CN103409213A - Lubricant for cold-rolling of cadmium/cadmium alloy plate strip - Google Patents

Lubricant for cold-rolling of cadmium/cadmium alloy plate strip Download PDF

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Publication number
CN103409213A
CN103409213A CN2013103754523A CN201310375452A CN103409213A CN 103409213 A CN103409213 A CN 103409213A CN 2013103754523 A CN2013103754523 A CN 2013103754523A CN 201310375452 A CN201310375452 A CN 201310375452A CN 103409213 A CN103409213 A CN 103409213A
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Prior art keywords
cadmium
alloy plate
plate strip
lubricant
rolling lubricant
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CN2013103754523A
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Chinese (zh)
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CN103409213B (en
Inventor
黄福川
毛汉领
莫宇飞
梁景
粟满荣
唐兴中
肖友程
蓝明新
李胜
梁慧
唐彩珍
田宗义
李宏君
赵钟兴
廖丹葵
刘琨
黄旖瑶
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Guangxi University
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Guangxi University
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Abstract

The invention discloses a lubricant for cold-rolling of a cadmium/cadmium alloy plate strip. 7# total loss system oil is used as base oil and is mixed with a plurality of composite additives, wherein the composite additives include an anti-wear agent, an oiliness agent, an anti-oxygen preservative, an anti-foaming agent, a demulsifying agent and a friction improver. The lubricant has excellent cooling, cleaning, lubricating, diffusing, high-temperature resistance and thermal oxidation stability performances and can better keep a certain continuity and thickness of an oil film; and the lubricant can reduce a friction coefficient and an adhesion between a roller and a rolled piece during cold-rolling, and can meet demands on plate shape and surface finish.

Description

Cadmium and alloy plate strip cold-rolling lubricant thereof
Technical field
The invention belongs to cadmium and alloy plate strip cold-rolling lubricant field thereof.
Background technology
Cadmium, be the glossiness metal of silvery white, 320.9 ℃ of fusing points, 765 ℃ of boiling points, density 8650kg/m 3.Flexible and ductility.Cadmium slow oxidation lose metalluster in damp atmosphere, during heating, surface forms brown oxide skin.Cadmium is mainly used in the plating of steel, iron, copper, brass and other metals, strong to the anti-corrosion capability of alkaline matter.Cadmium can be used for manufacturing the little and large battery of electrical capacity of volume.The compound of cadmium is also in a large number for the production of pigment and fluorescent material.It is a kind of good metal that absorbs neutron, makes rod and can in atomic reactor, slow down nucleon chain reaction speed, and also rather useful in zinc-cadmium cell.
Cadmium and alloy plate strip thereof be cold rolling typically refers to cadmium and alloy thereof are rolled below recrystallization temperature the mode of production.Its effect is to make the microstructure and property of product more even, more excellent performance; Precision is high simultaneously, any surface finish, and plate shape is good.Adopt different working moduluses or coordinate finished product thermal treatment, can obtain the product of various different states.The control of cooling in rolling, lubricated, cleaning and roll shape is very important, and can adopt larger tension force, increases the pass reduction of cold-strip.Exist simultaneously resistance to deformation high, pass reduction is smaller, the large characteristics of distortion energy consumption.Therefore, require lubricant should have good cooling, clean, lubricated, diffusion, the performance that high temperature resistant, thermooxidizing is stable; Continuity and the thickness that can better keep oil film; Reduce friction coefficient and the adherent phenomenon of roll and rolled piece when cold rolling, can meet plate shape and surface smoothness requirement.
Summary of the invention
The technical problem to be solved in the present invention be to provide a kind of have well cooling, clean, lubricated, diffusion, the performance that high temperature resistant, thermooxidizing is stable, keep that oil film has certain continuity and thickness, cadmium and the alloy plate strip cold-rolling lubricant thereof of can reduce friction coefficient and roll and rolled piece adherent phenomenon.
The present invention adopts following technical scheme to solve the problems of the technologies described above: adopt No. 7 total loss systems as base oil, to coordinate multiple composite additive with oily, its each component and mass percent are:
Component Content (mass percent)
Base oil 78%~82%
Anti-wear agent 5.0%~7.0%
Oiliness improver 8.0%~10.0%
Antioxidant preservative 0.5%~1.5%
Kilfoam 0.001%~0.003%
Non-emulsifying agent 0.2%~0.5%
Friction improver 3.0%~5.0%
Base oil is that No. 7 total loss systems are with oily.
Anti-wear agent is that thiophosphoric acid phenyl ester and 40%~50% the boronation phosphamidon ester of mass ratio 60%~50% is compound.
Oiliness improver is that sulfuration Oleum Gossypii semen and 60%~50% No. 75 Microcrystalline Waxes of mass ratio 40%~50% are compound.
Antioxidant preservative is the two octyl group basic zinc salt of sulphur phosphorus.
Kilfoam is dimethyl silicone oil.
Non-emulsifying agent is the polyethers macromolecular compound.
Friction improver is phosphoric acid ester.
Cadmium of the present invention and alloy plate strip cold-rolling lubricant thereof, have good cooling, clean, lubricated, diffusion, the performance that high temperature resistant, thermooxidizing is stable; Continuity and the thickness that can better keep certain oil film; Reduce friction coefficient and the adherent phenomenon of roll and rolled piece when cold rolling, can meet plate shape and surface smoothness requirement.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and forms by mass percentage:
Component Content (mass percent)
No. 7 total loss systems are with oily 78%
The thiophosphoric acid phenyl ester of mass ratio 60% and 40% boronation phosphamidon ester are compound 6.5%
The sulfuration Oleum Gossypii semen of mass ratio 40% and 60% No. 75 Microcrystalline Waxes are compound 9.5%
The two octyl group basic zinc salt of sulphur phosphorus 1.5%
Dimethyl silicone oil 0.003%
The polyethers macromolecular compound 0.497%
Phosphoric acid ester 4.0%
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and forms by mass percentage:
Component Content (mass percent)
No. 7 total loss systems are with oily 80%
The thiophosphoric acid phenyl ester of mass ratio 55% and 45% boronation phosphamidon ester are compound 6.0%
The sulfuration Oleum Gossypii semen of mass ratio 45% and 55% No. 75 Microcrystalline Waxes are compound 9.0%
The two octyl group basic zinc salt of sulphur phosphorus 1.0%
Dimethyl silicone oil 0.002%
The polyethers macromolecular compound 0.398%
Phosphoric acid ester 3.6%
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and forms by mass percentage:
Component Content (mass percent)
No. 7 total loss systems are with oily 82%
The thiophosphoric acid phenyl ester of mass ratio 50% and 50% boronation phosphamidon ester are compound 5.0%
The sulfuration Oleum Gossypii semen of mass ratio 50% and 50% No. 75 Microcrystalline Waxes are compound 8.5%
The two octyl group basic zinc salt of sulphur phosphorus 0.8%
Dimethyl silicone oil 0.001%
The polyethers macromolecular compound 0.299%
Phosphoric acid ester 3.4%
Above component summation is 100%.
Below the key technical indexes of embodiment 3 products:
Project Quality index
Moisture, % is not more than Vestige
40 ℃ of kinematic viscosity mm 2/s 6.60
Flash-point (opening) ℃, be greater than 110
Mechanical impurity, % is not more than Nothing
Last non seizure load (P b), Kg is not less than 80
Pour point, ℃, not higher than -5
Water soluble acid or alkali Nothing
Corrosion test (copper sheet, 100 ℃, 3h), level 1
Viscosity index, be not less than 80

