CN105772033B - 一种用非晶态合金制备Pd-S非晶材料的方法及其应用 - Google Patents
一种用非晶态合金制备Pd-S非晶材料的方法及其应用 Download PDFInfo
- Publication number
- CN105772033B CN105772033B CN201610112314.XA CN201610112314A CN105772033B CN 105772033 B CN105772033 B CN 105772033B CN 201610112314 A CN201610112314 A CN 201610112314A CN 105772033 B CN105772033 B CN 105772033B
- Authority
- CN
- China
- Prior art keywords
- content
- preparing
- amorphous alloy
- crystalline materials
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910000808 amorphous metal alloy Inorganic materials 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- 230000035484 reaction time Effects 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002178 crystalline material Substances 0.000 claims description 32
- 239000003054 catalyst Substances 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
- 229910052763 palladium Inorganic materials 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 238000002604 ultrasonography Methods 0.000 claims description 3
- 238000007605 air drying Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 4
- 239000002131 composite material Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000001308 synthesis method Methods 0.000 abstract 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 26
- 238000002360 preparation method Methods 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 8
- 238000004502 linear sweep voltammetry Methods 0.000 description 8
- 238000006555 catalytic reaction Methods 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 238000005868 electrolysis reaction Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000005300 metallic glass Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/043—Sulfides with iron group metals or platinum group metals
- B01J27/045—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/33—Electric or magnetic properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610112314.XA CN105772033B (zh) | 2016-02-29 | 2016-02-29 | 一种用非晶态合金制备Pd-S非晶材料的方法及其应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610112314.XA CN105772033B (zh) | 2016-02-29 | 2016-02-29 | 一种用非晶态合金制备Pd-S非晶材料的方法及其应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105772033A CN105772033A (zh) | 2016-07-20 |
CN105772033B true CN105772033B (zh) | 2018-09-18 |
Family
ID=56386544
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610112314.XA Active CN105772033B (zh) | 2016-02-29 | 2016-02-29 | 一种用非晶态合金制备Pd-S非晶材料的方法及其应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105772033B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110923737A (zh) * | 2018-09-20 | 2020-03-27 | 天津大学 | 一种纳米多孔产氢催化剂及其制备方法 |
CN112342567B (zh) * | 2019-08-09 | 2022-02-22 | 天津大学 | 用铝基合金制备Al-Ti-Ni晶体-非晶复合材料及其制备方法和应用 |
CN111318720B (zh) * | 2020-03-04 | 2022-10-25 | 王冲 | 一种立方体形貌PtCoS合金纳米颗粒及其制备方法 |
CN112742423B (zh) * | 2020-12-15 | 2022-01-18 | 中山大学 | 钯磷硫二维多晶材料的制备及其在电化学领域中的应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102304639A (zh) * | 2011-09-15 | 2012-01-04 | 北京航空航天大学 | 一种基于Al-Cu一步去合金化制备多孔Al2Cu化合物的方法 |
CN104475125A (zh) * | 2014-11-06 | 2015-04-01 | 天津大学 | 用非晶态合金脱合金制备Pd/CuO复合纳米多孔材料的方法及其应用 |
