CN106263024A - A kind of reduce the method for phenol content in cigarette smoke - Google Patents
A kind of reduce the method for phenol content in cigarette smoke Download PDFInfo
- Publication number
- CN106263024A CN106263024A CN201610657109.1A CN201610657109A CN106263024A CN 106263024 A CN106263024 A CN 106263024A CN 201610657109 A CN201610657109 A CN 201610657109A CN 106263024 A CN106263024 A CN 106263024A
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- CN
- China
- Prior art keywords
- momordica charantial
- momordica
- charantial
- cigarette
- filter stick
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/24—Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
- A24B15/26—Use of organic solvents for extraction
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention belongs to Nicotiana tabacum L. and cigarette additive field, relate to a kind of reducing the method for phenol content in cigarette smoke.The method of phenol content in cigarette smoke is reduced, including adding Momordica charantial or the step of the Fructus Momordicae charantiae extract containing Momordica charantial in filter stick and/or tobacco shred in particular it relates to a kind of.The present invention can be effectively reduced the content of phenol in cigarette smoke, is not significantly affected by tar content simultaneously, does not change cigarette original suction taste.
Description
Technical field
The invention belongs to Nicotiana tabacum L. and cigarette additive field, relate to a kind of reducing the method for phenol content in cigarette smoke.
Background technology
Phenol main source in cigarette smoke is glucide thermal decomposition and the Polyphenols chemical combination such as rutin and chlorogenic acid
Thing cracking produces, and is listed in the cigarette smoke that Hoffman nineteen ninety delivers in the list of 43 kinds of nuisances.In cigarette smoke
Phenolic compound be a kind of protoplasmic toxin, the mechanism of action is and the protein generation chemical reaction in cell, makes protein
Degeneration, further results in cell and loses activity.Additionally, it is dull to produce phenolic aldehyde taste, astringent taste etc. in aldehydes matter in flue gas
Jealous, abnormal smells from the patient and medicine burning sensation and unpleasant, dull suction taste, increase peculiar taste to flue gas, tart up
Complexity, causes astringent taste, pungent, pleasant impression the cleanest, thus affects mouthfeel and the suction quality of cigarette products.Therefore, use
The phenol that suitably means effectively reduce or remove in cigarette mainstream flue gas, can improve the safety of cigarette products.
Cigarette filter great majority are single acetate fiber unitary filter stick, it is impossible to the preferably benzene in absorption cigarette smoke
Phenol, currently also has and adds some functional materials in filter stick to improve the effect of absorption, such as cigarette industry Limited Liability in Hunan
Company discloses a kind of beta-schardinger dextrin--g-lactic acid copolymer active material particle that adds in fiber base material can reduce benzene in flue gas
The method (CN102987564A) of phenol 10.2%-35.1%.Although such technology can reduce phenol in main flume by selectivity,
But the preparation process of this material is more complicated, it is high that binary filter stick is combined cost, the repeatability of experiment and less stable, industrialization
Probability is less.
At present, the technique of phenol in the reduction flue gas wanting view new of still needing, and in order to keep the original suction of cigarette as far as possible
Taste, preferably will not significantly reduce tar content.
Summary of the invention
The present inventor is through in-depth study and performing creative labour, it has surprisingly been found that Momordica charantial (or containing Fructus Momordicae charantiae
The Fructus Momordicae charantiae extract of saponin) content of phenol in cigarette smoke can be effectively reduced, tar content change is little, and does not changes
Cigarette original suction taste.Thus provide following invention:
One aspect of the present invention relates to a kind of reducing the method for phenol content in cigarette smoke, including to filter stick and/or
Tobacco shred adds Momordica charantial or the step of the Fructus Momordicae charantiae extract containing Momordica charantial.
In one embodiment of the invention, described method, wherein, Momordica charantial or the Fructus Momordicae charantiae containing Momordica charantial carry
The addition taking thing is calculated as 1-150 μ g, preferably 5-according to the amount of the Momordica charantial in every Medicated cigarette or every filter stick
100 μ g or 10-50 μ g, more preferably 15-30 μ g, such as 15-25 μ g, 15-20 μ g, 20-30 μ g, 20-25 μ g, 15
μ g, 20 μ g, 25 μ g or 30 μ g.
In one embodiment of the invention, described method, wherein, by filter stick at Momordica charantial solution or containing hardship
The Fructus Momordicae charantiae extract of melon saponin soaks；Preferably, the filter stick after soaking dries or dries.
