CN105829366B - 二乙烯基苯/马来酸酐聚合物材料 - Google Patents
二乙烯基苯/马来酸酐聚合物材料 Download PDFInfo
- Publication number
- CN105829366B CN105829366B CN201480069510.2A CN201480069510A CN105829366B CN 105829366 B CN105829366 B CN 105829366B CN 201480069510 A CN201480069510 A CN 201480069510A CN 105829366 B CN105829366 B CN 105829366B
- Authority
- CN
- China
- Prior art keywords
- weight
- monomer
- polymer material
- monomer mixture
- divinylbenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
- B01J20/267—Cross-linked polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
- B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
- B01J20/28064—Surface area, e.g. B.E.T specific surface area being in the range 500-1000 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
- C08F212/36—Divinylbenzene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/044—Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361918079P | 2013-12-19 | 2013-12-19 | |
| US61/918,079 | 2013-12-19 | ||
| PCT/US2014/070478 WO2015095115A1 (en) | 2013-12-19 | 2014-12-16 | Divinylbenzene/maleic anhydride polymeric material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105829366A CN105829366A (zh) | 2016-08-03 |
| CN105829366B true CN105829366B (zh) | 2018-06-05 |
Family
ID=52273596
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480069510.2A Active CN105829366B (zh) | 2013-12-19 | 2014-12-16 | 二乙烯基苯/马来酸酐聚合物材料 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20160311996A1 (enExample) |
| EP (1) | EP3083725B1 (enExample) |
| JP (1) | JP6453342B2 (enExample) |
| KR (1) | KR102307437B1 (enExample) |
| CN (1) | CN105829366B (enExample) |
| WO (1) | WO2015095115A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10400050B2 (en) * | 2015-05-20 | 2019-09-03 | 3M Innovative Properties Company | Metal-containing polymeric materials |
| CN107708856B (zh) * | 2015-06-19 | 2020-07-03 | 3M创新有限公司 | 用于二氧化碳的水解二乙烯基苯/马来酸酐聚合物吸附剂 |
| WO2016205444A1 (en) * | 2015-06-19 | 2016-12-22 | 3M Innovative Properties Company | Divinylbenzene/maleic anhydride polymeric sorbents for carbon dioxide |
| KR20180095857A (ko) * | 2015-12-18 | 2018-08-28 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 알데하이드용 폴리머 수착제 |
| KR20180095856A (ko) * | 2015-12-18 | 2018-08-28 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 반응성 기체용 폴리머 수착제 |
| US11179698B2 (en) | 2015-12-18 | 2021-11-23 | 3M Innovative Properties Company | Polymeric sorbents for carbon dioxide |
| CN108778455B (zh) * | 2016-03-14 | 2021-12-14 | 3M创新有限公司 | 包含用于反应性气体的聚合吸附剂的空气过滤器 |
| KR102444323B1 (ko) * | 2016-03-14 | 2022-09-16 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 알데하이드용 중합체 수착제를 포함하는 복합 과립제 |
| US10960341B2 (en) | 2016-03-14 | 2021-03-30 | 3M Innovative Properties Company | Air filters comprising polymeric sorbents for aldehydes |
| JP6956103B2 (ja) * | 2016-03-14 | 2021-10-27 | スリーエム イノベイティブ プロパティズ カンパニー | アルデヒド用のポリマー収着剤を含むエアフィルタ |
| CN109952148B (zh) * | 2016-11-14 | 2023-01-20 | 3M创新有限公司 | 包括含金属的聚合物材料的复合颗粒 |
| KR20190077528A (ko) * | 2016-11-14 | 2019-07-03 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 금속-함유 중합체 수착제를 포함하는 공기 필터 |
| KR102640289B1 (ko) | 2017-01-20 | 2024-02-23 | 엘지전자 주식회사 | 유기 고분자 흡착제, 유기 고분자 흡착제 조성물 및 유기 고분자 흡착제 제조 방법 |
