CN106544118A - A kind of tungsten alloy grinding technique lubricant compositions - Google Patents
A kind of tungsten alloy grinding technique lubricant compositions Download PDFInfo
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- CN106544118A CN106544118A CN201610962489.XA CN201610962489A CN106544118A CN 106544118 A CN106544118 A CN 106544118A CN 201610962489 A CN201610962489 A CN 201610962489A CN 106544118 A CN106544118 A CN 106544118A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
- C10M2203/065—Well-defined aromatic compounds used as base material
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/003—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions used as base material
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/08—Halogenated waxes
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of tungsten alloy grinding technique lubricant compositions, oil based on being combined using the polyalphaolefin of mass ratio 50% and 50% alkylnaphthalene, coordinate various compound additives.Including:Antioxidant, metal deactivator, oiliness improver, friction improver, extreme pressure agent, antiwear additive, antirust agent, anti-foaming agent, anti emulsifier, dispersant, oxidation and corrosion inhibitor etc..The composition of the present invention has good cooling, lubricity, diffusivity, cleaning, anti-corrosive properties, rust-preventing characteristic, low volatility, non-oxidizability, microbial resistance and the intermiscibility to painting, and thermal capacity is big.
Description
Technical field
A kind of tungsten alloy grinding technique lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Tungsten alloy is the alloy for adding other elements composition with tungsten as base.In a metal, the fusing point highest of tungsten, elevated temperature strength
It is all good with creep-resistant property and heat conduction, conductive and electron emission capability, than great, except being largely used to manufacture hard alloy and work
Outside alloy addition, tungsten and its alloy are widely used in electronics, electric light source industry, are also used in the departments such as space flight, casting, weapon
Make rocket nozzle, die casting, armor-piercing bullet core, contact, heater and heat screen etc..
Grinding fluid is that one kind is used in metal removal process, industrial with workpiece for cooling down and lubricating cutter
Liquid.Metal cutting is important mechanical processing toolses, and as used by which, cutting element type can be divided into two big class.One class is to use knife
Tool carries out machining, and such as turning, drilling, boring, milling, wound is cut and broached;Another kind of is that the grinding carried out with abrasive material adds
Work, such as grinding, the top gem of a girdle-pendant are cut, grinding and superfinishing etc..By processing severe arrangement, machining can be divided into 16 kinds, wherein
Grinding ranks the first.Cutting lubricant is divided into two big class so as to use, that is, cut lubricant, be required for good cooling and profit
Sliding effect, but two kinds of processing modes have basic difference.In grinding, grinding speed is up to more than 1000r/min,
Temperature is more than 1100 DEG C, therefore it is required that there is higher cooling performance;In addition, grinding tool (such as emery wheel) hole is easily blocked, also therefore
Need higher detergency.Require that lubricant can reduce generation hot between grinding area abrasive particle and workpiece and make what is produced simultaneously
Heat obtains quick release, improves the use longevity of high-strength alloy workpiece surface quality, recovery of abrasive dust rate and efficiency and grinding fluid
Life.
The content of the invention
The technical problem to be solved in the present invention be to provide it is a kind of have good cooling, lubricity, diffusivity, cleaning,
Anti-corrosive properties, rust-preventing characteristic, low volatility, non-oxidizability, microbial resistance and the intermiscibility to painting, the big tungsten alloy of thermal capacity
Grinding technique lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of tungsten alloy grinding technique lubricant compositions, using mass ratio 50% poly alpha olefin and 50% alkane
Oil based on base naphthalene is compound, coordinates various compound additives, its each mass percent into being grouped into:
The mass percent summation of above each component is 100%.
Antioxidant is that dinonyldiphenylamine T558 of the sulfenyl phenolate T504 and 50% of mass ratio 50% is combined;
Metal deactivator be the thiadiazole of mass ratio 50% and 50% benzotriazole derivative T551 be combined.
Oiliness improver is sulfurized lard;Friction improver is sulphur molybdenum phosphate T461.Extreme pressure agent is chlorinated paraffin T301;
Antiwear additive is tricresyl phosphate T306.Antirust agent is the methyl benzotriazazole of mass ratio 50% and 50% ring
Alkanoic acid zinc T704;Anti-foaming agent is acrylate and ether copolymer T912.Anti emulsifier is amine and epoxides condensation product T1001;
Dispersant is polyisobutylene-bis-succinimide T161.Oxidation and corrosion inhibitor is dialkyl dithio amino formate.
