CN106520324A - Lubricant composition for nickel-based anti-wear alloy grinding machining process - Google Patents

Lubricant composition for nickel-based anti-wear alloy grinding machining process Download PDF

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Publication number
CN106520324A
CN106520324A CN201610963572.9A CN201610963572A CN106520324A CN 106520324 A CN106520324 A CN 106520324A CN 201610963572 A CN201610963572 A CN 201610963572A CN 106520324 A CN106520324 A CN 106520324A
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Prior art keywords
nickel
agent
alloy grinding
lubricant compositions
grinding technique
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黄福川
陈彪
马骁飞
韦开焕
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Guangxi University
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Guangxi University
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/16Naphthenic acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10M2215/086Imides
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/041Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving a condensation reaction
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2290/00Mixtures of base materials or thickeners or additives
    • C10M2290/04Synthetic base oils
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals

Abstract

The invention discloses a lubricant composition for a nickel-based anti-wear alloy grinding machining process. No. 7 industrial white oil is used as base oil and matched with a plurality of composite additives. The lubricant composition comprises an antioxidant, a metal deactivator, an oiliness agent, a friction modifier, an extreme-pressure agent, an anti-wear agent, an anti-rust agent, an anti-foaming agent, an anti-emulsifying agent, an anti-oxidant and anti-corrosive agent, a dispersant, a cooling accelerant and the like. The composition disclosed by the invention is high in cooling property, lubricating property, extreme-pressure anti-wear bearing property, diffusibility, cleaning property, anti-rust property and anti-oxidant and anti-corrosive property, low in volatility and smoke, capable of reducing surface scratches and abrasion of a workpiece, high in thermal capacity, high in surface smoothness, and long in anti-corrosive period.

