CN106520325A - Lubricant composition for zinc alloy grinding machining process - Google Patents
Lubricant composition for zinc alloy grinding machining process Download PDFInfo
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- CN106520325A CN106520325A CN201610963573.3A CN201610963573A CN106520325A CN 106520325 A CN106520325 A CN 106520325A CN 201610963573 A CN201610963573 A CN 201610963573A CN 106520325 A CN106520325 A CN 106520325A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/086—Imides
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2290/00—Mixtures of base materials or thickeners or additives
- C10M2290/04—Synthetic base oils
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
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- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a lubricant composition for a zinc alloy grinding machining process. HVIH 5 is used as base oil and matched with a plurality of composite additives. The lubricant composition comprises an antioxidant, a friction modifier, a metal deactivator, an oiliness agent, an extreme-pressure agent, an anti-wear agent, an anti-rust agent, a dispersant, an anti-foaming agent, an anti-emulsifying agent, a filler and the like. The composition disclosed by the invention is high in cooling property, lubricating property, extreme-pressure anti-wear bearing property, diffusibility, cleaning property, anti-rust property and anti-oxidant and anti-corrosive property, low in volatility and smoke, excellent in thermal oxidation stability, capable of reducing surface scratches and abrasion of a workpiece, and high in thermal capacity.
Description
Technical field
A kind of kirsite grinding technique lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Kirsite is the alloy that other elements composition is added based on zinc.Often plus alloying element have aluminium, copper, magnesium, cadmium,
The low temperature kirsite such as lead, titanium.Kirsite fusing point is low, good fluidity, easy melting welding, soldering and plastic working, corrosion-resistant in an atmosphere,
Maimed material is easy to reclaim and remelting;But creep strength is low, easily there is natrual ageing and cause change in size.Prepared by fusion method, die casting
Or pressure processing is become a useful person.Cast zinc alloy and deformation zinc alloy can be divided into by manufacturing process.Feature:1. compare great.2. cast
Make that performance is good, can, thin-walled complex-shaped with die casting precision part, cast(ing) surface is smooth.3. can be surface-treated:Plating, spray
Apply, paint, polishing, grinding etc..4. melt and iron is not inhaled during die casting, do not corrode die mould, not sticking to mould.5. good normal temperature machinery is had
Performance and wearability.6. fusing point is low, melts at 385 DEG C, easy die cast.The main adding elements of kirsite have aluminium, copper and
Magnesium etc..Kirsite can be divided into deformation and two class of cast zinc alloy by processing technology.Cast zinc alloy mobility and corrosion resistance compared with
It is good, it is adaptable to die casting instrument, auto parts shell etc..Different kirsites has different physics and mechanical property, is so pressure
Space of the foundry goods design there is provided selection.
Grinding fluid is that one kind is used in metal removal process, industrial with workpiece for cooling down and lubricating cutter
Liquid.Metal cutting is important mechanical processing toolses, and as used by which, cutting element type can be divided into two big class.One class is to use knife
Tool carries out machining, and such as turning, drilling, boring, milling, wound is cut and broached;Another kind of is that the grinding carried out with abrasive material adds
Work, such as grinding, the top gem of a girdle-pendant are cut, grinding and superfinishing etc..By processing severe arrangement, machining can be divided into 16 kinds, wherein
Grinding ranks the first.Cutting lubricant is divided into two big class so as to use, that is, cut lubricant and grinding lubricant, be required for good
Good cooling and lubricant effect, but two kinds of processing modes have basic difference.In grinding, grinding speed is up to
More than 1000r/min, temperature is more than 1100 DEG C, therefore it is required that there is higher cooling performance;In addition, grinding tool (such as emery wheel) hole holds
Easily block, also therefore need higher detergency.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, extreme-pressure anti-wear carrying
Property, diffusivity, cleaning, rust-preventing characteristic, antioxygen anti-corrosive properties, low volatility, low smog, thermal oxidation stability is excellent, reduces processing
The big kirsite grinding technique lubricant compositions of part surface scratch and scratch and thermal capacity.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of kirsite grinding technique lubricant compositions, using oil based on HVIH 5, coordinate various being combined to add
Plus agent, its each mass percent into being grouped into:
Component | Mass percentage content |
Base oil | Surplus |
Antioxidant | 0.04%~0.2% |
Friction improver | 1%~3% |
Metal deactivator | 0.1%~0.3% |
Oiliness improver | 4%~8% |
Extreme pressure agent | 2%~4% |
Antiwear additive | 3%~5% |
Antirust agent | 0.05%~0.1% |
Dispersant | 2%~4% |
Anti-foaming agent | 10ppm~30ppm |
Anti emulsifier | 0.08%~0.5% |
Filler | 1%~4% |
The mass percent summation of above each component is 100%.
