CN105969491A - Oily eco-friendly drawing lubricant replacing wire drawing powder and preparation technology thereof - Google Patents

Oily eco-friendly drawing lubricant replacing wire drawing powder and preparation technology thereof Download PDF

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Publication number
CN105969491A
CN105969491A CN201610292875.2A CN201610292875A CN105969491A CN 105969491 A CN105969491 A CN 105969491A CN 201610292875 A CN201610292875 A CN 201610292875A CN 105969491 A CN105969491 A CN 105969491A
Authority
CN
China
Prior art keywords
eco
friendly
oily
base oil
mineral base
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610292875.2A
Other languages
Chinese (zh)
Inventor
张刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cangzhou Yida Bohai Run Petrochemical Co Ltd
Original Assignee
Cangzhou Yida Bohai Run Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cangzhou Yida Bohai Run Petrochemical Co Ltd filed Critical Cangzhou Yida Bohai Run Petrochemical Co Ltd
Priority to CN201610292875.2A priority Critical patent/CN105969491A/en
Publication of CN105969491A publication Critical patent/CN105969491A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64Environmental friendly compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Metal Extraction Processes (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses an oily eco-friendly drawing lubricant replacing wire drawing powder and a preparation technology thereof. The oily eco-friendly drawing lubricant comprises mineral base oil, sulfuretted fat and additives. The additives comprise, by mass, 55-65% of sulfuretted fat, 3-8% of triazole fatty amine salt, 3-8% of polyisobutene and the balance mineral base oil. The oily eco-friendly drawing lubricant does not produce dust pollution in a work environment and dust damage to an operator, reduces friction and wear, prolongs a grinding tool service life by one time, improves product quality, realizes energy saving, and is convenient for eco-friendly product later treatment. The traditional drawing process is carried out at a high temperature under high pressure so that metal wire bonding is produced and labor, water and time consumption is large. The product treated by the drawing lubricant solves the above problem and only needs to be washed once.

Description

Replace oiliness environmental protection drawing compound and the preparation technology thereof of wire drawing powder
Technical field
The present invention relates to metal drawing shaping assistant technical field, be specifically related to a kind of oiliness environmental protection replacing wire drawing powder and draw Pull out lubricant and preparation technology thereof.
Background technology
There is a class to be belonging to bar, wire rod or tubing in metal working process and reach technological requirement by drawing molding Required shape or size, this technique is widely used in the wide spectrums such as industry, civilian and building, in actual production, for a long time Use powder to use as lubricant (drawing powder), be nearly all especially to use powder class lubrication in bar, wire drawing.Its Advantage is low cost, and effect is obvious, and shortcoming is owing to producing in the high-speed motion of wire rod and alternative process in drawing process Heat and electrostatic make to fill the air everywhere as the powder of Lubrication Composition, pollute environment, also the health of operator are caused wound simultaneously Evil, the anthraco-silicosis incidence rate of the personnel being engaged in this work post in this industry for a long time is the highest.
Therefore metal drawing industry is in the urgent need to a kind of products substitution safe and environment-friendly, efficient existing drawing powder, and I am public Department studies discovery by inquiry, and due to the particularity of its drawing process, a kind of substitute products difficulty of invention is very big, because drawing is raw In product, material modification amount is big, and speed is fast, and general oil product in use, all can not meet technique needs.
Summary of the invention
The invention provides a kind of oiliness environmental protection drawing compound replacing wire drawing powder and preparation technology thereof, existing to solve The problem that the metal drawing molding that technology exists can not use lubricating oil.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of oiliness environmental protection drawing compound replacing wire drawing powder, is made up of mineral base oil, sulfurized fatty and additive, adds Adding agent and include fatty amine triazole and polyisobutylene, the mass percent that described each component uses is: sulfurized fatty 55% ~ 65%; Fatty amine triazole 3% ~ 8%;Polyisobutylene 3% ~ 8%;Surplus is mineral base oil.
The preparation technology of the oiliness environmental protection drawing compound of above-mentioned replacement wire drawing powder is: add mineral base in reactor Plinth oil is warming up to 60 DEG C, is subsequently adding sulfurized fatty and fatty amine triazole under agitation, finally adds polyisobutylene, Treat after stirring one hour that it all dissolves and become stable, thickness, limpid state.
Adding fatty amine triazole in oiliness environmental protection drawing lubrication agent prescription of the present invention, fatty amine triazole is powder, Use as metallic reducing agent, the fretting wear between metal can be prevented effectively from.
The drawing compound of the present invention is oil preparation product, and working environment no dust pollution, operator are without dust harzard;Fall Low friction wear, grinding tool extends one times service life, and product quality is improved, and energy-saving effect is obvious simultaneously;At the product later stage Reason facilitates environmental protection, and the drawing in past is many under High Temperature High Pressure effect, has pinning phenomenon with metal wire rod, and later stage process is taken a lot of work, expense Water, time-consuming, with the product of drawing oil then without this phenomenon, only need to clean once.
Detailed description of the invention
A kind of oiliness environmental protection drawing compound replacing wire drawing powder, by mineral base oil, sulfurized fatty and additive group Becoming, additive includes fatty amine triazole and polyisobutylene, and the mass percent that described each component uses is: sulfurized fatty 55% ~ 65%;Fatty amine triazole 3% ~ 8%;Polyisobutylene 3% ~ 8%;Surplus is mineral base oil.The oiliness environmental protection replacing wire drawing powder draws The preparation technology pulling out lubricant is: adds mineral base oil in reactor and is warming up to 60 DEG C, the most then adds Enter sulfurized fatty and fatty amine triazole, finally add polyisobutylene, treat after stirring one hour its all dissolve become stable, Thickness, limpid state.
This lubricant is tried out in Duo Jia drawing enterprise, achieves positive effect, and comparing tradition drawing powder has following several Big advantage:
Working environment no dust pollution, operator are without dust harzard
Reducing friction wear, grinding tool extends one times service life, and product quality is improved, simultaneously energy-saving effect substantially (joint Electricity 10%)
The process of product later stage facilitates environmental protection, and the drawing in past is many under High Temperature High Pressure effect, has bonding existing with metal wire rod As, later stage process take a lot of work, water wasting, time-consuming, with the product of drawing oil then without this phenomenon, only need to clean once.

