CN106520325A - Lubricant composition for zinc alloy grinding machining process - Google Patents

Lubricant composition for zinc alloy grinding machining process Download PDF

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Publication number
CN106520325A
CN106520325A CN201610963573.3A CN201610963573A CN106520325A CN 106520325 A CN106520325 A CN 106520325A CN 201610963573 A CN201610963573 A CN 201610963573A CN 106520325 A CN106520325 A CN 106520325A
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China
Prior art keywords
kirsite
agent
lubricant compositions
grinding technique
technique lubricant
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CN201610963573.3A
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黄福川
李康春
邓富康
唐弓斌
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Guangxi University
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Guangxi University
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/16Naphthenic acids
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086Imides
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049Phosphite
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2290/00Mixtures of base materials or thickeners or additives
    • C10M2290/04Synthetic base oils
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a lubricant composition for a zinc alloy grinding machining process. HVIH 5 is used as base oil and matched with a plurality of composite additives. The lubricant composition comprises an antioxidant, a friction modifier, a metal deactivator, an oiliness agent, an extreme-pressure agent, an anti-wear agent, an anti-rust agent, a dispersant, an anti-foaming agent, an anti-emulsifying agent, a filler and the like. The composition disclosed by the invention is high in cooling property, lubricating property, extreme-pressure anti-wear bearing property, diffusibility, cleaning property, anti-rust property and anti-oxidant and anti-corrosive property, low in volatility and smoke, excellent in thermal oxidation stability, capable of reducing surface scratches and abrasion of a workpiece, and high in thermal capacity.

