CN1061982C - 制造n－膦酰甲基甘氨酸的方法 - Google Patents

制造n－膦酰甲基甘氨酸的方法 Download PDF

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Publication number
CN1061982C
CN1061982C CN95196267A CN95196267A CN1061982C CN 1061982 C CN1061982 C CN 1061982C CN 95196267 A CN95196267 A CN 95196267A CN 95196267 A CN95196267 A CN 95196267A CN 1061982 C CN1061982 C CN 1061982C
Authority
CN
China
Prior art keywords
phosphonomethylglycine
alkali metal
phosphonic acids
formaldehyde
aminomethyl phosphonic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN95196267A
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English (en)
Chinese (zh)
Other versions
CN1163617A (zh
Inventor
J·H·艾瑟顿
I·霍奇金森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SINZETA Ltd
Original Assignee
Zeneca Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zeneca Ltd filed Critical Zeneca Ltd
Publication of CN1163617A publication Critical patent/CN1163617A/zh
Application granted granted Critical
Publication of CN1061982C publication Critical patent/CN1061982C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
CN95196267A 1994-11-16 1995-11-02 制造n－膦酰甲基甘氨酸的方法 Expired - Fee Related CN1061982C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9423254.3 1994-11-16
GB9423254A GB9423254D0 (en) 1994-11-16 1994-11-16 Process

Publications (2)

Publication Number Publication Date
CN1163617A CN1163617A (zh) 1997-10-29
CN1061982C true CN1061982C (zh) 2001-02-14

Family

ID=10764573

Family Applications (1)

Application Number Title Priority Date Filing Date
CN95196267A Expired - Fee Related CN1061982C (zh) 1994-11-16 1995-11-02 制造n－膦酰甲基甘氨酸的方法

Country Status (29)

Country Link
US (1) US5679843A (OSRAM)
EP (1) EP0792277B1 (OSRAM)
JP (1) JP3576169B2 (OSRAM)
KR (1) KR100362553B1 (OSRAM)
CN (1) CN1061982C (OSRAM)
AR (1) AR000087A1 (OSRAM)
AT (1) ATE181554T1 (OSRAM)
AU (1) AU697316B2 (OSRAM)
BG (1) BG101523A (OSRAM)
BR (1) BR9509691A (OSRAM)
CA (1) CA2203553C (OSRAM)
CZ (1) CZ149097A3 (OSRAM)
DE (1) DE69510466T2 (OSRAM)
DK (1) DK0792277T3 (OSRAM)
ES (1) ES2133819T3 (OSRAM)
FI (1) FI972065A7 (OSRAM)
GB (1) GB9423254D0 (OSRAM)
GR (1) GR3030456T3 (OSRAM)
HU (1) HU217301B (OSRAM)
IL (1) IL115793A (OSRAM)
MA (1) MA23714A1 (OSRAM)
MY (1) MY112939A (OSRAM)
NO (1) NO972240L (OSRAM)
NZ (1) NZ294891A (OSRAM)
PL (1) PL187068B1 (OSRAM)
SK (1) SK61297A3 (OSRAM)
TW (1) TW296385B (OSRAM)
WO (1) WO1996015135A1 (OSRAM)
ZA (1) ZA959527B (OSRAM)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9515265D0 (en) * 1995-07-25 1995-09-20 Zeneca Ltd Chemical process
DE19629870A1 (de) * 1996-07-24 1998-01-29 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-Phosphonomethylglycin
ATE233271T1 (de) * 1996-09-12 2003-03-15 Monsanto Technology Llc Verfahren zur herstellung von n- phosphonomethylglyzin und ihre salze
US5948937A (en) * 1996-09-12 1999-09-07 Monsanto Company Method for producing N-phosphonomethylglycine and its salts
IL130700A (en) * 1996-12-30 2002-11-10 Monsanto Co Cyanophosphorus compounds and their preparation
JP2001507665A (ja) * 1996-12-30 2001-06-12 モンサント・カンパニー 新規シアノホスホネート誘導体及びこれらの調製方法
US5859278A (en) * 1996-12-30 1999-01-12 Monsanto Company Method for preparing cyanophosphonate derivatives from pyrophosphate or polyphosphate esters and cyanide
WO1998029106A2 (en) * 1996-12-30 1998-07-09 Monsanto Company Method for preparing cyanophosphonate derivatives from phosphoric anhydride and cyanide
BR9714449A (pt) * 1996-12-30 2000-03-21 Monsanto Co Método para a preparaçào de derivaods de fosfonato de aminometila através da hidrogenação de derivados de cianofosfonato
CA2276186A1 (en) * 1996-12-30 1998-07-09 Monsanto Company Hydrogenation of mixtures of cyanophosphonates and glycine
CA2276356A1 (en) * 1996-12-30 1998-07-09 Monsanto Company Method for preparing cyanophosphonate derivatives from phosphate esters and cyanide
US6218563B1 (en) 1998-12-03 2001-04-17 Monsanto Company Cyanophosphonamides and method for preparation
JP4651258B2 (ja) * 1999-12-27 2011-03-16 旭化成ケミカルズ株式会社 グリシンの製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4221583A (en) * 1978-12-22 1980-09-09 Monsanto Company N-Phosphonomethylglycinonitrile and certain derivatives thereof
EP0537786A1 (en) * 1991-10-17 1993-04-21 Showa Denko Kabushiki Kaisha Preparation of N-acylaminomethylphosphonic acid
WO1994022881A1 (en) * 1993-04-07 1994-10-13 Zeneca Limited Process for preparing n-phosphonomethylglycinonitrile or derivatives thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL156933B1 (pl) * 1988-02-16 1992-04-30 Politechnika Wroclawska Sposób wytwarzania N-(1-fosfonoalkilo) glicyn, zwlaszcza N-(fosfonometylo) glicyny PL
CA2053362A1 (en) * 1990-10-15 1992-04-16 Druce K. Crump Preparation of aminonitriles