In one embodiment of the invention, described method, wherein, Momordica charantial solution is that the alcohol of Momordica charantial is molten
Liquid；Preferably, for ethanol solution, butanol solution or the isoamyl alcohol of Momordica charantial；Preferably, described Momordica charantial solution
Concentration be 50-100mg/mL.
In one embodiment of the invention, described method, wherein, the time of described immersion is at least 5 seconds, preferably
For the 10-30 second.
In one embodiment of the invention, described method, wherein, described in dry or the temperature dried be 25 DEG C-
35 DEG C, the time is 4-6 hour.
In one embodiment of the invention, described method, wherein, described Momordica charantial is Momordica charantial A.
In one embodiment of the invention, before described method comprises the steps: rolled cigarette, by filter stick one
After determining to soak in the Momordica charantial solution of concentration, taking-up is placed in ventilation after drying at a temperature of certain and uses.Described hardship
Melon saponin solution be concentration be 50-100mg/mL Momordica charantial alcohol (preferably ethanol, n-butyl alcohol, isoamyl alcohol) solution, described leaching
The bubble time is the 10-30 second, described in dry temperature be 25 DEG C-35 DEG C, flash-off time is 4-6 hour.
Another aspect of the present invention relates to a tobacco articles, and it contains Momordica charantial or the Fructus Momordicae charantiae containing Momordica charantial extracts
Thing；Preferably, described tobacco product is Medicated cigarette or filter stick；Preferably, Momordica charantial or the Fructus Momordicae charantiae extract containing Momordica charantial
Content according to the amount of the Momordica charantial in every Medicated cigarette or every filter stick be calculated as 1-150 μ g, preferably 5-100 μ g or
Person 10-50 μ g, more preferably 15-30 μ g, such as 15-25 μ g, 15-20 μ g, 20-30 μ g, 20-25 μ g, 15 μ g, 20 μ
G, 25 μ g or 30 μ g；Preferably, described Momordica charantial is Momordica charantial A.
Another aspect of the invention relates to Momordica charantial or the Fructus Momordicae charantiae extract containing Momordica charantial in reducing cigarette smoke
Purposes in phenol content；Preferably, described Momordica charantial is Momordica charantial A.
Another aspect of the invention relates to a kind of cigarette additive, and it contains Momordica charantial or the Fructus Momordicae charantiae containing Momordica charantial carries
Take thing；Alternatively, described cigarette additive also comprises cigarette solvent such as ethanol, n-butyl alcohol or isoamyl alcohol；Preferably, described hardship
Melon saponin is Momordica charantial A.
In the present invention, if not otherwise specified, described " Fructus Momordicae charantiae " Cucurbitaceae Momordica plant Fructus Momordicae charantiae is referred to
The fruit of (Momordica charantia L.).Which kind of seed in fruit can be removed and not remove.
In the present invention, term " Momordica charantial " is also called momordica saponins, is mainly made up of momordica saponins A and momordica saponins B.
In yet other embodiments, described Momordica charantial refers to momordica saponins A (CAS 81910-41-0).
The beneficial effect of the invention
The present invention is capable of in following technique effect one or more:
(1) Momordica charantial can phenol in cigarette mainstream flue gas, amplitude reaches more than 20% (such as 28%), and then reaches
Reduce the purpose of Medicated cigarette hazardness.
(2) add Momordica charantial (or the Fructus Momordicae charantiae extract containing Momordica charantial) and do not change cigarette original suction taste.It is regardless of
In theoretical restriction, it may be possible to owing to the space structure of Momordica charantial is big, the obstruct to tar is little.
(3) those skilled in the art know, if tar content reduces, flue gas strength declines, and inhale taste and change.The present invention
Tar content in flue gas, it has surprisingly been found that the present invention is while reducing phenol, is but affected little, is conducive to keeping Medicated cigarette by people
Mouthfeel and fragrance.
(4) the micro-hardship of Momordica charantial, makes filter stick have the sense of promoting the production of body fluid of uniqueness, brings to consumer and different sucks experience.
(5) cost of manufacture is low, simple to operate, good stability, and solving original technology binary filter stick, to be combined cost high, experiment
Repeatability and less stable, the drawbacks such as industrialization probability is less.
Detailed description of the invention
Below in conjunction with embodiment, embodiment of the present invention are described in detail, but those skilled in the art will
Understanding, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.In embodiment unreceipted specifically
Condition person, the condition advised according to normal condition or manufacturer is carried out.Agents useful for same or instrument unreceipted production firm person, be
Can by city available from conventional products.