Description

A kind of nickel-base antiwear alloy grinding technique lubricant compositions
Technical field
A kind of nickel-base antiwear alloy grinding technique lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Nickel-base antiwear alloy main alloy element is chromium, molybdenum, tungsten, also containing a small amount of niobium, tantalum and indium.Except with wearability Can be outer, its anti-oxidant, corrosion-resistant, welding performance might as well.Wear-resisting spare part can be manufactured, also can be as covering material, by built-up welding Other substrate material surfaces are coated on spraying coating process.
Grinding fluid is that one kind is used in metal removal process, industrial with workpiece for cooling down and lubricating cutter Liquid.Metal cutting is important mechanical processing toolses, and as used by which, cutting element type can be divided into two big class.One class is to use knife Tool carries out machining, and such as turning, drilling, boring, milling, wound is cut and broached;Another kind of is that the grinding carried out with abrasive material adds Work, such as grinding, the top gem of a girdle-pendant are cut, grinding and superfinishing etc..By processing severe arrangement, machining can be divided into 16 kinds, wherein Grinding ranks the first.Cutting lubricant is divided into two big class so as to use, that is, cut lubricant and grinding lubricant, be required for good Good cooling and lubricant effect, but two kinds of processing modes have basic difference.In grinding, grinding speed is up to More than 1000r/min, temperature is more than 1100 DEG C, therefore it is required that there is higher cooling performance;In addition, grinding tool (such as emery wheel) hole holds Easily block, also therefore need higher detergency.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, extreme-pressure anti-wear carrying Property, diffusivity, cleaning, rust-preventing characteristic, antioxygen anti-corrosive properties, low volatility, low smog reduce work piece surface cut and scratch, Thermal capacity is big, and surface smoothness is high, the nickel alloy grinding technique lubricant compositions of anticorrosive cycle length.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of nickel-base antiwear alloy grinding technique lubricant compositions, using oil based on No. 7 technical white oils, coordinate Various compound additives, its each mass percent into being grouped into:
The mass percent summation of above each component is 100%.
Antioxidant is that dialkyl diphenylamine T534 of the sulfenyl phenolate T504 and 50% of mass ratio 50% is combined.
Metal deactivator is benzotriazole derivative T551.Oiliness improver is sulfurized lard.Friction improver is phosphate T451.
Extreme pressure agent is chlorinated paraffin T301.Antiwear additive is sulfide isobutene T321.
Antirust agent is that the zinc naphthenate T704 of the alkenyl succinic acid half ester T747 and 50% of mass ratio 50% is combined.
Anti-foaming agent is methyl-silicone oil T901.Anti emulsifier is amine and epoxide condensation product T1001.
Oxidation and corrosion inhibitor is molybdenum dithiophosphate MoPTC.Dispersant is polyisobutylene succinamide T154B.
Cryogen is urged to be petroleum sodium sulfonate.
The remarkable advantage of the present invention:There is the composition of the present invention good cooling, lubricity, extreme-pressure anti-wear to carry Property, diffusivity, cleaning, rust-preventing characteristic, antioxygen anti-corrosive properties, low volatility, low smog reduces work piece surface cut and scratch, Thermal capacity is big, and surface smoothness is high, and the anticorrosive cycle is long.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
No. 7 technical white oils Surplus
The sulfenyl phenolate (T504) of mass ratio 50% is combined with 50% dialkyl diphenylamine (T534) 0.04%
Benzotriazole derivative (T551) 0.03%
Sulfurized lard 4%
Phosphate (T451) 1%
Chlorinated paraffin (T301) 4%
Sulfide isobutene (T321) 3%
The alkenyl succinic acid half ester (T747) of mass ratio 50% is combined with 50% zinc naphthenate (T704) 0.05%
Methyl-silicone oil (T901) 10ppm
Amine and epoxide condensation product (T1001) 0.05%
Molybdenum dithiophosphate (MoPTC) 0.8%
Polyisobutylene succinamide (T154B) 1%
Petroleum sodium sulfonate (T702) 1%
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
No. 7 technical white oils Surplus
The sulfenyl phenolate (T504) of mass ratio 50% is combined with 50% dialkyl diphenylamine (T534) 0.1%
Benzotriazole derivative (T551) 0.06%
Sulfurized lard 6%
Phosphate (T451) 2%
Chlorinated paraffin (T301) 5%
Sulfide isobutene (T321) 5%
The alkenyl succinic acid half ester (T747) of mass ratio 50% is combined with 50% zinc naphthenate (T704) 0.1%
Methyl-silicone oil (T901) 20ppm
Amine and epoxide condensation product (T1001) 0.1%
Molybdenum dithiophosphate (MoPTC) 1.2%
Polyisobutylene succinamide (T154B) 2%
Petroleum sodium sulfonate (T702) 1.5%
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
No. 7 technical white oils Surplus
The sulfenyl phenolate (T504) of mass ratio 50% is combined with 50% dialkyl diphenylamine (T534) 0.2%
Benzotriazole derivative (T551) 0.1%
Sulfurized lard 8%
Phosphate (T451) 3%
Chlorinated paraffin (T301) 6%
Sulfide isobutene (T321) 6%
The alkenyl succinic acid half ester (T747) of mass ratio 50% is combined with 50% zinc naphthenate (T704) 0.2%
Methyl-silicone oil (T901) 30ppm
Amine and epoxide condensation product (T1001) 0.2%
Molybdenum dithiophosphate (MoPTC) 1.5%
Polyisobutylene succinamide (T154B) 4%
Petroleum sodium sulfonate (T702) 2%
Above each component mass percentage content summation is 100%.
The typical physiochemical techniques index of 3 product of embodiment:
Project Quality index
Kinematic viscosity (40 DEG C)/mm2/s-1 8.3
Flash-point (opening)/DEG C 184
Condensation point/DEG C -15
Viscosity index (VI) 131
Coefficient of friction 0.082
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min 293
Shear stability (40 DEG C of kinematic viscosity rates of descent)/% 3.5
Tetra-ball machine test/Pb/N 888
Sintering load/PD/N 6799
Terraced nurse agrees/N 287
FZG/ levels 14
Corrosivity (copper sheet, 100 DEG C, 3h)/level 1
Demulsification number, 54 DEG C of (40-37-3)/min 11
Moisture, % Vestige
Mechanical admixture, % Nothing
The typical physiochemical techniques index of 2 product of embodiment:
Project Quality index
Kinematic viscosity (40 DEG C)/mm2/s-1 7.9
Flash-point (opening)/DEG C 181
Condensation point/DEG C -11
Viscosity index (VI) 123
Coefficient of friction 0.083
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min 307
Shear stability (40 DEG C of kinematic viscosity rates of descent)/% 3.8
Tetra-ball machine test/Pb/N 895
Sintering load/PD/N 6990
Terraced nurse agrees/N 314
FZG/ levels 14
Corrosivity (copper sheet, 100 DEG C, 3h)/level 1
Demulsification number, 54 DEG C of (40-37-3)/min 12
Moisture, % Vestige
Mechanical admixture, % Nothing
The typical physiochemical techniques index of 1 product of embodiment:
Project Quality index
Kinematic viscosity (40 DEG C)/mm2/s-1 8.4
Flash-point (opening)/DEG C 179
Condensation point/DEG C -13
Viscosity index (VI) 112
Coefficient of friction 0.081
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min 387
Shear stability (40 DEG C of kinematic viscosity rates of descent)/% 3.2
Tetra-ball machine test/Pb/N 886
Sintering load/PD/N 6850
Terraced nurse agrees/N 304
FZG/ levels 14
Corrosivity (copper sheet, 100 DEG C, 3h)/level 1
Demulsification number, 54 DEG C of (40-37-3)/min 9
Moisture, % Vestige
Mechanical admixture, % Nothing

