CN106544118A - A kind of tungsten alloy grinding technique lubricant compositions - Google Patents

A kind of tungsten alloy grinding technique lubricant compositions Download PDF

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Publication number
CN106544118A
CN106544118A CN201610962489.XA CN201610962489A CN106544118A CN 106544118 A CN106544118 A CN 106544118A CN 201610962489 A CN201610962489 A CN 201610962489A CN 106544118 A CN106544118 A CN 106544118A
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tungsten alloy
lubricant compositions
grinding technique
alloy grinding
technique lubricant
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黄福川
王玥
潘发存
胡雄风
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Guangxi University
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Guangxi University
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085Phosphorus oxides, acids or salts
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06Well-defined aromatic compounds
    • C10M2203/065Well-defined aromatic compounds used as base material
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/003Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions used as base material
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/16Naphthenic acids
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16Antiseptic; (micro) biocidal or bactericidal
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of tungsten alloy grinding technique lubricant compositions, oil based on being combined using the polyalphaolefin of mass ratio 50% and 50% alkylnaphthalene, coordinate various compound additives.Including:Antioxidant, metal deactivator, oiliness improver, friction improver, extreme pressure agent, antiwear additive, antirust agent, anti-foaming agent, anti emulsifier, dispersant, oxidation and corrosion inhibitor etc..The composition of the present invention has good cooling, lubricity, diffusivity, cleaning, anti-corrosive properties, rust-preventing characteristic, low volatility, non-oxidizability, microbial resistance and the intermiscibility to painting, and thermal capacity is big.

Description

A kind of tungsten alloy grinding technique lubricant compositions
Technical field
A kind of tungsten alloy grinding technique lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Tungsten alloy is the alloy for adding other elements composition with tungsten as base.In a metal, the fusing point highest of tungsten, elevated temperature strength It is all good with creep-resistant property and heat conduction, conductive and electron emission capability, than great, except being largely used to manufacture hard alloy and work Outside alloy addition, tungsten and its alloy are widely used in electronics, electric light source industry, are also used in the departments such as space flight, casting, weapon Make rocket nozzle, die casting, armor-piercing bullet core, contact, heater and heat screen etc..
Grinding fluid is that one kind is used in metal removal process, industrial with workpiece for cooling down and lubricating cutter Liquid.Metal cutting is important mechanical processing toolses, and as used by which, cutting element type can be divided into two big class.One class is to use knife Tool carries out machining, and such as turning, drilling, boring, milling, wound is cut and broached;Another kind of is that the grinding carried out with abrasive material adds Work, such as grinding, the top gem of a girdle-pendant are cut, grinding and superfinishing etc..By processing severe arrangement, machining can be divided into 16 kinds, wherein Grinding ranks the first.Cutting lubricant is divided into two big class so as to use, that is, cut lubricant, be required for good cooling and profit Sliding effect, but two kinds of processing modes have basic difference.In grinding, grinding speed is up to more than 1000r/min, Temperature is more than 1100 DEG C, therefore it is required that there is higher cooling performance;In addition, grinding tool (such as emery wheel) hole is easily blocked, also therefore Need higher detergency.Require that lubricant can reduce generation hot between grinding area abrasive particle and workpiece and make what is produced simultaneously Heat obtains quick release, improves the use longevity of high-strength alloy workpiece surface quality, recovery of abrasive dust rate and efficiency and grinding fluid Life.
The content of the invention
The technical problem to be solved in the present invention be to provide it is a kind of have good cooling, lubricity, diffusivity, cleaning, Anti-corrosive properties, rust-preventing characteristic, low volatility, non-oxidizability, microbial resistance and the intermiscibility to painting, the big tungsten alloy of thermal capacity Grinding technique lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of tungsten alloy grinding technique lubricant compositions, using mass ratio 50% poly alpha olefin and 50% alkane Oil based on base naphthalene is compound, coordinates various compound additives, its each mass percent into being grouped into:
The mass percent summation of above each component is 100%.
Antioxidant is that dinonyldiphenylamine T558 of the sulfenyl phenolate T504 and 50% of mass ratio 50% is combined;
Metal deactivator be the thiadiazole of mass ratio 50% and 50% benzotriazole derivative T551 be combined.
Oiliness improver is sulfurized lard;Friction improver is sulphur molybdenum phosphate T461.Extreme pressure agent is chlorinated paraffin T301;
Antiwear additive is tricresyl phosphate T306.Antirust agent is the methyl benzotriazazole of mass ratio 50% and 50% ring Alkanoic acid zinc T704;Anti-foaming agent is acrylate and ether copolymer T912.Anti emulsifier is amine and epoxides condensation product T1001;
Dispersant is polyisobutylene-bis-succinimide T161.Oxidation and corrosion inhibitor is dialkyl dithio amino formate.
Advantages of the present invention:The composition of the present invention has good cooling, lubricity (extreme-pressure anti-wear carrying), diffusion Property, cleaning, anti-corrosive properties, rust-preventing characteristic, low volatility, non-oxidizability, microbial resistance and to paint intermiscibility, thermal capacity Greatly;Generation hot between grinding area abrasive particle and workpiece can be reduced and make the heat for having produced obtain quick release, be improved high intensity and close The service life of golden workpiece surface quality, recovery of abrasive dust rate and efficiency and grinding fluid.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
The poly alpha olefin of mass ratio 50% and 50% alkylnaphthalene are compound Surplus
The sulfenyl phenolate (T504) of mass ratio 50% and 50% dinonyldiphenylamine (T558) are compound 0.05%
The thiadiazole of mass ratio 50% and 50% benzotriazole derivative (T551) be combined 0.09%
Sulfurized lard 4.04%
Sulphur molybdenum phosphate (T461) 1.11%
Chlorinated paraffin (T301) 5.29%
Tricresyl phosphate (T306) 3.2%
The methyl benzotriazazole of mass ratio 50% and 50% zinc naphthenate (T704) 0.56%
Acrylate and ether copolymer (T912) 25ppm
Amine and epoxides condensation product (T1001) 0.1%
Polyisobutylene-bis-succinimide (T161) 2.16%
Dialkyl dithio amino formate 1.1%
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
The poly alpha olefin of mass ratio 50% and 50% alkylnaphthalene are compound Surplus
The sulfenyl phenolate (T504) of mass ratio 50% and 50% dinonyldiphenylamine (T558) are compound 0.12%
The thiadiazole of mass ratio 50% and 50% benzotriazole derivative (T551) be combined 0.1%
Sulfurized lard 6.04%
Sulphur molybdenum phosphate (T461) 1.51%
Chlorinated paraffin (T301) 6.29%
Tricresyl phosphate (T306) 3.8%
The methyl benzotriazazole of mass ratio 50% and 50% zinc naphthenate (T704) 0.76%
Acrylate and ether copolymer (T912) 30ppm
Amine and epoxides condensation product (T1001) 0.12%
Polyisobutylene-bis-succinimide (T161) 2.66%
Dialkyl dithio amino formate 1.5%
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
The poly alpha olefin of mass ratio 50% and 50% alkylnaphthalene are compound Surplus
The sulfenyl phenolate (T504) of mass ratio 50% and 50% dinonyldiphenylamine (T558) are compound 0.41%
The thiadiazole of mass ratio 50% and 50% benzotriazole derivative (T551) be combined 0.15%
Sulfurized lard 7.04%
Sulphur molybdenum phosphate (T461) 1.81%
Chlorinated paraffin (T301) 7.29%
Tricresyl phosphate (T306) 4.8%
The methyl benzotriazazole of mass ratio 50% and 50% zinc naphthenate (T704) 0.86%
Acrylate and ether copolymer (T912) 35ppm
Amine and epoxides condensation product (T1001) 0.18%
Polyisobutylene-bis-succinimide (T161) 3.66%
Dialkyl dithio amino formate 1.8%
Above each component mass percentage content summation is 100%.
The key technical indexes of 3 product of embodiment:
The key technical indexes of 2 product of embodiment:
The key technical indexes of 1 product of embodiment:

