CN106165906A - The burnt fragrant and sweet spice of a kind of Fructus Hordei Germinatus be applicable to cigarette products and the application tobacco product thereof - Google Patents
The burnt fragrant and sweet spice of a kind of Fructus Hordei Germinatus be applicable to cigarette products and the application tobacco product thereof Download PDFInfo
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- CN106165906A CN106165906A CN201610585395.5A CN201610585395A CN106165906A CN 106165906 A CN106165906 A CN 106165906A CN 201610585395 A CN201610585395 A CN 201610585395A CN 106165906 A CN106165906 A CN 106165906A
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- fructus hordei
- hordei germinatus
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- fragrant
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
- A24B15/303—Plant extracts other than tobacco
Abstract
The invention belongs to tobacco aromatics using technical field.Being specifically related to the burnt fragrant and sweet spice of a kind of Fructus Hordei Germinatus and the application in tobacco product thereof, this spice is to be prepared by the following method with Fructus Hordei Germinatus (parched to brown) for raw material: a. pretreatment of raw material；B. ethanol extraction；C. freezing dewaxing, d. membrance separation.Rich in compounds such as Pyrazine, furans, Furanones, pyranone and cyclopentenes ketones in the burnt fragrant and sweet spice of the Fructus Hordei Germinatus of the present invention, it is possible to give the fragrant and sweet breath of Jiao that Medicated cigarette is joyful, strengthen Chinese-style cigarette style and features.Extract to the property of the present invention is directed to and Jiao fragrant and sweet composition in separation and concentration Fructus Hordei Germinatus (parched to brown), effectively eliminate the plant waxiness that contains in Fructus Hordei Germinatus extract, protein, starch etc. have the composition of side effect to tobacco product sense organ.This preparation technology is simple to operation, low in raw material price, and production process is economic and environment-friendly, is suitable to large-scale industrial production application.The application in Medicated cigarette of this spice does not change the original processing technique of Medicated cigarette.
Description
Technical field
The invention belongs to tobacco aromatics using technical field, a kind of burnt fragrant and sweet spice of Fructus Hordei Germinatus being applicable to cigarette products and
Its application in tobacco product, the burnt fragrant and sweet spice of Fructus Hordei Germinatus i.e. prepared with Fructus Hordei Germinatus (parched to brown) for raw material and answering in tobacco product thereof
With.
Background technology
Burnt fragrant and sweet be the important note of Chinese-style cigarette aromatic style feature, cigarette sensory quality is had vital shadow
Ring.According to Chinese-style cigarette style and features sensory evaluation method, burnt fragrant and sweet (caramel-like aroma) and nutty (nutty
Aroma) fragrant (roast aroma) note of baking has been collectively constituted.China, Hibisci Mutabilis king, profit group, Mount Huang, Hongta, white sand, jade
The smoking result of the representative brand cigarette such as small stream shows, bakees perfume and is the important component part of its style and features.And to mostly
For number Chinese-style cigarette, Jiao is fragrant and sweet is that its main note bakeing fragrant note feature is adjusted.Such as aforementioned several cigarette brands, except Baisha brand
Bakeing perfume (or spice) mainly to show as outside nutty, remaining bakees perfume (or spice) and mainly shows as burnt fragrant and sweet feature.Therefore, flue gas Jiao is improved sweet
Fragrant feature, the lifting for Chinese-style cigarette organoleptic quality has obvious impetus.
Tobacco company is to being in succession found that furans, Furanones, ring penta in the research of cigarette smoke condensate both at home and abroad
Ketene and pyranone etc. with the compound of burnt fragrant and sweet feature, mainly maltol (maltol), 4-hydroxyl-2,5-diformazan
Base-3 (2H)-furanone (furaneol), methyl cyclopentenyl ketone (cyclotene), 5 methyl furfural (5-
Methylfurfural) etc..These materials, in addition to containing in Nicotiana tabacum L., also contain in the tradition tobacco aromatics usings such as Fructus Hordei Germinatus extract
Have.
Fructus Hordei Germinatus is that the mature fruit of Fructus Hordei Vulgaris is dried through germinateing and obtains, and after being soaked in water by wheat grain, keeps suitable epidemic disaster,
It is drying to obtain Fructus Hordei Germinatus when plumelet length to about 0.5 cm；Fructus Hordei Germinatus slow fire heats, and fries to surface brown color, and micro-have focal spot, i.e.