Claims (9)

1. a kind of nickel-base antiwear alloy grinding technique lubricant compositions, it is characterised in that:No. 7 technical white oils are adopted for base Plinth oil, coordinates various compound additives, its each mass percent into being grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.04%~0.2% Metal deactivator 0.03%~0.1% Oiliness improver 4%~8% Friction improver 1%~3% Extreme pressure agent 4%~6% Antiwear additive 3%~6% Antirust agent 0.05%~0.2% Anti-foaming agent 10ppm~30ppm Anti emulsifier 0.05%~0.2% Oxidation and corrosion inhibitor 0.8%~1.5% Dispersant 1%~4% Urge cryogen 1%~2%
The mass percent summation of above each component is 100%.
2. a kind of nickel-base antiwear alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Oxygen agent is that dialkyl diphenylamine T534 of the sulfenyl phenolate T504 and 50% of mass ratio 50% is combined.
3. a kind of nickel-base antiwear alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that gold Category passivator is benzotriazole derivative T551.
4. a kind of nickel-base antiwear alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that oil Property agent is sulfurized lard;Friction improver is phosphate T451.
5. a kind of nickel-base antiwear alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that pole Pressure agent is chlorinated paraffin T301;Antiwear additive is sulfide isobutene T321.
6. a kind of nickel-base antiwear alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Rust agent is that the zinc naphthenate T704 of the alkenyl succinic acid half ester T747 and 50% of mass ratio 50% is combined.
7. a kind of nickel-base antiwear alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Infusion is methyl-silicone oil T901;Anti emulsifier is amine and epoxide condensation product T1001.
8. a kind of nickel-base antiwear alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Oxygen anti-corrosion additive is molybdenum dithiophosphate MoPTC;Dispersant is polyisobutylene succinamide T154B.
9. a kind of nickel-base antiwear alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that urge Cryogen is petroleum sodium sulfonate.
CN201610963572.9A 2016-11-04 2016-11-04 Lubricant composition for nickel-based anti-wear alloy grinding machining process Withdrawn CN106520324A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104450087A (en) * 2014-11-27 2015-03-25 昆山瑞昱化工有限公司 Environmentally-friendly antirust cutting agent
CN105062630A (en) * 2015-07-20 2015-11-18 广西大学 Lubricant for drawn austenitic stainless steel wire material
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