CN106165906B - Suitable for the burnt fragrant and sweet spices of the malt of cigarette products and the application tobacco product - Google Patents

Suitable for the burnt fragrant and sweet spices of the malt of cigarette products and the application tobacco product Download PDF

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CN106165906B
CN106165906B CN201610585395.5A CN201610585395A CN106165906B CN 106165906 B CN106165906 B CN 106165906B CN 201610585395 A CN201610585395 A CN 201610585395A CN 106165906 B CN106165906 B CN 106165906B
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malt
sweet
cigarette
spices
fragrant
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CN106165906A (en
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张文娟
马骥
洪广峰
毛健
姬凌波
杨伟平
何保江
洪群业
柴国璧
张启东
王丁众
范武
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Zhengzhou Tobacco Research Institute of CNTC
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Zhengzhou Tobacco Research Institute of CNTC
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    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B3/00—Preparing tobacco in the factory
    • A24B3/12—Steaming, curing, or flavouring tobacco
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
    • A24B15/303—Plant extracts other than tobacco

Abstract

The invention belongs to tobacco aromaticss technical field.More particularly to a kind of burnt fragrant and sweet spices of malt and its application in tobacco product, the spices it is prepared by the following method by raw material of melanoidin malt：A. pretreatment of raw material；B. ethanol extracts；C. freezing dewaxing, d. UF membranes.Rich in compounds such as Pyrazine, furans, Furanones, pyranone and cyclopentene ketones in the burnt fragrant and sweet spices of the malt of the present invention, it can assign cigarette pleasant burnt fragrant and sweet breath, strengthen Chinese-style cigarette style and features.The present invention pointedly burnt fragrant and sweet composition in extraction and separation and concentration melanoidin malt, effectively to eliminate the plant wax contained in malt extract, protein, starch etc. have the composition of side effect to tobacco product sense organ.The preparation technology is simple to operation, and low in raw material price, production process is economic and environment-friendly, suitable for scale industrial production application.Application of the spices in cigarette does not change the original processing technology of cigarette.

Description

Suitable for the burnt fragrant and sweet spices of the malt of cigarette products and the application tobacco product
Technical field
The invention belongs to tobacco aromaticss technical field, the burnt fragrant and sweet spices of specifically a kind of malt suitable for cigarette products and Its application in tobacco product, i.e., using melanoidin malt as the burnt fragrant and sweet spices of malt prepared by raw material and its answering in tobacco product With.
Background technology
It is burnt it is fragrant and sweet be Chinese-style cigarette aromatic style feature important note, have vital shadow to cigarette sensory quality Ring.According to Chinese-style cigarette style and features sensory evaluation method, burnt fragrant and sweet (caramel-like aroma) and nut are fragrant（nutty aroma）Fragrant (roast aroma) note of baking is collectively constituted.China, lotus king, sharp group, Mount Huang, Hongta, white sand, jade The smoking result of the representative brand cigarette such as small stream is shown, bakees the important component that perfume is its style and features.And to most For number Chinese-style cigarette, fragrant and sweet Jiao is that it bakees the main note tune of note feature.Such as foregoing several cigarette brands, except Baisha brand Bakee perfume (or spice) and be mainly shown as that nut is fragrant outer, remaining bakees perfume and is mainly shown as burnt fragrant and sweet feature.Therefore, flue gas Jiao's sweet tea is improved Fragrant feature, the lifting for Chinese-style cigarette organoleptic quality have obvious impetus.
Domestic and international tobacco company to being found that furans, Furanones, ring penta in succession in the research of cigarette smoke condensate The compound with burnt fragrant and sweet feature such as ketene and pyranone, mainly maltol（maltol）, 4- hydroxyl -2,5- diformazans Base -3 (2H)-furanone（furaneol）, methyl cyclopentenyl ketone（cyclotene）, 5 methyl furfural（5- methylfurfural）Deng.These materials also contain in addition to containing in tobacco in traditional tobacco aromaticss such as malt extract Have.
