CN103436333A - Lubricating agent for cold rolling of vanadium and vanadium-alloy sheets - Google Patents

Lubricating agent for cold rolling of vanadium and vanadium-alloy sheets Download PDF

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Publication number
CN103436333A
CN103436333A CN2013103761264A CN201310376126A CN103436333A CN 103436333 A CN103436333 A CN 103436333A CN 2013103761264 A CN2013103761264 A CN 2013103761264A CN 201310376126 A CN201310376126 A CN 201310376126A CN 103436333 A CN103436333 A CN 103436333A
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vanadium
oil
alloy plate
plate strip
agent
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CN2013103761264A
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CN103436333B (en
Inventor
黄福川
毛汉领
莫宇飞
梁景
粟满荣
唐兴中
蓝明新
肖友程
李胜
梁慧
唐彩珍
田宗义
赵钟兴
廖丹葵
刘琨
黄旖瑶
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Guangxi University
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Guangxi University
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Abstract

The invention relates to a lubricating agent for the cold rolling of vanadium and vanadium-alloy sheets. The lubricating agent is characterized in that total-loss system oil No.15 is used as base oil and is coordinated with multiple compound additives which comprise an anti-wear agent, an oiliness agent, an antioxidant preservative, an antioxidant, an anti-foaming agent and a demulsifying agent. The lubricating agent has the property of reducing the hot adhesion of rollers and rolled pieces, low viscosity and low sulfur content as well as good cooling, lubricating, cleaning, diffusion and thermal oxidation stability mineral oil and does not generate oil patches during annealing.

