CN106520322A - Lubricant composition of manganese alloy power spinning processing technology - Google Patents
Lubricant composition of manganese alloy power spinning processing technology Download PDFInfo
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- CN106520322A CN106520322A CN201610963570.XA CN201610963570A CN106520322A CN 106520322 A CN106520322 A CN 106520322A CN 201610963570 A CN201610963570 A CN 201610963570A CN 106520322 A CN106520322 A CN 106520322A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
- C10M2207/2825—Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
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- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/08—Halogenated waxes
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/09—Complexes with metals
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
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Abstract
The invention discloses a lubricant composition of a manganese alloy power spinning processing technology. 50 percent of No.150 total loss system oil and 50 percent of ester oil dioctyl adipate are combined as compound base oil, and a plurality of composite additives are matched, wherein the composite additives include an antioxidant, a metal deactivator, an oiliness agent, a friction modifying addition, an extreme pressure agent, an antiwear agent, an antirust agent, an oxidation and corrosion inhibitor, a tackifier and the like. The composition provided by the invention has the characteristics of good cooling property, lubricity, extreme pressure antiwear bearing property, diffusivity, cleaning property, anti-rust property, antioxygen and anti-corrosive properties, oxidation stability and adhesive property; besides, surface abrasion and scratches are reduced.
Description
Technical field
A kind of manganese alloy shear spinning processing technology lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
The alloy that manganese alloy is made up of manganese, silicon, iron and a small amount of carbon and other elements.Major product has silicomanganese and ferromanganese,
Ferromanganese is divided into high carbon ferromanganese (C content 7%~7.5%) mid-carbon fe-mn (C content 1%~1.5%) low-carbon ferromanganese (C content again
0.2%~0.7%).
Shear spinning technique rely primarily on sotck thinkness it is thinning come realize shape, blank external diameter is held essentially constant.
Generally when shear spinning is carried out, the pressure that spinning roller is added on blank is more much bigger than during conventional spinning, the deformation of blank and
It is much bigger during conventional spinning, also differ widely when the deformation and conventional spinning of blank.During conventional spinning, blank is thick
Degree change is little, but diameter change is very big from large to small or changes from small to big.And in strong spinning process, blank diameter is basic
Keep constant, but thickness change is very thinning by thickness greatly.Therefore shear spinning is also called flow turning.From process analysis
Think:Shear spinning belongs to axial extension, deformed area material be in two to or three-dimensional stress state, thus higher deformation can be produced
Degree.According to the difference of the type and flow of metal mechanism of spinning part, shear spinning can be divided into Tapered Cup shear spinning and cut
Cut two kinds of spinning and power spinning of tube workpiece extrusion Qiang Xuan etc..Shear spinning is used for being spun into for the bodies such as various, cone
The process technology of shell body, is the method and technique of a kind of comparative maturity, is also boiling hot plate method.Manganese alloy shear spinning processing technology
Lubricating requirement reduce shear spinning machining load, promote metal flow in a mold, prevent mould stuck, reduce die wear and
Spillage of material, accelerates radiating, improves shear spinning workpiece quality and production efficiency.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, extreme-pressure anti-wear carrying
Property, diffusivity, cleaning, rust-preventing characteristic, antioxygen anti-corrosive properties, oxidation stability, adhesiveness, the manganese for reducing galled spots and cut closes
Golden shear spinning processing technology lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of manganese alloy shear spinning processing technology lubricant compositions, using No. 150 total loss systems of mass ratio 50%
System oil is compound with 50% Esters oil hexanedioic acid dioctyl ester to coordinate various compound additives as composite foundation oil, and which is each
Mass percent into being grouped into:
The mass percent summation of above each component is 100%.
Antioxidant is that the T532 of derivative containing benzotriazole of the sulfenyl phenolate T504 and 50% using mass ratio 50% is combined.
Metal deactivator be the thiadiazole of mass ratio 50% and 50% benzotriazole derivative T551 be combined.
Oiliness improver is sulfurized lard.
Friction improver is boronation phosphate T3011.
Extreme pressure agent is two butyric acid T304 of acid phosphorous acid.
Antiwear additive is that chlorinated paraffin T501 is combined.
Antirust agent is the heptadecenyl imidazolidene succinate of the petroleum sodium sulfonate T747 and 50% of mass ratio 50%
T703 is combined.
Oxidation and corrosion inhibitor is dialkyldithiocarbamacompositions tin.
Tackifier are ethylene-propylene copolymer T613A.
