CN106520335A - Common brass alloy grinding process technology lubricant composition - Google Patents

Common brass alloy grinding process technology lubricant composition Download PDF

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Publication number
CN106520335A
CN106520335A CN201610966126.3A CN201610966126A CN106520335A CN 106520335 A CN106520335 A CN 106520335A CN 201610966126 A CN201610966126 A CN 201610966126A CN 106520335 A CN106520335 A CN 106520335A
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China
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agent
brass alloy
alloy grinding
lubricant compositions
grinding technique
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CN201610966126.3A
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Chinese (zh)
Inventor
黄福川
肖锋
陈帆
陈一帆
胡雄风
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Guangxi University
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Guangxi University
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Priority to CN201610966126.3A priority Critical patent/CN106520335A/en
Publication of CN106520335A publication Critical patent/CN106520335A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/288—Partial esters containing free carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/30—Anti-misting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a common brass alloy grinding process technology lubricant composition. 50 mass percent of No. 5 total loss system oil and 50 mass percent of poly alpha-olefin are adopted to be compounded as base oil; multiple composite additives are matched, including an antioxygen, a metal deactivator, an oiliness agent, a friction improving agent, an extreme pressure agent, an antiwear agent, an anti-rust agent, an anti-foaming agent, an anticreaming agent, a dispersant, a cooling accelerant and the like. The lubricant composition has good high-speed lubricating property at a high temperature, and extreme pressure resisting, antiwear and bearing capabilities, has a good cooling effect, can be used to eliminate heat generated by high temperature deformation and friction, has good permeability, diffusivity, cleaning ability, chip removal property, anti-rust property, produces less oil mist, inhibits scratches, bruises and intermiscibility to paint, and is great in thermal capacity.

Description

A kind of basis brass alloy grinding technique lubricant compositions
Technical field
A kind of basis brass alloy grinding technique lubricant compositions of the present invention belong to metal working process lubricant Field.
Background technology
The alloy that basis brass is made up of copper and zinc.When zinc content is less than 35%, zinc can be dissolved in copper and form single-phase A, claims alpha brass, and plasticity is good, is suitable to cold and hot pressure processing.When zinc content is 36%～46%, there is a single-phase also with copper zinc For the β solid solution of base, claim two-phase pyrite, β phases pyrite plasticity is reduced and tensile strength rising, be adapted only to thermal pressure processing.
Grinding fluid is that one kind is used in the metal removal course of processing, industrial with workpiece for cooling down and lubricating cutter Liquid.Metal cutting is important mechanical processing toolses, and as used by which, cutting element type can be divided into two big class.One class is to use knife Tool carries out machining, and such as turning, drilling, boring, milling, wound is cut and broached；Another kind of is that the grinding carried out with abrasive material adds Work, such as grinding, the top gem of a girdle-pendant are cut, grinding and superfinishing etc..By processing severe arrangement, machining can be divided into 16 kinds, wherein Grinding ranks the first.Cutting lubricant is divided into two big class so as to use, that is, cut lubricant and grinding lubricant, be required for good Good cooling and lubricant effect, but two kinds of processing modes have basic difference.In grinding, grinding speed is up to More than 1000r/min, temperature is more than 1100 DEG C, therefore it is required that there is higher cooling performance；In addition, grinding tool (such as emery wheel) hole holds Easily block, also therefore need higher detergency.
The content of the invention
The technical problem to be solved in the present invention be to provide it is a kind of with good high temperature, high-speed lubrication and extreme pressure, it is wear-resistant, Bearing capacity；Good cooling effect, eliminates the heat that high temperature deformation and friction are produced；Good permeability, diffusibility, cleaning Property, chip resistance, rust-preventing characteristic, low mist of oil, suppress cut, scratch and the intermiscibility to painting, the big basis brass of thermal capacity is closed Golden grinding technique lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution：
A kind of basis brass alloy grinding technique lubricant compositions, using No. 5 total loss systems of mass ratio 50% System oil and 50% poly alpha olefin it is compound based on oil, coordinate various compound additives, its each mass percent into It is grouped into：
The mass percent summation of above each component is 100%.
Antioxidant is that the alkyl diphenylamine T543 of the 2,6 ditertbutylparacresol T501 and 50% of mass ratio 50% is combined.
Metal deactivator is benzotriazole derivant T551.
Oiliness improver is industrial lard.
Friction improver is boronation phosphate ester T3011.
Extreme pressure agent is acid dibutyl phosphite T304.
Antiwear additive is chlorinated paraffin T302.
Antirust agent is that the alkenyl succinic acid half ester T747 of the Benzotriazole Derivative T706 and 50% of mass ratio 50% is multiple Close.
Anti-foaming agent is ethyl silicon oil.
Anti emulsifier is polyethers macromolecular compound DL-32；
Dispersant is diene base succimide T152.
The barium mahogany sulfonate T701 of the petroleum sodium sulfonate T702 and 50% that cryogen is mass ratio 50% is urged to be combined.
The present invention remarkable advantage be：
The compositionss of the present invention have good high temperature, high-speed lubrication and extreme pressure, wear-resistant, bearing capacity；Good is cold But act on, eliminate the heat that high temperature deformation and friction are produced；Good permeability, diffusibility, cleaning, chip resistance, rust-preventing characteristic, Low mist of oil, suppression cut, scratch and the intermiscibility to painting, thermal capacity are big.
Specific embodiment
Embodiment 1：
Following each component is pressed the mediation of row mass percent to form：
Above each component mass percentage content summation is 100%.
Embodiment 2：
Following each component is pressed the mediation of row mass percent to form：
Above each component mass percentage content summation is 100%..
Embodiment 3：Following each component is pressed the mediation of row mass percent to form：
Above each component mass percentage content summation is 100%.
The main physical and chemical index of 1 product of embodiment：
The main physical and chemical index of 2 product of embodiment：
The main physical and chemical index of 3 product of embodiment：

