CN105934449B - 用于烯烃聚合的催化剂组合物 - Google Patents

用于烯烃聚合的催化剂组合物 Download PDF

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Publication number
CN105934449B
CN105934449B CN201480074317.8A CN201480074317A CN105934449B CN 105934449 B CN105934449 B CN 105934449B CN 201480074317 A CN201480074317 A CN 201480074317A CN 105934449 B CN105934449 B CN 105934449B
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alkyl
dimethoxy propanes
dimethoxy
methyl
propane
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Chinese (zh)
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CN105934449A (zh
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M·A·祖德维尔德
A·A·巴缇纳斯-格尔茨
G·D·布卡托弗
S·A·瑟基弗
V·A·扎卡罗夫
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SABIC Global Technologies BV
Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C08F4/6555—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof and magnesium or compounds thereof
    • C08F4/6557—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof and magnesium or compounds thereof and metals of C08F4/64 or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201480074317.8A 2013-12-20 2014-12-19 用于烯烃聚合的催化剂组合物 Active CN105934449B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13199173.9 2013-12-20
EP13199173 2013-12-20
EP14170833.9 2014-06-02
EP14170833 2014-06-02
PCT/EP2014/078797 WO2015091983A1 (en) 2013-12-20 2014-12-19 Catalyst system for polymerization of an olefin

Publications (2)

Publication Number Publication Date
CN105934449A CN105934449A (zh) 2016-09-07
CN105934449B true CN105934449B (zh) 2018-07-10

