CN106544121A - A kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions - Google Patents
A kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions Download PDFInfo
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- CN106544121A CN106544121A CN201610962496.XA CN201610962496A CN106544121A CN 106544121 A CN106544121 A CN 106544121A CN 201610962496 A CN201610962496 A CN 201610962496A CN 106544121 A CN106544121 A CN 106544121A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/2805—Esters used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/08—Halogenated waxes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/14—Containing carbon-to-nitrogen double bounds, e.g. guanidines, hydrazones, semicarbazones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions, oil based on being combined using the HVI120BS base oils of mass ratio 2/3rds and 1/3rd Esters oil Radialube7368, coordinate various compound additives.Including：Antioxidant, metal deactivator, oiliness improver, friction improver, extreme pressure agent, antiwear additive, antirust agent, oxidation and corrosion inhibitor, tackifier etc..The composition of the present invention has good cooling, lubricity, extreme-pressure anti-wear load, film strength, diffusivity, rust-preventing characteristic, antioxygen anti-corrosive properties, adhesiveness, reduces galled spots and cut.
Description
Technical field
A kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions of the present invention belong to metal working lubricant
Field.
Background technology
Nickel-base antiwear alloy main alloy element is chromium, molybdenum, tungsten, also containing a small amount of niobium, tantalum and indium.Except with wearability
Can be outer, its anti-oxidant, corrosion-resistant, welding performance might as well.Wear-resisting spare part can be manufactured, also can be as covering material, by built-up welding
Other substrate material surfaces are coated on spraying coating process.
Shear spinning technique rely primarily on sotck thinkness it is thinning come realize shape, blank external diameter is held essentially constant.
Generally when shear spinning is carried out, the pressure that spinning roller is added on blank is more much bigger than during conventional spinning, the deformation of blank and
It is much bigger during conventional spinning, also differ widely when the deformation and conventional spinning of blank.During conventional spinning, blank is thick
Degree change is little, but diameter change is very big --- from large to small or change from small to big.And in strong spinning process, blank diameter is basic
Keep constant, but thickness change be very big --- it is thinning by thickness.Therefore shear spinning is also called flow turning.From process analysis
Think：Shear spinning belongs to axial extension, deformed area material be in two to or three-dimensional stress state, thus higher deformation can be produced
Degree.According to the difference of the type and flow of metal mechanism of spinning part, shear spinning can be divided into Tapered Cup shear spinning --- cut
Cut spinning and power spinning of tube workpiece --- two kinds of extrusion Qiang Xuan etc..Shear spinning is used for being spun into for the bodies such as various, cone
The process technology of shell body, is the method and technique of a kind of comparative maturity, is also boiling hot plate method.Nickel-base antiwear alloy shear spinning is moistened
Lubrication prescription requires to solve：The continuity of high-toughness material curved surface deformation, the uniformity of material thickness, reduce the gold of lower pressure and material
Phase defect, extends die life, meets the high technical difficulty of spinning part surface quality requirements.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, extreme-pressure anti-wear carrying
Property, film strength, diffusivity, rust-preventing characteristic, antioxygen anti-corrosive properties, adhesiveness, reduce the nickel-base antiwear alloy of galled spots and cut
Shear spinning processing technology lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution：
A kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions, the HVI120BS of mass ratio 2/3rds
Base oil and 1/3rd Esters oil Radialube7368 it is compound based on oil, coordinate various compound additives, which is each
Mass percent into being grouped into：
The mass percent summation of above each component is 100%.
Antioxidant is that the phenolic ester type antioxidant T508 of the heterocyclic compound T552 and 50% of mass ratio 50% is combined.
Metal deactivator is the N of the complexing agent T531 and 50% of derivative containing benzotriazole of mass ratio 50%, bis- sub- bigcatkin willows of N-
Sour propane diamine T1201 is combined.Oiliness improver is sulfurized olefin cotton oil T405A.Friction improver is sulphur molybdenum phosphate T461.
Extreme pressure agent is sulphur phosphoric acid nitrogen containing derivative T305.Antiwear additive is chlorinated paraffin T302.
Antirust agent is barium dinonyl napthalene sulphonate.Oxidation and corrosion inhibitor is dialkyldithiocarbamacompositions tungsten.
Tackifier are polyisobutene T603C.
It is an advantage of the current invention that：There is the composition of the present invention good cooling, lubricity, extreme-pressure anti-wear to carry
Property, film strength, diffusivity, rust-preventing characteristic, antioxygen anti-corrosive properties, adhesiveness, reduce galled spots and cut.
Specific embodiment
Embodiment 1：
Following each component is pressed the mediation of row mass percent to form：
Above each component mass percentage content summation is 100%.
Embodiment 2：
Following each component is pressed the mediation of row mass percent to form：
Above each component mass percentage content summation is 100%.
Embodiment 3：
Following each component is pressed the mediation of row mass percent to form：
Above each component mass percentage content summation is 100%.