Description

Vanadium and alloy plate strip cold-rolling lubricant thereof
Technical field
The invention belongs to a kind of vanadium and alloy plate strip cold-rolling lubricant field thereof.
Background technology
Vanadium is a kind of silver-gray metal.1919 ± 2 ℃ of fusing points, belong to the row of high-melting-point rare metal.Its boiling point 3000--3400 ℃, the density of vanadium is every cubic centimetre of 6.11 gram.Pure vanadium has malleability, and apparently, vanadium and iron are worn silver-gray clothes equally, but vanadium is much harder than iron, and at normal temperatures, vanadium very " is cooled down ", and it can be not oxidized, even it is heated to 300 degree Celsius, it still as before, remains brightly lit.It is the corrosion of not water funk, various diluted acid and alkali lye also.In various metals, it can be very special.
Vanadium mainly is used in metallurgy, the same with other iron alloy, as catalyzer and reductive agent, but, because vanadium can increase wear resistance and the ductility of steel, makes it at excellent steel, special steel, in bar, sheet material and section bar, enjoys favor.Only need in steel, add the vanadium of percentum, just can make the elasticity of steel, intensity increase, resistance to wear fabulous with anti-cracking property, not only high temperature resistant but also anti-strange cold, in departments such as automobile, aviation, railway, electronic technology, national defense industry, be found everywhere the trace of vanadium.In addition, the oxide compound of vanadium has become one of optimum catalyst in chemical industry, and the title of " chemical bread " is arranged.Vanadium has physicals and the chemical property of numerous excellences, thereby the purposes of vanadium is very extensive, the metal that is otherwise known as " VITAMIN ".Initial vanadium is applied to iron and steel mostly, by tissue and the crystal grain of refinement steel, improves the grain coarsening temperature, thereby plays intensity, toughness and the wear resistance that increases steel.Afterwards, found again gradually the excellent improving effect of vanadium in titanium alloy, and be applied to aerospace field, thereby made aerospace industry obtain breakthrough progress.Along with developing by leaps and bounds of scientific and technological level, vanadium is more and more extensive in the application in non-steel field, and its scope has contained the various fields such as aerospace, chemistry, battery, pigment, glass, optics, medicine.
When vanadium and alloy plate strip cold rolling thereof, because elastic flattening makes the unit pressure of strip side portion very little, and the unit pressure at band middle part is very high.If adopt with pressure, increase and the remarkable lubricant increased of frictional coefficient, strip can produce very large edge extension and affect its planeness.Vanadium is when cold rolling, and along with the increasing of reduction in pass and roll speed are accelerated, surface smoothness can reduce, the hot sticky phenomenon of Here it is roll and rolled piece, and the small abrasion powder at this moment generated is attached on roll or material surface, makes plate surface coarse.When vanadium cold rolling (finish rolling), owing to laying particular emphasis on product surface quality, in the situation that meet plate shape, require, add less lubricant as far as possible.Therefore, be necessary to adopt the low viscosity that does not produce oil mark when annealing, low sulfur-bearing, high bearing capacity, there is the lubricant of good cooling, lubricated, clean, diffusion, thermal oxidation stability mineral oil simultaneously.
Summary of the invention
The technical problem to be solved in the present invention is to provide vanadium and the alloy plate strip cold-rolling lubricant thereof that a kind of hot sticky, when annealing of reducing roll and rolled piece do not produce oil mark, low viscosity, low sulfur-bearing.
The present invention is usingd following technical scheme and is solved the problems of the technologies described above: adopt No. 15 total loss systems with oil as base oil, coordinate multiple composite additive, its each component and mass percent are:
Component Content (mass percent)
Base oil 75%~85%
Anti-wear agent 3.0%~5.0%
Oiliness improver 10.0%~20.0%
Antioxidant preservative 0.5%~1.2%
Oxidation inhibitor 0.1%~0.3%
Kilfoam 0.001%~0.003%
Non-emulsifying agent 0.2%~0.5%
Base oil is No. 15 total loss system oil.
Anti-wear agent is that the tritolyl phosphate of the mass ratio boric acid ester that is 50%~40% and 50%~60% is compound.
Oiliness improver is that dimeracid and 40%~50% the rapeseed oil of mass ratio 60%~50% is compound.
Antioxidant preservative is sulphur phosphorus brothers base zinc salt.
Oxidation inhibitor is N, the inferior Whitfield's ointment propylene diamine of N-bis-.
Kilfoam is dimethyl silicone oil.
Non-emulsifying agent is the polyethers macromolecular compound.
Vanadium of the present invention and alloy plate strip cold-rolling lubricant thereof can significantly reduce hot sticky the phenomenon of roll and rolled piece; Do not produce the low viscosity of oil mark, low sulfur-bearing when annealing; The lubricant that simultaneously there is good cooling, lubricated, clean, diffusion, thermal oxidation stability mineral oil.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and forms by mass percentage:
Component Content (mass percent)
No. 15 total loss system oil 75%
The boric acid ester of mass ratio 50% and 50% tritolyl phosphate are compound 5.0%
The dimeracid of mass ratio 60% and 40% rapeseed oil are compound 18.0%
Sulphur phosphorus brothers base zinc salt 1.2%
N, the inferior Whitfield's ointment propylene diamine of N-bis- 0.297%
Dimethyl silicone oil 0.003%
The polyethers macromolecular compound 0.5%
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and forms by mass percentage:
Component Content (mass percent)
No. 15 total loss system oil 80%
The boric acid ester of mass ratio 45% and 55% tritolyl phosphate are compound 4.0%
The dimeracid of mass ratio 55% and 45% rapeseed oil are compound 14.5%
Sulphur phosphorus brothers base zinc salt 1.0%
N, the inferior Whitfield's ointment propylene diamine of N-bis- 0.198%
Dimethyl silicone oil 0.002%
The polyethers macromolecular compound 0.3%
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and forms by mass percentage:
Component Content (mass percent)
No. 15 total loss system oil 85%
The boric acid ester of mass ratio 40% and 60% tritolyl phosphate are compound 3.0%
The dimeracid of mass ratio 50% and 50% rapeseed oil are compound 11.0%
Sulphur phosphorus brothers base zinc salt 0.6%
N, the inferior Whitfield's ointment propylene diamine of N-bis- 0.199%
Dimethyl silicone oil 0.001%
The polyethers macromolecular compound 0.2%
Above component summation is 100%.
Be below the key technical indexes of embodiment 3 products:
Project Quality index
Moisture, % is not more than Vestige
40 ℃ of kinematic viscosity mm 2/s 14.8
Flash-point (opening) ℃, be greater than 150
Mechanical impurity, % is not more than 0.0050
Last non seizure load (P b), Kg is not less than 90
Pour point, ℃, not higher than -5
Water soluble acid or alkali Nothing
Corrosion test (copper sheet, 100 ℃, 3h), level 1
Viscosity index, be not less than 80

Claims (8)

