CN103409213B - Lubricant for cold-rolling of cadmium/cadmium alloy plate strip - Google Patents
Lubricant for cold-rolling of cadmium/cadmium alloy plate strip Download PDFInfo
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- CN103409213B CN103409213B CN201310375452.3A CN201310375452A CN103409213B CN 103409213 B CN103409213 B CN 103409213B CN 201310375452 A CN201310375452 A CN 201310375452A CN 103409213 B CN103409213 B CN 103409213B
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- CN
- China
- Prior art keywords
- cadmium
- lubricant
- rolling
- oil
- compound
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- 229910052793 cadmium Inorganic materials 0.000 title claims abstract description 14
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 238000005097 cold rolling Methods 0.000 title claims abstract description 11
- 239000000314 lubricant Substances 0.000 title claims abstract description 10
- 229910000925 Cd alloy Inorganic materials 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000002199 base oil Substances 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims abstract description 4
- 239000003755 preservative agent Substances 0.000 claims abstract description 4
- 230000002335 preservative effect Effects 0.000 claims abstract description 4
- 239000010729 system oil Substances 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 10
- -1 thiophosphoric acid phenyl ester Chemical class 0.000 claims description 10
- 229910045601 alloy Inorganic materials 0.000 claims description 7
- 239000000956 alloy Substances 0.000 claims description 7
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical compound [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 claims description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 229920002521 macromolecule Polymers 0.000 claims description 5
- 239000004200 microcrystalline wax Substances 0.000 claims description 5
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 5
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 150000003014 phosphoric acid esters Chemical group 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 210000000582 semen Anatomy 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 238000005987 sulfurization reaction Methods 0.000 claims description 5
- 150000003751 zinc Chemical class 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 8
- 238000001816 cooling Methods 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 230000001464 adherent effect Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- LUNUTDXQTSGSJG-LFABVHOISA-N (2S)-2-amino-2-cyclohexyl-N-(1-diphenoxyphosphorylethyl)acetamide Chemical compound C1([C@H](N)C(=O)NC(C)P(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)CCCCC1 LUNUTDXQTSGSJG-LFABVHOISA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 241001274660 Modulus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- CEKJAYFBQARQNG-UHFFFAOYSA-N cadmium zinc Chemical compound [Zn].[Cd] CEKJAYFBQARQNG-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a lubricant for cold-rolling of a cadmium/cadmium alloy plate strip. 7# total loss system oil is used as base oil and is mixed with a plurality of composite additives, wherein the composite additives include an anti-wear agent, an oiliness agent, an anti-oxygen preservative, an anti-foaming agent, a demulsifying agent and a friction improver. The lubricant has excellent cooling, cleaning, lubricating, diffusing, high-temperature resistance and thermal oxidation stability performances and can better keep a certain continuity and thickness of an oil film; and the lubricant can reduce a friction coefficient and an adhesion between a roller and a rolled piece during cold-rolling, and can meet demands on plate shape and surface finish.
Description
Technical field
The invention belongs to cadmium and alloy plate strip cold-rolling lubricant field thereof.
Background technology
Cadmium, is the glossiness metal of silvery white, 320.9 DEG C of fusing points, 765 DEG C of boiling points, density 8650kg/m
3.Flexible and ductility.Cadmium slow oxidation lose metalluster in damp atmosphere, when heating, surface forms brown oxide skin.Cadmium is mainly used in the plating of steel, iron, copper, brass and other metals, strong to the anti-corrosion capability of alkaline matter.Cadmium can be used for manufacturing the little and large battery of electrical capacity of volume.The compound of cadmium is also in a large number for the production of pigment and fluorescent material.It is a kind of good metal that absorbs neutron, makes rod and can in atomic reactor, slow down nucleon chain reaction speed, and also rather useful in zinc-cadmium cell.
Cadmium and alloy plate strip thereof be cold rolling typically refers to the mode of production that cadmium and alloy thereof are rolled below recrystallization temperature.Its effect is to make the microstructure and property of product more even, more excellent performance; Precision is high simultaneously, any surface finish, and plate shape is good.Adopt different working moduluses or coordinate finished product thermal treatment, can obtain the product of various different states.The control of cooling in rolling, lubricated, cleaning and roll shape is very important, and can adopt larger tension force, increases the pass reduction of cold-strip.Exist resistance to deformation high, pass reduction is smaller simultaneously, the large feature of distortion energy consumption.Therefore, require lubricant should have good cooling, clean, lubricated, diffusion, the performance that high temperature resistant, thermooxidizing is stable; Can better keep continuity and the thickness of oil film; Reduce frictional coefficient and the adherent phenomenon of roll and rolled piece when cold rolling, can meet plate shape and surface smoothness requirement.