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US (1) US9944731B2 (https=)
EP (1) EP3083719B1 (https=)
KR (1) KR102263502B1 (https=)
CN (1) CN105934449B (https=)
BR (1) BR112016013951B1 (https=)
EA (1) EA034562B1 (https=)
MX (1) MX2016008035A (https=)
WO (1) WO2015091983A1 (https=)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2016008041A (es) 2013-12-20 2017-03-03 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
CN105940023B (zh) 2013-12-20 2019-01-18 沙特基础工业公司 用于烯烃聚合的催化剂体系
EP3083722B1 (en) 2013-12-20 2021-11-10 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
MX2016008039A (es) 2013-12-20 2017-05-12 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
EP3181625A1 (en) 2015-12-18 2017-06-21 SABIC Global Technologies B.V. Composition comprising heterophasic propylene copolymer
EA038463B1 (ru) 2016-09-29 2021-08-31 Сабик Глоубл Текнолоджиз Б.В. Прокатализатор для полимеризации олефинов
US11117989B2 (en) 2016-09-29 2021-09-14 Sabic Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
CN109843945B (zh) 2016-09-29 2022-03-25 Sabic环球技术有限责任公司 用于烯烃聚合的主催化剂
CN109790251B (zh) * 2016-09-29 2021-11-23 Sabic环球技术有限责任公司 用于制备用于烯烃聚合的主催化剂的方法
WO2018059750A1 (en) 2016-09-29 2018-04-05 Sabic Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
WO2018059955A1 (en) 2016-09-29 2018-04-05 Sabic Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
WO2018069379A1 (en) 2016-10-12 2018-04-19 Sabic Global Technologies B.V. Process to prepare a solid support for a procatalyst suitable for polymerization of olefins
CN118515799A (zh) 2016-10-12 2024-08-20 Sabic环球技术有限责任公司 制备适用于烯烃聚合的主催化剂的固体载体的方法
CN110248968B (zh) * 2016-12-12 2022-05-27 Sabic环球技术有限责任公司 制造低排放均聚物或无规聚丙烯的方法
WO2018108927A1 (en) 2016-12-12 2018-06-21 Sabic Global Technologies B.V. Heterophasic propylene copolymer
CN110234663B (zh) 2017-03-17 2022-03-08 Sabic环球技术有限责任公司 制造聚烯烃的方法
WO2018167301A1 (en) 2017-03-17 2018-09-20 Sabic Global Technologies B.V. Process for the polymerization of a polyolefin
CN110382563B (zh) 2017-03-17 2022-08-26 Sabic环球技术有限责任公司 用于制备用于烯烃聚合的主催化剂的方法
CN111095355B (zh) 2017-07-05 2023-10-20 快砖知识产权私人有限公司 实时定位和定向跟踪器
WO2020104306A1 (en) 2018-11-19 2020-05-28 Sabic Global Technologies B.V. Food packaging comprising a polymer composition and use of said polymer composition for manufacturing food packaging
EP4021975B1 (en) 2019-08-27 2024-04-10 SABIC Global Technologies, B.V. Heterophasic propylene copolymer composition
WO2021043784A1 (en) 2019-09-06 2021-03-11 Sabic Global Technologies B.V. Healthcare article comprising a random propylene-ethylene copolymer.
WO2021064078A1 (en) * 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
EP4038110B1 (en) * 2019-10-04 2026-01-21 Borealis GmbH Ziegler-natta catalysts for olefin polymerization
CN114728276B (zh) * 2019-11-22 2025-09-23 Sabic环球技术有限责任公司 制备烯烃聚合所用主催化剂的方法
WO2021105373A1 (en) 2019-11-29 2021-06-03 Thai Polyethylene Co., Ltd. Catalyst composition for the polymerization of olefins
EP3650494A3 (en) 2020-02-14 2020-05-27 SABIC Global Technologies B.V. Matte film comprising heterophasic propylene copolymer composition
CN114929800B (zh) 2020-02-14 2024-09-03 Sabic环球技术有限责任公司 包含多相丙烯共聚物组合物的膜
EP3650495A3 (en) 2020-02-14 2020-05-27 SABIC Global Technologies B.V. Film comprising heterophasic propylene copolymer composition
CN115397911A (zh) 2020-03-27 2022-11-25 Sabic环球技术有限责任公司 低温下冲击强度改进的聚合物组合物
CN118369358A (zh) 2021-12-09 2024-07-19 Sabic环球技术有限责任公司 用于烯烃聚合的催化剂体系
CN118451137A (zh) 2021-12-21 2024-08-06 Sabic环球技术有限责任公司 高抗冲聚丙烯组合物
CN118871526A (zh) 2022-03-14 2024-10-29 Sabic环球技术有限责任公司 注塑成型方法
WO2023174732A1 (en) 2022-03-14 2023-09-21 Sabic Global Technologies B.V. Heterophasic propylene copolymer composition
WO2023217945A1 (en) 2022-05-13 2023-11-16 Sabic Global Technologies B.V. Heterophasic polypropylene composition with low emission
CN119183458A (zh) 2022-05-13 2024-12-24 Sabic环球技术有限责任公司 具有低的己烷提取物的多相聚丙烯组合物
EP4522666A1 (en) 2022-05-13 2025-03-19 SABIC Global Technologies B.V. Heterophasic polypropylene composition with low shrinkage
WO2024008770A1 (en) 2022-07-05 2024-01-11 Sabic Global Technologies B.V. Catalyst system for polymerization of an olefin

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1128724A (en) * 1966-05-30 1968-10-02 Mitsubishi Petrochemical Co Process for producing crystalline homopolymers or copolymers of olefin
US4211670A (en) * 1979-01-25 1980-07-08 Hercules Incorporated Titanium trichloride catalyst component for propylene polymerization
CN1109892A (zh) * 1995-02-20 1995-10-11 三井石油化学工业株式会社 乙烯聚合物、乙烯聚合物的制备方法、用于乙烯聚合的固态钛催化剂组分和乙烯聚合催化剂
CN1182748A (zh) * 1996-11-20 1998-05-27 三井化学株式会社 烯烃聚合催化剂、预聚合的催化剂和烯烃聚合方法
CN101104656A (zh) * 2006-07-13 2008-01-16 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
CN101965369A (zh) * 2007-12-31 2011-02-02 巴斯夫公司 对较大聚烯烃催化剂的摩尔比改变
CN102666598A (zh) * 2009-12-31 2012-09-12 晓星株式会社 烯烃聚合用齐格勒-纳塔催化剂
WO2012139897A1 (en) * 2011-04-12 2012-10-18 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
CN102918068A (zh) * 2010-02-26 2013-02-06 陶氏环球技术有限责任公司 酰胺酯内给电子体和方法

