CN105124759B - Cigarette mouth stick and preparation method thereof of the essence containing flavone compound - Google Patents

Cigarette mouth stick and preparation method thereof of the essence containing flavone compound Download PDF

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Publication number
CN105124759B
CN105124759B CN201510338815.5A CN201510338815A CN105124759B CN 105124759 B CN105124759 B CN 105124759B CN 201510338815 A CN201510338815 A CN 201510338815A CN 105124759 B CN105124759 B CN 105124759B
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China
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mouth stick
cigarette
flavone compound
essence containing
tipping paper
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CN201510338815.5A
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Chinese (zh)
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CN105124759A (en
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宋旭艳
魏敏
罗诚浩
陈义坤
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湖北中烟工业有限责任公司
黄鹤楼科技园(集团)有限公司
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Abstract

The present invention discloses a kind of cigarette mouth stick and preparation method thereof of essence containing flavone compound, 1) 20%~50% glycyrrhizin, 20%~50% eugenol, 10%~40% luteolin, 5%~20% aurantiin are weighed by weight percentage, extracting solution is obtained by filtration as Extraction solvent refluxing extraction in ethanol solution after mixing;2) extracting solution is uniformly sprayed to mouth stick tipping paper surfaces externally and internally;3) then that the mouth stick tipping paper in step 2) is dry;4) the mouth stick tipping paper after drying is wrapped in outside the forming paper of mouth stick, the cigarette mouth stick of the essence containing flavones is made.The mouth stick of the essence containing flavone compound of the invention has significant advantage in terms of reducing phenol in smoke and free radical, phenol reduced rate can achieve 10~45%, free radical reduced rate is 8~25%, and certain reduction can also be generated to other harmful substances matter in flue gas and acted on, and will not be had a negative impact to cigarette smoking quality.

Description

Cigarette mouth stick and preparation method thereof of the essence containing flavone compound

Technical field

The invention belongs to technical field of cigarettes, and in particular to a kind of cigarette mouth stick and its system of the essence containing flavone compound Preparation Method.

Background technique

Natural plants are widely used in tobacco aromaticss, wherein being much containing Flavonoid substances.According to Flavonoid substances Molecular characterization and interelectric active force power, Primary Study find the substance burning cracking after can generate Furans and its derivative, these substances are the main aroma components in flue gas, can be brought camerlsed to flue gas, it is fragrant and sweet, Roasting perfume, increases perfume quantity and aroma quality.Therefore in the allotment of essence spice for cigarette, there is the use of many flavonoids perfume materials.

Many researchs also indicate that, flavone compound has multiple biological activities, except using its antibacterial, anti-inflammatory, anti-mutation, Outside the effects of decompression, clearing heat and detoxicating, calm, diuresis, anti-oxidant, anticancer, anti-cancer, inhibit in terms of also have significant effect Fruit.It is the scavenger of most of oxygen radicals, thus the vigor of energy increased SOD (superoxide dismutase), reduces MDA (rouge Matter peroxide malonaldehyde) and OX-LDL (OxLDL ELISA) generation.It can increase coronary flow, to experiment Myocardial inyaretion has antagonism;There is protective effect to acute myocardial ischemia;Have to treatment coronary heart diseases and angina pectoris, hypertension etc. Remarkable result;To diastolic pressure is reduced, prevention and treatment arrhythmia cordis, cardiovascular disease and activating microcirculation and removing stasis medicinal also play an important role.

Phenolic compound is a kind of compound common in nature, in water, fuel, vehicle exhaust, air, wine and cigarette There is the presence of phenolic compound in flue gas.Reported phenolic compounds in cigarette smoke has more than 50 kinds, wherein most important phenol Class compound includes phenol, catechol, resorcinol, hydroquinone, o, m, 7 kinds of ingredients such as p- cresols.

Phenolic compound can cause protein denaturation, thin by being directly entered blood circulation with the contact of skin, mucous membrane Born of the same parents destroy and lose vigor.And induced by alkyl hydroxybenzene has endocrine disrupting activity, sends out the reproduction of mammal and aquatile It educates and impacts, referred to as phenols environmental estrogens, there is part phenols component genotoxicity and carcinogenic or promotion mutagenesis to make With.Above 7 kinds of phenols components are put into EPA harmful components list, and catechol is classified as 2B grades of carcinogenic components by IARC.Zheng State Bureau's key research project " cigarette harmfulness Research on Index System " project that state tobacco research institute undertakes is harmful by research The relationship of ingredient burst size and flue gas biological activity, discovery phenol are to influence the most important nocuousness of cigarette mainstream flue gas harmfulness One of ingredient.

