CN103695118A - Lubricant for drawing tin and alloy material thereof - Google Patents

Lubricant for drawing tin and alloy material thereof Download PDF

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Publication number
CN103695118A
CN103695118A CN201310701664.6A CN201310701664A CN103695118A CN 103695118 A CN103695118 A CN 103695118A CN 201310701664 A CN201310701664 A CN 201310701664A CN 103695118 A CN103695118 A CN 103695118A
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China
Prior art keywords
lubricant
alloy material
tin
drawing tin
agent
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CN201310701664.6A
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Chinese (zh)
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CN103695118B (en
Inventor
黄福川
覃克
李胜
肖友程
蓝明新
梁慧
唐彩珍
粟满荣
唐兴中
廖丹葵
刘琨
黄旖瑶
经建芳
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Guangxi University
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Guangxi University
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Abstract

The invention discloses a lubricant for drawing tin and an alloy material thereof. 15# total loss system oil is adopted as base oil and matched with a plurality of composite additives. The lubricant comprises an oiliness agent, an antiwear agent, an extreme pressure agent, an anti-foaming agent, an antioxidant and a friction modifier. The lubricant for drawing tin and the alloy material thereof disclosed by the invention has strong diffusivity and permeability, and is high in oil film strength, good in wearing quality and viscosity-temperature characteristics, strong in extreme pressure property, good in cooling property and lubricating property, and small in flow shear stress, abrasion of a drawing tool and a drawing die is reduced, the surface glossiness and the specification accuracy of metal are improved, and the lubricant has certain chemical stability, proper flash point and ignition point, is the lubricant which is low in viscosity, low in sulfur content, low in aromatic hydrocarbon, and convenient to use and clean.

Description

The lubricant of drawing tin and alloy material thereof
Technical field
The invention belongs to the field of lubricant of non-ferrous metal drawing processing and lubrication, particularly drawing tin and alloy material thereof.
Background technology
Tin, metallic element, a kind of low melting point metal element of slightly bluish white gloss, is argenteous soft metal, and proportion is 7.3, and fusing point only has 232 ℃, puts the liquid that just can be melt in coal dust ball stove as mercury into.Tin is very soft, with pocket knife, can cut it.The chemical property of tin is very stable, is difficult for being at normal temperatures oxidized by oxygen; Therefore, it often keeps the glittering gloss of silver.Tin is nontoxic, and plasticity-is strong and ductility is very poor, can not pull into filament.It can have various process of surface treatment, can make the product of multiple style, tin remains the indispensable crucial rare metal of modern industry, is known as " industrial monosodium glutamate ", is widely used in the industries such as electronics, information, electrical equipment, chemical industry, metallurgy, building materials, machinery, food product pack.
Conventionally the resistance to deformation of tin and alloy thereof increases with drawing deformation amount, should select effective lubricant and lubricating method, is lubricated, cleaning, cooling and reduce nib and drawing part adherent phenomenon, the damage that minimizing drawing part surface adhering causes.
Drawing is one of main production method of tubing, bar, section bar and wire rod.Press goods cross-sectional shape, drawing can be divided into: solid material drawing and the large class of hollow material drawing two.Drawing tin and alloy material thereof are that tin and alloy material blank thereof are imposed to pulling force, make it by nib to obtain the plastic processing method with nib sectional dimension, goods that shape is identical.
In drawing process, the friction except between material, drawing-die and steel core, on contact surface, because drawing speed improves, will occurrence temperature sharply rise.In order reducing, in drawing process, to there is heavy wear or sintering, thereby to require lubricant to play antifriction and wear prevention, cooling, lubricated effect; Be improved drawing speed and section reduction rate simultaneously, to improve output and the quality of drawing process processing, prevent the generation of the defects such as surface tear, fold, bending, bias, crackle, broken end, metal are pressed into.Guarantee output and the quality of drawing process processing.
Summary of the invention
The technical problem to be solved in the present invention is to provide the lubricant of a kind of drawing tin and alloy material thereof, this lubricant has stronger diffusion and perviousness, oil film strength is large, resistance to abrasion and sticky warm nature are good, and extreme pressure property is strong, Cooling and Lubricator is good, reduces the wearing and tearing of drawing device and drawing-die, there is less mobile shear-stress, improve metallic surface smooth finish and specification precision, and have certain chemical stability and suitable flash-point and point of ignition, low viscosity, low sulfur-bearing, low aromatic hydrocarbons.
The present invention is usingd following technical scheme and is solved the problems of the technologies described above: adopt No. 15 total loss systems with oil as base oil, coordinate multiple composite additive, its each component and mass percent are:
Component Content (mass percent)
Base oil Surplus
Oiliness improver 5.0%~10.0%
Anti-wear agent 5.0%~7.0%
Extreme pressure agent 3.0%~5.0%
Oxidation inhibitor 1.5%~2.0%
Friction improver 0.5%~3.0%
Kilfoam 0.01%~0.02%
Base oil is No. 15 oil for total loss system.
Oiliness improver is industrial lard.
Anti-wear agent is tritolyl phosphate.
Extreme pressure agent is dialkyldithiocarbamacompositions tin.
Oxidation inhibitor is that N-phenyl-a-naphthylamine and 40%~50% the 2,6 ditertiary butyl p cresol of mass ratio 60%~50% is compound.
Friction improver is that sulphur molybdenum phosphate and 40%~50% the boric acid molybdenum of mass ratio 60%~50% is compound.
Kilfoam is dimethyl silicone oil.
The lubricant of drawing tin of the present invention and alloy material thereof, have stronger diffusion and perviousness, oil film strength is large, and resistance to abrasion and sticky warm nature are good, extreme pressure property is strong, Cooling and Lubricator is good, reduce the wearing and tearing of drawing device and drawing-die, have less mobile shear-stress, improve metallic surface smooth finish and specification precision, there is certain chemical stability, having suitable flash-point and point of ignition, is the lubricant of low viscosity, low sulfur-bearing, low aromatic hydrocarbons, easy to use and cleaning.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and is formed by mass percentage:
Component Content (mass percent)
No. 15 oil for total loss system 72.98%
Industrial lard 10.0%
Tritolyl phosphate 7.0%
Dialkyldithiocarbamacompositions tin 5.0%
The N-phenyl-a-naphthylamine of mass ratio 60% and 40% 2,6 ditertiary butyl p cresol are compound 2.0%
The sulphur molybdenum phosphate of mass ratio 60% and 40% boric acid molybdenum are compound 3.0%
Dimethyl silicone oil 0.02%
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and is formed by mass percentage:
Component Content (mass percent)
No. 15 oil for total loss system 78.985%
Industrial lard 7.5%
Tritolyl phosphate 6.0%
Dialkyldithiocarbamacompositions tin 4.0%
The N-phenyl-a-naphthylamine of mass ratio 55% and 45% 2,6 ditertiary butyl p cresol are compound 1.75%
The sulphur molybdenum phosphate of mass ratio 55% and 45% boric acid molybdenum are compound 1.75%
Dimethyl silicone oil 0.015%
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and is formed by mass percentage:
Component Content (mass percent)
No. 15 oil for total loss system 84.99%
Industrial lard 5.0%
Tritolyl phosphate 5.0%
Dialkyldithiocarbamacompositions tin 3.0%
The N-phenyl-a-naphthylamine of mass ratio 50% and 50% 2,6 ditertiary butyl p cresol are compound 1.5%
The sulphur molybdenum phosphate of mass ratio 50% and 50% boric acid molybdenum are compound 0.5%
Dimethyl silicone oil 0.01%
Above component summation is 100%.
The main physical and chemical index of embodiment 2 products is:
Project Quality index
Moisture, % Vestige
40 ℃ of kinematic viscosity mm 2/s 15.5
Flash-point (opening) ℃, 160
Mechanical impurity, % Nothing
Last non seizure load (Pb), Kg 100
Pour point, ℃, -12
Water soluble acid or alkali Nothing
Corrosion test (copper sheet, 100 ℃, 3h), level 1
Viscosity index, is not less than 90

