CN107033995A - A kind of hafnium alloy cutting technology lubricant compositions - Google Patents

A kind of hafnium alloy cutting technology lubricant compositions Download PDF

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Publication number
CN107033995A
CN107033995A CN201610963556.XA CN201610963556A CN107033995A CN 107033995 A CN107033995 A CN 107033995A CN 201610963556 A CN201610963556 A CN 201610963556A CN 107033995 A CN107033995 A CN 107033995A
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lubricant compositions
cutting technology
alloy cutting
hafnium alloy
technology lubricant
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黄福川
唐弓斌
赵金城
胡雄风
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Guangxi University
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Guangxi University
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/047Thioderivatives not containing metallic elements
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049Phosphite
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling

Abstract

The invention discloses a kind of hafnium alloy cutting technology lubricant compositions, oil based on being combined using No. 5 technical white oils of mass ratio 50% and 50% polyalphaolefin coordinates a variety of compound additives.Including:Antioxidant, metal deactivator, oiliness improver, friction improver, extreme pressure agent, antiwear additive, antirust agent, dispersant, anti-foaming agent, anti emulsifier, urge cryogen, oxidation and corrosion inhibitor etc..The composition of the present invention has good cooling, lubricity, mobility, diffusivity, chip resistance, conductivity of heat, resistance to emulsion, cleaning and anti-corrosive properties, rust-preventing characteristic.