It is an advantage of the current invention that:
The composition of the present invention has good cooling, lubricity, extreme-pressure anti-wear load, diffusivity, cleaning, anti-
Rust property, antioxygen anti-corrosive properties, oxidation stability, adhesiveness, reduce galled spots and cut;Shear spinning machining load can be reduced,
Promote metal to flow in a mold, prevent mould stuck, reduce die wear and spillage of material, accelerate radiating, improve strength and revolve
Pressure workpiece quality and production efficiency.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
The key technical indexes of 3 product of embodiment
Project | Index |
40 DEG C of kinematic viscosity/(mm2S-1) | 235.6 |
Flash-point (opening)/DEG C | 256 |
Condensation point/DEG C | -20 |
Viscosity index (VI) | 152 |
Corrosion (copper sheet, 100 DEG C, 3h)/level | 1 |
82 DEG C of (40-37-3)/min of demulsification number | 10 |
Oxidation stability (rotary bomb oxidation test, 150 DEG C), min | 330 |
Tetra-ball machine test, Pb/N | 980 |
Sintering load, PD/N | 7550 |
Terraced nurse is agreed, N | 325 |
FZG, level | 14 |
Mechanical admixture, | Nothing |
Moisture, % | Vestige |
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % | 7.5 |
The key technical indexes of 2 product of embodiment
Project | Index |
40 DEG C of kinematic viscosity/(mm2S-1) | 237.2 |
Flash-point (opening)/DEG C | 261 |
Condensation point/DEG C | -21 |
Viscosity index (VI) | 161 |
Corrosion (copper sheet, 100 DEG C, 3h)/level | 1 |
82 DEG C of (40-37-3)/min of demulsification number | 8 |
Oxidation stability (rotary bomb oxidation test, 150 DEG C), min | 326 |
Tetra-ball machine test, Pb/N | 969 |
Sintering load, PD/N | 7515 |
Terraced nurse is agreed, N | 321 |
FZG, level | 14 |
Mechanical admixture, | Nothing |
Moisture, % | Vestige |
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % | 7.3 |
The key technical indexes of 1 product of embodiment
Project | Index |
40 DEG C of kinematic viscosity/(mm2S-1) | 236.3 |
Flash-point (opening)/DEG C | 258 |
Condensation point/DEG C | -22 |
Viscosity index (VI) | 157 |
Corrosion (copper sheet, 100 DEG C, 3h)/level | 1 |
82 DEG C of (40-37-3)/min of demulsification number | 9 |
Oxidation stability (rotary bomb oxidation test, 150 DEG C), min | 336 |
Tetra-ball machine test, Pb/N | 978 |
Sintering load, PD/N | 7570 |
Terraced nurse is agreed, N | 329 |
FZG, level | 14 |
Mechanical admixture, | Nothing |
Moisture, % | Vestige |
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % | 7.9 |
Claims (10)
1. a kind of manganese alloy shear spinning processing technology lubricant compositions, it is characterised in that:Using No. 150 of mass ratio 50%
Total loss system oil and 50% Esters oil hexanedioic acid dioctyl ester it is compound as composite foundation oil, coordinate various compound additions
Agent, its each mass percent into being grouped into:
The mass percent summation of above each component is 100%.
2. a kind of manganese alloy shear spinning processing technology lubricant compositions as claimed in claim 1, it is characterised in that antioxygen
Agent is that the T532 of derivative containing benzotriazole of the sulfenyl phenolate T504 and 50% using mass ratio 50% is combined.
3. a kind of manganese alloy shear spinning processing technology lubricant compositions as claimed in claim 1, it is characterised in that metal
Passivator be the thiadiazole of mass ratio 50% and 50% benzotriazole derivative T551 be combined.
4. a kind of manganese alloy shear spinning processing technology lubricant compositions as claimed in claim 1, it is characterised in that oiliness
Agent is sulfurized lard.
5. a kind of manganese alloy shear spinning processing technology lubricant compositions as claimed in claim 1, it is characterised in that friction
Modifier is boronation phosphate T3011.
6. a kind of manganese alloy shear spinning processing technology lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure
Agent is two butyric acid T304 of acid phosphorous acid.
7. a kind of manganese alloy shear spinning processing technology lubricant compositions as claimed in claim 1, it is characterised in that wear-resistant
Agent is chlorinated paraffin T501.
8. a kind of manganese alloy shear spinning processing technology lubricant compositions as claimed in claim 1, it is characterised in that antirust
Agent is that heptadecenyl imidazolidene succinate T703 of the petroleum sodium sulfonate T747 and 50% of mass ratio 50% is combined.
9. a kind of manganese alloy shear spinning processing technology lubricant compositions as claimed in claim 1, it is characterised in that antioxygen
Anti-corrosion additive is dialkyldithiocarbamacompositions tin.
10. a kind of manganese alloy shear spinning processing technology lubricant compositions as claimed in claim 1, it is characterised in that thickening
Agent is ethylene-propylene copolymer T613A.
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CN201610963570.XA CN106520322A (en) | 2016-11-04 | 2016-11-04 | Lubricant composition of manganese alloy power spinning processing technology |
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CN201610963570.XA Withdrawn CN106520322A (en) | 2016-11-04 | 2016-11-04 | Lubricant composition of manganese alloy power spinning processing technology |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104862059A (en) * | 2015-06-05 | 2015-08-26 | 广西大学 | Lubricant composition for cold spinning aluminum alloy pipe |
CN104927989A (en) * | 2015-06-05 | 2015-09-23 | 广西大学 | Lubricant composition for cold spinning of chromium alloy pipes |
-
2016
- 2016-11-04 CN CN201610963570.XA patent/CN106520322A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104862059A (en) * | 2015-06-05 | 2015-08-26 | 广西大学 | Lubricant composition for cold spinning aluminum alloy pipe |
CN104927989A (en) * | 2015-06-05 | 2015-09-23 | 广西大学 | Lubricant composition for cold spinning of chromium alloy pipes |
Non-Patent Citations (1)
Title |
---|
颜志光: "《润滑材料与润滑技术》", 31 January 2000, 中国石化出版社 * |
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