Claims (8)

1. a lubricant for drawing tin and alloy material thereof, is characterized in that adopting No. 15 total loss systems as base oil, to coordinate multiple composite additive with oily, and its each component and mass percent are:
Component Mass percentage content Base oil Surplus Oiliness improver 5.0%~10.0% Anti-wear agent 5.0%~7.0% Extreme pressure agent 3.0%~5.0% Oxidation inhibitor 1.5%~2.0% Friction improver 0.5%~3.0% Kilfoam 0.01%~0.02%
2. the lubricant of drawing tin as claimed in claim 1 and alloy material thereof, is characterized in that base oil is No. 15 oil for total loss system.
3. the lubricant of drawing tin as claimed in claim 1 and alloy material thereof, is characterized in that oiliness improver is industrial lard.
4. the lubricant of drawing tin as claimed in claim 1 and alloy material thereof, is characterized in that anti-wear agent is tritolyl phosphate.
5. the lubricant of drawing tin as claimed in claim 1 and alloy material thereof, is characterized in that extreme pressure agent is dialkyldithiocarbamacompositions tin.
6. the lubricant of drawing tin as claimed in claim 1 and alloy material thereof, is characterized in that oxidation inhibitor is that N-phenyl-a-naphthylamine and 40%~50% the 2,6 ditertiary butyl p cresol of mass ratio 60%~50% is compound.
7. the lubricant of drawing tin as claimed in claim 1 and alloy material thereof, is characterized in that friction improver is that sulphur molybdenum phosphate and 40%~50% the boric acid molybdenum of mass ratio 60%~50% is compound.
8. the lubricant of drawing tin as claimed in claim 1 and alloy material thereof, is characterized in that kilfoam is dimethyl silicone oil.
CN201310701664.6A 2013-12-18 2013-12-18 The lubricant of drawing tin and alloy material thereof Active CN103695118B (en)

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Application Number Priority Date Filing Date Title
CN201310701664.6A CN103695118B (en) 2013-12-18 2013-12-18 The lubricant of drawing tin and alloy material thereof

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CN103695118A true CN103695118A (en) 2014-04-02
CN103695118B CN103695118B (en) 2015-08-19

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106635295A (en) * 2016-09-21 2017-05-10 广西大学 Lubricant composition for rolling processing of cast carbon steel

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103436333A (en) * 2013-08-26 2013-12-11 广西大学 Lubricating agent for cold rolling of vanadium and vanadium-alloy sheets

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103436333A (en) * 2013-08-26 2013-12-11 广西大学 Lubricating agent for cold rolling of vanadium and vanadium-alloy sheets

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106635295A (en) * 2016-09-21 2017-05-10 广西大学 Lubricant composition for rolling processing of cast carbon steel

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