Currently, the method for phenol is mainly using the method for absorption in reduction flue gas, if mouth stick is to phenol in flue gas Filtering, because phenol is present in the granule phase substance of flue gas, can be retained down from flue gas by the method for physical absorption.It is existing The adsorbent of technical application is mainly the biggish porous material of surface area, while absorption, retention phenol, can also adsorb flue gas The aroma component and flue gas moisture of middle part cause to be easy to produce stimulation, perfume quantity deficiency, aroma quality decline when cigarette smoking, Seriously affect cigarette smoking quality.

Summary of the invention

In view of the deficiencies of the prior art, the present invention provide it is a kind of using antioxidation block that phenol generates containing flavonoids The cigarette of compound essence mouth stick and preparation method thereof has the function that reduce phenol in smoke.

The technical proposal adopted by the invention to solve the above technical problems is that: a kind of essence containing flavone compound is provided Cigarette mouth stick preparation method, the preparation method include the following steps:

1) 20%~50% glycyrrhizin, 20%~50% eugenol, 10%~40% are weighed by weight percentage Luteolin, 5%~20% aurantiin, extracting solution is obtained by filtration as Extraction solvent refluxing extraction in ethanol solution after mixing;

2) extracting solution is uniformly sprayed to mouth stick tipping paper surfaces externally and internally;

3) then that the mouth stick tipping paper in step 2) is dry;

4) the mouth stick tipping paper after drying is wrapped in outside the forming paper of mouth stick, the essence containing flavone compound is made Cigarette mouth stick.

Further, the mass percentage concentration of the ethanol solution is 70%~90%.

Further, refluxing extraction 2~4 times in the step 1), each refluxing extraction 2~4 hours.

Further, the drying temperature in the step 3) is 25 DEG C~40 DEG C.

A kind of cigarette mouth stick of the essence containing flavone compound, the cigarette mouth stick of the essence containing flavone compound are upper State the cigarette mouth stick of the essence containing flavone compound of the method preparation.

It is analyzed according to organic chemistry basic theories, influences to be most importantly hydroxyl in the oxidation resistant factor of flavone compound Change degree and hydroxy position, phenolic hydroxyl group are the chief active group of flavone compound antioxidation, while finding flavonoids Hydroxyl activity difference on each ring is larger, and be mainly manifested in: B ring is the main work of flavone compound oxidation and removing free radicals Property position, when the ring is there are when ortho-phenolic hydroxyl structure, antioxidant activity greatly enhances;When hydroxyl on c ring and unsaturated double-bond phase Lian Shi, c ring also have stronger antioxidant activity;The phenolic hydroxyl group of A ring is most weak.Phenolic hydroxyl group in flavones structure is living with hydrogen supply Property, hydrogen atom can be supplied to active oxygen radical, form the Phenoxy radical of stable low activity, to avoid these activity Oxygen radical generates phenolic compound to the attack of aromatic rings.Phenolic hydroxyl group number in flavones molecule is more, it is possible to provide to Hydrogen atom in conjunction with living radical is more, and therefore, flavone compound can use the life that antioxidation blocks phenol At to have the function of preferably reducing phenol release amount in flue gas.

The invention has the following advantages that

1, the mouth stick of the essence of the invention containing flavone compound has significant in terms of reducing phenol in smoke and free radical Advantage, phenol reduced rate can achieve 10~45%, and free radical reduced rate is 8~25%, and to other harmful substances in flue gas Matter can also generate certain reduction effect, and will not have a negative impact to cigarette smoking quality;

2, flavone compound essence of the invention has excellent natural breath, and addition, can be at cigarette filter tip position Unique, strong additional fragrance is brought to cigarette, and is not involved in cigarette burning, because without generating new bad object because of cracking Matter meets requirement of the consumer to health, low evil;

3, flavone compound flavor of raw material of the invention is from a wealth of sources, low in cost, easy to promote and utilize.

Specific embodiment

In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention It is further elaborated.The specific embodiments described herein are merely illustrative of the present invention, is not used to limit this hair It is bright.