Malt is that the ripening fruits of barley is dried and obtained through germination, after wheat is soaked in water, keeps suitable epidemic disaster, Fructus Hordei Germinatus are drying to obtain when young shoot length is to about 0.5 cm；Fructus Hordei Germinatus slow fire heats, and fries to surface brown color, micro- to have focal spot, i.e., For coloured malt；Fructus Hordei Germinatus are fried to coke yellow with high heat, there is detonans, as melanoidin malt.Fructus Hordei Germinatus, coloured malt and melanoidin malt make medicine With.Fructus Hordei Germinatus are also the primary raw material of Beer Brewage.
Malt extract（Including tincture and medicinal extract）It is a kind of conventional cigarette additive, it has increase flue gas Jiao's sweet tea Perfume (or spice), remove the effect of blue foreign smell.But existing commercially available malt extract be mostly using Fructus Hordei Germinatus be raw material use traditional water or Prepared by low ethanol sequential extractions, there are some shortcomings in this method：1. the part natural scents of malt in extraction process Loss, the burnt fragrant and sweet feature of product do not protrude；2. the most soluble in water or low-concentration ethanol of product, make it in application by certain Limitation, it is adapted to cigarette charging to use, is not suitable for perfuming cigarette；3. wherein containing partially protein, starch, hemicellulose etc. into Point, these materials can crack during cigarette is burnt and sucked produces some harmful components, increases the excitant of cigarette smoking and miscellaneous gas （Correlation analysis Yanbian Universitys agronomy between Chi Jingji, Wang Yanli tobacco leaf primary chemical indexs and its judging parameter Report 2006,28: 208-210.；Song Peng microbial fermentations reduce harmful constituents in cigarette flue gas and improve cigarette quality Study Xi'an:Northwest University; 2008.）；4. containing Activities of Some Plants wax, bring wax gas etc. bad when cigarette is burnt and sucked Breath.At present, it is domestic also to have researcher using zymotechnic, microbial fermentation technology（CN 101889728 A；CN 102178345 A）Deng carrying out flavouring, the fragrant processing of production to malt or malt extract, malt extraction is enriched to a certain extent The note of thing, add the content of flavor component.But products obtained therefrom is for main note with roasting fragrant, the fragrant and sweet or delicate fragrance of wine, sweet and pure perfume Rhythm, it is burnt it is fragrant and sweet does not protrude, and wherein different degrees of still contain macromolecular substances and plant wax.
The content of the invention
The purpose of the present invention is exactly for the problem of presently, there are, using melanoidin malt as raw material, using appropriate extracting and developing Purification process, a kind of burnt fragrant and sweet spices of malt is prepared, and be applied to cigarette shreds perfuming and stem, the increasing of reconstituted tobacco Perfume (or spice), burnt fragrant and sweet rhythm during cigarette smoking is improved, lift Chinese-style cigarette organoleptic quality.
The purpose of the present invention is achieved through the following technical solutions：
A kind of burnt fragrant and sweet spices of malt suitable for cigarette products, be using melanoidin malt as raw material is prepared by the following method and Into：
A. pretreatment of raw material：Melanoidin malt removal of impurities, crush；
B. ethanol extracts：It is more than 65% with concentration（V/V, similarly hereinafter）Ethanol extraction, filter out leaching liquor；
C. freezing dewaxing：Leaching liquor is concentrated under reduced pressure into soluble solid content about 20%, now the 95% of the quality such as addition Ethanol, mix and stand 6~12 hours under the conditions of -25~-10 DEG C, filter or centrifuge as early as possible afterwards, collect clear liquid；
D. UF membrane：The ethanol solution that appropriate concentration is 70%~90% is added into the clear liquid after dewaxing, makes it soluble Solid content is 2%~4%；The nm of aperture 50~200 micro-filtrate membrane filtration is first used, collects permeate；Again by micro-filtration permeate mistake Molecular cut off is 5 kD milipore filter, collects ultrafiltration permeate, produces the burnt fragrant and sweet spices of malt.
