CN106635288A - Babbitt metal spinning lubricant composition - Google Patents

Babbitt metal spinning lubricant composition Download PDF

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Publication number
CN106635288A
CN106635288A CN201610837710.9A CN201610837710A CN106635288A CN 106635288 A CN106635288 A CN 106635288A CN 201610837710 A CN201610837710 A CN 201610837710A CN 106635288 A CN106635288 A CN 106635288A
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Prior art keywords
lubricant compositions
pressing processing
rotary pressing
processing lubricant
metal rotary
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CN201610837710.9A
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Chinese (zh)
Inventor
黄福川
李康春
邓富康
唐弓斌
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Guangxi University
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Guangxi University
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Priority to CN201610837710.9A priority Critical patent/CN106635288A/en
Publication of CN106635288A publication Critical patent/CN106635288A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/16Naphthenic acids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/003Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a Babbitt metal spinning lubricant composition. The lubricant composition uses an MVI 90 BS base oil and boride phosphate composite as base oil and is supplemented with a plurality of complex additives including an oily agent, a friction modifier, an extreme pressure agent, an antiwear agent, an antioxidant, a metal deactivator, an anti-rust agent, an oxidation and corrosion inhibitor, a tackifier and so on. The lubricant composition provided by the invention has advantages of good diffusibility, fluidity, carrying capacity, lubrication performance, cooling performance, rust prevention property and corrosion resistance and easiness in cleaning.

