CN106520303A - Lubricant composition for molybdenum alloy cutting machining technology - Google Patents

Lubricant composition for molybdenum alloy cutting machining technology Download PDF

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CN106520303A
CN106520303A CN201610962491.7A CN201610962491A CN106520303A CN 106520303 A CN106520303 A CN 106520303A CN 201610962491 A CN201610962491 A CN 201610962491A CN 106520303 A CN106520303 A CN 106520303A
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molybdenum alloy
alloy cutting
lubricant compositions
cutting technology
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黄福川
胡雄风
唐弓斌
黄显昆
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Guangxi University
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Guangxi University
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • C10M2215/065Phenyl-Naphthyl amines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086Imides
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/041Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving a condensation reaction
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049Phosphite
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
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    • C10M2290/00Mixtures of base materials or thickeners or additives
    • C10M2290/04Synthetic base oils
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals

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  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a lubricant composition for a molybdenum alloy cutting machining technology. The lubricant composition is prepared by adopting 50% by mass of 7# total-loss system oil and 50% by mass of a poly-alpha-olefin compound as basic oil and cooperating with multiple composite additives including an antioxidant, a metal deactivator, an oiliness agent, a friction modifying agent, an extreme pressure agent, an antiwear agent, an antirust agent, a dispersing agent, an anti-foaming agent, a demulsifying agent, a cooling accelerant, an oxidation and a corrosion inhibitor and the like. The composition has the good cooling property, lubricating property, diffusing property, cleaning property, anti-corrosive property, chip removal property, low volatility and low smokiness, the intermiscibility with paint and the high thermal capacity.

Description

A kind of molybdenum alloy cutting technology lubricant compositions
Technical field
A kind of molybdenum alloy cutting technology lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Molybdenum alloy adds other elements and the non-ferrous alloy that constituted based on molybdenum.Main alloy element have titanium, zirconium, hafnium, Tungsten and rare earth element.Molybdenum alloy has good heat conduction, electric conductivity and the low coefficient of expansion, and (1100~1650 DEG C) have at high temperature High intensity, is easily worked than tungsten.Can be used as the grid and anode of electron tube, the backing material of electric light source, and be used to make Die casting and extrusion die, parts of spacecraft etc..The main reinforcing approach of molybdenum alloy is solution strengthening, precipitation strength and processing Hardening.Molybdenum alloy sheet material, band, foil, tubing, bar, wire rod and section bar can be obtained by plastic working, moreover it is possible to improve which strong Spend and improve cold plasticity.
The processing method of metal is various, but machining is most common, most widely used one kind all the time.Metal cutting is Important mechanical processing toolses, as used by which, cutting element type can be divided into two big class;One class is that the cutting carried out with cutter adds Work;Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of using the cutting element (knife with cutting edge Tool or emery wheel) excess metal of workpiece is cut on stock-removing machine, so as to be that workpiece obtains regular geometry, size is smart The processing method of degree and surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and in time removing. The two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion that this friction is consumed is heat, it Working (machining) efficiency and workpiece quality can be affected.As serious friction produces substantial amounts of heat, make cutter and workpiece overheated, reduce cutter In the life-span, affect Product Precision.In order to cool down and lubricate cutter and workpiece, it is necessary to produced with taking away cutting in time using cutting lubricant Raw heat, reduces the temperature of cutter and workpiece and plays lubrication;Workpiece surface finish is improved, and extends making for cutter Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be in the constant rubbing surface that moves repeatedly it Between, despite pressure it is very big, but easily form lubricating oil film.And cut the fresh table that oil is then that constantly contact cutting is formed Face, machined surface recur elastic deformation, thus the pressure born between cutter and machined surface is bigger than general lubricating status Much.It requires that lubricant has good cooling, lubricity, bearing capacity, antifriction vibration damping, cleaning and chip removal effect, It is antirust, antioxygen anticorrosion, defoaming, anti-corrupt, low smell, nonirritant, high intensity, heat-resisting, anti-corrosion, heat resistanceheat resistant oxygen can be improved and closed The cutting of golden material, shaping efficiency, improve cutting-tool's used life and workpiece quality;Simultaneously ensure chip, tapping process Industry security and protection.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, diffusivity, cleaning Property, anti-corrosive properties, chip resistance, low volatility, low smoke and to paint intermiscibility, the big molybdenum alloy machining of thermal capacity Technology lubricant composition.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of molybdenum alloy cutting technology lubricant compositions, using No. 7 total loss system oils of mass ratio 50% Based on compound with 50% poly alpha olefin, oil, coordinates various compound additives, its each mass percent into being grouped into:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.1%~0.2%
Metal deactivator 0.05%~0.2%
Oiliness improver 4.0%~8.0%
Friction improver 1.0%~2.0%
Extreme pressure agent 3.0%~5.0%
Antiwear additive 4.0%~6.0%
Antirust agent 0.05%~0.2%
Dispersant 1.0%~3.0%
Anti-foaming agent 10~30ppm
Anti emulsifier 0.05%~0.2%
Urge cryogen 1.0%~3.0%
Oxidation and corrosion inhibitor 0.8%~1.5%
The mass percent summation of above each component is 100%.
Antioxidant be the N- PAs of mass ratio 50% and 50% alkyl monosulfide T504 be combined;
Metal deactivator is that the thiadiazole of the thiadiazoles derivative T561 and 50% of mass ratio 50% is combined.
Oiliness improver is palm oil;Friction improver is sulphur molybdenum phosphate T461.
Extreme pressure agent is acid dibutyl phosphite T304;Antiwear additive is sulfide isobutene T321.
Antirust agent is that the wool grease of the alkenyl succinic acid half fat T747 and 50% of mass ratio 50% is combined;
Dispersant is polyene-based succimide T153.
Anti-foaming agent is methyl-silicone oil;Anti emulsifier is amine and epoxide condensation product T1001.
Cryogen is urged to be petroleum sodium sulfonate T702;Oxidation and corrosion inhibitor is molybdenum dithiophosphate MoDTP.
The remarkable advantage of the present invention:The composition of the present invention have good cooling, lubricity (extreme pressure carry wear-resistant), Diffusivity, cleaning, anti-corrosive properties, chip resistance, low volatility, low smoke and the intermiscibility to painting, thermal capacity are big;Can carry High high intensity, heat-resisting, the anti-corrosion, cutting of heat resistanceheat resistant oxygen alloy material, shaping efficiency, improve cutting-tool's used life and workpiece matter Amount;Ensure chip, the industry security of tapping process and protection simultaneously.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
No. 7 total loss system oils of mass ratio 50% and 50% poly alpha olefin are compound Surplus
The N- PAs of mass ratio 50% and 50% alkyl monosulfide (T504) be combined 0.18%
The thiadiazoles derivative (T561) of mass ratio 50% and 50% thiadiazole are compound 0.07%
Palm oil 4.05%
Sulphur molybdenum phosphate (T461) 1.9%
Acid dibutyl phosphite (T304) 3.29%
Sulfide isobutene (T321) 4.2%
Half fat of the alkenyl succinic acid (T747) of mass ratio 50% and 50% wool grease are compound 0.15%
Polyene-based succimide (T153) 1.34%
Methyl-silicone oil 20ppm
Amine and epoxide condensation product (T1001) 0.16%
Petroleum sodium sulfonate (T702) 1.16%
Molybdenum dithiophosphate (MoDTP) 0.9%
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
No. 7 total loss system oils of mass ratio 50% and 50% poly alpha olefin are compound Surplus
The N- PAs of mass ratio 50% and 50% alkyl monosulfide (T504) be combined 0.11%
The thiadiazoles derivative (T561) of mass ratio 50% and 50% thiadiazole are compound 0.17%
Palm oil 5.05%
Sulphur molybdenum phosphate (T461) 1.0%
Acid dibutyl phosphite (T304) 4.29%
Sulfide isobutene (T321) 5.21%
Half fat of the alkenyl succinic acid (T747) of mass ratio 50% and 50% wool grease are compound 0.1%
Polyene-based succimide (T153) 2.34%
Methyl-silicone oil 25ppm
Amine and epoxide condensation product (T1001) 0.18%
Petroleum sodium sulfonate (T702) 2.16%
Molybdenum dithiophosphate (MoDTP) 1.19%
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
No. 7 total loss system oils of mass ratio 50% and 50% poly alpha olefin are compound Surplus
The N- PAs of mass ratio 50% and 50% alkyl monosulfide (T504) be combined 0.13%
The thiadiazoles derivative (T561) of mass ratio 50% and 50% thiadiazole are compound 0.15%
Palm oil 7.05%
Sulphur molybdenum phosphate (T461) 1.5%
Acid dibutyl phosphite (T304) 4.79%
Sulfide isobutene (T321) 5.93%
Half fat of the alkenyl succinic acid (T747) of mass ratio 50% and 50% wool grease are compound 0.12%
Polyene-based succimide (T153) 2.74%
Methyl-silicone oil 27ppm
Amine and epoxide condensation product (T1001) 0.14%
Petroleum sodium sulfonate (T702) 2.66%
Molybdenum dithiophosphate (MoDTP) 1.39%
Above each component mass percentage content summation is 100%.
The key technical indexes of 3 product of embodiment:
The key technical indexes of 2 product of embodiment:
The key technical indexes of 1 product of embodiment:

Claims (7)

1. a kind of molybdenum alloy cutting technology lubricant compositions, it is characterised in that:Using No. 7 total loss of mass ratio 50% System oil and 50% poly alpha olefin it is compound based on oil, coordinate various compound additives, its respective mass percent Into being grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.1%~0.2% Metal deactivator 0.05%~0.2% Oiliness improver 4.0%~8.0% Friction improver 1.0%~2.0% Extreme pressure agent 3.0%~5.0% Antiwear additive 4.0%~6.0% Antirust agent 0.05%~0.2% Dispersant 1.0%~3.0% Anti-foaming agent 10~30ppm Anti emulsifier 0.05%~0.2% Urge cryogen 1.0%~3.0% Oxidation and corrosion inhibitor 0.8%~1.5%
The mass percent summation of above each component is 100%.
2. a kind of molybdenum alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antioxidant is The N- PAs of mass ratio 50% and 50% alkyl monosulfide T504 are compound;Metal deactivator is the thiophene of mass ratio 50% The thiadiazole of oxadiazole derivative T561 and 50% is combined.
3. a kind of molybdenum alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver is Palm oil;Friction improver is sulphur molybdenum phosphate T461.
4. a kind of molybdenum alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is Acid dibutyl phosphite T304;Antiwear additive is sulfide isobutene T321.
5. a kind of molybdenum alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is The wool grease of the alkenyl succinic acid half fat T747 and 50% of mass ratio 50% is combined;Dispersant is polyene-based succimide T153。
6. a kind of molybdenum alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that anti-foaming agent is Methyl-silicone oil;Anti emulsifier is amine and epoxide condensation product T1001.
7. a kind of molybdenum alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that urge the cryogen to be Petroleum sodium sulfonate T702;Oxidation and corrosion inhibitor is molybdenum dithiophosphate MoDTP.
CN201610962491.7A 2016-11-04 2016-11-04 Lubricant composition for molybdenum alloy cutting machining technology Withdrawn CN106520303A (en)

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Application publication date: 20170322