For Fructus Hordei Germinatus (parched)；Fructus Hordei Germinatus is fried with high heat to coke yellow, has detonans, is Fructus Hordei Germinatus (parched to brown).Fructus Hordei Germinatus, Fructus Hordei Germinatus (parched) and Fructus Hordei Germinatus (parched to brown) all make medicine
With.Fructus Hordei Germinatus is also the primary raw material of Beer Production.
Fructus Hordei Germinatus extract (including tincture and extractum) is a kind of conventional cigaret additive, and it is sweet that it has increase flue gas Jiao
Perfume (or spice), removes the effect of blue foreign smell.But, existing commercially available Fructus Hordei Germinatus extract be mostly with Fructus Hordei Germinatus for raw material use traditional water or
Prepared by low ethanol sequential extractions, this method there are disadvantages that: the part natural scents of Fructus Hordei Germinatus during 1. extracting
Loss, the burnt fragrant and sweet feature of product does not highlights；2. product is the most soluble in water or low-concentration ethanol so that it is when application by certain
Limit, be suitable for cigarette charging and use, be not suitable for perfuming cigarette；Wherein contain partially protein, starch, hemicellulose etc. to become
Point, these materials can crack some harmful components of generation during Medicated cigarette burns and sucks, and increases zest and the miscellaneous QI of cigarette smoking
(Chi Jingji, Wang Yanli. the correlation analysis between Nicotiana tabacum L. primary chemical index and judging parameter thereof. Yanbian University's agronomy
Report. 2006,28:208-210.；Song Peng. fermentable reduces harmful constituents in cigarette flue gas and improves cigarette quality
Research. Xi'an: Northwest University;2008.)；4. contain Activities of Some Plants waxiness, bring when Medicated cigarette burns and sucks waxiness gas etc. bad
Breath.At present, domestic also have researcher to utilize zymotechnic, microbial fermentation technology (CN 101889728 A；CN
102178345 A) etc. Fructus Hordei Germinatus or Fructus Hordei Germinatus extract carried out flavouring, produce perfume and process, enrich Fructus Hordei Germinatus to a certain extent and extract
The note of thing, adds the content of flavor component.But, products obtained therefrom is with roasting perfume (or spice), makes fragrant and sweet or delicate fragrance, sweet and pure perfume (or spice) as main note
Rhythm, burnt fragrant and sweet does not highlight, and the most in various degree still contain macromolecular substances and plant waxiness.
Summary of the invention
The purpose of the present invention is just for the problem that presently, there are, and with Fructus Hordei Germinatus (parched to brown) as raw material, uses suitable extracting and developing
Purification process, the burnt fragrant and sweet spice of a kind of Fructus Hordei Germinatus of preparation, and it is applied to cigarette shreds perfuming and stem, the increasing of reconstituted tobacco
Perfume (or spice), improves the fragrant and sweet rhythm of Jiao during cigarette smoking, promotes Chinese-style cigarette organoleptic quality.
It is an object of the invention to be achieved through the following technical solutions:
A kind of burnt fragrant and sweet spice of Fructus Hordei Germinatus being applicable to cigarette products, is to be prepared by the following method with Fructus Hordei Germinatus (parched to brown) for raw material to form:
A. pretreatment of raw material: Fructus Hordei Germinatus (parched to brown) remove impurity, pulverizing；
B. ethanol extraction: by concentration more than 65%(V/V, lower with) ethanol extraction, leach lixiviating solution；
C. freezing dewaxing: lixiviating solution is evaporated to soluble solid content about 20%, 95% second of the quality such as now addition
Alcohol, stands 6～12 hours after mixing under the conditions of-25～-10 DEG C, and sucking filtration or centrifugal, collects clear liquid the most as early as possible；
D. membrance separation: add, in the clear liquid after dewaxing, the ethanol solution that appropriate concentration is 70%～90% so that it is solubility solid
Thing content is 2%～4%；First with the micro-filtrate membrane filtration of aperture 50～200 nm, collect permeate；Again microfiltration permeate is crossed and retain
Molecular weight is the ultrafilter membrane of 5 kD, collects ultrafiltration permeate, obtains the burnt fragrant and sweet spice of Fructus Hordei Germinatus.
