CN105683137A - 催化脱氢方法 - Google Patents

催化脱氢方法 Download PDF

Info

Publication number
CN105683137A
CN105683137A CN201480059171.XA CN201480059171A CN105683137A CN 105683137 A CN105683137 A CN 105683137A CN 201480059171 A CN201480059171 A CN 201480059171A CN 105683137 A CN105683137 A CN 105683137A
Authority
CN
China
Prior art keywords
reactor
fluidized
catalytic
dehydrogenation process
seconds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201480059171.XA
Other languages
English (en)
Chinese (zh)
Inventor
M·T·普雷茨
M·W·斯图尔特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Priority to CN202010646524.3A priority Critical patent/CN111875468A/zh
Publication of CN105683137A publication Critical patent/CN105683137A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201480059171.XA 2013-11-12 2014-10-14 催化脱氢方法 Pending CN105683137A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010646524.3A CN111875468A (zh) 2013-11-12 2014-10-14 催化脱氢方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361903050P 2013-11-12 2013-11-12
US61/903050 2013-11-12
PCT/US2014/060371 WO2015073152A1 (en) 2013-11-12 2014-10-14 Catalytic dehydrogenation process

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN202010646524.3A Division CN111875468A (zh) 2013-11-12 2014-10-14 催化脱氢方法

Publications (1)

Publication Number Publication Date
CN105683137A true CN105683137A (zh) 2016-06-15

Family

ID=51842878

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201480059171.XA Pending CN105683137A (zh) 2013-11-12 2014-10-14 催化脱氢方法
CN202010646524.3A Pending CN111875468A (zh) 2013-11-12 2014-10-14 催化脱氢方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN202010646524.3A Pending CN111875468A (zh) 2013-11-12 2014-10-14 催化脱氢方法

Country Status (11)

Country Link
US (1) US9725382B2 (enExample)
EP (1) EP3068748B1 (enExample)
KR (1) KR102322348B1 (enExample)
CN (2) CN105683137A (enExample)
AR (1) AR098383A1 (enExample)
BR (1) BR112016009581B1 (enExample)
CA (1) CA2929594C (enExample)
MX (1) MX367860B (enExample)
RU (1) RU2665480C1 (enExample)
SA (1) SA516371017B1 (enExample)
WO (1) WO2015073152A1 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108473389A (zh) * 2016-01-21 2018-08-31 沙特基础全球技术有限公司 通过丙烷脱氢生产丙烯的方法
CN110300739A (zh) * 2017-03-13 2019-10-01 陶氏环球技术有限责任公司 用于由不同进料物流制备轻烯烃的方法
CN114072372A (zh) * 2019-06-28 2022-02-18 陶氏环球技术有限责任公司 包括使用冷却的产物作为再循环的骤冷流的形成轻质烯烃的方法

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9707533B2 (en) * 2015-12-01 2017-07-18 Dow Global Technologies Llc Fluidized catalyst stripping unit for displacing entrained gas from catalyst particles
AR109884A1 (es) 2016-11-02 2019-01-30 Dow Global Technologies Llc Métodos para diseñar reactores catalíticos fluidos ampliados
EP3535053B1 (en) 2016-11-02 2022-07-27 Dow Global Technologies LLC Fluid catalytic reactors which include flow directors
AR111237A1 (es) 2017-03-13 2019-06-19 Dow Global Technologies Llc Métodos y aparatos para formar olefinas ligeras por craqueo
AR111992A1 (es) 2017-06-19 2019-09-11 Dow Global Technologies Llc Sistemas de reactor que comprenden el reciclado de fluidos
CN112074499B (zh) 2018-03-23 2023-09-05 埃克森美孚化学专利公司 用于烃转化的方法和系统
US11760703B2 (en) * 2020-03-06 2023-09-19 Exxonmobil Chemical Patents Inc. Processes for upgrading alkanes and alkyl aromatic hydrocarbons
CN115210201B (zh) * 2020-03-06 2025-02-11 埃克森美孚化学专利公司 烷烃和烷基芳族烃的提质方法
US11000832B1 (en) * 2020-03-13 2021-05-11 Uop Llc Dehydrogenation catalyst with minimized aromatic production

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2982798A (en) * 1958-09-08 1961-05-02 Phillips Petroleum Co Co-current flow dehydrogenation system
CN102417432A (zh) * 2011-12-16 2012-04-18 天津市泰亨气体有限公司 采用丁烷催化脱氢制备1,3-丁二烯的方法
WO2013126210A1 (en) * 2012-02-20 2013-08-29 Dow Global Technologies Llc Reconstituted dehydrogenation catalyst showing slowed activity loss when compared with fresh catalyst