Claims (7)

1. a kind of tungsten alloy grinding technique lubricant compositions, it is characterised in that:Using the poly alpha olefin of mass ratio 50% Based on compound with 50% alkylnaphthalene, oil, coordinates various compound additives, its each mass percent into being grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.03%~0.5% Metal deactivator 0.05%~0.2% Oiliness improver 4.0%~8.0% Friction improver 1.0%~2.0% Extreme pressure agent 5.0%~8.0% Antiwear additive 3.0%~5.0% Antirust agent 0.5%~1.0% Anti-foaming agent 20~40ppm Anti emulsifier 0.08%~0.2% Dispersant 2.0%~4.0% Oxidation and corrosion inhibitor 1.0%~2.0%
The mass percent summation of above each component is 100%.
2. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antioxidant is Dinonyldiphenylamine T558 of the sulfenyl phenolate T504 and 50% of mass ratio 50% is combined;Metal deactivator is mass ratio 50% Thiadiazole and 50% benzotriazole derivative T551 be combined.
3. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver is Sulfurized lard;Friction improver is sulphur molybdenum phosphate T461.
4. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is Chlorinated paraffin T301;Antiwear additive is tricresyl phosphate T306.
5. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is The methyl benzotriazazole of mass ratio 50% and 50% zinc naphthenate T704;Anti-foaming agent is acrylate and ether copolymer T912。
6. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti emulsifier It is amine and epoxides condensation product T1001;Dispersant is polyisobutylene-bis-succinimide T161.
7. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that the anti-corruption of antioxygen Agent is dialkyl dithio amino formate.
CN201610962489.XA 2016-11-04 2016-11-04 A kind of tungsten alloy grinding technique lubricant compositions Withdrawn CN106544118A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101351533A (en) * 2005-12-28 2009-01-21 出光兴产株式会社 Lubricant for metal working
CN101787323A (en) * 2010-03-02 2010-07-28 江苏汇众石油化工有限公司 Energy-saving repairing engine lubricating oil

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101351533A (en) * 2005-12-28 2009-01-21 出光兴产株式会社 Lubricant for metal working
CN101787323A (en) * 2010-03-02 2010-07-28 江苏汇众石油化工有限公司 Energy-saving repairing engine lubricating oil

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Application publication date: 20170329