Description

A kind of bidery metal rotary pressing processing lubricant compositions
Technical field
The invention belongs to metal working lubricant field, particularly a kind of bidery metal rotary pressing processing lubricant compositions.
Background technology
Bidery metal is invented by American's Babbitt and gained the name, and because of its existing white, babbit is become again.Including tin-base bearing Alloy and lead-base bearing alloy, are widely used.It has friction reduction characteristics, is unique material for being adapted to and being rotated relative to soft axle Material, compared with other bearing materials, with more preferable adaptability and embedability, be widely used in big marine diesel engine, turbine, Alternating current generator, and other mining machineries and large rotating machinery etc..Its primary alloy constituent is tin, lead, antimony, copper.Antimony, Copper, to improve alloy strength and hardness.
The tissue characteristic of babbit is that hard phase particle is uniform-distribution with soft phase matrix, and soft phase matrix has alloy Have extraordinary embedding Tibetan property, compliance and seizure resistance, and after break-in, soft matrix indent, Hard Inclusion evagination, make sliding surface it Between form minim gap, become store oil space and grease channel, beneficial to antifriction;Convex Hard Inclusion play supporting role, favorably In carrying.
According to GB:Babbit is divided to two kinds of tinbase and lead-containing alloy.The intensity and hardness of lead-containing alloy compares kamash alloy Low, corrosion resistance is also poor.Therefore, generally when using babbit, generally from kamash alloy.Lead-containing alloy is using comparing It is economical.
Rotary pressure technology originates from ancient times pottery.It is that one kind combines forging, extruding, draw piece, bending, looping mill rolling, horizontal stroke Roll the few advanced technologies without machining with the process characteristic such as edging.Generally metal letter base, plate blank or prefabricated blank are used Tail top is held out against on spinning machine mould, and by main shaft plug and blank rotation are driven;Simultaneously spinning wheel extrudes material from blank side On the core of rotation, make material produce pointwise and be continuously plastically deformed, so as to obtain the hollow rotary body of various shape of generatrix Part.According to the blank thickness situation of change during rotary pressing processing, spinning process is divided into conventional spinning and shear spinning two Plant, i.e. conventional spinning and shear spinning.
The referred to as general rotation of conventional spinning.The thickness of blank is held essentially constant during general rotation, and shaping relies primarily on blank edge The contraction of circumference and along radial direction it is indeformable realizing with length.It is mainly characterized by forming process, can substantially be seen Go out the change of blank external diameter.The basic mode of conventional spinning has:Draw spinning (drawing rotation), necking in spindown (contracting rotation) and expanding bulging Three kinds of (expanding rotation) etc..In bidery metal rotary pressing processing technique, it is desirable to which lubricant has good diffusivity and mobility, carries energy Power, lubrication, cooling, antirust, anti-corrosive properties and easy cleaning.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good diffusivity and mobility, bearing capacity, profit The bidery metal rotary pressing processing lubricant compositions of cunning, cooling, antirust, anti-corrosive properties and easy cleaning.
The present invention adopts the following technical scheme that solution above-mentioned technical problem:
A kind of bidery metal rotary pressing processing lubricant compositions, it is characterised in that:Using the BS base oils of MVI 90 and boronation phosphorus Acid esters it is compound based on oil, coordinate various compound additives, its each mass percent into being grouped into:
Component Mass percentage content
Base oil Surplus
Oiliness improver 4~7%
Friction improver 3~5%
Extreme pressure agent 3~4%
Antiwear additive 4~8%
Antioxidant 0.08%~0.3%
Metal deactivator 0.03%~0.32%
Antirust agent 0.06%~0.5%
Oxidation and corrosion inhibitor 0.5%~1.2%
Tackifier 3%~8%
Above each component mass percent summation is 100%.
Based on being combined using the BS base oils of MVI 90 and 20~10% boronation phosphate of mass ratio 80~90% Oil.
Antioxidant is the pungent diphenylamines T557 of butyl of the 2,6- di-t-butyl mixed ester T502A and 50% of mass ratio 50% It is compound;Antiwear additive is chlorinated paraffin T301.
Metal deactivator is that the thiadiazole of the benzotriazole derivative T551 and 50% of mass ratio 50% is combined.
Antirust agent is the compound of the TTA of the barium mahogany sulfonate T701 and 33% of mass ratio 67%;Extreme pressure agent It is lead naphthenate T341.
Oiliness improver is sulfuration cottonseed oil T404.
Friction improver is monoolein;Oxidation and corrosion inhibitor is double octyl group basic zinc salts T203 of sulphur phosphorus.
Tackifier are polyisobutene T603.
The beneficial effect of the present composition is:With good diffusivity and mobility, bearing capacity, lubrication, cold But, antirust, anti-corrosive properties and easy cleaning.
Specific embodiment
Embodiment 1:
Following each component is reconciled by mass percentage and is formed:
Component Mass percentage content
The BS base oils of mass ratio 80%MVI 90 and 20% boronation phosphate are compound Surplus
The 2,6- di-t-butyls mixed ester and the pungent diphenylamines of 50% butyl (T557) of mass ratio 50% is combined 0.2%
Chlorinated paraffin (T301) 5%
The benzotriazole derivative (T551) of mass ratio 50% and 50% thiadiazole are compound 0.1%
The barium mahogany sulfonate (T701) of mass ratio 67% and 33% TTA are compound 0.2%
Lead naphthenate (T341) 3%
Sulfuration cottonseed oil (T404) 5%
Monoolein 4%
Double octyl groups basic zinc salt (T203) of sulphur phosphorus 1.1%
Polyisobutene (T603) 4.0%
Embodiment 2:
Following each component is reconciled by mass percentage and is formed:
Component Mass percentage content
The BS base oils of mass ratio 90%MVI 90 and 10% boronation phosphate are compound Surplus
The 2,6- di-t-butyls mixed ester and the pungent diphenylamines of 50% butyl (T557) of mass ratio 50% is combined 0.2%
Chlorinated paraffin (T301) 6%
The benzotriazole derivative (T551) of mass ratio 50% and 50% thiadiazole are compound 0.08%
The barium mahogany sulfonate (T701) of mass ratio 67% and 33% TTA are compound 0.5%
Lead naphthenate (T341) 3.5%
Sulfuration cottonseed oil (T404) 6%
Monoolein 3%
Double octyl groups basic zinc salt (T203) of sulphur phosphorus 1.2%
Polyisobutene (T603) 5.0%
Embodiment 3:
Following each component is reconciled by mass percentage and is formed:
Component Mass percentage content
Mass ratio 85%MVI90 BS base oils and 15% boronation phosphate are compound Surplus
The 2,6- di-t-butyls mixed ester and the pungent diphenylamines of 50% butyl (T557) of mass ratio 50% is combined 0.25%
Chlorinated paraffin (T301) 7%
The benzotriazole derivative (T551) of mass ratio 50% and 50% thiadiazole are compound 0.08%
The barium mahogany sulfonate (T701) of mass ratio 67% and 33% TTA are compound 0.5%
Lead naphthenate (T341) 3.2%
Sulfuration cottonseed oil (T404) 5.5%
Monoolein 3.5%
Double octyl groups basic zinc salt (T203) of sulphur phosphorus 0.7%
Polyisobutene (T603) 3.0%
The product typical technology index of embodiment 1:
Project Index
40 DEG C of kinematic viscosity mm2/s 218
Viscosity index (VI) 113
Flash-point (opening)/DEG C 278
Pour point/DEG C -10
Demulsification number, 82 DEG C of (40-37-3)/min 13
Corrosion (copper sheet, 100 DEG C, 3h)/level 1
Tetra-ball machine test Pb/N 780
Sintering load PD/N 4750
Terraced nurse agrees/N 310
FZG/ levels 11
Mechanical admixture, % Nothing
Moisture, % Vestige

