CN103666703A - Lubricant for stamping lead and lead alloy material - Google Patents
Lubricant for stamping lead and lead alloy material Download PDFInfo
- Publication number
- CN103666703A CN103666703A CN201310682260.7A CN201310682260A CN103666703A CN 103666703 A CN103666703 A CN 103666703A CN 201310682260 A CN201310682260 A CN 201310682260A CN 103666703 A CN103666703 A CN 103666703A
- Authority
- CN
- China
- Prior art keywords
- lead
- lubricant
- alloy material
- punching press
- lead alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000978 Pb alloy Inorganic materials 0.000 title claims abstract description 24
- 239000000956 alloy Substances 0.000 title claims abstract description 19
- 239000000314 lubricant Substances 0.000 title claims abstract description 18
- 239000002199 base oil Substances 0.000 claims abstract description 8
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000003112 inhibitor Substances 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims abstract description 4
- 238000004080 punching Methods 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 235000019198 oils Nutrition 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- QVXGKJYMVLJYCL-UHFFFAOYSA-N 2,3-di(nonyl)-N-phenylaniline Chemical compound C(CCCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCCC QVXGKJYMVLJYCL-UHFFFAOYSA-N 0.000 claims description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 5
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical compound [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 claims description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 239000010514 hydrogenated cottonseed oil Substances 0.000 claims description 5
- 150000002632 lipids Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 150000003751 zinc Chemical class 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 4
- 230000002335 preservative effect Effects 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 2
- 238000001816 cooling Methods 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 239000010729 system oil Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 208000037656 Respiratory Sounds Diseases 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910000897 Babbitt (metal) Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- -1 ferrous metals Chemical class 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a lubricant for stamping lead and lead alloy material, wherein No. 15 total loss system oil is used as base oil, and the base oil is matched up with various composite additives; the composite additives comprise an oiliness agent, an antiwear agent, an anti-foaming agent, an antioxygen, a friction improver and an antioxidant and corrosion inhibitor. The lubricant has excellent adsorbability and permeability to lead and a lead alloy material, is low in viscosity, has excellent lubricity, cooling property, antifriction property, sliding friction property and rust-proof property, and can prevent a crack and meshed jam.
Description
Technical field
The invention belongs to the field of lubricant of non-ferrous metals processing Sheet Metal Forming Technology lubricant, especially punching press lead and lead alloy material.
Background technology
Lead is bluish silvery white heavy metal, toxic, is a kind of malleable main group metal.327.5 ℃ of fusing points, 1740 ℃ of boiling points, density 11.34g/cm
3, hardness 1.5, quality is soft, and tensile strength is little.Lead is easy to get rusty---oxidation.Lead is often grizzly, is exactly because it is in air, very easily by airborne dioxygen oxidation, is become the plumbous oxide of grey black, makes its argenteous gloss gradually become intensely dark.The important use of metallic lead is to manufacture store battery.The resistance to deformation of lead alloy is little, and it is that the techniques such as available rolling, extruding are made sheet material, band, tubing, bar and wire rod that ingot casting does not need heating, and does not need process annealing to process.Because shearing, the creep strength of lead alloy are low, under certain load and rolling shear effect, the easily deformable and attenuate of lead alloy becomes paper tinsel shape; And the self-lubricity of lead alloy, running-in ability and damping property are good, and noise is little, because of but good bearing metal.Graphite metal and tinhase bearing metals are referred to as Babbitt metal, can make the Locomotive Bearing of high-load.
The feature of punching production technique is: use simple mechanical means, by Mould Machining, go out complicated product; Part accuracy is high, and interchangeability is good, conventionally no longer needs that a large amount of mechanical workout just can obtain that intensity is high, good rigidly, lightweight part; Can utilize cheap sheet material and band, be conducive to save metallic substance; Do not need heating, production efficiency is high, and product is with low cost; Be conducive to realize mechanize and automatization, alleviate workman's labour intensity and improve working conditions.Pressed part is widely used in the aspects such as motor, electrical equipment, household electrical appliance, haberdashery and hardware vessel and aerospace communications and transportation.
