CN106544122A - A kind of permalloy cutting technology lubricant compositions - Google Patents

A kind of permalloy cutting technology lubricant compositions Download PDF

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Publication number
CN106544122A
CN106544122A CN201610962501.7A CN201610962501A CN106544122A CN 106544122 A CN106544122 A CN 106544122A CN 201610962501 A CN201610962501 A CN 201610962501A CN 106544122 A CN106544122 A CN 106544122A
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permalloy
lubricant compositions
cutting technology
technology lubricant
agent
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黄福川
邓富康
李康春
唐弓斌
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Guangxi University
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Guangxi University
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • C10M2219/068Thiocarbamate metal salts
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
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    • C10M2290/00Mixtures of base materials or thickeners or additives
    • C10M2290/04Synthetic base oils
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/76Reduction of noise, shudder, or vibrations
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals

Abstract

The invention discloses a kind of permalloy cutting technology lubricant compositions, oil based on being combined using No. 5 technical white oils of mass ratio 50% and 50% polyalphaolefin, coordinate various compound additives.Including:Antioxidant, metal deactivator, oiliness improver, friction improver, extreme pressure agent, antiwear additive, oxidation and corrosion inhibitor, dispersant, urge cryogen, anti-foaming agent, antirust agent, anti emulsifier etc..The composition of the present invention has good cooling, lubricity, bearing capacity, antifriction vibration damping, cleaning and a chip removal effect, antirust, antioxygen anticorrosion, defoaming, anti-corrupt, low smell, nonirritant.

Description

A kind of permalloy cutting technology lubricant compositions
Technical field
A kind of permalloy cutting technology lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Permalloy refers to iron-nickel alloy, the wide range of its nickel content, between 35%-90%.The maximum of permalloy Feature is with very high low-intensity magnetic field permeability.Their saturation induction density is typically between 0.6--1.0T.Permalloy It is a kind of iron-nickel alloy for having higher magnetic conductivity under compared with low-intensity magnetic field, dilval of the nickel content more than 30%, in room temperature Shi Douwei single-phase face-centered cubic (γ) structure, but the phase structure near 30%Ni is very unstable, therefore the iron nickel of practicality Magnetically soft alloy, nickel content is all more than 36%.Iron-nickel alloy near nickeliferous 75% (atomic fraction), the meeting in this single-phase alloy Generation Ni3Fe long-range orders change, at this moment the lattice constant and physical property of alloy, and such as resistivity and magnetic etc. can all occur to become Change.Therefore, impact of the ordering transition to performance is considered.Generally in Ni3The additional elements such as a small amount of Mo or Cu are added in Fe alloys, To suppress the generation of long-range order.
The processing method of metal is various, but machining is most common, most widely used one kind all the time.Metal cutting is Important mechanical processing toolses, as used by which, cutting element type can be divided into two big class;One class is that the cutting carried out with cutter adds Work;Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of using the cutting element (knife with cutting edge Tool or emery wheel) excess metal of workpiece is cut on stock-removing machine, so as to be that workpiece obtains regular geometry, size is smart The processing method of degree and surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and in time removing. The two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion that this friction is consumed is heat, it Working (machining) efficiency and workpiece quality can be affected.As serious friction produces substantial amounts of heat, make cutter and workpiece overheated, reduce cutter In the life-span, affect Product Precision.In order to cool down and lubricate cutter and workpiece, it is necessary to produced with taking away cutting in time using cutting lubricant Raw heat, reduces the temperature of cutter and workpiece and plays lubrication;Workpiece surface finish is improved, and extends making for cutter Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be in the constant rubbing surface that moves repeatedly it Between, despite pressure it is very big, but easily form lubricating oil film.And cut the fresh table that oil is then that constantly contact cutting is formed Face, machined surface recur elastic deformation, thus the pressure born between cutter and machined surface is bigger than general lubricating status Much.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, bearing capacity, antifriction Vibration damping, cleaning and chip removal effect, antirust, antioxygen anticorrosion, defoaming, anti-corrupt, low smell, nonirritant permalloy are cut Cut processing technology lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of permalloy cutting technology lubricant compositions, using mass ratio 50% No. 5 technical white oils and Oil based on 50% poly alpha olefin is compound, coordinates various compound additives, its each mass percent into being grouped into:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.05%~0.2%
Metal deactivator 0.03%~0.5%
Oiliness improver 3.0%~8.0%
Friction improver 1.0%~2.0%
Extreme pressure agent 4.0%~6.0%
Antiwear additive 3.0%~5.0%
Oxidation and corrosion inhibitor 0.5%~1.0%
Dispersant 2.0%~3.0%
Urge cryogen 0.05%~0.2%
Anti-foaming agent 10~50ppm
Antirust agent 0.05%~0.3%
Anti emulsifier 0.05%~0.2%
The mass percent summation of above each component is 100%.
Antioxidant is the N of the 2,6- di-t-butyl mixed phenol T502 and 50% of mass ratio 50%, N- Asias salicylic acid phenylenediamine It is compound;
Metal deactivator is benzotriazole derivative T551.Oiliness improver is sulfuration cottonseed oil;Friction improver is sulphur molybdenum phosphate T461。
Extreme pressure agent is chlorinated paraffin T302.Antiwear additive is sulfide isobutene T321.
Oxidation and corrosion inhibitor is oil control property dialkyldithiocarbamacompositions sulfuration oxygen molybdenum MoPTC;
Dispersant is polyisobutene succinimide T154A.Cryogen is urged to be petroleum sodium sulfonate T762;Anti-foaming agent is methyl silicon Oil.
Antirust agent is that the alkenyl succinic acid T746 of the BTA T706 and 50% of mass ratio 50% is combined;
Anti emulsifier is polyethers macromolecular compound DL32.
A kind of remarkable advantage of permalloy cutting technology lubricant compositions of the present invention has:Good cooling, profit Sliding (extreme-pressure anti-wear carryings), diffusion, cleaning, anti-corrosion, low volatility, deslagging, thermal capacity greatly, have no irritating odor and to painting Intermiscibility.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
The mass percent summation of above each component is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
The mass percent summation of above each component is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
The mass percent summation of above each component is 100%.
The key technical indexes of 1 product of embodiment:
The key technical indexes of 2 product of embodiment:
The key technical indexes of 3 product of embodiment:

Claims (7)

1. a kind of permalloy cutting technology lubricant compositions, it is characterised in that:It is industrial using No. 5 of mass ratio 50% White oil and 50% poly alpha olefin it is compound based on oil, coordinate various compound additives, the composition of its respective mass percent Composition:
Component Mass percentage content Base oil Surplus Antioxidant 0.05%~0.2% Metal deactivator 0.03%~0.5% Oiliness improver 3.0%~8.0% Friction improver 1.0%~2.0% Extreme pressure agent 4.0%~6.0% Antiwear additive 3.0%~5.0% Oxidation and corrosion inhibitor 0.5%~1.0% Dispersant 2.0%~3.0% Urge cryogen 0.05%~0.2% Anti-foaming agent 10~50ppm Antirust agent 0.05%~0.3% Anti emulsifier 0.05%~0.2%
The mass percent summation of above each component is 100%.
2. a kind of permalloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antioxidant It is the N of the 2,6- di-t-butyl mixed phenol T502 and 50% of mass ratio 50%, N- Asias salicylic acid phenylenediamine is combined;Metal deactivator It is benzotriazole derivative T551.
3. a kind of permalloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver It is sulfuration cottonseed oil;Friction improver is sulphur molybdenum phosphate T461.
4. a kind of permalloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent It is chlorinated paraffin T302;Antiwear additive is sulfide isobutene T321.
5. a kind of permalloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antioxygen resists Rotten agent is oil-soluble dialkyldithiocarbamacompositions sulfuration oxygen molybdenum MoPTC;Dispersant is polyisobutene succinimide T154A。
6. a kind of permalloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that urge cryogen It is petroleum sodium sulfonate T762;Anti-foaming agent is methyl-silicone oil.
7. a kind of permalloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antirust agent Be mass ratio 50% BTA T706 and 50% alkenyl succinic acid T746 be combined;Anti emulsifier is polyethers family macromolecule Compound DL32.
CN201610962501.7A 2016-11-04 2016-11-04 A kind of permalloy cutting technology lubricant compositions Pending CN106544122A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101415807A (en) * 2006-03-31 2009-04-22 新日本石油株式会社 Polyfunctional hydrocarbon oil composition

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101415807A (en) * 2006-03-31 2009-04-22 新日本石油株式会社 Polyfunctional hydrocarbon oil composition

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Application publication date: 20170329