Claims (2)

1. replace an oiliness environmental protection drawing compound for wire drawing powder, it is characterized in that by mineral base oil, sulfurized fatty and add Adding agent composition, additive includes fatty amine triazole and polyisobutylene, and the mass percent that described each component uses is: sulfurized fat Fat 55% ~ 65%;Fatty amine triazole 3% ~ 8%;Polyisobutylene 3% ~ 8%;Surplus is mineral base oil.
2. the preparation technology of the oiliness environmental protection drawing compound replacing wire drawing powder described in claim 1, is characterized in that in reaction Add mineral base oil in still and be warming up to 60 DEG C, be subsequently adding sulfurized fatty and fatty amine triazole under agitation, After add polyisobutylene, treating after stirring one hour that it all dissolves becomes stable, thickness, limpid state.
CN201610292875.2A 2016-05-06 2016-05-06 Oily eco-friendly drawing lubricant replacing wire drawing powder and preparation technology thereof Pending CN105969491A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610292875.2A CN105969491A (en) 2016-05-06 2016-05-06 Oily eco-friendly drawing lubricant replacing wire drawing powder and preparation technology thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610292875.2A CN105969491A (en) 2016-05-06 2016-05-06 Oily eco-friendly drawing lubricant replacing wire drawing powder and preparation technology thereof

Publications (1)

Publication Number Publication Date
CN105969491A true CN105969491A (en) 2016-09-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610292875.2A Pending CN105969491A (en) 2016-05-06 2016-05-06 Oily eco-friendly drawing lubricant replacing wire drawing powder and preparation technology thereof

Country Status (1)

Country Link
CN (1) CN105969491A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867648A (en) * 2016-12-22 2017-06-20 当涂县宏宇金属炉料有限责任公司 A kind of waste lubricating oil makes wire drawing powder method
CN106867642A (en) * 2017-01-19 2017-06-20 南京百丝胜新材料科技有限公司 A kind of metal wire rod wire drawing powder and preparation method thereof
CN111876222A (en) * 2020-07-16 2020-11-03 常州市九鑫铜业有限公司 Crystallizer copper pipe drawing oil containing sulfuration modified swill-cooked dirty oil

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1150080A (en) * 1997-08-06 1999-02-23 Sumitomo Metal Ind Ltd Pre-die lubricant for wire drawing and lubrication treatment of base material for high strength bolt
CN103374452A (en) * 2012-04-27 2013-10-30 中国石油化工股份有限公司 Manual transmission lubricating oil composition
CN103695126A (en) * 2013-12-18 2014-04-02 广西大学 Lubricating agent for drawing of permalloy stainless steel plate
CN104974834A (en) * 2015-07-20 2015-10-14 广西大学 Rhenium filament drawing lubricant composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1150080A (en) * 1997-08-06 1999-02-23 Sumitomo Metal Ind Ltd Pre-die lubricant for wire drawing and lubrication treatment of base material for high strength bolt
CN103374452A (en) * 2012-04-27 2013-10-30 中国石油化工股份有限公司 Manual transmission lubricating oil composition
CN103695126A (en) * 2013-12-18 2014-04-02 广西大学 Lubricating agent for drawing of permalloy stainless steel plate
CN104974834A (en) * 2015-07-20 2015-10-14 广西大学 Rhenium filament drawing lubricant composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
沈萌红等: "《机械设计》", 30 September 2012, 华中科技大学出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867648A (en) * 2016-12-22 2017-06-20 当涂县宏宇金属炉料有限责任公司 A kind of waste lubricating oil makes wire drawing powder method
CN106867648B (en) * 2016-12-22 2020-04-21 当涂县宏宇金属炉料有限责任公司 Method for preparing wire drawing powder from waste lubricating oil
CN106867642A (en) * 2017-01-19 2017-06-20 南京百丝胜新材料科技有限公司 A kind of metal wire rod wire drawing powder and preparation method thereof
CN111876222A (en) * 2020-07-16 2020-11-03 常州市九鑫铜业有限公司 Crystallizer copper pipe drawing oil containing sulfuration modified swill-cooked dirty oil
CN111876222B (en) * 2020-07-16 2022-08-12 常州市九鑫铜业有限公司 Crystallizer copper pipe drawing oil containing sulfuration modified swill-cooked dirty oil

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C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
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Application publication date: 20160928