Punching press lead and lead alloy material are one of advanced production methods in lead and lead alloy shaping processing, it is on the basis of metal plastic deformation, utilize mould and press machine facility to carry out press working to slab, make it produce viscous deformation, thereby obtain the product of definite shape, size and performance.In order to prevent that lead and lead alloy material from crackle occurring in punching course or card is stung (wrinkle), guarantee tangent plane smooth bright and clean, extend and to rush the life-span of tool and to keep sword degree simultaneously, just need to there is the lubricant of good degreasing, weldability, oilness, cooling, antifriction characteristic, sliding friction, antioxidant.
Summary of the invention
The technical problem to be solved in the present invention is to provide the lubricant of a kind of punching press lead and lead alloy material, and that this lubricant has is low to the adsorptivity of lead and lead alloy material and good penetrability, viscosity, have good oilness and cooling, antifriction characteristic, sliding friction, anti-embroidery, can prevent crackle or card is stung.
The present invention is usingd following technical scheme and is solved the problems of the technologies described above: adopt No. 15 total loss systems with oil as base oil, coordinate multiple composite additive, its component and mass percent are:
| Component | Content (mass percent) |
| Base oil | Surplus |
| Oiliness improver | 10.0%～15.0% |
| Anti-wear agent | 5.0%～8.0% |
| Oxidation inhibitor | 0.8%～1.2% |
| Kilfoam | 0.005%～0.01% |
| Friction improver | 4.0%～6.0% |
| Antioxidant preservative | 0.5%～1.0% |
Base oil is No. 15 oil for total loss system.
Oiliness improver is hydrogenated cottonseed oil.
Anti-wear agent is that Zinic stearas and 50%～60% the lipid acid of mass ratio 50%～40% is compound.
Oxidation inhibitor is that 2,6 ditertiary butyl p cresol and 50%～60% the dinonyldiphenylamine of mass ratio 50%～40% is compound.
Kilfoam is dimethyl silicone oil.
Friction improver is No. 2 liquid petroleums.
Antioxidant preservative is the two octyl group basic zinc salt of sulphur phosphorus.
The lubricant of impact extrusion lead of the present invention and lead alloy material, have the adsorptivity of lead and lead alloy material and good penetrability, viscosity is low, has good oilness and cooling, antifriction characteristic, sliding friction, anti-embroidery are good, can prevent crackle or card is stung.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 15 oil for total loss system | 79.5% |
| Hydrogenated cottonseed oil | 10.0% |
| The Zinic stearas of mass ratio 50% and 50% lipid acid are compound | 5.195% |
| The 2,6 ditertiary butyl p cresol of mass ratio 40% and 60% dinonyldiphenylamine are compound | 0.8% |
| Dimethyl silicone oil | 0.005% |
| No. 2 liquid petroleums | 4.0% |
| The two octyl group basic zinc salt of sulphur phosphorus | 0.5% |
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 15 oil for total loss system | 68.8% |
| Hydrogenated cottonseed oil | 15.0% |
| The Zinic stearas of mass ratio 45% and 55% lipid acid are compound | 8.0% |
| The 2,6 ditertiary butyl p cresol of mass ratio 50% and 50% dinonyldiphenylamine are compound | 1.19% |
| Dimethyl silicone oil | 0.01% |
| No. 2 liquid petroleums | 6.0% |
| The two octyl group basic zinc salt of sulphur phosphorus | 1.0% |
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 15 oil for total loss system | 74.2% |
| Hydrogenated cottonseed oil | 12.0% |
| The Zinic stearas of mass ratio 45% and 55% lipid acid are compound | 7.0% |
| The 2,6 ditertiary butyl p cresol of mass ratio 50% and 50% dinonyldiphenylamine are compound | 1.093% |
| Dimethyl silicone oil | 0.007% |
| No. 2 liquid petroleums | 5.0% |
| The two octyl group basic zinc salt of sulphur phosphorus | 0.7% |
Above component summation is 100%.