The present invention can be extracted when being extracted with ethanol focusing malt powder using following various ways：Such as, room Temperature is lower to be extracted, and is extracted 2 times per batch materials, each feed liquid mass ratio 1:5~1:10, extract 3~7 days every time；In 50~80 DEG C of bars Heating extraction under part, feed liquid mass ratio 1:5~1:10, extract 2 times, every time 1~3 hour；Ultrasonic assistant extracts, ultrasonic wave frequency The kHz of rate 28~45, the W of power 500~1000, the min of extraction time 30~60,30~50 DEG C of Extracting temperature, feed liquid mass ratio 1: 10~1:15；Also other prior arts such as microwave radiation exaraction can be used.Wherein, preferable extraction process is：Concentration is more than 70% Ethanol, 65~80 DEG C of heating extractions twice, each feed liquid mass ratio 1:5~1:8,1.5~2 h are extracted every time.
The burnt fragrant and sweet spices of malt prepared by the present invention has the burnt fragrant and sweet note of feature.It is brown liquid at room temperature.
Application of the burnt fragrant and sweet spices of malt in tobacco product：
As cigarette shreds perfuming additive, it is diluted with finite concentration ethanol or with the mixed solvent of propane diols, Individually or uniformly it is sprayed onto with the perfuming link after other spices mixtures in production of cigarettes on pipe tobacco, dosage is tobacco quality 0.001%~0.01%；
For stalk filaments of tobacco stalks perfuming, adding it in stem feed liquid, dosage is the 0.002%~0.02% of stem quality, Routinely in stem charging process, uniformly spray adds on stem technique, is mixed after balance with cut tobacco and is configured to cigarette.
For reconstituted tobacco perfuming, add it in reconstituted tobacco coating fluid, dosage is reconstituted tobacco quality 0.002%~0.02%, afterwards routinely technique chopping, mix silk, be eventually fabricated cigarette.
The invention has the advantages that：
The burnt fragrant and sweet spices of the malt of the present invention can assign cigarette pleasant burnt fragrant and sweet breath, and it is special to strengthen Chinese-style cigarette style Sign, for the problems such as stem and reconstituted tobacco fragrance are weaker, stimulation is larger, fragrant drop thorn can be mended.And the application does not change tobacco The original production technology of product.
The preparation method of the burnt fragrant and sweet spices of the malt of the present invention, the melanoidin malt rich in burnt fragrant and sweet composition is have selected first as original Material.Fructus Hordei Germinatus can produce substantial amounts of furfuran compound, Pyrazine derivative, maltol etc. after processing, these chemistry into Divide and show as burnt fragrant and sweet breath mostly；And the frying of higher-strength can cause under the content of the organic acids such as the palmitic acid in malt Drop, reduce the fatty odor of its extract.The present invention pointedly in extraction and separation and concentration melanoidin malt it is burnt it is fragrant and sweet into Point, effectively eliminate the plant wax contained in malt extract, protein, starch etc. have to cigarette sense organ side effect into Point.Pyrazine, furans, Furanones, pyranone and cyclopentenone are rich in the burnt fragrant and sweet spices of malt prepared by the present invention Class compound.Products obtained therefrom is burnt fragrant and sweet more obvious, and fragrance component is more concentrated.
The preparation technology is simple to operation, low in raw material price, suitable for scale industrial production application, production process economy Environmental protection.
Brief description of the drawings
Fig. 1 is the GC-MS chromatograms of the burnt fragrant and sweet spices of the malt prepared using the method for embodiment 1.
Fig. 2 is the GC-MS chromatograms of the burnt fragrant and sweet spices of the malt prepared using the method for embodiment 2.
Embodiment
The present invention is described further with reference to embodiments, but the scope not limiting the invention in any way.