CN105148942A (zh) * | 2015-08-12 | 2015-12-16 | 天津大学 | 一种纳米多孔结构的硫化银-硫化铜复合粉末的制备方法及应用 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0400166D0 (en) * | 2004-01-06 | 2004-02-11 | Ic Innovations Ltd | Catalyst |
-
2016
- 2016-02-29 CN CN201610112314.XA patent/CN105772033B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102304639A (zh) * | 2011-09-15 | 2012-01-04 | 北京航空航天大学 | 一种基于Al-Cu一步去合金化制备多孔Al2Cu化合物的方法 |
CN104475125A (zh) * | 2014-11-06 | 2015-04-01 | 天津大学 | 用非晶态合金脱合金制备Pd/CuO复合纳米多孔材料的方法及其应用 |
CN105148942A (zh) * | 2015-08-12 | 2015-12-16 | 天津大学 | 一种纳米多孔结构的硫化银-硫化铜复合粉末的制备方法及应用 |
Non-Patent Citations (1)
Title |
---|
Formation of PdS Compounds in Direct Metallization via Pd/Sn Catalyst Activation;Yiying Chiang et al.;《Journal of The Electrochemical Society》;19991231;第146卷(第9期);第3255-3258页 * |
Also Published As
Publication number | Publication date |
---|---|
CN105772033A (zh) | 2016-07-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110331414B (zh) | 一种mof复合的铜基纳米棒阵列@泡沫铜基复合电极材料及其制备方法和用途 | |
CN110438528B (zh) | 一种改性泡沫镍负载贵金属催化剂析氢电极及其制备方法 | |
Xia et al. | Selenide-based electrocatalysts and scaffolds for water oxidation applications | |
CN105734457B (zh) | 一种用非晶态合金制备Pd‑Cu‑S非晶材料的方法及其应用 | |
CN109518220B (zh) | 以泡沫铜为基底构筑二维金属有机框架纳米水解电催化剂的制备方法及其应用于电解水析氢 | |
CN105772033B (zh) | 一种用非晶态合金制备Pd-S非晶材料的方法及其应用 | |
CN113430553B (zh) | 基于过渡金属异质层状结构双功能催化电极及制备方法 | |
CN109267089B (zh) | 一种纳米森林状的V掺杂的Ni3S2/NF自支撑电极及其制备方法 | |
CN104475125A (zh) | 用非晶态合金脱合金制备Pd/CuO复合纳米多孔材料的方法及其应用 | |
CN112791736A (zh) | WP2/Cu3P复合纳米结构催化剂在电解水产氢方面的应用 | |
CN102251266A (zh) | 一种脉冲电沉积制备纳米铂/二氧化钛纳米管电极的方法 | |
CN113061929B (zh) | 一种掺杂磷化镍铁基三维超薄纳米片材料及其制备方法和应用 | |
CN105413729A (zh) | 一种碳化钼颗粒嵌入的氮掺杂碳纳米纤维气凝胶的制备方法 | |
CN111054408A (zh) | 一种多孔镍钼基纳米片双功能电催化剂的制备方法 | |
CN109371419B (zh) | 一种短棒自组装成树枝状的V掺杂的Ni3S2/NF电极材料及其制备方法 | |
CN108906084A (zh) | 一种二硒化钴纳米棒的制备方法及应用 | |
CN105148942B (zh) | 一种纳米多孔结构的硫化银‑硫化铜复合粉末的制备方法及应用 | |
CN112725774B (zh) | 大电流下稳定的核-壳结构全解水催化剂及其制备方法 | |
CN112058282A (zh) | 一种基于钼、钨基层状材料pH广适催化剂的制备方法及其应用于电解水析氢反应 | |
Bhardwaj et al. | Nanostructured Cu foam and its derivatives: emerging materials for the heterogeneous conversion of CO 2 to fuels | |
CN109402654B (zh) | 一种具有衬底保护功能的MoS2/Ni3Se2复合析氢电催化剂及其制备方法 | |
CN110408947B (zh) | 一种复合氧化银的镍钴氧化物电极材料及其制备方法与应用 | |
CN109321959A (zh) | 一种纳米Ag嵌入式电极材料的电化学制备法 | |
CN105618084A (zh) | 一种用非晶态合金制备Pd/CuO-TiO2复合材料的方法及其应用 | |
KR102180882B1 (ko) | 초음파 분무 열분해법을 이용한 수전해 촉매 합성방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CP02 | Change in the address of a patent holder | ||
CP02 | Change in the address of a patent holder |
Address after: 300350 Haijing garden, Haihe Education Park, Jinnan, Tianjin, 135, Tianjin University. Patentee after: Tianjin University Address before: 300072 Tianjin City, Nankai District Wei Jin Road No. 92 Patentee before: Tianjin University |
|
CP02 | Change in the address of a patent holder | ||
CP02 | Change in the address of a patent holder |
Address after: 300452 Binhai Industrial Research Institute Campus of Tianjin University, No. 48 Jialingjiang Road, Binhai New Area, Tianjin Patentee after: Tianjin University Address before: 300350 Haijing garden, Haihe Education Park, Jinnan, Tianjin, 135, Tianjin University. Patentee before: Tianjin University |