CN106635295A - Lubricant composition for rolling processing of cast carbon steel - Google Patents

Lubricant composition for rolling processing of cast carbon steel Download PDF

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Publication number
CN106635295A
CN106635295A CN201610840658.2A CN201610840658A CN106635295A CN 106635295 A CN106635295 A CN 106635295A CN 201610840658 A CN201610840658 A CN 201610840658A CN 106635295 A CN106635295 A CN 106635295A
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CN
China
Prior art keywords
carbon steel
steel rolling
cast carbon
lubricant oil
processing lubricant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610840658.2A
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Chinese (zh)
Inventor
黄福川
黄显昆
赵金城
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Guangxi University
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Guangxi University
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Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201610840658.2A priority Critical patent/CN106635295A/en
Publication of CN106635295A publication Critical patent/CN106635295A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/09—Complexes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18—Anti-foaming property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel

Abstract

The invention discloses a lubricant composition for rolling processing of cast carbon steel; HVIS 150 is used as base oil along with various composite additives, including an antioxidant, an oiliness agent, a friction improver, an extreme pressure agent, an anti-wear agent, an antifoaming agent, an antioxidant preservative, an antirust agent and the like. The composition of the invention has excellent extreme pressure bearing and anti-wear properties, lowered friction coefficient and increased lubrication coefficient, and has cooling performance, diffusivity, detergent-dispersant performance, antirust property, oxidation stability, foaming resistance, emulsifying resistance, and washability.

Description

A kind of cast carbon steel rolling and processing lubricant oil composite
Technical field
The invention belongs to metal working lubricant field, more particularly to a kind of cast carbon steel rolling and processing lubricating oil composition Thing.
Background technology
Cast steel is the general name for producing the ferrous alloy of foundry goods that eutectic transformation is not suffered from process of setting.Casting Carbon steel is with carbon as main alloy element, and containing the cast steel of a small amount of elemental gas.Cast carbon steel.With carbon as major alloy Element and the cast steel containing a small amount of other elements.Less than 0.2% to cast mild steel, carbon containing 0.2%～0.5% is carbon containing Casting medium carbon steel, carbon containing is more than 0.5% to cast high-carbon steel.With the increase of phosphorus content, the intensity of cast carbon steel increases, firmly Degree is improved.Cast carbon steel has higher intensity, plasticity and toughness, and cost is relatively low, bears greatly for manufacture in heavy-duty machinery The part of load
Now machinery manufacturing industry develops just towards high accuracy, at high speed with high-power, digitized direction.Therefore to machinery The requirement of the material, machining accuracy and workmanship of part also more and more higher.And for improve machinery part surface quality and The hydraulic pressure processing technology of its physics, mechanical performance is improved, is widely applied.In hydraulic pressure processing, existed using hydraulic tool Under normal temperature state, pressure is applied to component surface, make matallic surface layer produce plastic deformation, amendment component surface microcosmic is put down Whole degree, to improve surface smoothness.At the same time it can also change the metallographic structure of component surface, favourable residual stress is formed Distribution, so as to improving the mechanical performance of parts and using service life.Rolling processing process cannot be only used for finishing and reinforcing Outer ring, endoporus and plane, and it is also applied to finishing and reinforcing screw thread, gear curved surface and various types of special surfaces etc..
In rolling technology using lubricant be in order to reduce the frictional force of roller and workpiece, so as to reduce rolling process in institute The power of consumption, improves the service life of roller and the surface smoothness of parts, and lubrication must firmly supply abundance during rolling, no Can interruption；In good time the processed part of cooling, reduces the generation of thermal stress effects.Therefore, rolling technology lubricant must have There is good extreme pressure to carry wear resistence, reduce coefficient of friction, improve slide coefficient, good cooling, diffusivity, peace and quiet dispersion Property, rust-preventing characteristic, oxidation stability, anti-foaming property, resistance to emulsion and cleaning.Good manufacturability (the welding that workpiece has Property and cold formability), it is adaptable to common engineering structure and standard machinery parts.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good extreme pressure carrying wear resistence, reduction friction system Number, raising slide coefficient, good cooling, diffusivity, detergent-dispersant performance, rust-preventing characteristic, oxidation stability, anti-foaming property, anti-breast The cast carbon steel rolling and processing lubricant oil composite of the property changed and cleaning.
The present invention employs the following technical solutions solution above-mentioned technical problem：
A kind of cast carbon steel rolling and processing lubricant oil composite, using oil based on the base oils of HVIS 150, coordinates many Kind of compound additive, its each mass percent into being grouped into：
Component Mass percentage content
Base oil Surplus
Antioxidant 0.05%～0.2%
Oiliness improver 6%～10%
Friction improver 0.5%～1.5%
Extreme pressure agent 4%～6%
Antiwear additive 3%～5%
Anti-foaming agent 30～50ppm
Oxidation and corrosion inhibitor 0.8%～1.2%
Antirust agent 0.1%～0.5%
Above each component mass percent summation is 100%.
Antioxidant is the butyl octyl diphenylamines T557 of the DBPC 2,6 ditertiary butyl p cresol T501 and 50% of mass ratio 50% It is compound.
Oiliness improver is rapeseed oil.Friction improver is phosphorus-nitrogen compound T452.Extreme pressure agent is chlorinated paraffin T301.
Antiwear additive is sulfide isobutene T321.Anti-foaming agent is methyl-silicone oil.
Oxidation and corrosion inhibitor is Sulphurized Oxymolybdenum Dialkylthiophosphate MoPTC.
Antirust agent is the compound of the alkyl phosphoric acid imidazoline salt T708 of the barium mahogany sulfonate T701 and 50% of mass ratio 50%.
The beneficial effects of the present invention is：There is the present composition good extreme pressure to carry wear resistence, reduce friction system Number, raising slide coefficient, good cooling, diffusivity, detergent-dispersant performance, rust-preventing characteristic, oxidation stability, anti-foaming property, anti-breast The property changed and cleaning.
Specific embodiment
Embodiment 1：
Following each component is reconciled by mass percentage and is formed：
Above each component mass percent summation is 100%.
Embodiment 2：
Following each component is reconciled by mass percentage and is formed：
Above each component mass percent summation is 100%.
Embodiment 3：
Following each component is reconciled by mass percentage and is formed：
Above each component mass percent summation is 100%.
The product typical technology index of embodiment 2：
Project Index
40 DEG C of kinematic viscosity mm2/s 32.6
Flash-point (opening)/DEG C 198
Pour point/DEG C -15
Corrosion experiment (copper sheet, 100 DEG C, 3h)/level 1
Oxidation stability (Rotary Oxygen elasticity, 150 DEG C) min 304
Tetra-ball machine test Pb/N 696
Sintering load PD/N 4210
Terraced nurse agrees/N 278
FZG, level 13
Mechanical admixture, % 0.008
Moisture, % Vestige
Water soluble acid or alkali Nothing
24 DEG C of foaming characteristics test 150/0
96℃ 100/0
24 DEG C afterwards 100/0
54 DEG C of demulsification number (40-40-0) 8
Evaporation loss (Angelika Noack method, 250 DEG C, 1h) (m), % 11