| WO2018229604A2 (en) * | 2017-06-16 | 2018-12-20 | 3M Innovative Properties Company | Air filters comprising polymeric sorbents for aldehydes |
| KR20200019878A (ko) * | 2017-06-16 | 2020-02-25 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 알데하이드용 중합체 수착제 |
| CN117504833B (zh) * | 2023-09-25 | 2025-03-28 | 浙江警察学院 | 一种混合模式弱阳离子交换磁性固相萃取吸附剂及其制备方法和应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1595895A1 (en) * | 2004-05-14 | 2005-11-16 | Nitto Denko Corporation | Production method of porous resin |
| CN101558087A (zh) * | 2006-11-02 | 2009-10-14 | 矢崎总业株式会社 | 聚苯乙烯-马来酸酐/氢氧化镁复合颗粒及其制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH022861A (ja) * | 1987-11-04 | 1990-01-08 | Mitsubishi Rayon Co Ltd | 多孔質膜及びその製造方法 |
| JPH02194039A (ja) * | 1989-01-24 | 1990-07-31 | Asahi Chem Ind Co Ltd | アニオン選択吸着性多孔膜とその製造方法 |
| JPH03292884A (ja) * | 1990-04-12 | 1991-12-24 | Mitsubishi Rayon Co Ltd | 細胞培養方法 |
| FR2837493B1 (fr) * | 2002-03-20 | 2004-05-21 | Commissariat Energie Atomique | Aerogel a base d'un polymere ou copolymere hydrocarbone et leur procede de preparation |
| JP4227512B2 (ja) * | 2003-02-14 | 2009-02-18 | 大日精化工業株式会社 | 熱脱着可能な多価カチオン性イオン吸着材の製造方法 |
| JP2008138161A (ja) * | 2006-11-02 | 2008-06-19 | Yazaki Corp | ポリスチレン−無水マレイン酸/水酸化マグネシウム複合粒子、及び、その製造方法 |
| EP2121779A4 (en) * | 2007-03-08 | 2012-11-14 | Agency Science Tech & Res | MESOPOROUS POLYMER COLLOIDS |
| JP2009113034A (ja) * | 2007-10-16 | 2009-05-28 | Kochi Prefecture | イオン収着材、その製造方法およびその使用方法 |
| CN102883805A (zh) * | 2010-04-28 | 2013-01-16 | 株式会社日立高新技术 | 吸附材料及其制造方法 |
-
2014
- 2014-12-16 US US15/102,810 patent/US20160311996A1/en not_active Abandoned
- 2014-12-16 EP EP14821451.3A patent/EP3083725B1/en active Active
- 2014-12-16 JP JP2016541034A patent/JP6453342B2/ja not_active Expired - Fee Related
- 2014-12-16 KR KR1020167019125A patent/KR102307437B1/ko not_active Expired - Fee Related
- 2014-12-16 CN CN201480069510.2A patent/CN105829366B/zh active Active
- 2014-12-16 WO PCT/US2014/070478 patent/WO2015095115A1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1595895A1 (en) * | 2004-05-14 | 2005-11-16 | Nitto Denko Corporation | Production method of porous resin |
| CN101558087A (zh) * | 2006-11-02 | 2009-10-14 | 矢崎总业株式会社 | 聚苯乙烯-马来酸酐/氢氧化镁复合颗粒及其制备方法 |
Non-Patent Citations (3)
| Title |
|---|
| Poly(divinylbenzene-alt-maleic anhydride) Microgels: Intermediates to Microspheres and Macrogels in Cross-Linking Copolymerization;Randy S. Frank等;《Macromolecules》;20020223;第35卷(第7期);第2728-2735页 * |
| Porous maleic anhydride-divinylbenzene copolymer beads as a subtractor for primary and secondary amines in reaction gas chromatography;Kumiko Harada等;《Bunseki Kagaku》;20100216;第111卷;参见第697页表1和第701页第3段 * |
| Synthesis of Divinylbenzene–Maleic Anhydride Microspheres Using Precipitation Polymerization;RANDY S. FRANK等;《Journal of Polymer Science: Part A: Polymer Chemistry》;19980930;第36卷;第2223-2227页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20160101976A (ko) | 2016-08-26 |
| JP2017500408A (ja) | 2017-01-05 |
| JP6453342B2 (ja) | 2019-01-16 |
| KR102307437B1 (ko) | 2021-09-30 |
| US20160311996A1 (en) | 2016-10-27 |
| EP3083725A1 (en) | 2016-10-26 |
| EP3083725B1 (en) | 2017-10-11 |
| CN105829366A (zh) | 2016-08-03 |
| WO2015095115A1 (en) | 2015-06-25 |
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