CN104974834A - Rhenium filament drawing lubricant composition - Google Patents

Rhenium filament drawing lubricant composition Download PDF

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Publication number
CN104974834A
CN104974834A CN201510427515.4A CN201510427515A CN104974834A CN 104974834 A CN104974834 A CN 104974834A CN 201510427515 A CN201510427515 A CN 201510427515A CN 104974834 A CN104974834 A CN 104974834A
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CN
China
Prior art keywords
compound composition
agent
rhenium
drawing compound
silk drawing
Prior art date
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Pending
Application number
CN201510427515.4A
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Chinese (zh)
Inventor
黄福川
李康春
邓富康
韦开焕
马骁飞
黄旖瑶
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Guangxi University
Original Assignee
Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201510427515.4A priority Critical patent/CN104974834A/en
Publication of CN104974834A publication Critical patent/CN104974834A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a rhenium filament drawing lubricant composition. Pentaerythritol oleate is taken as base oil and matched with multiple additives, wherein the multiple additives include an antioxidant, an oiliness solvent, an antiwear agent, an extreme-pressure agent, a friction promoter, an adhesive, an antioxidant and corrosion inhibitor and a reinforcing agent. The lubricant composition disclosed by the invention has the advantages of good lubricity, cooling property, wettability, permeability, diffusivity, anti-rust property, high adhesion, abrasion resistance, viscosity-temperature property, washability and good chemical stabilization, is capable of enhancing the oil film thickness in a deformation area, lowering friction coefficient, keeping stable oil film strength and thickness performance, reducing abrasion of a drawing die, has a relatively small flow shear stress, and has the beneficial effects of improving the surface smoothness and specification precision of a processed rhenium filament and prolonging the corrosion-resistant period.

Description

Rhenium silk drawing compound composition
Technical field
The invention belongs to intermetallic composite coating drawing process field of lubricant, particularly rhenium silk drawing compound composition.
Background technology
Rhenium is a kind of real rare elements, and it is a member in manganese subgroup, and the content in the earth's crust is all fewer than all rare earth elements; Meanwhile, add it and do not form fixing mineral, usually and other metal associations, Here it is, and it becomes last element that the current mankind find at occurring in nature.Pure rhenium is comparatively hard, and Mohs' hardness reaches 7, density 21.04g/cm 3, fusing point 3180 DEG C is one of refractory metal, and lattice types hexagonal is intensive, and outward appearance is similar to platinum, has good mechanical property.The normal association of rhenium, in the mineral such as molybdenum, copper, zinc, lead, be difficult to utilize separately, therefore rhenium is listed in dissipated metal.Its main application: as the catalyzer of petrochemical industry; Be applied to wireless, TV and other technologies; For high temperature instrument material, ultrahigh-temperature well heater, its major part is used to production aircraft engine.In addition, rhenium can improve tungsten, molybdenum, the intensity of chromium and plasticity simultaneously.The resistance to deformation of rhenium wire drawing increases with drawing deformation amount and increases, effective lubricant and lubricating method should be selected, carry out lubricating, clean, cool, protection against corrosion, reduce adhesion and thickness uneven phenomenon, reduce the damage and spot that cause because lubrication and cooling is bad on rhenium silk surface, it is long to improve the surface smoothness of processed rhenium silk, specification precision and anticorrosive cycle.
Summary of the invention
The technical problem to be solved in the present invention is to provide one and has good lubricating properties, cooling, wetting property, perviousness, diffustivity, rust-preventing characteristic, increases oil film strength in distorted area, reduces frictional coefficient, keeps oil film strength and thickness stable performance; Adhesivity is strong, and resistance to abrasion, sticky warm nature, washability, chemical stability are good; Reduce the wearing and tearing of drawing mould, have less flowing shear-stress, improve the rhenium silk drawing compound composition of the surface smoothness of processed rhenium silk, specification precision and length of anticorrosive cycle.
The present invention adopts following technical scheme to solve the problems of the technologies described above:
Rhenium silk drawing compound composition, adopt oil based on PETO, coordinate multiple additives, its each component and mass percent thereof are:
Component Mass percent content
Base oil Surplus
Oxidation inhibitor 0.5%~0.7%
Oiliness improver 3%~5%
Anti-wear agent 2%~4%
Extreme pressure agent 10%~12%
Friction improver 2%~3%
Adhesive agent 2%~4%
Antioxidant preservative 0.5%~0.8%
Strengthening agent 1%~2%
Oxidation inhibitor is alkyl diphenylamine.Oiliness improver is oleic acid glycol ester T403.
Anti-wear agent is sulfide isobutene T321.Extreme pressure agent is clorafin T302.
Friction improver is phosphoric acid ester T451.Adhesive agent is polyisobutene T603D.
Antioxidant preservative is that dibutyl dithiocaarbamate is plumbous.
Strengthening agent is methyl benzotriazazole.
Remarkable advantage of the present invention is: have good lubricating properties, cooling, wetting property, perviousness, diffustivity, rust-preventing characteristic, increases oil film strength in distorted area, reduces frictional coefficient, keeps oil film strength and thickness stable performance; Adhesivity is strong, and resistance to abrasion, sticky warm nature, washability, chemical stability are good; Reduce the wearing and tearing of drawing mould, have less flowing shear-stress, it is long to improve the surface smoothness of processed rhenium silk, specification precision and anticorrosive cycle.
Embodiment
Embodiment 1:
Each component is in harmonious proportion by following mass percent and forms:
Component Mass percent content
PETO 79%
Alkyl diphenylamine 0.5%
Oleic acid glycol ester (T403) 3%
Sulfide isobutene (T321) 2%
Clorafin (T302) 10%
Phosphoric acid ester T451 2%
Polyisobutene (T603D) 2%
Dibutyl dithiocaarbamate is plumbous 0.5%
Methyl benzotriazazole 1%
Embodiment 2:
Each component is in harmonious proportion by following mass percent and forms:
Component Mass percent content
PETO 73.8%
Alkyl diphenylamine 0.6%
Oleic acid glycol ester (T403) 4%
Sulfide isobutene (T321) 3%
Clorafin (T302) 11%
Phosphoric acid ester T451 2.5%
Polyisobutene (T603D) 3%
Dibutyl dithiocaarbamate is plumbous 0.6%
Methyl benzotriazazole 1.5%
Embodiment 3:
Each component is in harmonious proportion by following mass percent and forms:
Component Mass percent content
PETO 68.5%
Alkyl diphenylamine 0.7%
Oleic acid glycol ester (T403) 5%
Sulfide isobutene (T321) 4%
Clorafin (T302) 12%
Phosphoric acid ester T451 3%
Polyisobutene (T603D) 4%
Dibutyl dithiocaarbamate is plumbous 0.8%
Methyl benzotriazazole 2%
The main physical and chemical index of embodiment 3 product:
Project Quality index
Kinematic viscosity (40 DEG C)/mm 2/s 46.2
Viscosity index 126
Flash-point (opening)/DEG C 231
Pour point/DEG C -26
Mechanical impurity/% Nothing
Moisture/% Vestige
Corrosion test (copper sheet, 100 DEG C, 3h)/level 1
Oxidation stability (rotary bomb oxidation test, 150 DEG C)/%, min 243
Acid number/mgKOH/g 0.39
Supporting capacity P B/N 962

