CN105780500A - 一种表面接枝聚苯乙烯微球羽绒的处理方法 - Google Patents

一种表面接枝聚苯乙烯微球羽绒的处理方法 Download PDF

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CN105780500A
CN105780500A CN201610249739.5A CN201610249739A CN105780500A CN 105780500 A CN105780500 A CN 105780500A CN 201610249739 A CN201610249739 A CN 201610249739A CN 105780500 A CN105780500 A CN 105780500A
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eider down
down feather
polystyrene microsphere
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周务农
周茂林
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ANHUI WANLING DOWN AND FEATHER PRODUCTS Co Ltd
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Abstract

本发明公开了一种表面接枝聚苯乙烯微球羽绒的处理方法，这种方法将羽绒进行三步法处理，先利用前处理液对羽绒进行微蚀处理，增加蛋白纤维的反应接触点，在交联改性处理过程中将戊二醛、羧基化聚苯乙烯微球交联接枝到蛋白纤维上，使得纤维表面分布微球，使得羽绒间能长时间保持蓬松，尤其是在多次水洗后仍能快速恢复蓬松的手感，保持保暖效果，再经过后处理液处理后更便于整理包装。本发明工艺与现有技术相比生产工艺简单，纤维的改性效果稳定持久，赋予羽绒更佳的使用效果，增加经济价值。

Description

一种表面接枝聚苯乙烯微球羽绒的处理方法
技术领域
本发明涉及羽绒纤维处理技术领域，尤其涉及一种表面接枝聚苯乙烯微球羽绒的处理方法。
背景技术
羽绒纤维是一种天然动物蛋白质纤维，其轻质膨松，透气透湿，保暖效果极佳，常被用于羽绒服饰及制品。在生产过程中，羽绒原料需要经过一系列的处理后才能作为填充料使用，羽绒毛料要经过清洗、除脂、除臭、消毒、烘干等程序，如果前处理过程处置不当，将会直接影响羽绒的使用效果。
由于羽绒属于动物质类产品，其本身具有易燃、易虫蛀、易滋生微生物、产品附加值低、养护及洗涤要求高等缺点，如果能对羽绒应用一些处理手段，扬长避短，将会极大的拓宽羽绒制品的使用范围。目前报道的对羽绒进行阻燃、抗菌等处理方法，大多直接将羽绒与处理剂混合进行简单的表面处理，这样处理后产品的效果维持时间短，随着洗涤过程性能会逐渐失效。《羽绒纤维经戊二醛接枝二氰二胺处理后的阻燃性能》一文对羽绒纤维进行阻燃接枝改性处理，虽然在一定程度上提高了羽绒的阻燃时效，但是接枝的二氰二胺有一定的毒性，直接接触皮肤有危害，实际应用价值偏低。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种表面接枝聚苯乙烯微球羽绒的处理方法。
本发明是通过以下技术方案实现的：
一种表面接枝聚苯乙烯微球羽绒的处理方法，所述的处理方法包括以下步骤：
（1）前处理：先将羽绒进行水洗、除脂、除杂后干燥，随后将羽绒与前处理液按照1:4-5的体积比混合搅拌处理10-15h，处理结束后取出水洗3-5次后备用，其中所述的前处理液是按十二烷基硫酸钠：硫脲：去离子水=0.5:1:80-120的重量比配制而成；
（2）交联改性处理：将步骤（1）得到的羽绒投入浓度为2-5%的戊二醛水溶液中，在55-60℃条件下反应1-1.5h，反应结束后投入羧基化聚苯乙烯微球，搅拌混合均匀后在60-65℃条件下超声反应2-3h，反应结束后过滤，过滤物在70-80℃条件下热处理1-2h后备用；
（3）后处理：将步骤（2）的产物投入后处理液中搅拌浸泡1.5-2h后取出，用去离子水清洗3-5次后烘干即得所述羽绒成品，其中所述的后处理液为聚季铵盐-6、乙醇、去离子水按照1-1.5:20-40:100-150的比例配制而成。
所述的步骤（2）中羽绒、戊二醛水溶液的体积比为1:2-3，戊二醛水溶液与羧基化聚苯乙烯微球的重量比为1:0.001-0.002。
本发明先利用前处理液对羽绒进行微蚀处理，增加蛋白纤维的反应接触点，在交联改性处理过程中将戊二醛、羧基化聚苯乙烯微球交联接枝到蛋白纤维上，使得纤维表面分布微球，使得羽绒间能长时间保持蓬松，尤其是在多次水洗后仍能快速恢复蓬松的手感，保持保暖效果，再经过后处理液处理后更便于整理包装。本发明工艺与现有技术相比生产工艺简单，纤维的改性效果稳定持久，赋予羽绒更佳的使用效果，增加经济价值。
具体实施方式
该实施例采用鸭羽绒毛进行处理，处理步骤为：
（1）前处理：先将羽绒进行水洗、除脂、除杂后干燥，随后将羽绒与前处理液按照1:4的体积比混合搅拌处理10h，处理结束后取出水洗3次后备用，其中所述的前处理液是按十二烷基硫酸钠：硫脲：去离子水=0.5:1:80的重量比配制而成；
（2）交联改性处理：将步骤（1）得到的羽绒投入浓度为2%的戊二醛水溶液中，在55℃条件下反应1h，反应结束后投入羧基化聚苯乙烯微球，搅拌混合均匀后在60℃条件下超声反应2h，反应结束后过滤，过滤物在70℃条件下热处理1h后备用；
（3）后处理：将步骤（2）的产物投入后处理液中搅拌浸泡1.5h后取出，用去离子水清洗3次后烘干即得所述羽绒成品，其中所述的后处理液为聚季铵盐、乙醇、去离子水按照1:20:100的比例配制而成。
其中步骤（2）中羽绒、戊二醛水溶液的体积比为1:2，戊二醛水溶液与羧基化聚苯乙烯微球的重量比为1:0.001。
处理后的鸭羽绒毛样品蓬松，手感良好，无异味，透湿量为10500WVT（g/m2.d）；透气率为280.0mm/s，水洗200次后仍具有良好的蓬松度。