The present invention, when extracting with ethanol focusing Fructus Hordei Germinatus powder, can use following various ways to extract: as, room
The lower extraction of temperature, every batch materials extracts 2 times, each feed liquid mass ratio 1:5～1:10, every time extraction 3～7 days；At 50～80 DEG C of bars
Heating extraction under part, feed liquid mass ratio 1:5～1:10, extract 2 times, each 1～3 hour；Ultrasonic assistant extracts, ultrasound wave frequency
Rate 28～45 kHz, power 500～1000 W, extraction time 30～60 min, Extracting temperature 30～50 DEG C, feed liquid mass ratio 1:
10～1:15；Also other prior aries such as microwave radiation exaraction can be used.Wherein, preferred extraction process is: concentration is more than 70%
Ethanol, 65～80 DEG C of heating extraction twice, each feed liquid mass ratio 1:5～1:8, extract 1.5～2 h every time.
The burnt fragrant and sweet spice of Fructus Hordei Germinatus prepared by the present invention has the fragrant and sweet note of Jiao of feature.It it is brown liquid under room temperature.
The burnt fragrant and sweet spice application in tobacco product of Fructus Hordei Germinatus:
As cigarette shreds perfuming additive, finite concentration ethanol or the mixed solvent with propylene glycol is used to dilute, individually
Or be uniformly sprayed onto on tobacco shred in the perfuming link of production of cigarettes after other spice mixture, consumption is the 0.001% of tobacco quality
～0.01%；
For stalk filaments of tobacco stalks perfuming, adding it in stem feed liquid, consumption is the 0.002%～0.02% of stem quality, by often
Rule technique is uniformly sprayed at stem charging process and is added on stem, mixes with cut tobacco and be configured to Medicated cigarette after balance.
For reconstituted tobacco perfuming, adding it in reconstituted tobacco coating fluid, consumption is reconstituted tobacco quality
0.002%～0.02%, technique shredding the most routinely, mix silk, be eventually fabricated Medicated cigarette.
The method have the advantages that
The burnt fragrant and sweet spice of the Fructus Hordei Germinatus of the present invention can give the Medicated cigarette fragrant and sweet breath of joyful Jiao, strengthens Chinese-style cigarette style and features,
The problems such as, stimulation more weak for stem and reconstituted tobacco fragrance is bigger, it is possible to mend perfume fall thorn.And this application does not change tobacco product
Original production technology.
The preparation method of the burnt fragrant and sweet spice of the Fructus Hordei Germinatus of the present invention, it is former for first have selected the Fructus Hordei Germinatus (parched to brown) rich in burnt fragrant and sweet composition
Material.Fructus Hordei Germinatus can produce substantial amounts of furfuran compound, Pyrazine derivative, maltol etc. after concocting, and these chemistry become
Divide and mostly show as burnt fragrant and sweet breath；And the parch of higher-strength can make under the content of the organic acid such as the Palmic acid in Fructus Hordei Germinatus
Fall, reduces the fatty odor of its extract.Extract to the property of the present invention is directed to and Jiao fragrant and sweet one-tenth in separation and concentration Fructus Hordei Germinatus (parched to brown)
Point, effectively eliminate the plant waxiness that contains in Fructus Hordei Germinatus extract, protein, starch etc. have the one-tenth of side effect to Medicated cigarette sense organ
Point.Rich in Pyrazine, furans, Furanones, pyranone and cyclopentenone in the burnt fragrant and sweet spice of Fructus Hordei Germinatus prepared by the present invention
Compounds.Products obtained therefrom Jiao is fragrant and sweet to be become apparent from, and fragrance component is more concentrated.
This preparation technology is simple to operation, low in raw material price, is suitable to large-scale industrial production application, production process economy
Environmental protection.
Accompanying drawing explanation
Fig. 1 is the GC-MS chromatogram of the burnt fragrant and sweet spice of the Fructus Hordei Germinatus using embodiment 1 method to prepare.
Fig. 2 is the GC-MS chromatogram of the burnt fragrant and sweet spice of the Fructus Hordei Germinatus using embodiment 2 method to prepare.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, but and limits the scope of the present invention never in any form.