Description

A kind of kirsite grinding technique lubricant compositions
Technical field
A kind of kirsite grinding technique lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Kirsite is the alloy that other elements composition is added based on zinc.Often plus alloying element have aluminium, copper, magnesium, cadmium, The low temperature kirsite such as lead, titanium.Kirsite fusing point is low, good fluidity, easy melting welding, soldering and plastic working, corrosion-resistant in an atmosphere, Maimed material is easy to reclaim and remelting;But creep strength is low, easily there is natrual ageing and cause change in size.Prepared by fusion method, die casting Or pressure processing is become a useful person.Cast zinc alloy and deformation zinc alloy can be divided into by manufacturing process.Feature:1. compare great.2. cast Make that performance is good, can, thin-walled complex-shaped with die casting precision part, cast(ing) surface is smooth.3. can be surface-treated:Plating, spray Apply, paint, polishing, grinding etc..4. melt and iron is not inhaled during die casting, do not corrode die mould, not sticking to mould.5. good normal temperature machinery is had Performance and wearability.6. fusing point is low, melts at 385 DEG C, easy die cast.The main adding elements of kirsite have aluminium, copper and Magnesium etc..Kirsite can be divided into deformation and two class of cast zinc alloy by processing technology.Cast zinc alloy mobility and corrosion resistance compared with It is good, it is adaptable to die casting instrument, auto parts shell etc..Different kirsites has different physics and mechanical property, is so pressure Space of the foundry goods design there is provided selection.
Grinding fluid is that one kind is used in metal removal process, industrial with workpiece for cooling down and lubricating cutter Liquid.Metal cutting is important mechanical processing toolses, and as used by which, cutting element type can be divided into two big class.One class is to use knife Tool carries out machining, and such as turning, drilling, boring, milling, wound is cut and broached;Another kind of is that the grinding carried out with abrasive material adds Work, such as grinding, the top gem of a girdle-pendant are cut, grinding and superfinishing etc..By processing severe arrangement, machining can be divided into 16 kinds, wherein Grinding ranks the first.Cutting lubricant is divided into two big class so as to use, that is, cut lubricant and grinding lubricant, be required for good Good cooling and lubricant effect, but two kinds of processing modes have basic difference.In grinding, grinding speed is up to More than 1000r/min, temperature is more than 1100 DEG C, therefore it is required that there is higher cooling performance;In addition, grinding tool (such as emery wheel) hole holds Easily block, also therefore need higher detergency.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, extreme-pressure anti-wear carrying Property, diffusivity, cleaning, rust-preventing characteristic, antioxygen anti-corrosive properties, low volatility, low smog, thermal oxidation stability is excellent, reduces processing The big kirsite grinding technique lubricant compositions of part surface scratch and scratch and thermal capacity.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of kirsite grinding technique lubricant compositions, using oil based on HVIH 5, coordinate various being combined to add Plus agent, its each mass percent into being grouped into:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.04%~0.2%
Friction improver 1%~3%
Metal deactivator 0.1%~0.3%
Oiliness improver 4%~8%
Extreme pressure agent 2%~4%
Antiwear additive 3%~5%
Antirust agent 0.05%~0.1%
Dispersant 2%~4%
Anti-foaming agent 10ppm~30ppm
Anti emulsifier 0.08%~0.5%
Filler 1%~4%
The mass percent summation of above each component is 100%.
Antioxidant is that dialkyl diphenylamine T534 of the phenolic ester base antioxidant T504 and 50% of mass ratio 50% is combined.
Friction improver is alkyl phosphite.
Metal deactivator is benzotriazole derivative T551.
Oiliness improver is soybean oil.
Extreme pressure agent is acid dibutyl phosphite T304.
Antiwear additive is tricresyl phosphate T304.
Antirust agent is that the alkenyl succinic acid half ester T747 of the zinc naphthenate T704 and 50% of mass ratio 50% is combined.
Dispersant is diene base succimide T152.
Anti-foaming agent is methyl-silicone oil.
Anti emulsifier is polyethers macromolecular compound DL32.
Filler is atoleine.
The remarkable advantage of the present invention:There is the composition of the present invention good cooling, lubricity, extreme-pressure anti-wear to carry Property, diffusivity, cleaning, rust-preventing characteristic, antioxygen anti-corrosive properties, low volatility, low smog, thermal oxidation stability is excellent, reduces processing Part surface scratch and scratch and thermal capacity are big.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
HVIH 5 Surplus
Phenolic ester base antioxidant (T504) of mass ratio 50% is combined with 50% dialkyl diphenylamine (T534) 0.04%
Alkyl phosphite 1%
Benzotriazole derivative (T551) 0.1%
Soybean oil 4%
Acid dibutyl phosphite (T304) 2%
Tricresyl phosphate (T304 3%
The zinc naphthenate (T704) of mass ratio 50% is combined with 50% alkenyl succinic acid half ester (T747) 0.05%
Diene base succimide (T152) 2%
Methyl-silicone oil 10ppm
Polyethers macromolecular compound (DL32) 0.08%
Atoleine 1%
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
HVIH 5 Surplus
Phenolic ester base antioxidant (T504) of mass ratio 50% is combined with 50% dialkyl diphenylamine (T534) 0.1%
Alkyl phosphite 2%
Benzotriazole derivative (T551) 0.2%
Soybean oil 6%
Acid dibutyl phosphite (T304) 3%
Tricresyl phosphate (T304 4%
The zinc naphthenate (T704) of mass ratio 50% is combined with 50% alkenyl succinic acid half ester (T747) 0.08%
Diene base succimide (T152) 3%
Methyl-silicone oil 20ppm
Polyethers macromolecular compound (DL32) 0.3%
Atoleine 2%
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Component Mass percentage content
HVIH 5 Surplus
Phenolic ester base antioxidant (T504) of mass ratio 50% is combined with 50% dialkyl diphenylamine (T534) 0.2%
Alkyl phosphite 3%
Benzotriazole derivative (T551) 0.3%
Soybean oil 8%
Acid dibutyl phosphite (T304) 4%
Tricresyl phosphate (T304 5%
The zinc naphthenate (T704) of mass ratio 50% is combined with 50% alkenyl succinic acid half ester (T747) 0.1%
Diene base succimide (T152) 4%
Methyl-silicone oil 30ppm
Polyethers macromolecular compound (DL32) 0.5%
Atoleine 4%
Above each component mass percentage content summation is 100%.
The typical physiochemical techniques index of 1 product of embodiment:
Project Quality index
Kinematic viscosity (40 DEG C)/mm2/s-1 8.9
Flash-point (opening)/DEG C 181
Condensation point/DEG C -14
Viscosity index (VI) 142
Coefficient of friction 0.081
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min 277
Shear stability (40 DEG C of kinematic viscosity rates of descent)/% 3.4
Tetra-ball machine test/Pb/N 735
Sintering load/PD/N 6395
Terraced nurse agrees/N 262
FZG/ levels 12
Corrosivity (copper sheet, 100 DEG C, 3h)/level 1
Demulsification number, 54 DEG C of (40-37-3)/min 10.5
Moisture, % Vestige
Mechanical admixture, % Nothing
The typical physiochemical techniques index of 2 product of embodiment:
Project Quality index
Kinematic viscosity (40 DEG C)/mm2/s-1 8.6
Flash-point (opening)/DEG C 178
Condensation point/DEG C -15
Viscosity index (VI) 137
Coefficient of friction 0.083
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min 277
Shear stability (40 DEG C of kinematic viscosity rates of descent)/% 3.7
Tetra-ball machine test/Pb/N 710
Sintering load/PD/N 6490
Terraced nurse agrees/N 277
FZG/ levels 12
Corrosivity (copper sheet, 100 DEG C, 3h)/level 1
Demulsification number, 54 DEG C of (40-37-3)/min 10.5
Moisture, % Vestige
Mechanical admixture, % Nothing
The typical physiochemical techniques index of 3 product of embodiment:
Project Quality index
Kinematic viscosity (40 DEG C)/mm2/s-1 7.96
Flash-point (opening)/DEG C 169
Condensation point/DEG C -16
Viscosity index (VI) 146
Coefficient of friction 0.082
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min 255
Shear stability (40 DEG C of kinematic viscosity rates of descent)/% 3.6
Tetra-ball machine test/Pb/N 710
Sintering load/PD/N 6310
Terraced nurse agrees/N 258
FZG/ levels 12
Corrosivity (copper sheet, 100 DEG C, 3h)/level 1
Demulsification number, 54 DEG C of (40-37-3)/min 11
Moisture, % Vestige
Mechanical admixture, % Nothing

