CN105772033A - 一种用非晶态合金制备Pd-S非晶材料的方法及其应用 - Google Patents
一种用非晶态合金制备Pd-S非晶材料的方法及其应用 Download PDFInfo
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- CN105772033A CN105772033A CN201610112314.XA CN201610112314A CN105772033A CN 105772033 A CN105772033 A CN 105772033A CN 201610112314 A CN201610112314 A CN 201610112314A CN 105772033 A CN105772033 A CN 105772033A
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- 239000000463 material Substances 0.000 title claims abstract description 18
- 229910000808 amorphous metal alloy Inorganic materials 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- 230000035484 reaction time Effects 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002178 crystalline material Substances 0.000 claims description 30
- 239000003054 catalyst Substances 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- 239000005300 metallic glass Substances 0.000 claims description 8
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- 238000007605 air drying Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 6
- 239000002131 composite material Substances 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000001308 synthesis method Methods 0.000 abstract 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 26
- 238000002360 preparation method Methods 0.000 description 16
- 238000006555 catalytic reaction Methods 0.000 description 9
- 238000004502 linear sweep voltammetry Methods 0.000 description 8
- 229910052763 palladium Inorganic materials 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/043—Sulfides with iron group metals or platinum group metals
- B01J27/045—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/33—Electric or magnetic properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610112314.XA CN105772033B (zh) | 2016-02-29 | 2016-02-29 | 一种用非晶态合金制备Pd-S非晶材料的方法及其应用 |
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CN201610112314.XA CN105772033B (zh) | 2016-02-29 | 2016-02-29 | 一种用非晶态合金制备Pd-S非晶材料的方法及其应用 |
Publications (2)
Publication Number | Publication Date |
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CN105772033A true CN105772033A (zh) | 2016-07-20 |
CN105772033B CN105772033B (zh) | 2018-09-18 |
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CN201610112314.XA Active CN105772033B (zh) | 2016-02-29 | 2016-02-29 | 一种用非晶态合金制备Pd-S非晶材料的方法及其应用 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110923737A (zh) * | 2018-09-20 | 2020-03-27 | 天津大学 | 一种纳米多孔产氢催化剂及其制备方法 |
CN111318720A (zh) * | 2020-03-04 | 2020-06-23 | 王冲 | 一种立方体形貌PtCoS合金纳米颗粒及其制备方法 |
CN112342567A (zh) * | 2019-08-09 | 2021-02-09 | 天津大学 | 用铝基合金制备Al-Ti-Ni晶体-非晶复合材料及其制备方法和应用 |
CN112742423A (zh) * | 2020-12-15 | 2021-05-04 | 中山大学 | 钯磷硫二维多晶材料的制备及其在电化学领域中的应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090075139A1 (en) * | 2004-01-06 | 2009-03-19 | Ic Innovations Limited | Nanoporous/mesoporous palladium catalyst |
CN102304639A (zh) * | 2011-09-15 | 2012-01-04 | 北京航空航天大学 | 一种基于Al-Cu一步去合金化制备多孔Al2Cu化合物的方法 |
CN104475125A (zh) * | 2014-11-06 | 2015-04-01 | 天津大学 | 用非晶态合金脱合金制备Pd/CuO复合纳米多孔材料的方法及其应用 |
CN105148942A (zh) * | 2015-08-12 | 2015-12-16 | 天津大学 | 一种纳米多孔结构的硫化银-硫化铜复合粉末的制备方法及应用 |
-
2016
- 2016-02-29 CN CN201610112314.XA patent/CN105772033B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090075139A1 (en) * | 2004-01-06 | 2009-03-19 | Ic Innovations Limited | Nanoporous/mesoporous palladium catalyst |
CN102304639A (zh) * | 2011-09-15 | 2012-01-04 | 北京航空航天大学 | 一种基于Al-Cu一步去合金化制备多孔Al2Cu化合物的方法 |
CN104475125A (zh) * | 2014-11-06 | 2015-04-01 | 天津大学 | 用非晶态合金脱合金制备Pd/CuO复合纳米多孔材料的方法及其应用 |
CN105148942A (zh) * | 2015-08-12 | 2015-12-16 | 天津大学 | 一种纳米多孔结构的硫化银-硫化铜复合粉末的制备方法及应用 |
Non-Patent Citations (1)
Title |
---|
YIYING CHIANG ET AL.: "Formation of PdS Compounds in Direct Metallization via Pd/Sn Catalyst Activation", 《JOURNAL OF THE ELECTROCHEMICAL SOCIETY》 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110923737A (zh) * | 2018-09-20 | 2020-03-27 | 天津大学 | 一种纳米多孔产氢催化剂及其制备方法 |
CN112342567A (zh) * | 2019-08-09 | 2021-02-09 | 天津大学 | 用铝基合金制备Al-Ti-Ni晶体-非晶复合材料及其制备方法和应用 |
CN112342567B (zh) * | 2019-08-09 | 2022-02-22 | 天津大学 | 用铝基合金制备Al-Ti-Ni晶体-非晶复合材料及其制备方法和应用 |
CN111318720A (zh) * | 2020-03-04 | 2020-06-23 | 王冲 | 一种立方体形貌PtCoS合金纳米颗粒及其制备方法 |
CN111318720B (zh) * | 2020-03-04 | 2022-10-25 | 王冲 | 一种立方体形貌PtCoS合金纳米颗粒及其制备方法 |
CN112742423A (zh) * | 2020-12-15 | 2021-05-04 | 中山大学 | 钯磷硫二维多晶材料的制备及其在电化学领域中的应用 |
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Publication number | Publication date |
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CN105772033B (zh) | 2018-09-18 |
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Address after: 300350 Haijing garden, Haihe Education Park, Jinnan, Tianjin, 135, Tianjin University. Patentee after: Tianjin University Address before: 300072 Tianjin City, Nankai District Wei Jin Road No. 92 Patentee before: Tianjin University |
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Address after: 300452 Binhai Industrial Research Institute Campus of Tianjin University, No. 48 Jialingjiang Road, Binhai New Area, Tianjin Patentee after: Tianjin University Address before: 300350 Haijing garden, Haihe Education Park, Jinnan, Tianjin, 135, Tianjin University. Patentee before: Tianjin University |