Embodiment 1
(1) the preparation of the burnt fragrant and sweet spice of Fructus Hordei Germinatus
Commercially available Chinese herbal medicine Fructus Hordei Germinatus (parched to brown) 1 kg, remove impurity, it is crushed to 20 mesh.The ethanol using concentration 85% is heated to 80 DEG C of extractions, material
Liquid mass ratio is 1:5, extracts twice, each 2 h.Merging twice lixiviating solution, being evaporated to soluble solid content is
20%, 95% ethanol of the quality such as now addition, under the conditions of-10 DEG C, stand 6 hours after mixing；Sucking filtration the most as early as possible, to gained
Filtrate adds the ethanol solution that appropriate concentration is 85% so that it is soluble solid content is 3%；First micro-with aperture 50 nm
Membrane filtration, collects permeate；Microfiltration permeate is crossed the ultrafilter membrane that molecular cut off is 5 kD again, collects ultrafiltration permeate,
Obtain the burnt fragrant and sweet spice of Fructus Hordei Germinatus.
(2) the analysis of aroma components of the burnt fragrant and sweet spice of Fructus Hordei Germinatus
Accurately weigh the burnt fragrant and sweet spice of a certain amount of Fructus Hordei Germinatus, by internal standard extract (ethanol solution of 2,6-xylenols, concentration 30
μ g/mL) fully dissolve and be settled in volumetric flask, detect with Agilent 7890A-5975C gas chromatograph-mass spectrometer (GC-MS).
GC-MS condition: DB-WAXetr(60 m × 250 μ m 0.25 μm) capillary chromatographic column；Carrier gas: He,
99.999%；Flow velocity: 1.0 mL/min；Injector temperature: 250 DEG C；Sample size: 1 μ L；Sample introduction pattern: split sampling, split ratio
5:1；Heating schedule: initial temperature 40 DEG C, keeps 4 min, rises to 160 DEG C with the speed of 2 DEG C/min, then with 5 DEG C/min's
Speed rises to 240 DEG C, keeps 15 min.Ion source: electron bombardment (EI), electron energy 70 eV；Ion source temperature 230 DEG C；Pass
Defeated line temperature: 150 DEG C；Scan pattern: full scan, mass scan range is 10～550 a.m.u.；The solvent delay time: 16
min。
The GC-MS chromatogram of the burnt fragrant and sweet spice of Fructus Hordei Germinatus is shown in accompanying drawing 1, and the analysis result of main aromatic components is shown in Table 1.From analysis
Result is it can be seen that rich in Pyrazine, furans (furfural, furfuryl alcohol, 5 methyl furfural, 5-methylol in the burnt fragrant and sweet spice of Fructus Hordei Germinatus
Furfural), Furanones, pyranone (maltol, 5-hydroxyl maltol, DDMP) and cyclopentenone compounds.Wherein, Fructus Hordei Germinatus
Phenol, methyl cyclopentenyl ketone, 4-hydroxyl-2,5-dimethyl-3 (2H)-furanone has typical burnt fragrant and sweet fragrance.Pyrazine
Compound majority have nutty, bakee perfume, as 2-methylpyrazine, 2,5-dimethyl pyrazine, 2，3，5-trimethylpyrazine etc., they
Also it is conventional cigarette monomer perfume.Furfural, 5 methyl furfural, 5 hydroxymethyl furfural, furfuryl alcohol and DDMP are in cigarette smoke
Proper constituent, though not directly translating into burnt fragrant and sweet note, but they be food generation caramelization or Maillard reaction main
Product, has the note of caramel sample, fermentation, coordinates with cigarette perfume (or spice), abundant fragrance intension.2-acetyl pyrrole has nutty, baking
Roasting note.