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4221583A (en) * 1978-12-22 1980-09-09 Monsanto Company N-Phosphonomethylglycinonitrile and certain derivatives thereof
EP0537786A1 (en) * 1991-10-17 1993-04-21 Showa Denko Kabushiki Kaisha Preparation of N-acylaminomethylphosphonic acid
WO1994022881A1 (en) * 1993-04-07 1994-10-13 Zeneca Limited Process for preparing n-phosphonomethylglycinonitrile or derivatives thereof

Also Published As

Publication number Publication date
BR9509691A (pt) 1997-10-14
AR000087A1 (es) 1997-05-21
FI972065L (fi) 1997-05-14
NO972240D0 (no) 1997-05-15
PL321158A1 (en) 1997-11-24
CZ149097A3 (en) 1997-08-13
NO972240L (no) 1997-05-15
EP0792277A1 (en) 1997-09-03
IL115793A (en) 1999-10-28
ES2133819T3 (es) 1999-09-16
CN1163617A (zh) 1997-10-29
PL187068B1 (pl) 2004-05-31
KR970707136A (ko) 1997-12-01
US5679843A (en) 1997-10-21
BG101523A (en) 1998-01-30
CA2203553C (en) 2005-01-18
MA23714A1 (fr) 1996-07-01
ZA959527B (en) 1996-06-18
HU217301B (hu) 1999-12-28
EP0792277B1 (en) 1999-06-23
DE69510466D1 (de) 1999-07-29
JPH10509705A (ja) 1998-09-22
GB9423254D0 (en) 1995-01-04
AU697316B2 (en) 1998-10-01
IL115793A0 (en) 1996-05-14
AU3810495A (en) 1996-06-06
WO1996015135A1 (en) 1996-05-23
FI972065A0 (fi) 1997-05-14
SK61297A3 (en) 1997-11-05
JP3576169B2 (ja) 2004-10-13
FI972065A7 (fi) 1997-05-14
NZ294891A (en) 1998-12-23
HUT77022A (hu) 1998-03-02
MY112939A (en) 2001-10-31
DE69510466T2 (de) 1999-11-18
GR3030456T3 (en) 1999-09-30
CA2203553A1 (en) 1996-05-23
KR100362553B1 (ko) 2003-01-24
TW296385B (OSRAM) 1997-01-21
ATE181554T1 (de) 1999-07-15
DK0792277T3 (da) 1999-12-13

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Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: SIGENTIS CO., LTD.

Free format text: FORMER NAME OR ADDRESS: ZENECA LTD

CP03 Change of name, title or address

Address after: surrey

Patentee after: Sinzeta Ltd.

Address before: London, England, England

Patentee before: Zeneca Limited

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20010214

Termination date: 20111102