Description

A kind of hafnium alloy cutting technology lubricant compositions
Technical field
A kind of hafnium alloy cutting technology lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
The purposes of hafnium:It is very useful due to its easy launching electronics (filament as being used as incandescent lamp).As X-ray tube Negative electrode, hafnium can as many inflation systems getter.It is the control rod for making the nuclear reactor that the purposes of hafnium, which also has,.It is pure Hafnium has plasticity, easy processing, high-temperature-resistant and anti-corrosion, is atomic energy industry important materials.The thermal neutron capture cross section of hafnium is big, is Comparatively ideal neutron absorber, can make the control rod and protection device of atomic pile.Hafnium powder can make the propeller of rocket.Hafnium is Silver-gray glossy metal, 2227 DEG C of fusing point, 4602 DEG C of boiling point, the gram per centimeter of density 13.313;Metal hafnium has higher neutron Capture ability.With good corrosion resistance, do not corroded by general soda acid;It is soluble in hydrofluoric acid;Can be with oxygen, nitrogen etc. under high temperature The direct chemical combination of gas.Metal hafnium moderate strength, can make the surface-coating of base metal.
The processing method of metal is various, but machining is most common, most widely used one kind all the time.Metal cutting is Important mechanical processing toolses, can be divided into two major classes by its cutting element type used;One class is that the cutting carried out with cutter adds Work;Another kind of is to carry out grinding with abrasive material.Metal cutting and grinding are a kind of cutting element (knife of the utilization with cutting edge Tool or emery wheel) excess metal of workpiece cut on stock-removing machine, so as to be the geometry that workpiece obtains rule, size essence The processing method of degree and surface quality.Metal cutting process is commonly divided into two stages, that is, the generation cut and in time removing. The two stages have the friction between cutter and workpiece, cutter and chip, and the energy conversion of this friction consumption is heat, it Processing efficiency and workpiece quality can be influenceed.Because serious friction produces substantial amounts of heat, cutter and workpiece are overheated, cutter is reduced In the life-span, influence Product Precision.In order to cool down and lubricate cutter and workpiece, it is necessary to produced using cutting lubricant with taking away cutting in time The temperature of raw heat, reduction cutter and workpiece simultaneously plays lubrication;Workpiece surface finish is improved, and extends making for cutter Use the life-span.
Cutting oil is different from plain oil applying working condition, plain oil be in the constant rubbing surface that moves repeatedly it Between, in spite of pressure it is very big, but easily form lubricating oil film.And it is then the fresh table that constantly contact cutting is formed to cut oil Face, it is bigger than general lubricating status that machined surface recurs the pressure born between elastic deformation, thus cutter and machined surface Much.It requires hafnium alloy cutting technology lubricant and can improve high intensity, it is heat-resisting, anti-corrosion, heat resistanceheat resistant oxygen alloy material Cutting, shaping efficiency, improve cutting-tool's used life and workpiece quality;Ensure chip, the industry security of tapping process simultaneously And protection.
The content of the invention
There is good cooling, lubricity, mobility, diffusion the technical problem to be solved in the present invention is to provide a kind of Property, chip resistance, conductivity of heat, resistance to emulsion, cleaning and anti-corrosive properties, the hafnium alloy cutting technology lubricant group of rust-preventing characteristic Compound.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of hafnium alloy cutting technology lubricant compositions, using No. 5 technical white oils of mass ratio 50% and 50% Poly alpha olefin it is compound based on oil, coordinate a variety of compound additives, the composition composition of its respective mass percent:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.05%~0.3%
Metal deactivator 0.05%~0.5%
Oiliness improver 3.0%~6.0%
Friction improver 0.5%~2.0%
Extreme pressure agent 4.0%~6.0%
Antiwear additive 3.0%~5.0%
Antirust agent 0.05%~0.2%
Dispersant 1.0%~4.0%
Anti-foaming agent 10~30ppm
Anti emulsifier 0.1%~0.5%
Urge cryogen 0.5%~2.0%
Oxidation and corrosion inhibitor 0.5%~1.2%
The mass percent summation of above each component is 100%.
Antioxidant is that the phenol fat antioxidant T508 and 50% of mass ratio 50% butyl octyl diphenylamines T537 is combined;
Metal deactivator is that the thiadiazoles derivative T561 and 50% of mass ratio 50% benzotriazole derivative T551 is combined.
Oiliness improver is tallow;Friction improver is benzotriazole aliphatic acid amine salt T406.
Extreme pressure agent is acid dibutyl phosphite T304;Antiwear additive is sulfide isobutene T321.
Antirust agent is that the BTA T706 and 50% of mass ratio 50% lanolin magnesium soap is combined;
Dispersant is polyisobutene succinimide T155.
Anti-foaming agent is methyl-silicone oil;Anti emulsifier is polyether high molecular compound DL32.
It is petroleum sodium sulfonate T702 to urge cryogen;Oxidation and corrosion inhibitor is Sulphurized Oxymolybdenum Dialkylthiophosphate MoDTP.
The remarkable advantage of the present invention:The present invention composition have good cooling, lubricity, mobility, diffusivity, Chip resistance, conductivity of heat, resistance to emulsion, cleaning and anti-corrosive properties, rust-preventing characteristic;High intensity, heat-resisting, anti-corrosion, heat resistanceheat resistant oxygen can be improved The cutting of alloy material, shaping efficiency, improve cutting-tool's used life and workpiece quality;Ensure chip, tapping process simultaneously Industry security and protection.
Embodiment
Embodiment 1:
Following each component is pressed into the mediation of row mass percent to form:
Component Mass percentage content
No. 5 technical white oils of mass ratio 50% and 50% poly alpha olefin are compound Surplus
The phenol fat antioxidant (T508) of mass ratio 50% and 50% butyl octyl diphenylamines (T537) are compound 0.08%
The thiadiazoles derivative (T561) of mass ratio 50% and 50% benzotriazole derivative (T551) are compound 0.07%
Tallow 3.05%
Benzotriazole aliphatic acid amine salt (T406) 0.9%
Acid dibutyl phosphite (T304) 4.29%
Sulfide isobutene (T321) 4.2%
The BTA (T706) of mass ratio 50% and 50% lanolin magnesium soap are compound 0.15%
Polyisobutene succinimide (T155) 1.34%
Methyl-silicone oil 20ppm
Polyether high molecular compound (DL32); 0.16%
Petroleum sodium sulfonate (T702) 0.66%
Sulphurized Oxymolybdenum Dialkylthiophosphate (MoDTP) 0.9%
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed into the mediation of row mass percent to form:
Component Mass percentage content
No. 5 technical white oils of mass ratio 50% and 50% poly alpha olefin are compound Surplus
The phenol fat antioxidant (T508) of mass ratio 50% and 50% butyl octyl diphenylamines (T537) are compound 0.18%
The thiadiazoles derivative (T561) of mass ratio 50% and 50% benzotriazole derivative (T551) are compound 0.17%
Tallow 4.05%
Benzotriazole aliphatic acid amine salt (T406) 1.2%
Acid dibutyl phosphite (T304) 5.29%
Sulfide isobutene (T321) 3.2%
The BTA (T706) of mass ratio 50% and 50% lanolin magnesium soap are compound 0.07%
Polyisobutene succinimide (T155) 1.33%
Methyl-silicone oil 25ppm
Polyether high molecular compound (DL32); 0.36%
Petroleum sodium sulfonate (T702) 1.05%
Sulphurized Oxymolybdenum Dialkylthiophosphate (MoDTP) 1.1%
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed into the mediation of row mass percent to form:
Component Mass percentage content
No. 5 technical white oils of mass ratio 50% and 50% poly alpha olefin are compound Surplus
The phenol fat antioxidant (T508) of mass ratio 50% and 50% butyl octyl diphenylamines (T537) are compound 0.28%
The thiadiazoles derivative (T561) of mass ratio 50% and 50% benzotriazole derivative (T551) are compound 0.37%
Tallow 5.05%
Benzotriazole aliphatic acid amine salt (T406) 1.8%
Acid dibutyl phosphite (T304) 5.59%
Sulfide isobutene (T321) 4.2%
The BTA (T706) of mass ratio 50% and 50% lanolin magnesium soap are compound 0.17%
Polyisobutene succinimide (T155) 3.33%
Methyl-silicone oil 26ppm
Polyether high molecular compound (DL32) 0.46%
Petroleum sodium sulfonate (T702) 1.95%
Sulphurized Oxymolybdenum Dialkylthiophosphate (MoDTP) 1.1%
Above each component mass percentage content summation is 100%.
The key technical indexes of the product of embodiment 3:
The key technical indexes of the product of embodiment 2:
The key technical indexes of the product of embodiment 1:

Claims (7)

1. a kind of hafnium alloy cutting technology lubricant compositions, it is characterised in that:It is white using No. 5 industry of mass ratio 50% Oil based on oil and 50% poly alpha olefin are compound, coordinates a variety of compound additives, its each mass percent into packet Into:
Component Mass percentage content Base oil Surplus Antioxidant 0.05%~0.3% Metal deactivator 0.05%~0.5% Oiliness improver 3.0%~6.0% Friction improver 0.5%~2.0% Extreme pressure agent 4.0%~6.0% Antiwear additive 3.0%~5.0% Antirust agent 0.05%~0.2% Dispersant 1.0%~4.0% Anti-foaming agent 10~30ppm Anti emulsifier 0.1%~0.5% Urge cryogen 0.5%~2.0% Oxidation and corrosion inhibitor 0.5%~1.2%
The mass percent summation of above each component is 100%.
2. a kind of hafnium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antioxidant is The phenol fat antioxidant T508 and 50% of mass ratio 50% butyl octyl diphenylamines T537 is combined;Metal deactivator is mass ratio 50% thiadiazoles derivative T561 and 50% benzotriazole derivative T551 is combined.
3. a kind of hafnium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver is Tallow;Friction improver is benzotriazole aliphatic acid amine salt T406.
4. a kind of hafnium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is Acid dibutyl phosphite T304;Antiwear additive is sulfide isobutene T321.
5. a kind of hafnium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is The BTA T706 and 50% of mass ratio 50% lanolin magnesium soap is combined;Dispersant is polyisobutene succinimide T155。
6. a kind of hafnium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that anti-foaming agent is Methyl-silicone oil;Anti emulsifier is polyether high molecular compound DL32.
7. a kind of hafnium alloy cutting technology lubricant compositions as claimed in claim 1, it is characterised in that urge the cryogen to be Petroleum sodium sulfonate T702;Oxidation and corrosion inhibitor is molybdenum dithiophosphate MoDTP.
CN201610963556.XA 2016-11-04 2016-11-04 A kind of hafnium alloy cutting technology lubricant compositions Withdrawn CN107033995A (en)

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CN103695110A (en) * 2013-12-14 2014-04-02 广西大学 Lubricant for pressing of aluminium plate for air conditioner
CN103710102A (en) * 2013-12-14 2014-04-09 广西大学 Lubricant for automobile body aluminum plate pressing
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Publication number Priority date Publication date Assignee Title
CN1922293A (en) * 2004-03-31 2007-02-28 新日本石油株式会社 Metalworking fluid
CN103695110A (en) * 2013-12-14 2014-04-02 广西大学 Lubricant for pressing of aluminium plate for air conditioner
CN103710102A (en) * 2013-12-14 2014-04-09 广西大学 Lubricant for automobile body aluminum plate pressing
CN104450081A (en) * 2014-11-18 2015-03-25 广西大学 Lubricant composition for adiabatic gasoline engine

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牛茹轩等: "《废有机溶剂与废矿物油污染防治知识问答》", 31 May 2016, 冶金工业出版社 *

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