Table 1 embodiment 1 prepares the main aromatic components analysis result of the burnt fragrant and sweet spice of Fructus Hordei Germinatus
| Numbering | Retention time/min | Compound name | Relative amount/% |
| 1 | 28.96 | 2-methylpyrazine | 1.54 |
| 2 | 32.56 | 2,5-dimethyl pyrazine | 0.70 |
| 3 | 32.96 | 2,6 dimethyl pyrazine | 1.38 |
| 4 | 33.40 | Ethyl pyrazine | 0.59 |
| 5 | 34.14 | 2,3-dimethyl pyrazine | 0.57 |
| 6 | 36.67 | 2-ethyl-6-methylpyrazine | 0.91 |
| 7 | 37.07 | 2-ethyl-5-methylpyrazine | 0.18 |
| 8 | 37.81 | 2,3,5-trimethylpyrazine | 0.34 |
| 9 | 37.92 | 2-ethyl-3-methylpyrazine | 0.37 |
| 10 | 40.44 | 3-ethyl-2,5-dimethyl pyrazine | 0.52 |
| 11 | 41.49 | 2-ethyl-3,5-dimethyl pyrazine | 0.17 |
| 12 | 42.03 | Furfural | 1.67 |
| 13 | 48.75 | 5 methyl furfural | 4.04 |
| 14 | 54.07 | Furfuryl alcohol | 2.65 |
| 15 | 63.01 | Methyl cyclopentenyl ketone | 1.05 |
| 16 | 67.03 | 3-methyl-2-methylol pyrazine | 0.08 |
| 17 | 67.11 | 2,6-xylenol | Internal standard |
| 18 | 67.80 | 1-(2-pyrazine)-1-ethanol | 0.43 |
| 19 | 69.14 | Maltol | 30.61 |
| 20 | 69.46 | 2-acetyl pyrrole | 0.96 |
| 21 | 71.37 | 4-hydroxyl-2,5-dimethyl-3 (2H)-furanone | 1.79 |
| 22 | 77.62 | 2,3-dihydro-3,5-dihydroxy-6-methyl-4 (H)-pyrans-4-ketone (DDMP) | 4.40 |
| 23 | 77.97 | 5-hydroxyl maltol | 1.84 |
| 24 | 82.37 | 5 hydroxymethyl furfural | 31.71 |
(3) the burnt fragrant and sweet spice application in tobacco product of Fructus Hordei Germinatus
A. cigarette shreds perfuming
Weigh the burnt fragrant and sweet spice of the 0.05 above-mentioned Fructus Hordei Germinatus of g, be diluted to the mixed solvent of 85% ethanol and propylene glycol mass ratio 20:1
10 g, mixing, standby.Weighing 1 kg to cut filler, be uniformly divided into two parts, a uniformly spray adds the dilution of the burnt fragrant and sweet spice of Fructus Hordei Germinatus
Liquid (perfuming amount is 0.01%, is designated as testing Medicated cigarette)；Another part uniformly sprays the 10 above-mentioned mixed solvents of g as comparison tobacco shred.It
Rear roll into cigarette respectively.Test Medicated cigarette and comparison Medicated cigarette are respectively put into constant temperature (22 ± 1 DEG C), constant humidity (relative humidity 60 ± 2%)
Case inner equilibrium 48 more than h.Comment with reference to YC/T 497 2014 " Chinese-style cigarette style sensory evaluation method " through the 10 above judging panels of people
Inhaling, evaluation result is averaged.Result (table 2 and table 3) shows: add the test Medicated cigarette of the burnt fragrant and sweet spice of Fructus Hordei Germinatus, at fragrance and
Rich aspect all has lifting, and flue gas concentration is increased slightly, and bakees fragrant (the most burnt fragrant and sweet) and fragrant and sweet prominent, fragrance coordination,
Simultaneously miscellaneous QI and zest alleviate, pleasant impression comfortable, overall sucking quality is improved, and style and features becomes apparent from.
B. stalk filaments of tobacco stalks perfuming
Take 1 kg expanded cut stem, and weigh the original formulation stem feed liquid of broiler diets, be added to 0.2 g Fructus Hordei Germinatus Jiao fragrant and sweet
Spice, mixing, spray is added in expanded cut stem equably, and the stem after charging seals placement 6 h at room temperature, and by 5%, (quality is divided
Number) ratio uniform ground mix during Virginian-type cigarette cuts filler, roll into Medicated cigarette (being denoted as testing sample) by conventional method.Comparison
Sample is the feed liquid adding 0.2 g 85% ethanol in original formulation stem feed liquid, by same procedure charging, steel wire storage, mixes silk, Medicated cigarette.
Test sample and control sample are respectively placed in temperature (22 ± 1) DEG C and relative humidity (60 ± 2) % environment and balance 48 more than h, by
10 people above Medicated cigarette sensory evaluation judging panel is with reference to YC/T 497 2014 method evaluation.Result (table 4 and table 5) shows, expansion stem
After silk feed liquid adds the burnt fragrant and sweet spice of Fructus Hordei Germinatus, fragrance and rich have certain lifting when made Medicated cigarette burns and sucks, bakee fragrant (predominantly
Burnt fragrant and sweet) and fragrant and sweet obvious increase, fragrance coordination, pleasant impression is comfortable, and overall sucking quality is improved, and style and features is brighter
Aobvious.