Embodiment 1
(1) the preparation of the burnt fragrant and sweet spices of malt
The commercially available kg of Chinese herbal medicine melanoidin malt 1, removal of impurities, is crushed to 20 mesh.80 DEG C are heated to using the ethanol of concentration 85% to carry Take, feed liquid mass ratio is 1:5, extract twice, every time 2 h.Merge leaching liquor twice, be concentrated under reduced pressure into soluble solid content For 20%, 95% ethanol of quality such as now add, mix and stand 6 hours under the conditions of -10 DEG C；Filter as early as possible afterwards, to institute The ethanol solution for adding that appropriate concentration is 85% in filtrate is obtained, it is 3% to make its soluble solid content；First with the nm's of aperture 50 Micro-filtrate membrane filtration, collect permeate；Micro-filtration permeate is crossed into the milipore filter that molecular cut off is 5 kD again, ultrafiltration is collected and passes through Liquid, produce the burnt fragrant and sweet spices of malt.
(2) the analysis of aroma components of the burnt fragrant and sweet spices of malt
The burnt fragrant and sweet spices of a certain amount of malt is accurately weighed, with internal standard extract（The ethanol solution of 2,6- xylenols is dense Spend 30 μ g/mL）Fully dissolve and be settled in volumetric flask, with Agilent 7890A-5975C gas chromatograph-mass spectrometer (GC-MS)s Detection.
GC-MS conditions：DB-WAXetr（60 m×250 μm×0.25 μm）Capillary chromatographic column；Carrier gas：He, 99.999%；Flow velocity：1.0 mL/min；Injector temperature：250℃；Sample size：1 μL；Sample introduction pattern：Split sampling, split ratio 5:1；Heating schedule：40 DEG C of initial temperature, 4 min are kept, 160 DEG C are risen to 2 DEG C/min speed, then with 5 DEG C/min's Speed rises to 240 DEG C, keeps 15 min.Ion gun：Electron bombardment（EI）, the eV of electron energy 70；230 DEG C of ion source temperature；Pass Defeated line temperature：150℃；Scan pattern：Full scan, mass scan range are 10~550 a.m.u.；The solvent delay time：16 min。
The GC-MS chromatograms of the burnt fragrant and sweet spices of malt are shown in accompanying drawing 1, and the analysis result of main aromatic components is shown in Table 1.From analysis As a result as can be seen that rich in Pyrazine, furans in the burnt fragrant and sweet spices of malt（Furfural, furfuryl alcohol, 5 methyl furfural, 5- methylols Furfural）, Furanones, pyranone（Maltol, 5- hydroxyls maltol, DDMP）With cyclopentene ketone compounds.Wherein, malt Phenol, methyl cyclopentenyl ketone, 4- hydroxyl -2,5- dimethyl -3 (2H)-furanone has typical burnt fragrant and sweet fragrance.Pyrazine Compound is most to have that nut is fragrant, it is fragrant to bakee, such as 2- methylpyrazines, 2,5- dimethyl pyrazines, 2,3,5- trimethylpyrazines etc., they And conventional cigarette monomer perfume.Furfural, 5 methyl furfural, 5 hydroxymethyl furfural, furfuryl alcohol and DDMP are in cigarette smoke Proper constituent, though not directly translating into burnt fragrant and sweet note, they are that caramelization occurs for food or Maillard reacts main Product, there is caramel sample, the note of fermentation, coordinate with cigarette perfume, enrich fragrance intension.2- acetyl pyrroles have nut perfume, dried Roast note.