Claims (2)

1.一种表面接枝聚苯乙烯微球羽绒的处理方法，其特征在于，所述的处理方法包括以下步骤：
（1）前处理：先将羽绒进行水洗、除脂、除杂后干燥，随后将羽绒与前处理液按照1:4-5的体积比混合搅拌处理10-15h，处理结束后取出水洗3-5次后备用，其中所述的前处理液是按十二烷基硫酸钠：硫脲：去离子水=0.5:1:80-120的重量比配制而成；
（2）交联改性处理：将步骤（1）得到的羽绒投入浓度为2-5%的戊二醛水溶液中，在55-60℃条件下反应1-1.5h，反应结束后投入羧基化聚苯乙烯微球，搅拌混合均匀后在60-65℃条件下超声反应2-3h，反应结束后过滤，过滤物在70-80℃条件下热处理1-2h后备用；
（3）后处理：将步骤（2）的产物投入后处理液中搅拌浸泡1.5-2h后取出，用去离子水清洗3-5次后烘干即得所述羽绒成品，其中所述的后处理液为聚季铵盐-6、乙醇、去离子水按照1-1.5:20-40:100-150的比例配制而成。
2.如权利要求1所述的一种表面接枝聚苯乙烯微球羽绒的处理方法，其特征在于，所述的步骤（2）中羽绒、戊二醛水溶液的体积比为1:2-3，戊二醛水溶液与羧基化聚苯乙烯微球的重量比为1:0.001-0.002。
CN201610249739.5A 2016-04-21 2016-04-21 一种表面接枝聚苯乙烯微球羽绒的处理方法 Pending CN105780500A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109944073A (zh) * 2019-03-14 2019-06-28 东华大学 一种溶剂致变色光子晶体织物及其制备和应用
CN114892406A (zh) * 2022-06-16 2022-08-12 安徽古麒绒材股份有限公司 一种高蓬松疏水羽绒纤维的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1854384A (zh) * 2005-04-20 2006-11-01 中科波司登纳米服饰（苏州）有限公司 具有自清洁功能的羽绒服面料的制备方法
CN103485186A (zh) * 2013-08-16 2014-01-01 陕西科技大学 一种提高羽绒蓬松度的方法
CN104264275A (zh) * 2014-09-09 2015-01-07 安徽省含山县富强羽绒制品有限公司 一种防水羽绒复合纤维及其制作方法
CN105113125A (zh) * 2015-08-14 2015-12-02 池州市徽风茶文化艺术发展有限公司 一种能净化空气的羽绒复合絮料及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1854384A (zh) * 2005-04-20 2006-11-01 中科波司登纳米服饰（苏州）有限公司 具有自清洁功能的羽绒服面料的制备方法
CN103485186A (zh) * 2013-08-16 2014-01-01 陕西科技大学 一种提高羽绒蓬松度的方法
CN104264275A (zh) * 2014-09-09 2015-01-07 安徽省含山县富强羽绒制品有限公司 一种防水羽绒复合纤维及其制作方法
CN105113125A (zh) * 2015-08-14 2015-12-02 池州市徽风茶文化艺术发展有限公司 一种能净化空气的羽绒复合絮料及其制备方法

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
张建春等: "《化纤仿毛技术原理与生产实践》", 30 September 2003, 中国纺织出版社 *
张政朴等: "《反应性与功能性高分子材料》", 28 February 2005, 化学工业出版社 *
李洁: ""聚苯乙烯微球的粒径控制制备及工程化研究"，李洁，《中国优秀硕士学位论文全文数据库 工程科技I辑》，第02期，第B016-170页", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *
李秋雁等: ""羽绒纤维经戊二醛接枝二氰二胺处理后的阻燃性能"，李秋雁等，毛纺科技，第40卷第6期，第26-29页", 《毛纺科技》 *
梁红: "《化学工程与工艺专业实验》", 30 April 2009, 广东科技出版社 *
王为强等: ""单分散大粒径交联聚苯乙烯微球的制备及功能化改性的研究进展"，王为强等，《化工进展》，第28卷第1期，第93-98,125页", 《化工进展》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109944073A (zh) * 2019-03-14 2019-06-28 东华大学 一种溶剂致变色光子晶体织物及其制备和应用
CN109944073B (zh) * 2019-03-14 2021-11-09 东华大学 一种溶剂致变色光子晶体织物及其制备和应用
CN114892406A (zh) * 2022-06-16 2022-08-12 安徽古麒绒材股份有限公司 一种高蓬松疏水羽绒纤维的制备方法

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