Claims (9)

1. rhenium silk drawing compound composition, is characterized in that: adopt oil based on PETO, coordinate multiple additives, its each component and mass percent thereof are:
Base oil surplus,
Oxidation inhibitor 0.5% ~ 0.7%,
Oiliness improver 3% ~ 5%,
Anti-wear agent 2% ~ 4%,
Extreme pressure agent 10% ~ 12%,
Friction improver 2% ~ 3%,
Adhesive agent 2% ~ 4%,
Antioxidant preservative 0.5% ~ 0.8%,
Strengthening agent 1% ~ 2%.
2. rhenium silk drawing compound composition as claimed in claim 1, it is characterized in that, oxidation inhibitor is alkyl diphenylamine.
3. rhenium silk drawing compound composition as claimed in claim 1, it is characterized in that, oiliness improver is oleic acid glycol ester T403.
4. rhenium silk drawing compound composition as claimed in claim 1, it is characterized in that, anti-wear agent is sulfide isobutene T321.
5. rhenium silk drawing compound composition as claimed in claim 1, it is characterized in that, extreme pressure agent is clorafin T302.
6. rhenium silk drawing compound composition as claimed in claim 1, it is characterized in that, friction improver is phosphoric acid ester T451.
7. rhenium silk drawing compound composition as claimed in claim 1, it is characterized in that, adhesive agent is polyisobutene T603D.
8. rhenium silk drawing compound composition as claimed in claim 1, is characterized in that, antioxidant preservative is that dibutyl dithiocaarbamate is plumbous.
9. rhenium silk drawing compound composition according to claim 1, it is characterized in that, strengthening agent is methyl benzotriazazole.
CN201510427515.4A 2015-07-20 2015-07-20 Rhenium filament drawing lubricant composition Pending CN104974834A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510427515.4A CN104974834A (en) 2015-07-20 2015-07-20 Rhenium filament drawing lubricant composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510427515.4A CN104974834A (en) 2015-07-20 2015-07-20 Rhenium filament drawing lubricant composition

Publications (1)

Publication Number Publication Date
CN104974834A true CN104974834A (en) 2015-10-14

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Family Applications (1)

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CN201510427515.4A Pending CN104974834A (en) 2015-07-20 2015-07-20 Rhenium filament drawing lubricant composition

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CN (1) CN104974834A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105969491A (en) * 2016-05-06 2016-09-28 沧州市亿达渤润石化有限公司 Oily eco-friendly drawing lubricant replacing wire drawing powder and preparation technology thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725376A (en) * 2013-12-18 2014-04-16 广西大学 Lubricating agent for drawing steel pipe
CN103725378A (en) * 2013-12-18 2014-04-16 广西大学 Lubricant for drawing high-finish aluminum and aluminum alloy pipes
CN104726171A (en) * 2013-12-23 2015-06-24 天津驰美润滑油有限公司 Novel zinc alloy drawing lubricating oil and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725376A (en) * 2013-12-18 2014-04-16 广西大学 Lubricating agent for drawing steel pipe
CN103725378A (en) * 2013-12-18 2014-04-16 广西大学 Lubricant for drawing high-finish aluminum and aluminum alloy pipes
CN104726171A (en) * 2013-12-23 2015-06-24 天津驰美润滑油有限公司 Novel zinc alloy drawing lubricating oil and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
董元虎: "《汽车油料使用问答》", 31 January 2009 *
郑发正: "《润滑剂性质与应用》", 31 August 2006 *
钟泰岗: "《汽车用精细化学品丛书 汽车用润滑脂及添加剂》", 31 July 2006 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105969491A (en) * 2016-05-06 2016-09-28 沧州市亿达渤润石化有限公司 Oily eco-friendly drawing lubricant replacing wire drawing powder and preparation technology thereof

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Application publication date: 20151014

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