Embodiment 1

1) flavone compound essence is mixed according to ratio in table 1, it is molten is dissolved in the ethyl alcohol that mass percentage concentration is 70% In liquid, refluxing extraction 2 times, extracts 3 hours every time, filter, be mixed to get extracting solution;

2) extracting solution in step 1) is uniformly sprayed to mouth stick tipping paper surfaces externally and internally;

3) then that the mouth stick tipping paper in step 2) is dry at 25 DEG C;

4) the mouth stick tipping paper after drying is wrapped in outside the forming paper of mouth stick, the essence containing flavone compound is made Cigarette mouth stick.

Table 1

Flavones type Glycyrrhizin Eugenol Luteolin Aurantiin Weight percent 25% 25% 30% 20%

Embodiment 2

1) flavone compound essence is mixed according to ratio in table 1, it is molten is dissolved in the ethyl alcohol that mass percentage concentration is 70% In liquid, refluxing extraction 2 times, extracts 4 hours every time, filter, be mixed to get extracting solution;

2) extracting solution in step 1) is uniformly sprayed to mouth stick tipping paper surfaces externally and internally;

3) then that the mouth stick tipping paper in step 2) is dry at 35 DEG C;

4) the mouth stick tipping paper after drying is wrapped in outside the forming paper of mouth stick, the essence containing flavone compound is made Cigarette mouth stick.

Table 2

Flavones type Glycyrrhizin Eugenol Luteolin Aurantiin Weight percent 30% 30% 20% 20%

Embodiment 3

1) flavone compound essence is mixed according to ratio in table 1, it is molten is dissolved in the ethyl alcohol that mass percentage concentration is 70% In liquid, refluxing extraction 2 times, extracts 4 hours every time, filter, be mixed to get extracting solution;

2) extracting solution in step 1) is uniformly sprayed to mouth stick tipping paper surfaces externally and internally;

3) then that the mouth stick tipping paper in step 2) is dry at 35 DEG C;

4) the mouth stick tipping paper after drying is wrapped in outside the forming paper of mouth stick, the essence containing flavone compound is made Cigarette mouth stick.

Table 3

Flavones type Glycyrrhizin Eugenol Luteolin Aurantiin Weight percent 35% 35% 15% 15%

Embodiment 4

1) flavone compound essence is mixed according to ratio in table 1, it is molten is dissolved in the ethyl alcohol that mass percentage concentration is 70% In liquid, refluxing extraction 2 times, extracts 4 hours every time, filter, be mixed to get extracting solution;

2) extracting solution in step 1) is uniformly sprayed to mouth stick tipping paper surfaces externally and internally;

3) then that the mouth stick tipping paper in step 2) is dry at 35 DEG C;

4) the mouth stick tipping paper after drying is wrapped in outside the forming paper of mouth stick, the essence containing flavone compound is made Cigarette mouth stick.

Table 4

Flavones type Glycyrrhizin Eugenol Luteolin Aurantiin Weight percent 40% 40% 10% 10%

Embodiment 5

1) flavone compound essence is mixed according to ratio in table 1, it is molten is dissolved in the ethyl alcohol that mass percentage concentration is 70% In liquid, refluxing extraction 2 times, extracts 4 hours every time, filter, be mixed to get extracting solution;

2) extracting solution in step 1) is uniformly sprayed to mouth stick tipping paper surfaces externally and internally;

3) then that the mouth stick tipping paper in step 2) is dry at 35 DEG C;

4) the mouth stick tipping paper after drying is wrapped in outside the forming paper of mouth stick, the essence containing flavone compound is made Cigarette mouth stick.

Table 5

Flavones type Glycyrrhizin Eugenol Luteolin Aurantiin Weight percent 50% 20% 20% 10%

Embodiment 6

1) flavone compound essence is mixed according to ratio in table 1, it is molten is dissolved in the ethyl alcohol that mass percentage concentration is 70% In liquid, refluxing extraction 2 times, extracts 4 hours every time, filter, be mixed to get extracting solution;

2) extracting solution in step 1) is uniformly sprayed to mouth stick tipping paper surfaces externally and internally;

3) then that the mouth stick tipping paper in step 2) is dry at 35 DEG C;

4) the mouth stick tipping paper after drying is wrapped in outside the forming paper of mouth stick, the essence containing flavone compound is made Cigarette mouth stick.