1. a vanadium and alloy plate strip cold-rolling lubricant thereof, it is characterized in that adopting No. 15 total loss systems with oil as base oil, coordinate multiple composite additive, its component and mass percent are:
Component Mass percentage content Base oil 75%~85% Anti-wear agent 3.0%~5.0% Oiliness improver 10.0%~20.0% Antioxidant preservative 0.5%~1.2% Oxidation inhibitor 0.1%~0.3% Kilfoam 0.001%~0.003% Non-emulsifying agent 0.2%~0.5%
2. vanadium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that base oil is No. 15 total loss system oil.
3. vanadium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that anti-wear agent is that boric acid ester and 50%~60% the tritolyl phosphate of mass ratio 50%~40% is compound.
4. vanadium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that oiliness improver is that dimeracid and 40%~50% the rapeseed oil of mass ratio 60%~50% is compound.
5. vanadium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that antioxidant preservative is sulphur phosphorus brothers base zinc salt.
6. vanadium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that oxidation inhibitor is N, the inferior Whitfield's ointment propylene diamine of N-bis-.
7. vanadium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that kilfoam is dimethyl silicone oil.
8. vanadium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that non-emulsifying agent is the polyethers macromolecular compound.
CN201310376126.4A 2013-08-26 2013-08-26 Vanadium and alloy plate strip cold-rolling lubricant thereof Expired - Fee Related CN103436333B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103695118A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for drawing tin and alloy material thereof
CN103695087A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for cold die forging of copper and copper alloy metal plates
CN103710105A (en) * 2013-12-14 2014-04-09 广西大学 Lubricant for extruding tin and tin alloy materials
CN104974838A (en) * 2015-07-20 2015-10-14 广西大学 Rotary cold-forging vanadium alloy lubricant composition
CN106520298A (en) * 2016-11-04 2017-03-22 广西大学 A lubricant composition for a cupronickel grinding process
CN106544131A (en) * 2016-11-04 2017-03-29 广西大学 A kind of cold rolling processing technique lubricant compositions of bell metal Strip

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030195125A1 (en) * 2002-04-08 2003-10-16 Motoharu Akiyama Bearing for electronically controlled throttle motor
CN103215112A (en) * 2013-04-09 2013-07-24 苏州美贝尔工业油品有限公司 Lubricating oil for cold reduction of tubes and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030195125A1 (en) * 2002-04-08 2003-10-16 Motoharu Akiyama Bearing for electronically controlled throttle motor
CN103215112A (en) * 2013-04-09 2013-07-24 苏州美贝尔工业油品有限公司 Lubricating oil for cold reduction of tubes and preparation method thereof

Non-Patent Citations (1)

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Title
李德峰等: "有色金属轧制工艺润滑技术研究", 《轻金属》, no. 6, 31 December 2000 (2000-12-31), pages 58 - 61 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710105A (en) * 2013-12-14 2014-04-09 广西大学 Lubricant for extruding tin and tin alloy materials
CN103710105B (en) * 2013-12-14 2015-06-17 广西大学 Lubricant for extruding tin and tin alloy materials
CN103695118A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for drawing tin and alloy material thereof
CN103695087A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for cold die forging of copper and copper alloy metal plates
CN103695087B (en) * 2013-12-18 2015-06-24 广西大学 Lubricant for cold die forging of copper and copper alloy metal plates
CN103695118B (en) * 2013-12-18 2015-08-19 广西大学 The lubricant of drawing tin and alloy material thereof
CN104974838A (en) * 2015-07-20 2015-10-14 广西大学 Rotary cold-forging vanadium alloy lubricant composition
CN106520298A (en) * 2016-11-04 2017-03-22 广西大学 A lubricant composition for a cupronickel grinding process
CN106544131A (en) * 2016-11-04 2017-03-29 广西大学 A kind of cold rolling processing technique lubricant compositions of bell metal Strip

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Inventor after: Huang Fuchuan

Inventor after: Tang Caizhen

Inventor after: Tian Zongyi

Inventor after: Zhao Zhongxing

Inventor after: Liao Dankui

Inventor after: Liu Kun

Inventor after: Huang Yiyao

Inventor after: Mo Yufei

Inventor after: Liang Jing

Inventor after: Su man Rong

Inventor after: Tang Xingzhong

Inventor after: Lan Mingxin

Inventor after: Xiao Youcheng

Inventor after: Li Sheng

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Inventor before: Huang Fuchuan

Inventor before: Liang Hui

Inventor before: Tang Caizhen

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Inventor before: Zhao Zhongxing

Inventor before: Liao Dankui

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Inventor before: Su man Rong

Inventor before: Tang Xingzhong

Inventor before: Lan Mingxin

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Free format text: CORRECT: INVENTOR; FROM: HUANG FUCHUAN MAO HANLING MO YUFEI LIANG JING SU MANRONG TANG XINGZHONG LAN MINGXIN XIAO YOUCHENG LI SHENG LIANG HUI TANG CAIZHEN TIAN ZONGYI ZHAO ZHONGXING LIAO DANKUI LIU KUN HUANG YIYAO TO: HUANG FUCHUAN MO YUFEI LIANG JING SU MANRONG TANG XINGZHONG LAN MINGXIN XIAO YOUCHENG LI SHENG LIANG HUI TANG CAIZHEN TIAN ZONGYI ZHAO ZHONGXING LIAO DANKUI LIU KUN HUANG YIYAO

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