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4579716A (en) 1983-09-06 1986-04-01 Mobil Oil Corporation Closed reactor FCC system with provisions for surge capacity
US5190650A (en) 1991-06-24 1993-03-02 Exxon Research And Engineering Company Tangential solids separation transfer tunnel
US5254788A (en) * 1991-09-10 1993-10-19 Stone And Webster Engineering Corporation Process for the production of olefins from light paraffins
US5220093A (en) * 1992-04-03 1993-06-15 Stone & Webster Engineering Corporation Process for production of olefins from mixtures of light paraffins
RU2178399C1 (ru) * 2000-12-09 2002-01-20 Институт катализа им. Г.К. Борескова СО РАН Способ каталитического дегидрирования углеводородов
ITMI20012709A1 (it) * 2001-12-20 2003-06-20 Snam Progetti Composizione catalitica per la deidrogenazione di idrocarburi alchilaromatici
BRPI0506606B1 (pt) 2004-02-09 2015-03-31 Dow Chemical Co Processo para desidrogenar um hidrocarboneto
DE102005010586A1 (de) * 2005-03-08 2006-09-14 Basf Ag Verfahren zur Herstellung von Propen aus Propan
WO2013009820A1 (en) 2011-07-13 2013-01-17 Dow Global Technologies Llc Reactivating propane dehydrogenation catalyst

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2982798A (en) * 1958-09-08 1961-05-02 Phillips Petroleum Co Co-current flow dehydrogenation system
CN102417432A (zh) * 2011-12-16 2012-04-18 天津市泰亨气体有限公司 采用丁烷催化脱氢制备1,3-丁二烯的方法
WO2013126210A1 (en) * 2012-02-20 2013-08-29 Dow Global Technologies Llc Reconstituted dehydrogenation catalyst showing slowed activity loss when compared with fresh catalyst

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108473389A (zh) * 2016-01-21 2018-08-31 沙特基础全球技术有限公司 通过丙烷脱氢生产丙烯的方法
CN110300739A (zh) * 2017-03-13 2019-10-01 陶氏环球技术有限责任公司 用于由不同进料物流制备轻烯烃的方法
CN114072372A (zh) * 2019-06-28 2022-02-18 陶氏环球技术有限责任公司 包括使用冷却的产物作为再循环的骤冷流的形成轻质烯烃的方法

Also Published As

Publication number Publication date
MX2016005412A (es) 2016-08-19
CA2929594C (en) 2021-12-07
RU2016122616A (ru) 2017-12-19
WO2015073152A1 (en) 2015-05-21
EP3068748B1 (en) 2019-07-03
MX367860B (es) 2019-09-09
KR20160093001A (ko) 2016-08-05
AR098383A1 (es) 2016-05-26
US20160272559A1 (en) 2016-09-22
BR112016009581A2 (enExample) 2017-08-01
EP3068748A1 (en) 2016-09-21
CA2929594A1 (en) 2015-05-21
SA516371017B1 (ar) 2017-12-05
CN111875468A (zh) 2020-11-03
KR102322348B1 (ko) 2021-11-09
BR112016009581B1 (pt) 2021-09-21
RU2665480C1 (ru) 2018-08-30
US9725382B2 (en) 2017-08-08

Similar Documents

Publication Publication Date Title
CN105683137A (zh) 催化脱氢方法
JP6230722B2 (ja) メタノール及び／又はジメチルエーテルから低級オレフィンを製造する反応装置
JP6199493B2 (ja) 酸素含有化合物から低級オレフィンを製造する方法、及び、それに用いられる装置
JP2017501987A (ja) 酸素含有化合物から低級オレフィンを製造する方法
JP2017504654A5 (enExample)
CN104437274A (zh) 一种用于轻烯烃裂解、甲醇制烯烃的流化床反应器
WO2013177723A1 (zh) 一种烷烃脱氢制烯烃的方法
CN102844102B (zh) 反应器
CN114286720B (zh) 最大化低碳烯烃产率的带挡板的湍流/快速流化床反应器
CN110300739A (zh) 用于由不同进料物流制备轻烯烃的方法
CN105218288B (zh) 用于甲醇制烯烃的高效气固快速分离与沉降方法
JP7585244B2 (ja) 冷却された生成物をリサイクルされた急冷ストリームとして使用することを含む軽質オレフィンを形成するための方法
US12012556B2 (en) Dense phase riser to maximize light olefins yields for naphtha catalytic cracking
CN105268381B (zh) 用于甲醇制烯烃的下行床反应‑再生装置及其反应方法
US12060528B2 (en) Multiple dense phase risers to maximize light olefins yields for naphtha catalytic cracking
CN105315119B (zh) 基于高密度反应器的甲醇制烯烃的方法
TWI849449B (zh) 具高產率及選擇性的生產輕烯烴之方法及系統
JP2024525615A (ja) 流動接触分解反応器及び再生器を含むプロセスの熱統合
CN111278793A (zh) 将正丁烷转化为异丁烷的系统和方法
JP2025510614A (ja) 熱交換器システムを利用して軽質オレフィンを形成する方法
KR20240024911A (ko) 높은 수율 및 선택도를 갖는 경질 올레핀 생성 방법 및 시스템

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160615