CN104862045A - Lubricant combination for cold spinning copper alloy tube - Google Patents

Lubricant combination for cold spinning copper alloy tube Download PDF

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Publication number
CN104862045A
CN104862045A CN201510303865.XA CN201510303865A CN104862045A CN 104862045 A CN104862045 A CN 104862045A CN 201510303865 A CN201510303865 A CN 201510303865A CN 104862045 A CN104862045 A CN 104862045A
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CN
China
Prior art keywords
cold spinning
alloy pipe
lubricant compositions
tin alloy
lubricant combination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510303865.XA
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Chinese (zh)
Inventor
黄福川
李康春
卢朝霞
黄旖瑶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi University
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Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201510303865.XA priority Critical patent/CN104862045A/en
Publication of CN104862045A publication Critical patent/CN104862045A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a lubricant combination for a cold spinning copper alloy tube. The lubricant combination is characterized by adopting 250SN base oil as base oil and cooperating with various additives including an oiliness agent, a friction modifier, an anti-wear agent, an anti-oxidation preservative and a metal deactivator. The lubricant combination disclosed by the invention is enough in oil film thickness, higher in diffusivity and permeability, high in oil film strength, good in wear resistance and viscosity-temperature property, high in extreme pressure property, good in cooling, cleaning and lubricating properties and smaller in flow shear stress, improves the surface smoothness and the side and specification precision of the metal tube, has a certain chemical stability and proper flash points and ignition points and is low in viscosity, low in sulfur and low in aromatics.

Description

Cold spinning tin alloy pipe lubricant compositions
Technical field
The invention belongs to metal working lubricant field, particularly cold spinning tin alloy pipe lubricant compositions.
Background technology
Tin, metallic element, a kind of low melting point metal element of white gloss of bit bluish is argenteous soft metal, and proportion is 7.3, and fusing point only has 232 DEG C, puts in coal dust ball stove the liquid that just can be melt into as mercury into.Tin is very soft, can cut it with pocket knife.The chemical property of tin is very stable, is not easily oxidized by oxygen at normal temperatures; Therefore, it often keeps silver-colored glittering gloss.Tin is nontoxic, and plasticity-is strong and ductility is very poor, can not pull into filament.It can have various process of surface treatment, the product of multiple style can be made, tin remains the indispensable crucial rare metal of modern industry, is known as " industrial monosodium glutamate ", is widely used in the industries such as electronics, information, electrical equipment, chemical industry, metallurgy, building materials, machinery, food product pack.
The resistance to deformation of usual cold spinning tin alloy pipe increases with rotary pressure deformation amount and increases, effective lubricant and lubricating method should be selected, carry out lubricating, clean, cool, protection against corrosion and reduce adhesion and phenomenon, reduce damage and spot that tube surface causes because lubrication and cooling is bad.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind ofly has enough oil film thicknesses, stronger diffusion, perviousness, oil film strength is large, resistance to abrasion and sticky warm nature good, extreme pressure property is strong, cooling, cleaning and oilness good, have less flowing shear-stress, improve surface smoothness and the dimensions precision of metal tube, and have certain chemical stability and suitable flash-point and point of ignition, the cold spinning tin alloy pipe lubricant compositions of low viscosity, low sulfur-bearing, low aromatic hydrocarbons.
The present invention adopts following technical scheme to solve the problems of the technologies described above:
Cold spinning tin alloy pipe lubricant compositions, adopt oil based on 250SN base oil, coordinate multiple additives, its each component and mass percent thereof are:
Component Mass percent content
Base oil Surplus
Oiliness improver 5.0%~6.0%
Friction improver 2.0%~3.0%
Anti-wear agent 2.0%~3.0%
Oxidation inhibitor 0.1%~0.3%
Antioxidant preservative 0.1%~0.7%
Metal passivator 0.5%~1.0%
Oiliness improver is ethyl oleate.
Friction improver is phosphoric acid ester.
Anti-wear agent is sulphur phosphoric acid nitrogen containing derivative.
Oxidation inhibitor is 2,6 ditertiary butyl p cresol T501.
Antioxidant preservative is dialkyldithiocarbamacompositions tin.
Metal passivator is thiadiazole.
Remarkable advantage of the present invention has: have enough oil film thicknesses, stronger diffusion, perviousness, oil film strength is large, resistance to abrasion and sticky warm nature good, extreme pressure property is strong, cooling, cleaning and oilness good, have less flowing shear-stress, improve surface smoothness and the dimensions precision of metal tube, and have certain chemical stability and suitable flash-point and point of ignition, low viscosity, low sulfur-bearing, low virtue.
Embodiment
Embodiment 1:
Each component of following masses percentage ratio is in harmonious proportion and forms:
Component Mass percent content
250SN base oil Surplus
Ethyl oleate 5.0%
Phosphoric acid ester 2.0%
Sulphur phosphoric acid nitrogen containing derivative 2.5%
2,6 ditertiary butyl p cresol (T501) 0.2%
Dialkyldithiocarbamacompositions tin 0.5%
Thiadiazole 0.7%
Embodiment 2:
Each component of following masses percentage ratio is in harmonious proportion and forms:
Component Mass percent content
250SN base oil Surplus
Ethyl oleate 5.5%
Phosphoric acid ester 2.5%
Sulphur phosphoric acid nitrogen containing derivative 3.0%
2,6 ditertiary butyl p cresol (T501) 0.2%
Dialkyldithiocarbamacompositions tin 0.4%
Thiadiazole 0.8%
Embodiment 3: each component of following masses percentage ratio is in harmonious proportion and forms:
Component Mass percent content
250SN base oil Surplus
Ethyl oleate 6.0%
Phosphoric acid ester 2.5%
Sulphur phosphoric acid nitrogen containing derivative 2.5%
2,6 ditertiary butyl p cresol (T501) 0.3%
Dialkyldithiocarbamacompositions tin 0.5%
Thiadiazole 0.9%
The main physical and chemical index of embodiment 3 typical case:
Project Quality index
40 DEG C of kinematic viscosity/(mm 2﹒s -1) 50.1
Viscosity index 103
Pour point/DEG C -11
Flash-point (opening)/DEG C 232
Corrosion test (copper sheet, 100 DEG C, 3h) 1
Acid number/mg KOH ﹒ g -1 0.036
Moisture, % Vestige
Last non seizure load P B/N 854
Mechanical impurity, % Nothing