The main aromatic components analysis result of the burnt fragrant and sweet spices of malt is made in the embodiment 1 of table 1
Numbering Retention time/min Compound name Relative amount/%
1 28.96 2- methylpyrazines 1.54
2 32.56 2,5-dimethyl pyrazine 0.70
3 32.96 2,6 dimethyl pyrazine 1.38
4 33.40 Ethyl pyrazine 0.59
5 34.14 2,3- dimethyl pyrazines 0.57
6 36.67 2- ethyl -6- methylpyrazines 0.91
7 37.07 2- ethyl -5- methylpyrazines 0.18
8 37.81 2,3,5- trimethylpyrazines 0.34
9 37.92 2- ethyl -3- methylpyrazines 0.37
10 40.44 3- ethyls -2,5-dimethyl pyrazine 0.52
11 41.49 2- ethyl -3,5- dimethyl pyrazines 0.17
12 42.03 Furfural 1.67
13 48.75 5 methyl furfural 4.04
14 54.07 Furfuryl alcohol 2.65
15 63.01 Methyl cyclopentenyl ketone 1.05
16 67.03 3- methyl -2- methylol pyrazines 0.08
17 67.11 2,6- xylenols Internal standard
18 67.80 1- (2- pyrazines) -1- ethanol 0.43
19 69.14 Maltol 30.61
20 69.46 2- acetyl pyrroles 0.96
21 71.37 4- hydroxyl -2,5- dimethyl -3 (2H)-furanone 1.79
22 77.62 2,3- dihydro -3,5- dihydroxy -6- methyl -4 (H)-pyrans -4- ketone（DDMP） 4.40
23 77.97 5- hydroxyl maltols 1.84
24 82.37 5 hydroxymethyl furfural 31.71
(3) application of the burnt fragrant and sweet spices of malt in tobacco product
A. cigarette shreds perfuming
The burnt fragrant and sweet spices of the above-mentioned malt of 0.05 g is weighed, with 85% ethanol and propane diols mass ratio 20:1 mixed solvent is dilute Release to 10 g, mix, it is standby.Weigh 1 kg to cut filler, be uniformly divided into two parts, a uniformly spray adds the burnt fragrant and sweet spices of malt Dilution（Perfuming amount is 0.01%, is designated as testing cigarette）；Uniformly the above-mentioned mixed solvents of 10 g of sprinkling are used as control cigarette for another Silk.Roll into cigarette respectively afterwards.Experiment cigarette and control cigarette are respectively put into constant temperature（22±1℃）, constant humidity（Relative humidity 60 ±2%）More than the h of case inner equilibrium 48.Through 10 people's above judging panels with reference to YC/T 497-2014《Chinese-style cigarette style sensory evaluation side Method》Smoke panel test, evaluation result is averaged.As a result（Table 2 and table 3）Display：The experiment cigarette of the burnt fragrant and sweet spices of malt is added, in perfume (or spice) Gas and rich aspect have lifting, and flue gas concentration is increased slightly, and bakee fragrant（It is predominantly burnt fragrant and sweet）With fragrant and sweet protrusion, fragrance association Adjust, while miscellaneous gas and excitant mitigate, pleasant impression is comfortable, overall sucking quality is improved, and style and features are more obvious.
B. stalk filaments of tobacco stalks perfuming
1 kg expanded cut stems are taken, and weigh the original formulation stem feed liquid of broiler diets, add 0.2 g malt Jiao thereto Fragrant and sweet spices, mix, equably spray is added in expanded cut stem, and the stem after charging seals at room temperature places 6 h, by 5% (matter Amount fraction) ratio uniform mix during Virginian-type cigarette cuts filler, roll into cigarette with conventional method（It is denoted as test sample）. Control sample is that the feed liquid of the ethanol of 0.2 g 85% is added into original formulation stem feed liquid, is fed by same procedure, steel wire storage, mixes silk, volume Cigarette.Test sample and control sample are respectively placed in temperature (22 ± 1) DEG C and relative humidity (60 ± 2) % environment and balance 48 more than h, By 10 people's above cigarette sensory evaluation judging panels with reference to the evaluation of the methods of YC/T 497-2014.As a result (table 4 and table 5) shows, expansion After the burnt fragrant and sweet spices of stem feed liquid addition malt, when made cigarette is burnt and sucked fragrance and it is rich have certain lifting, bakee fragrant（Mainly It is fragrant and sweet for Jiao）With fragrant and sweet obvious increase, fragrance is coordinated, and pleasant impression is comfortable, and overall sucking quality is improved, and style and features are brighter It is aobvious.