Claims (9)

1. a kind of cast carbon steel rolling and processing lubricant oil composite, it is characterised in that：Based on the base oils of HVIS 150 Oil, coordinates various compound additives, its each mass percent into being grouped into：
Component Mass percentage content Base oil Surplus Antioxidant 0.05%～0.2% Oiliness improver 6%～10% Friction improver 0.5%～1.5% Extreme pressure agent 4%～6% Antiwear additive 3%～5% Anti-foaming agent 30～50ppm Oxidation and corrosion inhibitor 0.8%～1.2% Antirust agent 0.1%～0.5%
Above each component mass percent summation is 100%.
2. a kind of cast carbon steel rolling and processing lubricant oil composite as claimed in claim 1, it is characterised in that antioxidant is matter The butyl octyl diphenylamines T557's of DBPC 2,6 ditertiary butyl p cresol T501 and 50% of the amount than 50% is compound.
3. a kind of cast carbon steel rolling and processing lubricant oil composite as claimed in claim 1, it is characterised in that oiliness improver is dish Seed oil.
4. a kind of cast carbon steel rolling and processing lubricant oil composite as claimed in claim 1, it is characterised in that friction improver It is phosphorus-nitrogen compound T452.
5. a kind of cast carbon steel rolling and processing lubricant oil composite as claimed in claim 1, it is characterised in that extreme pressure agent is chlorine Fossil waxes T301.
6. a kind of cast carbon steel rolling and processing lubricant oil composite as claimed in claim 1, it is characterised in that antiwear additive is sulphur Change isobutene T321.
7. a kind of cast carbon steel rolling and processing lubricant oil composite as claimed in claim 1, it is characterised in that anti-foaming agent is first Base silicone oil.
8. a kind of cast carbon steel rolling and processing lubricant oil composite as claimed in claim 1, it is characterised in that oxidation and corrosion inhibitor It is Sulphurized Oxymolybdenum Dialkylthiophosphate MoPTC.
9. a kind of cast carbon steel rolling and processing lubricant oil composite as claimed in claim 1, it is characterised in that antirust agent is matter The alkyl phosphoric acid imidazoline salt T708's of barium mahogany sulfonate T701 and 50% of the amount than 50% is compound.
CN201610840658.2A 2016-09-21 2016-09-21 Lubricant composition for rolling processing of cast carbon steel Pending CN106635295A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610840658.2A CN106635295A (en) 2016-09-21 2016-09-21 Lubricant composition for rolling processing of cast carbon steel

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Application Number Priority Date Filing Date Title
CN201610840658.2A CN106635295A (en) 2016-09-21 2016-09-21 Lubricant composition for rolling processing of cast carbon steel

Publications (1)

Publication Number Publication Date
CN106635295A true CN106635295A (en) 2017-05-10

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Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107723080A (en) * 2017-11-20 2018-02-23 苏州永创达电子有限公司 A kind of multifunctional vibration damping wearable environment protection lubricating oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5888947A (en) * 1995-06-06 1999-03-30 Agro Management Group, Inc. Vegetable oil lubricants for internal combustion engines and total loss lubrication
CN102492525A (en) * 2011-11-15 2012-06-13 徐州希弗重工科技有限公司 Hydraulic oil additive combination and preparation method thereof
CN103695118A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for drawing tin and alloy material thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5888947A (en) * 1995-06-06 1999-03-30 Agro Management Group, Inc. Vegetable oil lubricants for internal combustion engines and total loss lubrication
CN102492525A (en) * 2011-11-15 2012-06-13 徐州希弗重工科技有限公司 Hydraulic oil additive combination and preparation method thereof
CN103695118A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for drawing tin and alloy material thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107723080A (en) * 2017-11-20 2018-02-23 苏州永创达电子有限公司 A kind of multifunctional vibration damping wearable environment protection lubricating oil

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Application publication date: 20170510