Claims (7)

1. cold spinning tin alloy pipe lubricant compositions, is characterized in that: adopt oil based on 250SN base oil, coordinate multiple additives, its each component and mass percent thereof are:
2. cold spinning tin alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, oiliness improver is ethyl oleate.
3. cold spinning tin alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, friction improver is phosphoric acid ester.
4. cold spinning tin alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, anti-wear agent is sulphur phosphoric acid nitrogen containing derivative.
5. cold spinning tin alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, oxidation inhibitor is 2,6 ditertiary butyl p cresol T501.
6. cold spinning tin alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, antioxidant preservative is dialkyldithiocarbamacompositions tin.
7. cold spinning tin alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, metal passivator is thiadiazole.
CN201510303865.XA 2015-06-05 2015-06-05 Lubricant combination for cold spinning copper alloy tube Pending CN104862045A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510303865.XA CN104862045A (en) 2015-06-05 2015-06-05 Lubricant combination for cold spinning copper alloy tube

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510303865.XA CN104862045A (en) 2015-06-05 2015-06-05 Lubricant combination for cold spinning copper alloy tube

Publications (1)

Publication Number Publication Date
CN104862045A true CN104862045A (en) 2015-08-26

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510303865.XA Pending CN104862045A (en) 2015-06-05 2015-06-05 Lubricant combination for cold spinning copper alloy tube

Country Status (1)

Country Link
CN (1) CN104862045A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106544086A (en) * 2016-11-04 2017-03-29 广西大学 A kind of tin and its alloy rotary pressing processing technology lubricant composition
CN106635288A (en) * 2016-09-21 2017-05-10 广西大学 Babbitt metal spinning lubricant composition

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004263087A (en) * 2003-03-03 2004-09-24 Kao Corp Lubricating oil for use in hot rolling oil for aluminum plate
CN103695091A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for cold forging of aluminum and aluminum alloy materials
CN103695124A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for drawing of aluminum and aluminum alloy tubes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004263087A (en) * 2003-03-03 2004-09-24 Kao Corp Lubricating oil for use in hot rolling oil for aluminum plate
CN103695091A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for cold forging of aluminum and aluminum alloy materials
CN103695124A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for drawing of aluminum and aluminum alloy tubes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106635288A (en) * 2016-09-21 2017-05-10 广西大学 Babbitt metal spinning lubricant composition
CN106544086A (en) * 2016-11-04 2017-03-29 广西大学 A kind of tin and its alloy rotary pressing processing technology lubricant composition

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Application publication date: 20150826