CN106520342A - Lubricant composition of manganese alloy spinning process - Google Patents
Lubricant composition of manganese alloy spinning process Download PDFInfo
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- CN106520342A CN106520342A CN201610966164.9A CN201610966164A CN106520342A CN 106520342 A CN106520342 A CN 106520342A CN 201610966164 A CN201610966164 A CN 201610966164A CN 106520342 A CN106520342 A CN 106520342A
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- manganese alloy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/284—Esters of aromatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/288—Partial esters containing free carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a lubricant composition of a manganese alloy spinning process. According to the lubricant composition, 70%-80% of MIV90BS base oil and 30%-20% of esters oil RADIA7543 are compounded to obtain base oil and the base oil is compounded with a plurality of types of compound additives. The plurality of types of compound additives include an antioxidant, a metal deactivating agent, an oiliness agent, a friction improvement agent, an extreme-pressure agent, an anti-wearing agent, an anti-rusting agent, an oxidation and corrosion inhibitor, a thickening agent and the like. The composition disclosed by the invention has good cooling property, lubricating property, extreme pressure anti-wearing and loading capability, oxidation and corrosion inhibition property, oxidation stability, flowability and anti-rusting property.
Description
Technical field
A kind of manganese alloy rotary pressing processing technology lubricant compositionss of the present invention belong to metal working lubricant field.
Background technology
Manganese alloy is by manganese, silicon, ferrum and a small amount of carbon and other elementary composition alloys.Major product has silicomanganese and ferromanganese,
Ferromanganese is divided into high carbon ferromanganese (C content 7%~7.5%) mid-carbon fe-mn (C content 1%~1.5%) low-carbon ferromanganese (C content again
0.2%~0.7%).
Rotary pressure technology originates from ancient times pottery.He is that one kind combines forging, extruding, draw piece, bending, looping mill rolling, horizontal stroke
Roll the few advanced technologies without machining with the process characteristic such as edging.Generally metal letter base, plate blank or prefabricated blank are used
Tail top is held out against on spinning machine mould, drives plug and blank rotation by main shaft;Material is extruded by spinning wheel from blank side simultaneously
On the core of rotation, material is made to produce the continuous plastic deformation of pointwise, so as to obtain the hollow rotary body of various shape of generatrix
Part.According to the blank thickness situation of change during rotary pressing processing, spinning process is divided into conventional spinning and shear spinning two
Plant, i.e. conventional spinning and shear spinning.
The referred to as general rotation of conventional spinning.During general rotation, the thickness of blank is held essentially constant, and shaping relies primarily on blank edge
The contraction of circumference and along radial direction it is indeformable realizing with length.Which is mainly characterized by forming process, substantially can be seen
Go out the change of blank external diameter.The basic mode of conventional spinning has:Draw spinning (drawing rotation), necking in spindown (contracting rotation) and expanding bulging
Three kinds of (expanding rotation) etc..Manganese alloy rotary pressing processing technology lubricant requires to reduce rotary pressing processing load, promotes metal to flow in a mold
It is dynamic, prevent mould stuck, reduce die wear and spillage of material, accelerate radiating, improve flow formed part quality, the detritus response rate and
Production efficiency.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, extreme-pressure anti-wear bearing capacity, antioxygen
The manganese alloy rotary pressing processing technology lubricant compositionss of anti-corrosive properties, oxidation stability, mobility and rust-preventing characteristic.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of manganese alloy rotary pressing processing technology lubricant compositionss, the MIV90BS using mass ratio 70%~80% are basic
Oil and 30%~20% Esters oil RADIA7543 are complex as base oil, coordinate various compound additives, its respective quality percentage
It is several into being grouped into:
The mass percent summation of above each component is 100%.
Antioxidant is 2,6- di-t-butyl -4- carboxyl phenyl propionic esters.Metal deactivator is 2- sulfenyl benzimidazoles.
Oiliness improver is sulfurized lard.Friction improver is phosphate ester T451.Extreme pressure agent is two butanoic acid T304 of acid phosphorous acid.
Antiwear additive is that sulfide isobutene T321 is combined.
Antirust agent is the 17 alkenyl imidazoline allyl butyrates two of the thiazolinyl two butanoic acid half ester T747 and 50% of mass ratio 50%
Hydrochlorate T703 is combined.Oxidation and corrosion inhibitor is dialkyl dithio amino formate.Viscosifier are ethylene-propylene copolymer T613.