Advantages of the present invention:The composition of the present invention has good cooling, lubricity (extreme-pressure anti-wear carrying), diffusion
Property, cleaning, anti-corrosive properties, rust-preventing characteristic, low volatility, non-oxidizability, microbial resistance and to paint intermiscibility, thermal capacity
Greatly;Generation hot between grinding area abrasive particle and workpiece can be reduced and make the heat for having produced obtain quick release, be improved high intensity and close
The service life of golden workpiece surface quality, recovery of abrasive dust rate and efficiency and grinding fluid.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
The poly alpha olefin of mass ratio 50% and 50% alkylnaphthalene are compound | Surplus |
The sulfenyl phenolate (T504) of mass ratio 50% and 50% dinonyldiphenylamine (T558) are compound | 0.05% |
The thiadiazole of mass ratio 50% and 50% benzotriazole derivative (T551) be combined | 0.09% |
Sulfurized lard | 4.04% |
Sulphur molybdenum phosphate (T461) | 1.11% |
Chlorinated paraffin (T301) | 5.29% |
Tricresyl phosphate (T306) | 3.2% |
The methyl benzotriazazole of mass ratio 50% and 50% zinc naphthenate (T704) | 0.56% |
Acrylate and ether copolymer (T912) | 25ppm |
Amine and epoxides condensation product (T1001) | 0.1% |
Polyisobutylene-bis-succinimide (T161) | 2.16% |
Dialkyl dithio amino formate | 1.1% |
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
The poly alpha olefin of mass ratio 50% and 50% alkylnaphthalene are compound | Surplus |
The sulfenyl phenolate (T504) of mass ratio 50% and 50% dinonyldiphenylamine (T558) are compound | 0.12% |
The thiadiazole of mass ratio 50% and 50% benzotriazole derivative (T551) be combined | 0.1% |
Sulfurized lard | 6.04% |
Sulphur molybdenum phosphate (T461) | 1.51% |
Chlorinated paraffin (T301) | 6.29% |
Tricresyl phosphate (T306) | 3.8% |
The methyl benzotriazazole of mass ratio 50% and 50% zinc naphthenate (T704) | 0.76% |
Acrylate and ether copolymer (T912) | 30ppm |
Amine and epoxides condensation product (T1001) | 0.12% |
Polyisobutylene-bis-succinimide (T161) | 2.66% |
Dialkyl dithio amino formate | 1.5% |
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
The poly alpha olefin of mass ratio 50% and 50% alkylnaphthalene are compound | Surplus |
The sulfenyl phenolate (T504) of mass ratio 50% and 50% dinonyldiphenylamine (T558) are compound | 0.41% |
The thiadiazole of mass ratio 50% and 50% benzotriazole derivative (T551) be combined | 0.15% |
Sulfurized lard | 7.04% |
Sulphur molybdenum phosphate (T461) | 1.81% |
Chlorinated paraffin (T301) | 7.29% |
Tricresyl phosphate (T306) | 4.8% |
The methyl benzotriazazole of mass ratio 50% and 50% zinc naphthenate (T704) | 0.86% |
Acrylate and ether copolymer (T912) | 35ppm |
Amine and epoxides condensation product (T1001) | 0.18% |
Polyisobutylene-bis-succinimide (T161) | 3.66% |
Dialkyl dithio amino formate | 1.8% |
Above each component mass percentage content summation is 100%.
The key technical indexes of 3 product of embodiment:
The key technical indexes of 2 product of embodiment:
The key technical indexes of 1 product of embodiment:
Claims (7)
1. a kind of tungsten alloy grinding technique lubricant compositions, it is characterised in that:Using the poly alpha olefin of mass ratio 50%
Based on compound with 50% alkylnaphthalene, oil, coordinates various compound additives, its each mass percent into being grouped into:
The mass percent summation of above each component is 100%.
2. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antioxidant is
Dinonyldiphenylamine T558 of the sulfenyl phenolate T504 and 50% of mass ratio 50% is combined;Metal deactivator is mass ratio 50%
Thiadiazole and 50% benzotriazole derivative T551 be combined.
3. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that oiliness improver is
Sulfurized lard;Friction improver is sulphur molybdenum phosphate T461.
4. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is
Chlorinated paraffin T301;Antiwear additive is tricresyl phosphate T306.
5. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is
The methyl benzotriazazole of mass ratio 50% and 50% zinc naphthenate T704;Anti-foaming agent is acrylate and ether copolymer
T912。
6. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti emulsifier
It is amine and epoxides condensation product T1001;Dispersant is polyisobutylene-bis-succinimide T161.
7. a kind of tungsten alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that the anti-corruption of antioxygen
Agent is dialkyl dithio amino formate.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101351533A (en) * | 2005-12-28 | 2009-01-21 | 出光兴产株式会社 | Lubricant for metal working |
CN101787323A (en) * | 2010-03-02 | 2010-07-28 | 江苏汇众石油化工有限公司 | Energy-saving repairing engine lubricating oil |
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- 2016-11-04 CN CN201610962489.XA patent/CN106544118A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101351533A (en) * | 2005-12-28 | 2009-01-21 | 出光兴产株式会社 | Lubricant for metal working |
CN101787323A (en) * | 2010-03-02 | 2010-07-28 | 江苏汇众石油化工有限公司 | Energy-saving repairing engine lubricating oil |
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Application publication date: 20170329 |