Summary of the invention
The technical problem to be solved in the present invention be to provide a kind of have well cooling, clean, lubricated, diffusion, the performance that high temperature resistant, thermooxidizing is stable, keep oil film to have certain continuity and thickness, can reduce cadmium and the alloy plate strip cold-rolling lubricant thereof of frictional coefficient and roll and rolled piece adherent phenomenon.
The present invention adopts following technical scheme to solve the problems of the technologies described above: adopt No. 7 total loss system oil as base oil, coordinate multiple composite additive, its each component and mass percent are:
| Component | Content (mass percent) |
| Base oil | 78%～82% |
| Anti-wear agent | 5.0%～7.0% |
| Oiliness improver | 8.0%～10.0% |
| Antioxidant preservative | 0.5%～1.5% |
| Kilfoam | 0.001%～0.003% |
| Non-emulsifying agent | 0.2%～0.5% |
| Friction improver | 3.0%～5.0% |
Base oil is No. 7 oil for total loss system.
Anti-wear agent is that thiophosphoric acid phenyl ester and 40%～50% the boronation phosphamidon ester of mass ratio 60%～50% is compound.
Oiliness improver is that sulfuration Oleum Gossypii semen and 60%～50% No. 75 Microcrystalline Waxes of mass ratio 40%～50% are compound.
Antioxidant preservative is the two octyl group basic zinc salt of sulphur phosphorus.
Kilfoam is dimethyl silicone oil.
Non-emulsifying agent is polyethers macromolecular compound.
Friction improver is phosphoric acid ester.
Cadmium of the present invention and alloy plate strip cold-rolling lubricant thereof, have good cooling, clean, lubricated, diffusion, the performance that high temperature resistant, thermooxidizing is stable; Can better keep continuity and the thickness of certain oil film; Reduce frictional coefficient and the adherent phenomenon of roll and rolled piece when cold rolling, can meet plate shape and surface smoothness requirement.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 7 oil for total loss system | 78% |
| The thiophosphoric acid phenyl ester of mass ratio 60% and 40% boronation phosphamidon ester are compound | 6.5% |
| The sulfuration Oleum Gossypii semen of mass ratio 40% and 60% No. 75 Microcrystalline Waxes are compound | 9.5% |
| The two octyl group basic zinc salt of sulphur phosphorus | 1.5% |
| Dimethyl silicone oil | 0.003% |
| Polyethers macromolecular compound | 0.497% |
| Phosphoric acid ester | 4.0% |
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 7 oil for total loss system | 80% |
| The thiophosphoric acid phenyl ester of mass ratio 55% and 45% boronation phosphamidon ester are compound | 6.0% |
| The sulfuration Oleum Gossypii semen of mass ratio 45% and 55% No. 75 Microcrystalline Waxes are compound | 9.0% |
| The two octyl group basic zinc salt of sulphur phosphorus | 1.0% |
| Dimethyl silicone oil | 0.002% |
| Polyethers macromolecular compound | 0.398% |
| Phosphoric acid ester | 3.6% |
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 7 oil for total loss system | 82% |
| The thiophosphoric acid phenyl ester of mass ratio 50% and 50% boronation phosphamidon ester are compound | 5.0% |
| The sulfuration Oleum Gossypii semen of mass ratio 50% and 50% No. 75 Microcrystalline Waxes are compound | 8.5% |
| The two octyl group basic zinc salt of sulphur phosphorus | 0.8% |
| Dimethyl silicone oil | 0.001% |
| Polyethers macromolecular compound | 0.299% |
| Phosphoric acid ester | 3.4% |
Above component summation is 100%.