It is an advantage of the current invention that:There is the compositionss of the present invention good cooling, extreme-pressure anti-wear bearing capacity, antioxygen to prevent
Corruption, oxidation stability, mobility and rust-preventing characteristic;Rotary pressing processing load can be reduced, is promoted metal to flow in a mold, is prevented
Mould is stuck, reduces die wear and spillage of material, accelerates radiating, improves flow formed part quality, the detritus response rate and production effect
Rate.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
The key technical indexes of 3 product of embodiment
Project | Index |
Kinematic viscosity/100 DEG C (mm2S-1) | 218.1 |
Flash-point (opening)/DEG C | 275 |
Condensation point/DEG C | -10 |
Viscosity index (VI) | 94 |
Corrosion (copper sheet, 100 DEG C, 3h)/level | 1 |
82 DEG C of (40-37-3)/min of demulsification number | 15 |
Oxidation stability (rotary bomb oxidation test, 150 DEG C), min | 236 |
Tetra-ball machine test, Pb/N | 975 |
Sintering load, PD/N | 6750 |
Terraced nurse is agreed, N | 316 |
FZG, level | 14 |
Moisture, % | Vestige |
Mechanical admixture, % | Nothing |
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % | 7.8 |
The key technical indexes of 2 product of embodiment
Project | Index |
Kinematic viscosity/100 DEG C (mm2S-1) | 217.8 |
Flash-point (opening)/DEG C | 269 |
Condensation point/DEG C | -11 |
Viscosity index (VI) | 95 |
Corrosion (copper sheet, 100 DEG C, 3h)/level | 1 |
82 DEG C of (40-37-3)/min of demulsification number | 14 |
Oxidation stability (rotary bomb oxidation test, 150 DEG C), min | 241 |
Tetra-ball machine test, Pb/N | 983 |
Sintering load, PD/N | 6995 |
Terraced nurse is agreed, N | 314 |
FZG, level | 14 |
Moisture, % | Vestige |
Mechanical admixture, % | Nothing |
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % | 7.7 |
The key technical indexes of 1 product of embodiment
Project | Index |
Kinematic viscosity/100 DEG C (mm2S-1) | 220.1 |
Flash-point (opening)/DEG C | 278 |
Condensation point/DEG C | -10 |
Viscosity index (VI) | 97 |
Corrosion (copper sheet, 100 DEG C, 3h)/level | 1 |
82 DEG C of (40-37-3)/min of demulsification number | 13 |
Oxidation stability (rotary bomb oxidation test, 150 DEG C), min | 242 |
Tetra-ball machine test, Pb/N | 980 |
Sintering load, PD/N | 6770 |
Terraced nurse is agreed, N | 319 |
FZG, level | 14 |
Moisture, % | Vestige |
Mechanical admixture, % | Nothing |
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % | 7.4 |
Claims (10)
1. a kind of manganese alloy rotary pressing processing technology lubricant compositionss, it is characterised in that:Using mass ratio 70%~80%
MIV90BS base oils and 30%~20% Esters oil RADIA7543 are complex as base oil, coordinate various compound additives, its
Each mass percent into being grouped into:
The mass percent summation of above each component is 100%.
2. a kind of manganese alloy rotary pressing processing technology lubricant compositionss as claimed in claim 1, it is characterised in that antioxidant is
2,6- di-t-butyl -4- carboxyl phenyl propionic esters.
3. a kind of manganese alloy rotary pressing processing technology lubricant compositionss as claimed in claim 1, it is characterised in that metal deactivating
Agent is 2- sulfenyl benzimidazoles.
4. a kind of manganese alloy rotary pressing processing technology lubricant compositionss as claimed in claim 1, it is characterised in that oiliness improver is
Sulfurized lard.
5. a kind of manganese alloy rotary pressing processing technology lubricant compositionss as claimed in claim 1, it is characterised in that friction is improved
Agent is phosphate ester T451.
6. a kind of manganese alloy rotary pressing processing technology lubricant compositionss as claimed in claim 1, it is characterised in that extreme pressure agent is
Two butanoic acid T304 of acid phosphorous acid.
7. a kind of manganese alloy rotary pressing processing technology lubricant compositionss as claimed in claim 1, it is characterised in that antiwear additive is
Sulfide isobutene T321 is combined.
8. a kind of manganese alloy rotary pressing processing technology lubricant compositionss as claimed in claim 1, it is characterised in that antirust agent is
Heptadecenyl imidazolidene succinate T703 of the thiazolinyl two butanoic acid half ester T747 and 50% of mass ratio 50% is combined.
9. a kind of manganese alloy rotary pressing processing technology lubricant compositionss as claimed in claim 1, it is characterised in that the anti-corruption of antioxygen
Agent is dialkyl dithio amino formate.
10. a kind of manganese alloy rotary pressing processing technology lubricant compositionss as claimed in claim 1, it is characterised in that viscosifier are
Ethylene-propylene copolymer T613.
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CN201610966164.9A CN106520342A (en) | 2016-11-04 | 2016-11-04 | Lubricant composition of manganese alloy spinning process |
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CN201610966164.9A CN106520342A (en) | 2016-11-04 | 2016-11-04 | Lubricant composition of manganese alloy spinning process |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103374452A (en) * | 2012-04-27 | 2013-10-30 | 中国石油化工股份有限公司 | Manual transmission lubricating oil composition |
CN103710085A (en) * | 2013-11-19 | 2014-04-09 | 广西大学 | Cold rolling lubricant for silver and silver alloy foil |
CN104877747A (en) * | 2015-06-05 | 2015-09-02 | 广西大学 | Lubricant composition for cold-spinning stainless steel pipe |
CN104962344A (en) * | 2015-06-05 | 2015-10-07 | 广西大学 | Lubricant composition for cold spinning of zirconium alloy pipe |
CN105542919A (en) * | 2015-12-23 | 2016-05-04 | 天津川美环保科技发展有限公司 | A preparing method of environmental friendly stamping oil |
-
2016
- 2016-11-04 CN CN201610966164.9A patent/CN106520342A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103374452A (en) * | 2012-04-27 | 2013-10-30 | 中国石油化工股份有限公司 | Manual transmission lubricating oil composition |
CN103710085A (en) * | 2013-11-19 | 2014-04-09 | 广西大学 | Cold rolling lubricant for silver and silver alloy foil |
CN104877747A (en) * | 2015-06-05 | 2015-09-02 | 广西大学 | Lubricant composition for cold-spinning stainless steel pipe |
CN104962344A (en) * | 2015-06-05 | 2015-10-07 | 广西大学 | Lubricant composition for cold spinning of zirconium alloy pipe |
CN105542919A (en) * | 2015-12-23 | 2016-05-04 | 天津川美环保科技发展有限公司 | A preparing method of environmental friendly stamping oil |
Non-Patent Citations (1)
Title |
---|
熊云等: "《油品应用及管理》", 30 May 2004 * |
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