The main physical and chemical index of embodiment 1 product is:
| Project | Quality index |
| Moisture, % is not more than | Vestige |
| 40 ℃ of kinematic viscosity mm 2/s | 15.8 |
| Flash-point (opening) ℃, is greater than | 160 |
| Mechanical impurity, % is not more than | Nothing |
| Last non seizure load (Pb), Kg is not less than | 80 |
| Pour point, ℃, not higher than | -10 |
| Water soluble acid or alkali | Nothing |
| Corrosion test (copper sheet, 100 ℃, 3h), level | 1 |
| Viscosity index, is not less than | 90 |
Claims (8)
1. a lubricant for punching press lead and lead alloy material, is characterized in that adopting No. 15 total loss systems as base oil, to coordinate multiple composite additive with oily, and its each component and mass percent are:
2. the lubricant of punching press lead as claimed in claim 1 and lead alloy material, is characterized in that base oil is No. 15 oil for total loss system.
3. the lubricant of punching press lead as claimed in claim 1 and lead alloy material, is characterized in that oiliness improver is hydrogenated cottonseed oil.
4. the lubricant of punching press lead as claimed in claim 1 and lead alloy material, is characterized in that anti-wear agent is that Zinic stearas and 50%～60% the lipid acid of mass ratio 50%～40% is compound.
5. the lubricant of punching press lead as claimed in claim 1 and lead alloy material, is characterized in that oxidation inhibitor is that 2,6 ditertiary butyl p cresol and 50%～60% the dinonyldiphenylamine of mass ratio 50%～40% is compound.
6. the lubricant of punching press lead as claimed in claim 1 and lead alloy material, is characterized in that kilfoam is dimethyl silicone oil.
7. the lubricant of punching press lead as claimed in claim 1 and lead alloy material, is characterized in that friction improver is No. 2 liquid petroleums.
8. the lubricant of punching press lead as claimed in claim 1 and lead alloy material, is characterized in that antioxidant preservative is the two octyl group basic zinc salt of sulphur phosphorus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310682260.7A CN103666703B (en) | 2013-12-14 | 2013-12-14 | Lubricant for stamping lead and lead alloy material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310682260.7A CN103666703B (en) | 2013-12-14 | 2013-12-14 | Lubricant for stamping lead and lead alloy material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666703A true CN103666703A (en) | 2014-03-26 |
| CN103666703B CN103666703B (en) | 2015-04-29 |
Family
ID=50305481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310682260.7A Expired - Fee Related CN103666703B (en) | 2013-12-14 | 2013-12-14 | Lubricant for stamping lead and lead alloy material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666703B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106433920A (en) * | 2016-09-21 | 2017-02-22 | 广西大学 | Lubricant composition for cutting machining of ordinary carbon structure steel gear |
| CN106635306A (en) * | 2016-09-21 | 2017-05-10 | 广西大学 | Composition for bidery metal sheet stamping lubricant |
| CN114317072A (en) * | 2020-09-29 | 2022-04-12 | 惠州金永信五金制品有限公司 | Lubricant suitable for metal stamping |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996028528A1 (en) * | 1995-03-15 | 1996-09-19 | Henkel Corporation | Stamping lubricants |
| CN103409213A (en) * | 2013-08-26 | 2013-11-27 | 广西大学 | Lubricant for cold-rolling of cadmium/cadmium alloy plate strip |
| CN103421587A (en) * | 2013-08-26 | 2013-12-04 | 广西大学 | Magnesium and magnesium alloy sheet strip cold rolling lubricating agent |
-
2013
- 2013-12-14 CN CN201310682260.7A patent/CN103666703B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996028528A1 (en) * | 1995-03-15 | 1996-09-19 | Henkel Corporation | Stamping lubricants |
| CN103409213A (en) * | 2013-08-26 | 2013-11-27 | 广西大学 | Lubricant for cold-rolling of cadmium/cadmium alloy plate strip |
| CN103421587A (en) * | 2013-08-26 | 2013-12-04 | 广西大学 | Magnesium and magnesium alloy sheet strip cold rolling lubricating agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106433920A (en) * | 2016-09-21 | 2017-02-22 | 广西大学 | Lubricant composition for cutting machining of ordinary carbon structure steel gear |
| CN106635306A (en) * | 2016-09-21 | 2017-05-10 | 广西大学 | Composition for bidery metal sheet stamping lubricant |
| CN114317072A (en) * | 2020-09-29 | 2022-04-12 | 惠州金永信五金制品有限公司 | Lubricant suitable for metal stamping |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666703B (en) | 2015-04-29 |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150429 |