Table 6

Flavones type Glycyrrhizin Eugenol Luteolin Aurantiin Weight percent 35% 30% 30% 10%

The cigarette mouth stick of the essence containing flavone compound prepared in above 6 embodiments is engaged with pipe tobacco and is made into cigarette Branch carries out detection of exhaust gas compositions to cigarette, and carries out phenol reduced rate and compare, and is specifically shown in the following table 7

Table 7

The smoke components mainly reduced have phenol, crotonaldehyde, free radical, while smoke hazard index is also in that decline becomes Gesture, specific reduced rate result see the table below 8

Sample number into spectrum Phenol Crotonaldehyde Index Free radical Embodiment 1 9.9% 9.6% 11.4% 8.8% Embodiment 2 20.6% 11.0% 11.4% 13.9% Embodiment 3 27.5% 13.0% 12.7% 15.2% Embodiment 4 32.8% 21.9% 13.9% 18.7% Embodiment 5 38.2% 27.4% 16.5% 20.5% Embodiment 6 41.2% 29.5% 17.7% 22.9%

The cigarette of the essence containing flavone compound prepared in embodiment in above 6 embodiments is engaged with mouth stick with pipe tobacco It is made into cigarette, carry out sensory evaluation is carried out to cigarette, as a result such as table 9

Table 9

The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any Belong to those skilled in the art in the technical scope disclosed by the present invention, any changes or substitutions that can be easily thought of, all answers It is included within the scope of the present invention.Therefore, protection scope of the present invention should be subject to the protection scope in claims.

Claims (3)

1. a kind of cigarette of essence containing flavone compound mouth stick preparation method, it is characterised in that: the preparation method includes such as Lower step:
1) weigh by weight percentage 20%~50% glycyrrhizin, 20%~50% eugenol, 10%~40% sweet-scented osmanthus Careless element, 5%~20% aurantiin, extracting solution is obtained by filtration as Extraction solvent refluxing extraction in ethanol solution after mixing, flows back It extracts 2~4 times, each refluxing extraction 2~4 hours;
2) extracting solution is uniformly sprayed to mouth stick tipping paper surfaces externally and internally;
3) then that the mouth stick tipping paper in step 2) is dry, drying temperature is 25 DEG C~40 DEG C;
4) the mouth stick tipping paper after drying is wrapped in outside the forming paper of mouth stick, the cigarette that the essence containing flavone compound is made is used Mouth stick.
2. the cigarette of the essence according to claim 1 containing flavone compound mouth stick preparation method, it is characterised in that: described The mass percentage concentration of ethanol solution is 70%~90%.
3. a kind of cigarette mouth stick of essence containing flavone compound, it is characterised in that: the cigarette of the essence containing flavone compound With the cigarette mouth stick for the essence containing flavone compound that mouth stick is the method preparation of any one of claim 1~2.
CN201510338815.5A 2015-06-17 2015-06-17 Cigarette mouth stick and preparation method thereof of the essence containing flavone compound CN105124759B (en)

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Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1072579A (en) * 1992-09-28 1993-06-02 李瀚旻 Disposable micro-multistage liquid containing filter tip for cigarette
CN1100612A (en) * 1993-09-21 1995-03-29 杨万申 Health-care cigarette filter
WO2005077176A1 (en) * 2004-02-11 2005-08-25 The Trustees Of Columbia University In The City Of New York Anthocyanin compounds and methods of use thereof
US20060018867A1 (en) * 2004-05-12 2006-01-26 Ichimaru Pharcos Co., Ltd Cosmetic composition and production thereof
CN1813601B (en) * 2006-02-16 2010-05-12 重庆烟草工业有限责任公司 Cigarette filter tip additive capable of reducing smoke harmful effect to respiratory system
CN100556322C (en) * 2007-09-28 2009-11-04 川渝中烟工业公司 A kind of method of utilizing Chinese herbal medicine to reduce content of phenolic compounds in the cigarette mainstream flue gas
CN101619266A (en) * 2008-07-03 2010-01-06 朱述兴 Method for preparing liquorice essence
CN102613705A (en) * 2012-03-20 2012-08-01 山鑫科陶科技(北京)股份有限公司 Cigarette filter tip with health care function
CN104623670A (en) * 2013-11-06 2015-05-20 高松 Compositions Containing Enriched Natural Crocin and/or Crocetin, and Their Therapeutic or Nutraceutical Uses

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