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5077357A (en) 1990-10-22 1991-12-31 Shell Oil Company Olefin polymerization catalyst
US5106806A (en) 1990-10-18 1992-04-21 Shell Oil Company Olefin polymerization catalyst
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
CA1141093A (en) 1979-05-17 1983-02-08 Brian L. Goodall Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
US4384087A (en) 1980-03-24 1983-05-17 Phillips Petroleum Company Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst
IT1190681B (it) 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
US4866022A (en) 1984-03-23 1989-09-12 Amoco Corporation Olefin polymerization catalyst
US5567665A (en) 1994-03-31 1996-10-22 Union Carbide Chemicals & Plastics Technology Corporation Shape-shifted magnesium alkoxide component for polymerizing olefins
US4771024A (en) 1986-02-28 1988-09-13 Shell Oil Company Olefin polymerization catalyst composition
US5093415A (en) 1987-05-19 1992-03-03 Union Carbide Chemicals & Plastics Technology Corporation Process for producing stereoregular polymers having a narrow molecular weight distribution
IT1227259B (it) 1988-09-30 1991-03-28 Himont Inc Catalizzatori per la polimerizzazione di olefine.
JP2838310B2 (ja) 1989-05-17 1998-12-16 三菱化学株式会社 オレフィン重合体の製造方法
US5556820A (en) 1989-12-28 1996-09-17 Idemitsu Petrochemical Co., Ltd. Catalyst component for olefin polymerization and process for producing polyolefins
WO1996032426A1 (en) 1995-04-10 1996-10-17 Dsm N.V. Method for the preparation of a catalyst suitable for the polymerisation of an olefine
US5820981A (en) 1996-04-02 1998-10-13 Montell North America Inc. Radiation visbroken polypropylene and fibers made therefrom
CA2204464A1 (en) 1996-11-06 1998-11-05 Ube Industries Limited Process for polymerization of .alpha.-olefin
WO1999057160A1 (en) 1998-05-06 1999-11-11 Montell Technology Company B.V. Catalyst components for the polymerization of olefins
EP1086961A1 (en) 1999-09-27 2001-03-28 Dsm N.V. Process for the preparation of a catalyst component for the polymerisation of an olefin
ES2224049T3 (es) 2001-03-05 2005-03-01 Stichting Dutch Polymer Institute Componente catalizador de la polimerizacion de olefinas, sistema catalizador y procedimiento de polimerizacion que usa dicho sitema catalizador.
ES2387885T5 (es) 2001-03-30 2019-11-28 Toho Titanium Co Ltd Procedimiento para producir un componente catalizador sólido para la polimerización de olefinas
US6825146B2 (en) 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation
PT1273595E (pt) 2001-06-20 2006-10-31 Borealis Tech Oy Preparacao de um componente catalisador para polimerizacao de olefina
ATE370184T1 (de) 2001-06-27 2007-09-15 Borealis Tech Oy Verfahren zur herstellung einer polymerfolie die ein statistisches propylencopolymer enthält
CN1169845C (zh) 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
AU2003257555A1 (en) 2002-08-19 2004-03-03 Ube Industries, Ltd. CATALYSTS FOR POLYMERIZATION OR COPOLYMERIZATION OF Alpha-OLEFINS, CATALYST COMPONENTS THEREOF, AND PROCESSES FOR POLYMERIZATION OF Alpha-OLEFINS WITH THE CATALYSTS
JP4137736B2 (ja) 2003-07-28 2008-08-20 宇部興産株式会社 オレフィン類重合用触媒
EP1783145A1 (en) 2004-07-28 2007-05-09 Mitsui Chemicals, Inc. Olefin polymerization catalyst and method of polymerization using the catalyst
EP1781737B1 (en) 2004-07-30 2008-12-03 Saudi Basic Industries Corporation Propylene copolymer compositions with high transparency
EP1661917A1 (en) 2004-11-26 2006-05-31 Saudi Basic Industries Corporation (Sabic) Process for the preparation of a catalyst component for the polymerization of an olefin
EP1717269A1 (en) 2005-04-28 2006-11-02 Borealis Technology Oy Alpha-olefin homo-or copolymer compositions
BRPI0711891B1 (pt) 2006-05-24 2018-05-02 Saudi Basic Industries Corporation Processo para a preparação de um componente catalisador para a polimerização de propileno
EP2845868A1 (en) 2006-05-31 2015-03-11 Borealis Technology Oy Oxidation state of Ti as means for increasing catalyst activity
WO2008007770A1 (fr) 2006-07-14 2008-01-17 Dai Nippon Printing Co., Ltd. Film revêtu d'une couche conductrice transparente et son utilisation
JP2008106089A (ja) 2006-10-23 2008-05-08 Japan Polypropylene Corp ポリプロピレン系射出成形半導体関連部品搬送ケース
CN102186889B (zh) 2008-08-21 2013-11-06 陶氏环球技术有限责任公司 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法
US8088872B2 (en) 2008-11-25 2012-01-03 Dow Global Technologies Llc Procatalyst composition including silyl ester internal donor and method
CN102333749B (zh) 2008-12-31 2015-04-22 陶氏环球技术有限责任公司 取代的亚苯基芳族二酯的生产方法
RU2632200C2 (ru) 2010-02-26 2017-10-03 У.Р.Грейс Энд Ко.-Конн. Галогенированный сложный амидоэфир и его применение в качестве внутреннего донора электронов
EP2545087B1 (en) 2010-02-26 2016-06-22 W.R. Grace & Co.-Conn. Procatalyst composition with substituted amide ester internal electron donor
EP2621961B1 (en) 2010-09-28 2016-12-07 Basell Polyolefine GmbH Method for feeding an antistatic compound to a polymerization reactor
EP2736971A1 (en) 2011-07-29 2014-06-04 Dow Global Technologies LLC Semi-crystalline polyolefin composition, method of producing the same, and articles made therefrom
MX2014010130A (es) 2012-02-22 2014-09-08 Saudi Basic Ind Corp Componente catalizador para la polimerizacion de olefinas.
EP2867264B1 (en) 2012-06-29 2016-04-20 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins
US9587051B2 (en) 2013-01-31 2017-03-07 Saudi Basic Industries Corporation Process for preparing a catalyst component for polymerization of olefins
WO2015091984A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Procatalyst for polymerization of olefins
MX2016008039A (es) 2013-12-20 2017-05-12 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
US10059656B2 (en) 2013-12-20 2018-08-28 Sabic Global Technologies B.V. Catalyst composition for polymerization of olefins
EP3083722B1 (en) 2013-12-20 2021-11-10 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
MX2016008041A (es) 2013-12-20 2017-03-03 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
CN105940023B (zh) 2013-12-20 2019-01-18 沙特基础工业公司 用于烯烃聚合的催化剂体系