C. reconstituted tobacco perfuming
1 kg reconstituted tobacco chip bases are taken, and weigh the original formulation coating fluid of broiler diets, add 0.2 g malt thereto Burnt fragrant and sweet spices, mixes, is uniformly applied in reconstituted tobacco chip base, papermaking-method reconstituted tobaccos finished product is obtained after drying；Will again Mix with making the ratio uniform after tobacco leaf chopping by 5% (mass fraction) during Virginian-type cigarette cuts filler, rolled with conventional method Into cigarette（It is denoted as test sample）.Control sample is that the coating fluid of the ethanol of 0.2 g 85% is added into original formulation coating fluid, by phase Tongfang Method coating, drying, chopping, mix silk, cigarette.Test sample and control sample are respectively placed in temperature (22 ± 1) DEG C and relative humidity (60 ± 2) 48 more than h are balanced in % environment, by 10 people's above cigarette sensory evaluation judging panels with reference to the evaluation of the methods of YC/T 497-2014. As a result (table 6 and table 7) shows, after the burnt fragrant and sweet spices of reconstituted tobacco coating fluid addition malt, fragrance and cigarette when made cigarette is burnt and sucked Gas concentration has certain lifting, bakees fragrant（It is predominantly burnt fragrant and sweet）With fragrant and sweet obvious increase, fragrance is coordinated, and pleasant impression is comfortable, overall to inhale Food matter is improved, and style and features are more obvious.
Embodiment 2
(1) the preparation of the burnt fragrant and sweet spices of malt
The commercially available kg of Chinese herbal medicine melanoidin malt 1.1, removal of impurities, is crushed to 40 mesh.With the ethanol of concentration 75% of 15 times of its weight in At room temperature using 20 L ultrasonic wave circulation extractor extraction, the kHz of ultrasonic frequency 45, the W of power 750, total time 50 is extracted Min, ultrasonic time and interval time are 2 s/1 s, the rpm of mixing speed 1500.Extraction is filtered by vacuum after terminating, filtrate decompression It is 20% to be concentrated into soluble solid content, and now 95% ethanol of the quality such as addition, mixes and 12 are stood under the conditions of -25 DEG C Hour；Filter as early as possible afterwards, the ethanol solution that appropriate concentration is 75% is added into gained filtrate, contains its soluble solid Measure as 4%；The nm of aperture 200 micro-filtrate membrane filtration is first used, collects permeate；It is 5 kD that micro-filtration permeate is crossed into molecular cut off again Milipore filter, collect ultrafiltration permeate, produce the burnt fragrant and sweet spices of malt.
(2) the analysis of aroma components of the burnt fragrant and sweet spices of malt
The burnt fragrant and sweet spices of malt manufactured in the present embodiment is analyzed using GC-MS methods same as Example 1, As shown in Figure 2, main aromatic components analysis result is shown in Table 8 to GC-MS chromatograms.From analysis result as can be seen that the malt is burnt Rich in compositions such as maltol, 5 hydroxymethyl furfural, furfuryl alcohol, methyl cyclopentenyl ketones in fragrant and sweet spices.