Antioxidant is that dialkyl diphenylamine T534 of the phenolic ester base antioxidant T504 and 50% of mass ratio 50% is combined.
Friction improver is alkyl phosphite.
Metal deactivator is benzotriazole derivative T551.
Oiliness improver is soybean oil.
Extreme pressure agent is acid dibutyl phosphite T304.
Antiwear additive is tricresyl phosphate T304.
Antirust agent is that the alkenyl succinic acid half ester T747 of the zinc naphthenate T704 and 50% of mass ratio 50% is combined.
Dispersant is diene base succimide T152.
Anti-foaming agent is methyl-silicone oil.
Anti emulsifier is polyethers macromolecular compound DL32.
Filler is atoleine.
The remarkable advantage of the present invention:There is the composition of the present invention good cooling, lubricity, extreme-pressure anti-wear to carry
Property, diffusivity, cleaning, rust-preventing characteristic, antioxygen anti-corrosive properties, low volatility, low smog, thermal oxidation stability is excellent, reduces processing
Part surface scratch and scratch and thermal capacity are big.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
HVIH 5 | Surplus |
Phenolic ester base antioxidant (T504) of mass ratio 50% is combined with 50% dialkyl diphenylamine (T534) | 0.04% |
Alkyl phosphite | 1% |
Benzotriazole derivative (T551) | 0.1% |
Soybean oil | 4% |
Acid dibutyl phosphite (T304) | 2% |
Tricresyl phosphate (T304 | 3% |
The zinc naphthenate (T704) of mass ratio 50% is combined with 50% alkenyl succinic acid half ester (T747) | 0.05% |
Diene base succimide (T152) | 2% |
Methyl-silicone oil | 10ppm |
Polyethers macromolecular compound (DL32) | 0.08% |
Atoleine | 1% |
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
HVIH 5 | Surplus |
Phenolic ester base antioxidant (T504) of mass ratio 50% is combined with 50% dialkyl diphenylamine (T534) | 0.1% |
Alkyl phosphite | 2% |
Benzotriazole derivative (T551) | 0.2% |
Soybean oil | 6% |
Acid dibutyl phosphite (T304) | 3% |
Tricresyl phosphate (T304 | 4% |
The zinc naphthenate (T704) of mass ratio 50% is combined with 50% alkenyl succinic acid half ester (T747) | 0.08% |
Diene base succimide (T152) | 3% |
Methyl-silicone oil | 20ppm |
Polyethers macromolecular compound (DL32) | 0.3% |
Atoleine | 2% |
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Component | Mass percentage content |
HVIH 5 | Surplus |
Phenolic ester base antioxidant (T504) of mass ratio 50% is combined with 50% dialkyl diphenylamine (T534) | 0.2% |
Alkyl phosphite | 3% |
Benzotriazole derivative (T551) | 0.3% |
Soybean oil | 8% |
Acid dibutyl phosphite (T304) | 4% |
Tricresyl phosphate (T304 | 5% |
The zinc naphthenate (T704) of mass ratio 50% is combined with 50% alkenyl succinic acid half ester (T747) | 0.1% |
Diene base succimide (T152) | 4% |
Methyl-silicone oil | 30ppm |
Polyethers macromolecular compound (DL32) | 0.5% |
Atoleine | 4% |
Above each component mass percentage content summation is 100%.