Claims (8)

1. a cadmium and alloy plate strip cold-rolling lubricant thereof, it is characterized in that adopting No. 7 total loss systems with oil as base oil, coordinate multiple composite additive, its each component and mass percent are:
Component Mass percentage content Base oil 78%~82% Anti-wear agent 5.0%~7.0% Oiliness improver 8.0%~10.0% Antioxidant preservative 0.5%~1.5% Kilfoam 0.001%~0.003% Non-emulsifying agent 0.2%~0.5% Friction improver 3.0%~5.0%
2. cadmium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that base oil is that No. 7 total loss systems are with oily.
3. cadmium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that anti-wear agent is that thiophosphoric acid phenyl ester and 40%~50% the boronation phosphamidon ester of mass ratio 60%~50% is compound.
4. cadmium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that oiliness improver is that sulfuration Oleum Gossypii semen and 60%~50% No. 75 Microcrystalline Waxes of mass ratio 40%~50% are compound.
5. cadmium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that antioxidant preservative is the two octyl group basic zinc salt of sulphur phosphorus.
6. cadmium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that kilfoam is dimethyl silicone oil.
7. cadmium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that non-emulsifying agent is the polyethers macromolecular compound.
8. cadmium as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that friction improver is phosphoric acid ester.
CN201310375452.3A 2013-08-26 2013-08-26 Lubricant for cold-rolling of cadmium/cadmium alloy plate strip Active CN103409213B (en)

Priority Applications (1)

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CN201310375452.3A CN103409213B (en) 2013-08-26 2013-08-26 Lubricant for cold-rolling of cadmium/cadmium alloy plate strip

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Application Number Priority Date Filing Date Title
CN201310375452.3A CN103409213B (en) 2013-08-26 2013-08-26 Lubricant for cold-rolling of cadmium/cadmium alloy plate strip

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CN103409213B CN103409213B (en) 2014-08-27