The main aromatic components analysis result of the burnt fragrant and sweet spices of malt is made in the embodiment 2 of table 8
Numbering Retention time/min Compound name Relative amount/%
1 28.96 2- methylpyrazines 0.38
2 32.56 2,5-dimethyl pyrazine 0.25
3 32.96 2,6 dimethyl pyrazine 0.56
4 33.40 Ethyl pyrazine 0.19
5 34.14 2,3- dimethyl pyrazines 0.21
6 36.67 2- ethyl -6- methylpyrazines 0.40
7 37.07 2- ethyl -5- methylpyrazines 0.12
8 37.81 2,3,5- trimethylpyrazines 0.21
9 37.92 2- ethyl -3- methylpyrazines 0.37
10 40.44 3- ethyls -2,5-dimethyl pyrazine 0.36
11 41.49 2- ethyl -3,5- dimethyl pyrazines 0.11
12 42.04 Furfural 1.33
13 48.75 5 methyl furfural 2.40
14 49.53 4- cyclopentene -1,3- diketone 0.82
15 53.98 Furfuryl alcohol 3.51
16 63.04 Methyl cyclopentenyl ketone 1.18
17 67.08 2,6- xylenols Internal standard
18 69.29 Maltol 35.46
19 69.46 2- acetyl pyrroles 0.94
20 71.35 4- hydroxyl -2,5- dimethyl -3 (2H)-furanone 1.36
21 77.60 2,3- dihydro -3,5- dihydroxy -6- methyl -4 (H)-pyrans -4- ketone（DDMP） 2.55
22 77.97 5- hydroxyl maltols 1.85
23 82.37 5 hydroxymethyl furfural 22.09
(3) application of the burnt fragrant and sweet spices of malt in tobacco product
1. the burnt fragrant and sweet spices of malt is added to reconstituted tobacco according to the use ratio of reconstituted tobacco chip base quality 0.002% In coating fluid, it is applied to after well mixed in reconstituted tobacco chip base, papermaking-method reconstituted tobaccos finished product, chopping is obtained after drying.② The burnt fragrant and sweet spices of malt is added in stem feed liquid according to the use ratio of expanded cut stem quality 0.002%, uniformly sprayed after mixing Spill into expanded cut stem, the stem after charging seals at room temperature places 6 h.1. the reconstituted tobacco silk and stalk that will be obtained in and 2. Silk respectively by 3% (mass fraction) ratio uniform mix Virginian-type cigarette be formulated cut tobacco in, cut filler；Again thereto The uniformly dilution of spray plus the burnt fragrant and sweet spices of malt（With 75% ethanol and propane diols mass ratio 19:1 mixed solvent dilution）, wheat The relative addition to cut filler of the burnt fragrant and sweet spices of bud is 0.002%, rolls into cigarette afterwards（It is denoted as testing cigarette）.Control sample is Be not added with the reconstituted tobacco of the burnt fragrant and sweet spices of malt and what stem each 3% was mixed cut filler, uniformly spray plus with test sample equivalent 75% ethanol and propane diols mass ratio 19:1 mixed solvent, cigarette is rolled into conventional method.Will experiment cigarette and control cigarette point Constant temperature is not put into it（22±1℃）, constant humidity（Relative humidity 60 ± 2%）More than the h of case inner equilibrium 48.Commented through 10 people's above cigarette sense organs Valency judging panel averages with reference to the evaluation of the methods of YC/T 497-2014, evaluation result.As a result（Table 9 and table 10）Display：Add wheat The experiment cigarette of the burnt fragrant and sweet spices of bud, there is lifting in fragrance and rich aspect, flue gas concentration increase, bakee fragrant（Predominantly It is burnt fragrant and sweet）With fragrant and sweet obvious increase, fragrance is coordinated, and pleasant impression is comfortable, and overall sucking quality is improved, and style and features are brighter It is aobvious.

Claims (5)

  1. A kind of 1. burnt fragrant and sweet spices of malt suitable for cigarette products, it is characterised in that：Be pass through using melanoidin malt as raw material it is following Method is prepared：
    A. pretreatment of raw material：Melanoidin malt removal of impurities, crush；
    B. ethanol extracts：Extracted with ethanol of the concentration more than 65%, filter out leaching liquor；In this step, take following any one Kind extracting mode：
    （1）Extract, extracted 2 times per batch materials, each feed liquid mass ratio 1 at room temperature:5~1:10, extract 3~7 days every time；
    （2）The heating extraction under the conditions of 50~80 DEG C, feed liquid mass ratio 1:5~1:10, extract 2 times, every time 1~3 hour；
    （3）Ultrasonic assistant extracts, the kHz of ultrasonic frequency 28~45, the W of power 500~1000, extraction time 30~60 Min, 30~50 DEG C of Extracting temperature, feed liquid mass ratio 1:10~1:15；
    （4）Using microwave radiation exaraction；
    C. freezing dewaxing：Leaching liquor is concentrated under reduced pressure into soluble solid content 20%, now 95% ethanol of the quality such as addition, Mixing stands 6~12 hours under the conditions of -25~-10 DEG C, filters or centrifuges as early as possible afterwards, collects clear liquid；
    D. UF membrane：The ethanol solution that concentration is 70%~90% is added into the clear liquid after dewaxing, contains its soluble solid Measure as 2%~4%；50~200nm of aperture micro-filtrate membrane filtration is first used, collects permeate；Micro-filtration permeate is crossed into retention molecule again Measure the milipore filter for 5kD, collect ultrafiltration permeate, produce the burnt fragrant and sweet spices of malt, the burnt fragrant and sweet spices of the malt rich in Pyrazine, Furans, Furanones, pyranone and cyclopentene ketone compounds.