C. reconstituted tobacco perfuming
Take 1 kg reconstituted tobacco chip base, and weigh the original formulation coating fluid of broiler diets, be added to 0.2 g Fructus Hordei Germinatus Jiao sweet
Fragrant spice, mixing, it is uniformly applied in reconstituted tobacco chip base, after drying, obtains papermaking-method reconstituted tobaccos finished product；Cigarette will be reproduced
In cutting filler by the ratio uniform ground incorporation Virginian-type cigarette of 5% (mass fraction) after leaf shredding, roll rolling by conventional method
Cigarette (is denoted as testing sample).Control sample is to add the coating fluid of 0.2 g 85% ethanol in original formulation coating fluid, is coated with by same procedure
Cloth, drying, shredding, mix silk, Medicated cigarette.Test sample and control sample are respectively placed in temperature (22 ± 1) DEG C and relative humidity (60 ±
2) % environment balances 48 more than h, by 10 people above Medicated cigarette sensory evaluation judging panel with reference to YC/T 497 2014 method evaluation.Knot
Really (table 6 and table 7) shows, after reconstituted tobacco coating fluid adds the burnt fragrant and sweet spice of Fructus Hordei Germinatus, and fragrance and flue gas when made Medicated cigarette burns and sucks
Concentration has certain lifting, bakees fragrant (the most burnt fragrant and sweet) and fragrant and sweet obvious increase, and fragrance is coordinated, and pleasant impression is comfortable, and entirety is sucked
Quality is improved, and style and features becomes apparent from.
Embodiment 2
(1) the preparation of the burnt fragrant and sweet spice of Fructus Hordei Germinatus
Commercially available Chinese herbal medicine Fructus Hordei Germinatus (parched to brown) 1.1 kg, remove impurity, it is crushed to 40 mesh.With concentration 75% ethanol of its weight 15 times in room temperature
The ultrasound wave circulation extractor of lower employing 20 L extracts, and ultrasonic frequency 45 kHz, power 750 W extract total time 50 min,
Ultrasonic time and interval time are 2 s/1 s, mixing speed 1500 rpm.Extract and terminate final vacuum sucking filtration, filtrate reduced in volume
It is 20% to soluble solid content, 95% ethanol of the quality such as now addition, under the conditions of-25 DEG C, stand 12 after mixing little
Time；Sucking filtration the most as early as possible, adds the ethanol solution that appropriate concentration is 75% so that it is soluble solid content in gained filtrate
It is 4%；First with the micro-filtrate membrane filtration of aperture 200 nm, collect permeate；It is 5 kD's that microfiltration permeate is crossed molecular cut off again
Ultrafilter membrane, collects ultrafiltration permeate, obtains the burnt fragrant and sweet spice of Fructus Hordei Germinatus.
(2) the analysis of aroma components of the burnt fragrant and sweet spice of Fructus Hordei Germinatus
The burnt fragrant and sweet spice of Fructus Hordei Germinatus using GC-MS method same as in Example 1 to prepare the present embodiment is analyzed, GC-MS
As shown in Figure 2, main aromatic components analysis result is shown in Table 8 to chromatogram.From analysis result it can be seen that the burnt fragrant and sweet perfume (or spice) of this Fructus Hordei Germinatus
Rich in compositions such as maltol, 5 hydroxymethyl furfural, furfuryl alcohol, methyl cyclopentenyl ketones in material.