The key technical indexes of 3 product of embodiment
| Project | Index |
| 40 DEG C of kinematic viscosity/(mm2﹒ s-1) | 476 |
| Flash-point (opening)/DEG C | 272 |
| Pour point/DEG C | -15 |
| Viscosity index (VI) | 156 |
| Corrosion (copper sheet, 100 DEG C, 3h)/level | 1 |
| 84 DEG C of demulsification number (40-37-3) | 12 |
| Oxidation stability, (rotary oxygen bomb, 150 DEG C), min | 340 |
| Tetra-ball machine test, Pb/N | 1080 |
| Sintering load, PD/N | 7710 |
| Terraced nurse is agreed, N | 341 |
| FZG, level | 14 |
| Mechanical admixture, % | Nothing |
| Moisture, % | Vestige |
| Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % | 7 |
The key technical indexes of 2 product of embodiment
| Project | Index |
| 40 DEG C of kinematic viscosity/(mm2﹒ s-1) | 481.1 |
| Flash-point (opening)/DEG C | 281 |
| Pour point/DEG C | -16 |
| Viscosity index (VI) | 156 |
| Corrosion (copper sheet, 100 DEG C, 3h)/level | 1 |
| 84 DEG C of demulsification number (40-37-3) | 10 |
| Oxidation stability, (rotary oxygen bomb, 150 DEG C), min | 347 |
| Tetra-ball machine test, Pb/N | 1065 |
| Sintering load, PD/N | 7595 |
| Terraced nurse is agreed, N | 328 |
| FZG, level | 14 |
| Mechanical admixture, % | Nothing |
| Moisture, % | Vestige |
| Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % | 9 |
The key technical indexes of 1 product of embodiment
| Project | Index |
| 40 DEG C of kinematic viscosity/(mm2﹒ s-1) | 479.2 |
| Flash-point (opening)/DEG C | 272 |
| Pour point/DEG C | -18 |
| Viscosity index (VI) | 156 |
| Corrosion (copper sheet, 100 DEG C, 3h)/level | 1 |
| 84 DEG C of demulsification number (40-37-3) | 11 |
| Oxidation stability, (rotary oxygen bomb, 150 DEG C), min | 343 |
| Tetra-ball machine test, Pb/N | 1045 |
| Sintering load, PD/N | 7550 |
| Terraced nurse is agreed, N | 338 |
| FZG, level | 14 |
| Mechanical admixture, % | Nothing |
| Moisture, % | Vestige |
| Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % | 8 |
Claims (10)
1. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions, it is characterised in that：Using three points of mass ratio
Two HVI 120BS base oils and 1/3rd Esters oil Radialube7368 it is compound based on oil, coordinate various multiple
Close additive, its each mass percent into being grouped into：
The mass percent summation of above each component is 100%.
2. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions as claimed in claim 1, its feature exist
In antioxidant be mass ratio 50% heterocyclic compound T552 and 50% phenolic ester type antioxidant T508 be combined.
3. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions as claimed in claim 1, its feature exist
It is the N of the complexing agent T531 and 50% of derivative containing benzotriazole of mass ratio 50% in metal deactivator, bis- sub- salicylic acids of N- the third two
Amine T1201 is combined.
4. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions as claimed in claim 1, its feature exist
In oiliness improver be sulfurized olefin cotton oil T405A.
5. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions as claimed in claim 1, its feature exist
In friction improver be sulphur molybdenum phosphate T461.
6. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions as claimed in claim 1, its feature exist
In extreme pressure agent be sulphur phosphoric acid nitrogen containing derivative T305.
7. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions as claimed in claim 1, its feature exist
In antiwear additive be chlorinated paraffin T302.
8. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions as claimed in claim 1, its feature exist
In antirust agent be barium dinonyl napthalene sulphonate.
9. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions as claimed in claim 1, its feature exist
In oxidation and corrosion inhibitor be dialkyldithiocarbamacompositions tungsten.
10. a kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions as claimed in claim 1, its feature exist
In tackifier be polyisobutene T603C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610962496.XA CN106544121A (en) | 2016-11-04 | 2016-11-04 | A kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions |
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| CN201610962496.XA CN106544121A (en) | 2016-11-04 | 2016-11-04 | A kind of nickel-base antiwear alloy shear spinning processing technology lubricant compositions |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233956A (en) * | 2018-10-16 | 2019-01-18 | 广西大学 | A kind of composition of the cold stamping shaped processing material lubricant of nitrogen bearing duplex stainless steel plate |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103374452A (en) * | 2012-04-27 | 2013-10-30 | 中国石油化工股份有限公司 | Manual transmission lubricating oil composition |
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- 2016-11-04 CN CN201610962496.XA patent/CN106544121A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103374452A (en) * | 2012-04-27 | 2013-10-30 | 中国石油化工股份有限公司 | Manual transmission lubricating oil composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233956A (en) * | 2018-10-16 | 2019-01-18 | 广西大学 | A kind of composition of the cold stamping shaped processing material lubricant of nitrogen bearing duplex stainless steel plate |
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