Claims (7)

1. a kind of basis brass alloy grinding technique lubricant compositions, it is characterised in that：Using No. 5 of mass ratio 50% Total loss system oil and 50% poly alpha olefin it is compound coordinate various compound additives as composite foundation oil, its respective matter Amount percent into being grouped into：
Component Mass percentage content Base oil Surplus Antioxidant 0.08%～0.2% Metal deactivator 0.03%～0.2% Oiliness improver 3.0%～8.0% Friction improver 1.0%～3.0% Extreme pressure agent 3.0%～4.0% Antiwear additive 5.0%～8.0% Antirust agent 0.08%～0.2% Anti-foaming agent 10～30ppm Anti emulsifier 0.02%～0.5% Dispersant 2.0%～3.0% Urge cryogen 0.05%～0.3%
The mass percent summation of above each component is 100%.
2. a kind of basis brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Oxygen agent is that the alkyl diphenylamine T543 of the 2,6 ditertbutylparacresol T501 and 50% of mass ratio 50% is combined；Metal deactivator It is benzotriazole derivant T551.
3. a kind of basis brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that oil Property agent is industrial lard；Friction improver is boronation phosphate ester T3011.
4. a kind of basis brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that pole Pressure agent is acid dibutyl phosphite T304；Antiwear additive is chlorinated paraffin T302.
5. a kind of basis brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Rust agent is that the alkenyl succinic acid half ester T747 of the Benzotriazole Derivative T706 and 50% of mass ratio 50% is combined；Anti-foaming agent is Ethyl silicon oil.
6. a kind of basis brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Emulsifying agent is polyethers macromolecular compound DL-32；Dispersant is diene base succimide T152.
7. a kind of basis brass alloy grinding technique lubricant compositions as claimed in claim 1, it is characterised in that urge Cryogen is that the barium mahogany sulfonate T701 of the petroleum sodium sulfonate T702 and 50% of mass ratio 50% is combined.
CN201610966126.3A 2016-11-04 2016-11-04 Common brass alloy grinding process technology lubricant composition Withdrawn CN106520335A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610966126.3A CN106520335A (en) 2016-11-04 2016-11-04 Common brass alloy grinding process technology lubricant composition

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Application Number Priority Date Filing Date Title
CN201610966126.3A CN106520335A (en) 2016-11-04 2016-11-04 Common brass alloy grinding process technology lubricant composition

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CN106520335A true CN106520335A (en) 2017-03-22

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Country Status (1)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710085A (en) * 2013-11-19 2014-04-09 广西大学 Cold rolling lubricant for silver and silver alloy foil

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710085A (en) * 2013-11-19 2014-04-09 广西大学 Cold rolling lubricant for silver and silver alloy foil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王先会: "《润滑油脂生产原料和设备实用手册》", 31 March 2007, 中国石化出版社 *

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