Table 8 embodiment 2 prepares the main aromatic components analysis result of the burnt fragrant and sweet spice of Fructus Hordei Germinatus
| Numbering | Retention time/min | Compound name | Relative amount/% |
| 1 | 28.96 | 2-methylpyrazine | 0.38 |
| 2 | 32.56 | 2,5-dimethyl pyrazine | 0.25 |
| 3 | 32.96 | 2,6 dimethyl pyrazine | 0.56 |
| 4 | 33.40 | Ethyl pyrazine | 0.19 |
| 5 | 34.14 | 2,3-dimethyl pyrazine | 0.21 |
| 6 | 36.67 | 2-ethyl-6-methylpyrazine | 0.40 |
| 7 | 37.07 | 2-ethyl-5-methylpyrazine | 0.12 |
| 8 | 37.81 | 2,3,5-trimethylpyrazine | 0.21 |
| 9 | 37.92 | 2-ethyl-3-methylpyrazine | 0.37 |
| 10 | 40.44 | 3-ethyl-2,5-dimethyl pyrazine | 0.36 |
| 11 | 41.49 | 2-ethyl-3,5-dimethyl pyrazine | 0.11 |
| 12 | 42.04 | Furfural | 1.33 |
| 13 | 48.75 | 5 methyl furfural | 2.40 |
| 14 | 49.53 | 4-cyclopentenes-1,3-diketone | 0.82 |
| 15 | 53.98 | Furfuryl alcohol | 3.51 |
| 16 | 63.04 | Methyl cyclopentenyl ketone | 1.18 |
| 17 | 67.08 | 2,6-xylenol | Internal standard |
| 18 | 69.29 | Maltol | 35.46 |
| 19 | 69.46 | 2-acetyl pyrrole | 0.94 |
| 20 | 71.35 | 4-hydroxyl-2,5-dimethyl-3 (2H)-furanone | 1.36 |
| 21 | 77.60 | 2,3-dihydro-3,5-dihydroxy-6-methyl-4 (H)-pyrans-4-ketone (DDMP) | 2.55 |
| 22 | 77.97 | 5-hydroxyl maltol | 1.85 |
| 23 | 82.37 | 5 hydroxymethyl furfural | 22.09 |
(3) the burnt fragrant and sweet spice application in tobacco product of Fructus Hordei Germinatus
1. burnt for Fructus Hordei Germinatus fragrant and sweet spice is added to reconstituted tobacco coating according to the use ratio of reconstituted tobacco chip base quality 0.002%
In liquid, it is applied to after mix homogeneously in reconstituted tobacco chip base, after drying, obtains papermaking-method reconstituted tobaccos finished product, shredding.2. according to
Burnt for Fructus Hordei Germinatus fragrant and sweet spice is added in stem feed liquid by the use ratio of expanded cut stem quality 0.002%, is uniformly sprayed to after mixing
In expanded cut stem, the stem after charging seals placement 6 h at room temperature.1. and 2. by each to the reconstituted tobacco silk and the stem that obtain in
Mix in Virginian-type cigarette formula cut tobacco by the ratio uniform ground of 3% (mass fraction), cut filler；The most uniform
Spray adds the diluent (with the mixed solvent dilution of 75% ethanol with propylene glycol mass ratio 19:1) of the burnt fragrant and sweet spice of Fructus Hordei Germinatus, and Fructus Hordei Germinatus is burnt
The addition that fragrant and sweet spice cuts filler relatively is 0.002%, rolls into cigarette (being denoted as testing Medicated cigarette) afterwards.Control sample is not for add
Adding the reconstituted tobacco of the burnt fragrant and sweet spice of Fructus Hordei Germinatus and stem each 3% is mixed cuts filler, uniformly spray adds and the 75% of test sample equivalent
Ethanol and the mixed solvent of propylene glycol mass ratio 19:1, roll into cigarette by conventional method.Will test Medicated cigarette and comparison Medicated cigarette difference
Put into constant temperature (22 ± 1 DEG C), constant humidity (relative humidity 60 ± 2%) case inner equilibrium 48 more than h.Through 10 people above Medicated cigarette sensory evaluation
Judging panel is with reference to YC/T 497 2014 method evaluation, and evaluation result is averaged.Result (table 9 and table 10) shows: add Fructus Hordei Germinatus
The test Medicated cigarette of burnt fragrant and sweet spice, all has lifting at fragrance and rich aspect, and flue gas concentration increases, and bakees fragrant (predominantly burnt
Fragrant and sweet) and fragrant and sweet obvious increase, fragrance coordination, pleasant impression is comfortable, and overall sucking quality is improved, and style and features becomes apparent from.