In the following examples, if not otherwise specified, Momordica charantial used is Momordica charantial A, purchased from Shanghai
Grand along bio tech ltd, CAS 81910-41-0.
Embodiment 1: the mensuration (1) of phenol content and tar content
Before the trade mark 1 cigarette sample rolls, after filter stick is soaked 30 seconds in 50mg/mL Momordica charantial ethanol solution, take out
It is placed in ventilation after drying in the air at 25 DEG C 6 hours and uses.Cigarette machine simulation suction is carried out, to benzene in flue gas with unprocessed sample
The content of phenol detects.
The mensuration of phenol is carried out according to following document: Liu Fang etc., and ultrasonic extraction-high-speed HPLC method measures Medicated cigarette main flow
Phenol, cresol and Benzodiazepines in flue gas, Nicotiana tabacum L. science and technology, the 10th phase in 2007 (total 243rd phase), p31-35.
The mensuration of tar content is carried out according to GB/T 19609.
Experimental result is as shown in Table 1 below.
Table 1: the effectiveness comparison of selectivity fall phenol
Result shows, Momordica charantial can be effectively reduced the content of phenol in flue gas, decreases by more than 20%.Tar content
Change is little.
Embodiment 2: the mensuration (2) of phenol content and tar content
Before the trade mark 2 cigarette sample rolls, after filter stick is soaked 20 seconds in 75mg/mL Momordica charantial butanol solution, take
Go out to be placed in ventilation dry in the air 5 hours at 30 DEG C after use.With unprocessed sample carry out cigarette machine simulation suction, according to reality
Execute example 1 identical method phenol content in flue gas and tar content are detected.
Result is as shown in Table 2 below.
Table 2: the effectiveness comparison of selectivity fall phenol
Result shows, Momordica charantial can be effectively reduced the content of phenol in flue gas, decreases by more than 20%.Tar content
Change is little.
Embodiment 3: the mensuration (3) of phenol content and tar content
Before the trade mark 3 cigarette sample rolls, after filter stick is soaked 10 seconds in 100mg/mL Momordica charantial alcohol isoamyl alcohol,
Taking-up is placed in ventilation after drying in the air at 35 DEG C 4 hours and uses.With unprocessed sample carry out cigarette machine simulation suction, according to
Phenol content in flue gas and tar content are detected by the method that embodiment 1 is identical.
Result is as shown in Table 3 below.
Table 3: the effectiveness comparison of selectivity fall phenol
Result shows, Momordica charantial can be effectively reduced the content of phenol in flue gas, decreases by more than 20%.Tar content
Change is little.
Embodiment 4: the mensuration of Momordica charantial addition in filter stick
Measure the content/addition of Momordica charantial in the cigarette sample filter stick prepared in embodiment 1-3.Assay method is pressed
Carry out according to following list of references: stone snow duckweed etc., the content of HPLC ELSD mensuration momordica saponins, research and development of natural products,
Nat Prod Res Dev, 2006,18:471-473.
The Momordica charantial content that result records in embodiment 1-3 in every filter stick is respectively 14.5 μ g, 21.0 μ g, 29.8 μ
g.It addition, be not limited to the restriction of theory, owing to phenol and the tar content of different Medicated cigarette scripts all differ, and filter stick is beaten
The impact of the factors such as hole, filter tip degree of ventilation, causes in different Medicated cigarette, and phenol reduces degree and not necessarily adds with Momordica charantial
Amount is proportionate.
Embodiment 5: experiment of smokeing panel test
1. smoke panel test sample: sample 1-3 prepared by embodiment 1-3, and do not add the blank trade mark 1-of Momordica charantial
3 Medicated cigarette.
2. smoke panel test method: evaluate and analyse with reference to YC/T 497-2014 Medicated cigarette Chinese-style cigarette style sensory evaluation method.
3. smoking result:
Overall assessment: after interpolation, Medicated cigarette the most substantially changes compared with adding front blank cigarette odor-absorbing.Filter stick after interpolation
The most hardening, but filter stick slightly bitterness after adding, promote the production of body fluid sense more preferably.
Although the detailed description of the invention of the present invention has obtained detailed description, it will be understood to those of skill in the art that.Root
According to disclosed all teachings, those details can be carried out various amendment and replacement, these change all the guarantor of the present invention
Within the scope of protecting.The four corner of the present invention is given by claims and any equivalent thereof.