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1128724A (en) * 1966-05-30 1968-10-02 Mitsubishi Petrochemical Co Process for producing crystalline homopolymers or copolymers of olefin
US4211670A (en) * 1979-01-25 1980-07-08 Hercules Incorporated Titanium trichloride catalyst component for propylene polymerization
CN1109892A (zh) * 1995-02-20 1995-10-11 三井石油化学工业株式会社 乙烯聚合物、乙烯聚合物的制备方法、用于乙烯聚合的固态钛催化剂组分和乙烯聚合催化剂
CN1182748A (zh) * 1996-11-20 1998-05-27 三井化学株式会社 烯烃聚合催化剂、预聚合的催化剂和烯烃聚合方法
CN101104656A (zh) * 2006-07-13 2008-01-16 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
CN101965369A (zh) * 2007-12-31 2011-02-02 巴斯夫公司 对较大聚烯烃催化剂的摩尔比改变
CN102666598A (zh) * 2009-12-31 2012-09-12 晓星株式会社 烯烃聚合用齐格勒-纳塔催化剂
CN102918068A (zh) * 2010-02-26 2013-02-06 陶氏环球技术有限责任公司 酰胺酯内给电子体和方法
WO2012139897A1 (en) * 2011-04-12 2012-10-18 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins

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CN105934449A (zh) 2016-09-07
MX2016008035A (es) 2017-03-03
EP3083719B1 (en) 2018-12-19
US9944731B2 (en) 2018-04-17
US20160311947A1 (en) 2016-10-27
BR112016013951B1 (pt) 2022-02-22
KR102263502B1 (ko) 2021-06-11
BR112016013951A2 (https=) 2017-08-08
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WO2015091983A1 (en) 2015-06-25
EA201691284A1 (ru) 2016-12-30
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