The typical physiochemical techniques index of 1 product of embodiment:
Project | Quality index |
Kinematic viscosity (40 DEG C)/mm2/s-1 | 8.9 |
Flash-point (opening)/DEG C | 181 |
Condensation point/DEG C | -14 |
Viscosity index (VI) | 142 |
Coefficient of friction | 0.081 |
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min | 277 |
Shear stability (40 DEG C of kinematic viscosity rates of descent)/% | 3.4 |
Tetra-ball machine test/Pb/N | 735 |
Sintering load/PD/N | 6395 |
Terraced nurse agrees/N | 262 |
FZG/ levels | 12 |
Corrosivity (copper sheet, 100 DEG C, 3h)/level | 1 |
Demulsification number, 54 DEG C of (40-37-3)/min | 10.5 |
Moisture, % | Vestige |
Mechanical admixture, % | Nothing |
The typical physiochemical techniques index of 2 product of embodiment:
Project | Quality index |
Kinematic viscosity (40 DEG C)/mm2/s-1 | 8.6 |
Flash-point (opening)/DEG C | 178 |
Condensation point/DEG C | -15 |
Viscosity index (VI) | 137 |
Coefficient of friction | 0.083 |
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min | 277 |
Shear stability (40 DEG C of kinematic viscosity rates of descent)/% | 3.7 |
Tetra-ball machine test/Pb/N | 710 |
Sintering load/PD/N | 6490 |
Terraced nurse agrees/N | 277 |
FZG/ levels | 12 |
Corrosivity (copper sheet, 100 DEG C, 3h)/level | 1 |
Demulsification number, 54 DEG C of (40-37-3)/min | 10.5 |
Moisture, % | Vestige |
Mechanical admixture, % | Nothing |
The typical physiochemical techniques index of 3 product of embodiment:
Project | Quality index |
Kinematic viscosity (40 DEG C)/mm2/s-1 | 7.96 |
Flash-point (opening)/DEG C | 169 |
Condensation point/DEG C | -16 |
Viscosity index (VI) | 146 |
Coefficient of friction | 0.082 |
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min | 255 |
Shear stability (40 DEG C of kinematic viscosity rates of descent)/% | 3.6 |
Tetra-ball machine test/Pb/N | 710 |
Sintering load/PD/N | 6310 |
Terraced nurse agrees/N | 258 |
FZG/ levels | 12 |
Corrosivity (copper sheet, 100 DEG C, 3h)/level | 1 |
Demulsification number, 54 DEG C of (40-37-3)/min | 11 |
Moisture, % | Vestige |
Mechanical admixture, % | Nothing |
Claims (10)
1. a kind of kirsite grinding technique lubricant compositions, it is characterised in that:Using oil based on HVIH 5, coordinate many
Kind of compound additive, its each mass percent into being grouped into:
The mass percent summation of above each component is 100%.
2. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antioxidant is
Dialkyl diphenylamine T534 of the phenolic ester base antioxidant T504 and 50% of mass ratio 50% is combined.
3. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that friction is improved
Agent is alkyl phosphite.
4. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that metal deactivating
Agent is benzotriazole derivative T551;Oiliness improver is soybean oil.
5. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that extreme pressure agent is
Acid dibutyl phosphite T304;Antiwear additive is tricresyl phosphate T304.
6. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that antirust agent is
The alkenyl succinic acid half ester T747 of the zinc naphthenate T704 and 50% of mass ratio 50% is combined.
7. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that dispersant is
Diene base succimide T152.
8. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti-foaming agent is
Methyl-silicone oil.
9. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that anti emulsifier
It is polyethers macromolecular compound DL32.
10. a kind of kirsite grinding technique lubricant compositions as claimed in claim 1, it is characterised in that filler is
Atoleine.
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CN104862036A (en) * | 2015-06-05 | 2015-08-26 | 广西大学 | Lubricant combination for cold tension reducing stainless steel tube |
CN104987943A (en) * | 2015-07-20 | 2015-10-21 | 广西大学 | High-temperature precise die-forging carbon steel lubricant composition |
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2016
- 2016-11-04 CN CN201610963573.3A patent/CN106520325A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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