Claims (10)
1. reduce a method for phenol content in cigarette smoke, including adding Momordica charantial in filter stick and/or tobacco shred or containing
The step of the Fructus Momordicae charantiae extract of Momordica charantial.
Method the most according to claim 1, wherein, the addition of Momordica charantial or the Fructus Momordicae charantiae extract containing Momordica charantial is pressed
Amount according to the Momordica charantial in every Medicated cigarette or every filter stick is calculated as 1-150 μ g, preferably 5-100 μ g or 10-50
μ g, more preferably 15-30 μ g.
Method the most according to claim 1 and 2, wherein, by filter stick in Momordica charantial solution or the hardship containing Momordica charantial
Melon extract soaks；Preferably, the filter stick after soaking dries or dries.
Method the most according to claim 3, wherein, Momordica charantial solution is the alcoholic solution of Momordica charantial；Preferably, for hardship
The ethanol solution of melon saponin, butanol solution or isoamyl alcohol；Preferably, the concentration of described Momordica charantial solution is 50-
100mg/mL。
Method the most according to claim 3, wherein, the time of described immersion is at least 5 seconds, the preferably 10-30 second.
Method the most according to claim 3, wherein, described in dry or the temperature dried is 25 DEG C-35 DEG C, the time is 4-
6 hours.
7. according to the method described in any claim in claim 1 to 6, wherein, described Momordica charantial is Momordica charantial A.
8. a tobacco articles, it contains Momordica charantial or the Fructus Momordicae charantiae extract containing Momordica charantial；Preferably, described tobacco product
For Medicated cigarette or filter stick；Preferably, the content of Momordica charantial or the Fructus Momordicae charantiae extract containing Momordica charantial according to every Medicated cigarette or
The amount of the Momordica charantial in every filter stick is calculated as 1-150 μ g, preferably 5-100 μ g or 10-50 μ g, more preferably
15-30 μ g；Preferably, described Momordica charantial is Momordica charantial A.
9. Momordica charantial or the Fructus Momordicae charantiae extract containing the Momordica charantial purposes in phenol content in reducing cigarette smoke；Preferably
Ground, described Momordica charantial is Momordica charantial A.
10. a cigarette additive, it contains Momordica charantial or the Fructus Momordicae charantiae extract containing Momordica charantial；Alternatively, described cigarette is used
Additive also comprises cigarette solvent such as ethanol, n-butyl alcohol or isoamyl alcohol；Preferably, described Momordica charantial is Momordica charantial A.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610657109.1A CN106263024A (en) | 2016-08-12 | 2016-08-12 | A kind of reduce the method for phenol content in cigarette smoke |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610657109.1A CN106263024A (en) | 2016-08-12 | 2016-08-12 | A kind of reduce the method for phenol content in cigarette smoke |
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Cited By (3)
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| CN106833893A (en) * | 2017-02-27 | 2017-06-13 | 河南中烟工业有限责任公司 | Milk fragrance additive of phenol and its preparation method and application in a kind of reduction cigarette smoke |
| CN113549639A (en) * | 2021-07-21 | 2021-10-26 | 云南中烟工业有限责任公司 | Regulatory gene for reducing content of total protein and smoke phenol in tobacco leaves |
| CN113893613A (en) * | 2021-09-28 | 2022-01-07 | 深圳市真味生物科技有限公司 | Filtering material convenient to replace, filtering device and heating non-combustion appliance |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833893A (en) * | 2017-02-27 | 2017-06-13 | 河南中烟工业有限责任公司 | Milk fragrance additive of phenol and its preparation method and application in a kind of reduction cigarette smoke |
| CN113549639A (en) * | 2021-07-21 | 2021-10-26 | 云南中烟工业有限责任公司 | Regulatory gene for reducing content of total protein and smoke phenol in tobacco leaves |
| CN113549639B (en) * | 2021-07-21 | 2022-07-29 | 云南中烟工业有限责任公司 | Regulatory gene for reducing contents of total proteins and phenol in flue gas of tobacco leaves |
| CN113893613A (en) * | 2021-09-28 | 2022-01-07 | 深圳市真味生物科技有限公司 | Filtering material convenient to replace, filtering device and heating non-combustion appliance |
| CN113893613B (en) * | 2021-09-28 | 2023-09-12 | 深圳市真味生物科技有限公司 | Filter material convenient to replace, filter device and heating non-combustion appliance |
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Application publication date: 20170104 |