Claims (10)

1. a kind of kirsite grinding technique lubricant compositions, it is characterised in that:Using oil based on HVIH 5, coordinate many Kind of compound additive, its each mass percent into being grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.04%~0.2% Friction improver 1%~3% Metal deactivator 0.1%~0.3% Oiliness improver 4%~8% Extreme pressure agent 2%~4% Antiwear additive 3%~5% Antirust agent 0.05%~0.1% Dispersant 2%~4% Anti-foaming agent 10ppm~30ppm Anti emulsifier 0.08%~0.5% Filler 1%~4%
The mass percent summation of above each component is 100%.
2. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antioxidant is Dialkyl diphenylamine T534 of the phenolic ester base antioxidant T504 and 50% of mass ratio 50% is combined.
3. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that friction is improved Agent is alkyl phosphite.
4. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that metal deactivating Agent is benzotriazole derivative T551;Oiliness improver is soybean oil.
5. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is Acid dibutyl phosphite T304;Antiwear additive is tricresyl phosphate T304.
6. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is The alkenyl succinic acid half ester T747 of the zinc naphthenate T704 and 50% of mass ratio 50% is combined.
7. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that dispersant is Diene base succimide T152.
8. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti-foaming agent is Methyl-silicone oil.
9. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti emulsifier It is polyethers macromolecular compound DL32.
10. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that filler is Atoleine.
CN201610963573.3A 2016-11-04 2016-11-04 Lubricant composition for zinc alloy grinding machining process Withdrawn CN106520325A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104862036A (en) * 2015-06-05 2015-08-26 广西大学 Lubricant combination for cold tension reducing stainless steel tube
CN104987943A (en) * 2015-07-20 2015-10-21 广西大学 High-temperature precise die-forging carbon steel lubricant composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104862036A (en) * 2015-06-05 2015-08-26 广西大学 Lubricant combination for cold tension reducing stainless steel tube
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