Claims (7)
1. the burnt fragrant and sweet spice of Fructus Hordei Germinatus being applicable to cigarette products, it is characterised in that: it is by following with Fructus Hordei Germinatus (parched to brown) for raw material
Method is prepared from:
A. pretreatment of raw material: Fructus Hordei Germinatus (parched to brown) remove impurity, pulverizing；
B. ethanol extraction: be more than the ethanol extraction of 65% by concentration, leach lixiviating solution；
C. freezing dewaxing: lixiviating solution is evaporated to soluble solid content about 20%, 95% second of the quality such as now addition
Alcohol, stands 6～12 hours after mixing under the conditions of-25～-10 DEG C, and sucking filtration or centrifugal, collects clear liquid the most as early as possible；
D. membrance separation: add the ethanol solution that concentration is 70%～90% in the clear liquid after dewaxing so that it is soluble solid contains
Amount is 2%～4%；First with the micro-filtrate membrane filtration of aperture 50～200 nm, collect permeate；Again microfiltration permeate is crossed and retain molecule
Amount is the ultrafilter membrane of 5 kD, collects ultrafiltration permeate, obtains the burnt fragrant and sweet spice of Fructus Hordei Germinatus.
The burnt fragrant and sweet spice of Fructus Hordei Germinatus being applicable to cigarette products the most according to claim 1, it is characterised in that: carry in b step
In taking, any one extracting mode following can be taked:
(1) extracting under room temperature, every batch materials extracts 2 times, each feed liquid mass ratio 1:5～1:10, every time extraction 3～7 days；
(2) heating extraction under the conditions of 50～80 DEG C, feed liquid mass ratio 1:5～1:10, extract 2 times, each 1～3 hour；
(3) ultrasonic assistant extracts, ultrasonic frequency 28～45 kHz, power 500～1000 W, extraction time 30～60
Min, Extracting temperature 30～50 DEG C, feed liquid mass ratio 1:10～1:15；
(4) microwave radiation exaraction is used.
The most according to claim 1 and 2 be applicable to cigarette products the burnt fragrant and sweet spice of Fructus Hordei Germinatus, it is characterised in that: walk at b
In rapid extraction, preferred extracting mode is: the concentration ethanol more than 70%, 65～80 DEG C of heating extraction twice, each feed liquid matter
Amount ratio 1:5～1:8, extracts 1.5～2 h every time.
The burnt fragrant and sweet spice of Fructus Hordei Germinatus being applicable to cigarette products the most according to claim 1, it is characterised in that: described Fructus Hordei Germinatus is burnt
Fragrant and sweet spice has burnt fragrant and sweet note, is brown liquid under room temperature.
5. according to the burnt fragrant and sweet spice of the Fructus Hordei Germinatus being applicable to cigarette products described in claim 1 or 4, it is characterised in that: described wheat
The burnt fragrant and sweet spice of bud is rich in Pyrazine, furans, Furanones, pyranone and cyclopentenone compounds.
6. the burnt fragrant and sweet spice application in tobacco product of Fructus Hordei Germinatus as claimed in claim 1, it is characterised in that: this Fructus Hordei Germinatus
Burnt fragrant and sweet fragrance applications is in cigarette shreds perfuming, stalk filaments of tobacco stalks perfuming or reconstituted tobacco perfuming, it is possible to give Jiao that Medicated cigarette is joyful
Fragrant and sweet breath, strengthens Chinese-style cigarette style and features, mends perfume fall thorn, and does not change the original production technology of tobacco product.
The burnt fragrant and sweet spice of Fructus Hordei Germinatus the most according to claim 6 is in the application in tobacco product, it is characterised in that: application side
Method is as follows:
As cigarette shreds perfuming additive, finite concentration ethanol or the mixed solvent with propylene glycol is used to dilute, individually
Or be uniformly sprayed onto on tobacco shred in the perfuming link of production of cigarettes after other spice mixture, consumption is the 0.001% of tobacco quality
～0.01%；
For stalk filaments of tobacco stalks perfuming, adding it in stem feed liquid, consumption is the 0.002%～0.02% of stem quality, by often
Rule technique is uniformly sprayed at stem charging process and is added on stem, mixes with cut tobacco and be configured to Medicated cigarette after balance；
For reconstituted tobacco perfuming, add it in reconstituted tobacco coating fluid, consumption be reconstituted tobacco quality 0.002%～
0.02%, technique shredding the most routinely, mix silk, be eventually fabricated Medicated cigarette.
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| CN106770795A (en) * | 2017-01-23 | 2017-05-31 | 中国烟草总公司郑州烟草研究院 | 14 kinds of methods of the fragrant and sweet composition of Jiao in heating non-burning cigarette smoke are determined simultaneously |
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