AR098383A1 - Proceso de deshidrogenación catalítica - Google Patents

Proceso de deshidrogenación catalítica

Info

Publication number
AR098383A1
AR098383A1 ARP140104240A ARP140104240A AR098383A1 AR 098383 A1 AR098383 A1 AR 098383A1 AR P140104240 A ARP140104240 A AR P140104240A AR P140104240 A ARP140104240 A AR P140104240A AR 098383 A1 AR098383 A1 AR 098383A1
Authority
AR
Argentina
Prior art keywords
fluidized
reactor
range
separation system
cyclonic separation
Prior art date
Application number
ARP140104240A
Other languages
English (en)
Inventor
Pretz Matthew
Stewart Mark
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of AR098383A1 publication Critical patent/AR098383A1/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • C07C5/3335Catalytic processes with metals
    • C07C5/3337Catalytic processes with metals of the platinum group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42Platinum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12Silica and alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42Platinum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56Platinum group metals
    • C07C2523/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un proceso de deshidrogenación. catalítica. mejorado, el procedimiento que comprende poner en contacto una corriente de alimentación de alcano o alquilo aromático con un catalizador de deshidrogenación en condiciones catalíticas en un reactor fluidizado de flujo ascendente en el que el reactor fluidizado contiene uno o más reactores, cuyas condiciones catalíticas incluyen una temperatura dentro de un rango de 500 - 800º C, una velocidad espacial horaria en peso dentro de un rango de 0,1 a 1000, un tiempo de residencia de gas dentro de un rango de 0,1 a 10 segundos y, subsecuente al reactor fluidizado, efectuando la separación del catalizador arrastrado desde el efluente del reactor mediante el uso de un sistema de separación ciclónica, en el que la mejora comprende la interposición de un medio de enfriamiento entre un reactor fluidizado de flujo ascendente y el sistema de separación ciclónica para detener sustancialmente las reacciones térmicas, aumentando así eficazmente la selectividad molar global de producto alqueno.
ARP140104240A 2013-11-12 2014-11-11 Proceso de deshidrogenación catalítica AR098383A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201361903050P 2013-11-12 2013-11-12

Publications (1)

Publication Number Publication Date
AR098383A1 true AR098383A1 (es) 2016-05-26

Family

ID=51842878

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP140104240A AR098383A1 (es) 2013-11-12 2014-11-11 Proceso de deshidrogenación catalítica

Country Status (11)

Country Link
US (1) US9725382B2 (es)
EP (1) EP3068748B1 (es)
KR (1) KR102322348B1 (es)
CN (2) CN105683137A (es)
AR (1) AR098383A1 (es)
BR (1) BR112016009581B1 (es)
CA (1) CA2929594C (es)
MX (1) MX367860B (es)
RU (1) RU2665480C1 (es)
SA (1) SA516371017B1 (es)
WO (1) WO2015073152A1 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9707533B2 (en) 2015-12-01 2017-07-18 Dow Global Technologies Llc Fluidized catalyst stripping unit for displacing entrained gas from catalyst particles
WO2017125836A1 (en) * 2016-01-21 2017-07-27 Sabic Global Technologies B.V. Methods for producing propylene by the dehydrogenation of propane
AR109884A1 (es) 2016-11-02 2019-01-30 Dow Global Technologies Llc Métodos para diseñar reactores catalíticos fluidos ampliados
AR109885A1 (es) 2016-11-02 2019-01-30 Dow Global Technologies Llc Reactores catalíticos fluidos que incluyen directores de flujo
AR111124A1 (es) 2017-03-13 2019-06-05 Dow Global Technologies Llc Métodos para fabricar olefinas ligeras a partir de corrientes de alimentación diferentes
AR111237A1 (es) 2017-03-13 2019-06-19 Dow Global Technologies Llc Métodos y aparatos para formar olefinas ligeras por craqueo
AR111992A1 (es) 2017-06-19 2019-09-11 Dow Global Technologies Llc Sistemas de reactor que comprenden el reciclado de fluidos
CA3094796C (en) 2018-03-23 2023-02-28 Exxonmobil Chemical Patents Inc. Processes and systems for the conversion of hydrocarbons
US11987547B2 (en) * 2019-06-28 2024-05-21 Dow Global Technologies Llc Methods for forming light olefins that include use of cooled product as a recycled quench stream
US11760703B2 (en) * 2020-03-06 2023-09-19 Exxonmobil Chemical Patents Inc. Processes for upgrading alkanes and alkyl aromatic hydrocarbons
WO2021178115A1 (en) * 2020-03-06 2021-09-10 Exxonmobil Chemical Patents Inc. Processes for upgrading alkanes and alkyl aromatic hydrocarbons
US11000832B1 (en) * 2020-03-13 2021-05-11 Uop Llc Dehydrogenation catalyst with minimized aromatic production

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2982798A (en) * 1958-09-08 1961-05-02 Phillips Petroleum Co Co-current flow dehydrogenation system
US4579716A (en) 1983-09-06 1986-04-01 Mobil Oil Corporation Closed reactor FCC system with provisions for surge capacity
US5190650A (en) 1991-06-24 1993-03-02 Exxon Research And Engineering Company Tangential solids separation transfer tunnel
US5254788A (en) * 1991-09-10 1993-10-19 Stone And Webster Engineering Corporation Process for the production of olefins from light paraffins
US5220093A (en) * 1992-04-03 1993-06-15 Stone & Webster Engineering Corporation Process for production of olefins from mixtures of light paraffins
RU2178399C1 (ru) * 2000-12-09 2002-01-20 Институт катализа им. Г.К. Борескова СО РАН Способ каталитического дегидрирования углеводородов
ITMI20012709A1 (it) * 2001-12-20 2003-06-20 Snam Progetti Composizione catalitica per la deidrogenazione di idrocarburi alchilaromatici
ZA200606323B (en) 2004-02-09 2008-02-27 Dow Chemical Co Process for the preparation of dehydrogenated hydrocarbon compounds
DE102005010586A1 (de) * 2005-03-08 2006-09-14 Basf Ag Verfahren zur Herstellung von Propen aus Propan
RU2608732C2 (ru) 2011-07-13 2017-01-23 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Регенерация катализатора дегидрогенизации пропана
CN102417432A (zh) * 2011-12-16 2012-04-18 天津市泰亨气体有限公司 采用丁烷催化脱氢制备1,3-丁二烯的方法
CN104169244B (zh) * 2012-02-20 2016-04-06 陶氏环球技术有限责任公司 与新鲜催化剂相比显示出减慢的活性损失的重建脱氢催化剂

Also Published As

Publication number Publication date
US20160272559A1 (en) 2016-09-22
RU2665480C1 (ru) 2018-08-30
KR20160093001A (ko) 2016-08-05
RU2016122616A (ru) 2017-12-19
EP3068748A1 (en) 2016-09-21
US9725382B2 (en) 2017-08-08
CA2929594A1 (en) 2015-05-21
MX367860B (es) 2019-09-09
KR102322348B1 (ko) 2021-11-09
CN111875468A (zh) 2020-11-03
WO2015073152A1 (en) 2015-05-21
CA2929594C (en) 2021-12-07
EP3068748B1 (en) 2019-07-03
MX2016005412A (es) 2016-08-19
BR112016009581B1 (pt) 2021-09-21
BR112016009581A2 (es) 2017-08-01
SA516371017B1 (ar) 2017-12-05
CN105683137A (zh) 2016-06-15

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