  2. 2. the burnt fragrant and sweet spices of the malt according to claim 1 suitable for cigarette products, it is characterised in that：In b step In extraction, extracting mode is：Concentration be more than 70% ethanol, 65~80 DEG C of heating extractions twice, each feed liquid mass ratio 1:5~ 1:8,1.5~2 h are extracted every time.
  3. 3. the burnt fragrant and sweet spices of the malt according to claim 1 suitable for cigarette products, it is characterised in that：The malt is burnt Fragrant and sweet spices has burnt fragrant and sweet note, is at room temperature brown liquid.
  4. A kind of 4. application of burnt fragrant and sweet spices of malt as claimed in claim 1 in tobacco product, it is characterised in that：The malt Burnt fragrant and sweet fragrance applications can assign cigarette pleasant Jiao in cigarette shreds perfuming, stalk filaments of tobacco stalks perfuming or reconstituted tobacco perfuming Fragrant and sweet breath, strengthen Chinese-style cigarette style and features, mend fragrant drop thorn, and do not change the original production technology of tobacco product.
  5. 5. application of the burnt fragrant and sweet spices of malt according to claim 4 in tobacco product, it is characterised in that：Application process It is as follows：
    As cigarette shreds perfuming additive, it is diluted with ethanol or the mixed solvent of ethanol and propane diols, individually or with Perfuming link after other spices mixtures in production of cigarettes is uniformly sprayed onto on pipe tobacco, dosage for tobacco quality 0.001%~ 0.01%；
    For stalk filaments of tobacco stalks perfuming, add it in stem feed liquid, dosage is the 0.002%~0.02% of stem quality, by normal In stem charging process, uniformly spray adds on stem rule technique, is mixed after balance with cut tobacco and is configured to cigarette；
    For reconstituted tobacco perfuming, add it in reconstituted tobacco coating fluid, dosage for reconstituted tobacco quality 0.002%~ 0.02%, afterwards routinely technique chopping, mix silk, be eventually fabricated cigarette.
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CN106645517B (en) * 2017-01-23 2019-03-01 中国烟草总公司郑州烟草研究院 The method for measuring 14 kinds of fragrant and sweet ingredients of coke in cigarette mainstream flue gas simultaneously
CN106770795B (en) * 2017-01-23 2019-03-01 中国烟草总公司郑州烟草研究院 The method for heating 14 kinds of fragrant and sweet ingredients of coke in non-burning cigarette smoke is measured simultaneously
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Family Cites Families (5)

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KR0167708B1 (en) * 1995-10-31 1998-12-01 박명규 Flavouring material for tobacco containing extract of pimpinella anisum.l.
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CN104531351B (en) * 2014-12-03 2017-08-08 河南中烟工业有限责任公司 A kind of tobacco juice for electronic smoke additive and preparation method thereof
CN104946390B (en) * 2015-05-31 2018-10-23 中国烟草总公司郑州烟草研究院 A kind of processing method of electronics natural perfume for cigarette
CN105768033B (en) * 2016-03-10 2019-03-19 安徽中烟工业有限责任公司 A kind of baked barley tea flavor Maillard reaction essence and preparation method thereof and evaluation method

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