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103666655A (en) * 2013-12-14 2014-03-26 广西大学 Lubricant for drawing magnesium and magnesium alloy wires and pipes
CN103666702A (en) * 2013-12-14 2014-03-26 广西大学 Lubricant for stamping aluminum and aluminum alloy material
CN103666703A (en) * 2013-12-14 2014-03-26 广西大学 Lubricant for stamping lead and lead alloy material
CN103695127A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for cold die forging of nickel and nickel alloy metal plates
CN103710079A (en) * 2013-12-18 2014-04-09 广西大学 Lubricant for cold forging of copper and copper alloy materials
CN106479634A (en) * 2016-09-21 2017-03-08 广西大学 Carbon structural steel rolling screw-threads processing and lubrication cooling liquid composition
CN106635291A (en) * 2016-09-21 2017-05-10 广西大学 Environment-friendly plain carbon structural steel boring fluid composition

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1357610A (en) * 2000-12-08 2002-07-10 刘凤梅 Jilibao series of lubricant oil
US20070191240A1 (en) * 2003-12-25 2007-08-16 Satoshi Suda Metal working fluid
CN103194302A (en) * 2013-04-19 2013-07-10 上海禾泰特种润滑技术有限公司 Worm gear oil composition and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1357610A (en) * 2000-12-08 2002-07-10 刘凤梅 Jilibao series of lubricant oil
US20070191240A1 (en) * 2003-12-25 2007-08-16 Satoshi Suda Metal working fluid
CN103194302A (en) * 2013-04-19 2013-07-10 上海禾泰特种润滑技术有限公司 Worm gear oil composition and preparation method thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103666655A (en) * 2013-12-14 2014-03-26 广西大学 Lubricant for drawing magnesium and magnesium alloy wires and pipes
CN103666702A (en) * 2013-12-14 2014-03-26 广西大学 Lubricant for stamping aluminum and aluminum alloy material
CN103666703A (en) * 2013-12-14 2014-03-26 广西大学 Lubricant for stamping lead and lead alloy material
CN103666703B (en) * 2013-12-14 2015-04-29 广西大学 Lubricant for stamping lead and lead alloy material
CN103666702B (en) * 2013-12-14 2015-06-03 广西大学 Lubricant for stamping aluminum and aluminum alloy material
CN103695127A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for cold die forging of nickel and nickel alloy metal plates
CN103710079A (en) * 2013-12-18 2014-04-09 广西大学 Lubricant for cold forging of copper and copper alloy materials
CN103710079B (en) * 2013-12-18 2015-07-22 广西大学 Lubricant for cold forging of copper and copper alloy materials
CN103695127B (en) * 2013-12-18 2015-07-22 广西大学 Lubricant for cold die forging of nickel and nickel alloy metal plates
CN106479634A (en) * 2016-09-21 2017-03-08 广西大学 Carbon structural steel rolling screw-threads processing and lubrication cooling liquid composition
CN106635291A (en) * 2016-09-21 2017-05-10 广西大学 Environment-friendly plain carbon structural steel boring fluid composition

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Inventor after: Huang Fuchuan

Inventor after: Tang Caizhen

Inventor after: Tian Zongyi

Inventor after: Li Hongjun

Inventor after: Zhao Zhongxing

Inventor after: Liao Dankui

Inventor after: Liu Kun

Inventor after: Huang Yiyao

Inventor after: Mo Yufei

Inventor after: Liang Jing

Inventor after: Su Manrong

Inventor after: Tang Xingzhong

Inventor after: Xiao Youcheng

Inventor after: Lan Mingxin

Inventor after: Li Sheng

Inventor after: Liang Hui

Inventor before: Huang Fuchuan

Inventor before: Liang Hui

Inventor before: Tang Caizhen

Inventor before: Tian Zongyi

Inventor before: Li Hongjun

Inventor before: Zhao Zhongxing

Inventor before: Liao Dankui

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Inventor before: Huang Yiyao

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Inventor before: Mo Yufei

Inventor before: Liang Jing

Inventor before: Su Manrong

Inventor before: Tang Xingzhong

Inventor before: Xiao Youcheng

Inventor before: Lan Mingxin

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Free format text: CORRECT: INVENTOR; FROM: HUANG FUCHUAN MAO HANLING MO YUFEI LIANG JING SU MANRONG TANG XINGZHONG XIAO YOUCHENG LAN MINGXIN LI SHENG LIANG HUI TANG CAIZHEN TIAN ZONGYI LI HONGJUN ZHAO ZHONGXING LIAO DANKUI LIU KUN HUANG YIYAO TO: HUANG FUCHUAN MO YUFEI LIANG JING SU MANRONG TANG XINGZHONG XIAO YOUCHENG LAN MINGXIN LI SHENG LIANG HUI TANG CAIZHEN TIAN ZONGYI LI HONGJUN ZHAO ZHONGXING LIAO DANKUI LIU KUN HUANG YIYAO

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