Claims (8)

1. a kind of bidery metal rotary pressing processing lubricant compositions, it is characterised in that:Using MVI 90BS base oils and boronation phosphoric acid Ester it is compound based on oil, coordinate various compound additives, its each mass percent into being grouped into:
Component Mass percentage content Base oil Surplus Oiliness improver 4~7% Friction improver 3~5% Extreme pressure agent 3~4% Antiwear additive 4~8% Antioxidant 0.08%~0.3% Metal deactivator 0.03%~0.32% Antirust agent 0.06%~0.5% Oxidation and corrosion inhibitor 0.5%~1.2% Tackifier 3%~8%
Above each component mass percent summation is 100%.
2. a kind of bidery metal rotary pressing processing lubricant compositions as claimed in claim 1, it is characterised in that:Using mass ratio 80 ~90% MVI 90BS base oils and 20~10% boronation phosphate are complex as base oil.
3. a kind of bidery metal rotary pressing processing lubricant compositions as claimed in claim 1, it is characterised in that:Antioxidant is quality The pungent diphenylamines T557's of butyl of the 2,6- di-t-butyl mixed ester T502A and 50% than 50% is compound;Antiwear additive is chlorination stone Wax T301.
4. a kind of bidery metal rotary pressing processing lubricant compositions as claimed in claim 1, it is characterised in that:Metal deactivator is The thiadiazole of the benzotriazole derivative T551 and 50% of mass ratio 50% is combined.
5. a kind of bidery metal rotary pressing processing lubricant compositions as claimed in claim 1, it is characterised in that:Antirust agent is quality The TTA of the barium mahogany sulfonate T701 and 33% than 67% it is compound;Extreme pressure agent is lead naphthenate T341.
6. a kind of bidery metal rotary pressing processing lubricant compositions as claimed in claim 1, it is characterised in that:Oiliness improver is sulfuration Cottonseed oil T404.
7. a kind of bidery metal rotary pressing processing lubricant compositions as claimed in claim 1, it is characterised in that:Friction improver is Monoolein;Oxidation and corrosion inhibitor is double octyl group basic zinc salts T203 of sulphur phosphorus.
8. a kind of bidery metal rotary pressing processing lubricant compositions as claimed in claim 1, it is characterised in that:Tackifier are poly- different Butylene T603.
CN201610837710.9A 2016-09-21 2016-09-21 Babbitt metal spinning lubricant composition Withdrawn CN106635288A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104862045A (en) * 2015-06-05 2015-08-26 广西大学 Lubricant combination for cold spinning copper alloy tube
CN105132091A (en) * 2015-07-20 2015-12-09 广西大学 Tin thread drawing lubricant composition
CN105482886A (en) * 2015-11-25 2016-04-13 铜陵市金利电子有限公司 Heatproof electric power lubricating grease

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104862045A (en) * 2015-06-05 2015-08-26 广西大学 Lubricant combination for cold spinning copper alloy tube
CN105132091A (en) * 2015-07-20 2015-12-09 广西大学 Tin thread drawing lubricant composition
CN105482886A (en) * 2015-11-25 2016-04-13 铜陵市金利电子有限公司 Heatproof electric power lubricating grease

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