05%~0.2%
Oiliness improver 3%~6%
Friction improver 0.5%~1%
Extreme pressure agent 2%~4%
Antiwear additive 3%~5%
Antirust agent 0.05%~0.3%
Anti-foaming agent 10ppm~30ppm
Anti emulsifier 0.05%~0.3%
Filler 1%~4%
The mass percent summation of above each component is 100%.
Antioxidant is that 2, the 6- di-t-butyl mixed phenols T502 of the cupric antioxidant T541 and 50% of mass ratio 50% is combined.
Metal deactivator is that the thiadiazole of the benzotriazole derivative T551 and 50% of mass ratio 50% is combined.
Oiliness improver is rapeseed oil.
Friction improver is benzotriazole aliphatic acid ammonia salt T406.
Extreme pressure agent is tricresyl phosphate T306.
Antiwear additive is chlorinated paraffin T301.
Antirust agent is that the lanolin of the zinc naphthenate T704 and 50% of mass ratio 50% is combined.
Anti-foaming agent is methyl-silicone oil T901.
Anti emulsifier is amine and epoxide condensation product T1001.
Filler is atoleine.
It is an advantage of the current invention that:The present invention composition have good cooling, lubricity, wellability, diffusivity, Cleaning, anti-corrosive properties, rust-preventing characteristic, chip resistance, low volatility, low oil fume, are conducive to cutter protection and improve stock-removing efficiency, heat Capacity is big, and the good intermiscibility to paint, surface smoothness are high, and anticorrosive, usage cycles are long.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
The typical physiochemical techniques index of 1 product of embodiment:
The typical physiochemical techniques index of 2 product of embodiment:
The typical physiochemical techniques index of 3 product of embodiment:

Claims (9)

1. a kind of White brass alloy cutting technology lubricant compositions, it is characterised in that:Based on HVIS150 base oils Oil, coordinates various compound additives, its each mass percent into being grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.02%~0.3% Metal deactivator 0.05%~0.2% Oiliness improver 3%~6% Friction improver 0.5%~1% Extreme pressure agent 2%~4% Antiwear additive 3%~5% Antirust agent 0.05%~0.3% Anti-foaming agent 10ppm~30ppm Anti emulsifier 0.05%~0.3% Filler 1%~4%
The mass percent summation of above each component is 100%.
2. a kind of White brass alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antioxidant Be mass ratio 50% cupric antioxidant T541 and 50% 2,6- di-t-butyl mixed phenols T502 be combined.
3. a kind of White brass alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that metal subtracts Agent living is that the thiadiazole of the benzotriazole derivative T551 and 50% of mass ratio 50% is combined.
4. a kind of White brass alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver It is rapeseed oil.
5. a kind of White brass alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that friction changes It is benzotriazole aliphatic acid ammonia salt T406 to enter agent.
6. a kind of White brass alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent It is tricresyl phosphate T306.
7. a kind of White brass alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antiwear additive It is chlorinated paraffin T301;Antirust agent is that the lanolin of the zinc naphthenate T704 and 50% of mass ratio 50% is combined.
8. a kind of White brass alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that anti-foaming agent It is methyl-silicone oil T901;Anti emulsifier is amine and epoxide condensation product T1001.
9. a kind of White brass alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that filler It is atoleine.
CN201610963527.3A 2016-11-04 2016-11-04 A kind of White brass alloy cutting technology lubricant compositions Withdrawn CN106544125A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86103006A (en) * 1986-04-28 1987-01-24 武汉机床厂 The powerful mill (cutting) that is shaped of a kind of high speed is cut does not have burn cooling-lubricant and preparation method
CN1548507A (en) * 2003-05-24 2004-11-24 启东尤希路化学工业有限公司 Water insoluble cutting oil
CN101240209A (en) * 2008-03-12 2008-08-13 益田润石(北京)化工有限公司 Multifunctional metal cutting oil composition
CN103710085A (en) * 2013-11-19 2014-04-09 广西大学 Cold rolling lubricant for silver and silver alloy foil
CN105001961A (en) * 2015-07-20 2015-10-28 广西大学 Zirconium rod rotary swaging lubricant composition
CN105238523A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Half-plant type pure-oil-based cutting oil and application thereof
CN105524688A (en) * 2014-09-29 2016-04-27 天津隆德精密机械有限公司 Extreme pressure cutting oil used for achieving performance stability in metal processing and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86103006A (en) * 1986-04-28 1987-01-24 武汉机床厂 The powerful mill (cutting) that is shaped of a kind of high speed is cut does not have burn cooling-lubricant and preparation method
CN1548507A (en) * 2003-05-24 2004-11-24 启东尤希路化学工业有限公司 Water insoluble cutting oil
CN101240209A (en) * 2008-03-12 2008-08-13 益田润石(北京)化工有限公司 Multifunctional metal cutting oil composition
CN103710085A (en) * 2013-11-19 2014-04-09 广西大学 Cold rolling lubricant for silver and silver alloy foil
CN105524688A (en) * 2014-09-29 2016-04-27 天津隆德精密机械有限公司 Extreme pressure cutting oil used for achieving performance stability in metal processing and preparation method thereof
CN105001961A (en) * 2015-07-20 2015-10-28 广西大学 Zirconium rod rotary swaging lubricant composition
CN105238523A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Half-plant type pure-oil-based cutting oil and application thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
熊云等: "《油品应用及管理》", 30 May 2004, 中国石化出版社 *

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Application publication date: 20170329