Below the key technical indexes of embodiment 3 products:
| Project | Quality index |
| Moisture, % is not more than | Vestige |
| 40 DEG C of kinematic viscosity mm 2/s | 6.60 |
| Flash-point (opening) DEG C, is greater than | 110 |
| Mechanical impurity, % is not more than | Nothing |
| Last non seizure load (P b), Kg is not less than | 80 |
| Pour point, DEG C, not higher than | -5 |
| Water soluble acid or alkali | Nothing |
| Corrosion test (copper sheet, 100 DEG C, 3h), level | 1 |
| Viscosity index, is not less than | 80 |
Claims (1)
1. cadmium and an alloy plate strip cold-rolling lubricant thereof, is characterized in that adopting No. 7 total loss system oil as base oil, coordinates multiple composite additive, and its each component and mass percent are:
Each component percentage ratio summation is 100% above;
Wherein:
Anti-wear agent is that thiophosphoric acid phenyl ester and 40% ~ 50% the boronation phosphamidon ester of mass ratio 60% ~ 50% is compound;
Oiliness improver is that sulfuration Oleum Gossypii semen and 60% ~ 50% No. 75 Microcrystalline Waxes of mass ratio 40% ~ 50% are compound;
Antioxidant preservative is the two octyl group basic zinc salt of sulphur phosphorus;
Kilfoam is dimethyl silicone oil;
Non-emulsifying agent is polyethers macromolecular compound;
Friction improver is phosphoric acid ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310375452.3A CN103409213B (en) | 2013-08-26 | 2013-08-26 | Lubricant for cold-rolling of cadmium/cadmium alloy plate strip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310375452.3A CN103409213B (en) | 2013-08-26 | 2013-08-26 | Lubricant for cold-rolling of cadmium/cadmium alloy plate strip |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103409213A CN103409213A (en) | 2013-11-27 |
| CN103409213B true CN103409213B (en) | 2014-08-27 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310375452.3A Expired - Fee Related CN103409213B (en) | 2013-08-26 | 2013-08-26 | Lubricant for cold-rolling of cadmium/cadmium alloy plate strip |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103409213B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666702B (en) * | 2013-12-14 | 2015-06-03 | 广西大学 | Lubricant for stamping aluminum and aluminum alloy material |
| CN103666703B (en) * | 2013-12-14 | 2015-04-29 | 广西大学 | Lubricant for stamping lead and lead alloy material |
| CN103666655B (en) * | 2013-12-14 | 2015-04-29 | 广西大学 | Lubricant for drawing magnesium and magnesium alloy wires and pipes |
| CN103695127B (en) * | 2013-12-18 | 2015-07-22 | 广西大学 | Lubricant for cold die forging of nickel and nickel alloy metal plates |
| CN103710079B (en) * | 2013-12-18 | 2015-07-22 | 广西大学 | Lubricant for cold forging of copper and copper alloy materials |
| CN106635291A (en) * | 2016-09-21 | 2017-05-10 | 广西大学 | Environment-friendly plain carbon structural steel boring fluid composition |
| CN106479634A (en) * | 2016-09-21 | 2017-03-08 | 广西大学 | Carbon structural steel rolling screw-threads processing and lubrication cooling liquid composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1357610A (en) * | 2000-12-08 | 2002-07-10 | 刘凤梅 | Jilibao series of lubricant oil |
| WO2005063947A1 (en) * | 2003-12-25 | 2005-07-14 | Nippon Oil Corporation | Metalworking fluid |
| CN103194302B (en) * | 2013-04-19 | 2014-07-09 | 上海禾泰特种润滑技术有限公司 | Worm gear oil composition and preparation method thereof |
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- 2013-08-26 CN CN201310375452.3A patent/CN103409213B/en not_active Expired - Fee Related
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| CN103409213A (en) | 2013-11-27 |
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| PB01 | Publication | ||
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| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Huang Fuchuan Inventor after: Tang Caizhen Inventor after: Tian Zongyi Inventor after: Li Hongjun Inventor after: Zhao Zhongxing Inventor after: Liao Dankui Inventor after: Liu Kun Inventor after: Huang Yiyao Inventor after: Mo Yufei Inventor after: Liang Jing Inventor after: Su man Rong Inventor after: Tang Xingzhong Inventor after: Xiao Youcheng Inventor after: Lan Mingxin Inventor after: Li Sheng Inventor after: Liang Hui Inventor before: Huang Fuchuan Inventor before: Liang Hui Inventor before: Tang Caizhen Inventor before: Tian Zongyi Inventor before: Li Hongjun Inventor before: Zhao Zhongxing Inventor before: Liao Dankui Inventor before: Liu Kun Inventor before: Huang Yiyao Inventor before: Mao Hanling Inventor before: Mo Yufei Inventor before: Liang Jing Inventor before: Su man Rong Inventor before: Tang Xingzhong Inventor before: Xiao Youcheng Inventor before: Lan Mingxin Inventor before: Li Sheng |
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| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: HUANG FUCHUAN MAO HANLING MO YUFEI LIANG JING SU MANRONG TANG XINGZHONG XIAO YOUCHENG LAN MINGXIN LI SHENG LIANG HUI TANG CAIZHEN TIAN ZONGYI LI HONGJUN ZHAO ZHONGXING LIAO DANKUI LIU KUN HUANG YIYAO TO: HUANG FUCHUAN MO YUFEI LIANG JING SU MANRONG TANG XINGZHONG XIAO YOUCHENG LAN MINGXIN LI SHENG LIANG HUI TANG CAIZHEN TIAN ZONGYI LI HONGJUN ZHAO ZHONGXING LIAO DANKUI LIU KUN HUANG YIYAO |
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Granted publication date: 20140827 |
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| CF01 | Termination of patent right due to non-payment of annual fee |