KR102307437B1 - 다이비닐벤젠/말레산 무수물 중합체 재료 - Google Patents

다이비닐벤젠/말레산 무수물 중합체 재료 Download PDF

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KR102307437B1
KR102307437B1 KR1020167019125A KR20167019125A KR102307437B1 KR 102307437 B1 KR102307437 B1 KR 102307437B1 KR 1020167019125 A KR1020167019125 A KR 1020167019125A KR 20167019125 A KR20167019125 A KR 20167019125A KR 102307437 B1 KR102307437 B1 KR 102307437B1
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polymeric material
monomer mixture
divinylbenzene
styrene
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KR20160101976A (ko
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마이클 에스 웬드랜드
마이클 더블유 고베
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쓰리엠 이노베이티브 프로퍼티즈 캄파니
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26Synthetic macromolecular compounds
    • B01J20/265Synthetic macromolecular compounds modified or post-treated polymers
    • B01J20/267Cross-linked polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • C08J9/286Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • B01J20/28061Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • B01J20/28064Surface area, e.g. B.E.T specific surface area being in the range 500-1000 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078Pore diameter
    • B01J20/2808Pore diameter being less than 2 nm, i.e. micropores or nanopores
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078Pore diameter
    • B01J20/28083Pore diameter being in the range 2-50 nm, i.e. mesopores
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36Divinylbenzene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/04Anhydrides, e.g. cyclic anhydrides
    • C08F222/06Maleic anhydride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00Foams characterised by their properties
    • C08J2205/04Foams characterised by their properties characterised by the foam pores
    • C08J2205/044Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Polymerisation Methods In General (AREA)
KR1020167019125A 2013-12-19 2014-12-16 다이비닐벤젠/말레산 무수물 중합체 재료 Expired - Fee Related KR102307437B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361918079P 2013-12-19 2013-12-19
US61/918,079 2013-12-19
PCT/US2014/070478 WO2015095115A1 (en) 2013-12-19 2014-12-16 Divinylbenzene/maleic anhydride polymeric material

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Publication Number Publication Date
KR20160101976A KR20160101976A (ko) 2016-08-26
KR102307437B1 true KR102307437B1 (ko) 2021-09-30

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US (1) US20160311996A1 (enExample)
EP (1) EP3083725B1 (enExample)
JP (1) JP6453342B2 (enExample)
KR (1) KR102307437B1 (enExample)
CN (1) CN105829366B (enExample)
WO (1) WO2015095115A1 (enExample)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10400050B2 (en) * 2015-05-20 2019-09-03 3M Innovative Properties Company Metal-containing polymeric materials
CN107708856B (zh) * 2015-06-19 2020-07-03 3M创新有限公司 用于二氧化碳的水解二乙烯基苯/马来酸酐聚合物吸附剂
WO2016205444A1 (en) * 2015-06-19 2016-12-22 3M Innovative Properties Company Divinylbenzene/maleic anhydride polymeric sorbents for carbon dioxide
KR20180095857A (ko) * 2015-12-18 2018-08-28 쓰리엠 이노베이티브 프로퍼티즈 캄파니 알데하이드용 폴리머 수착제
KR20180095856A (ko) * 2015-12-18 2018-08-28 쓰리엠 이노베이티브 프로퍼티즈 캄파니 반응성 기체용 폴리머 수착제
US11179698B2 (en) 2015-12-18 2021-11-23 3M Innovative Properties Company Polymeric sorbents for carbon dioxide
CN108778455B (zh) * 2016-03-14 2021-12-14 3M创新有限公司 包含用于反应性气体的聚合吸附剂的空气过滤器
KR102444323B1 (ko) * 2016-03-14 2022-09-16 쓰리엠 이노베이티브 프로퍼티즈 캄파니 알데하이드용 중합체 수착제를 포함하는 복합 과립제
US10960341B2 (en) 2016-03-14 2021-03-30 3M Innovative Properties Company Air filters comprising polymeric sorbents for aldehydes
JP6956103B2 (ja) * 2016-03-14 2021-10-27 スリーエム イノベイティブ プロパティズ カンパニー アルデヒド用のポリマー収着剤を含むエアフィルタ
CN109952148B (zh) * 2016-11-14 2023-01-20 3M创新有限公司 包括含金属的聚合物材料的复合颗粒
KR20190077528A (ko) * 2016-11-14 2019-07-03 쓰리엠 이노베이티브 프로퍼티즈 캄파니 금속-함유 중합체 수착제를 포함하는 공기 필터
KR102640289B1 (ko) 2017-01-20 2024-02-23 엘지전자 주식회사 유기 고분자 흡착제, 유기 고분자 흡착제 조성물 및 유기 고분자 흡착제 제조 방법
WO2018229604A2 (en) * 2017-06-16 2018-12-20 3M Innovative Properties Company Air filters comprising polymeric sorbents for aldehydes
KR20200019878A (ko) * 2017-06-16 2020-02-25 쓰리엠 이노베이티브 프로퍼티즈 캄파니 알데하이드용 중합체 수착제
CN117504833B (zh) * 2023-09-25 2025-03-28 浙江警察学院 一种混合模式弱阳离子交换磁性固相萃取吸附剂及其制备方法和应用

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JP2005520881A (ja) * 2002-03-20 2005-07-14 コミツサリア タ レネルジー アトミーク 炭化水素系ポリマー又はコポリマーに基づくエーロゲル、およびその調製方法
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JP2004261793A (ja) * 2003-02-14 2004-09-24 Dainichiseika Color & Chem Mfg Co Ltd 熱脱着可能な多価カチオン性イオン吸着材、その製造方法および多価カチオン性イオンの回収方法
US20100210744A1 (en) * 2007-03-08 2010-08-19 Singapore Agency For Science, Technology And Resea Mesoporous Polymer Colloids

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Publication number Publication date
KR20160101976A (ko) 2016-08-26
JP2017500408A (ja) 2017-01-05
JP6453342B2 (ja) 2019-01-16
US20160311996A1 (en) 2016-10-27
EP3083725A1 (en) 2016-10-26
CN105829366B (zh) 2018-06-05
EP3083725B1 (en) 2017-10-11
CN105829366A (zh) 2016-08-03
WO2015095115A1 (en) 2015-06-25

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