BR112016009581B1 - Processo de desidrogenação catalítico - Google Patents
Processo de desidrogenação catalítico Download PDFInfo
- Publication number
- BR112016009581B1 BR112016009581B1 BR112016009581-2A BR112016009581A BR112016009581B1 BR 112016009581 B1 BR112016009581 B1 BR 112016009581B1 BR 112016009581 A BR112016009581 A BR 112016009581A BR 112016009581 B1 BR112016009581 B1 BR 112016009581B1
- Authority
- BR
- Brazil
- Prior art keywords
- reactor
- catalytic
- cooling
- fluidized
- catalyst
- Prior art date
Links
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000006356 dehydrogenation reaction Methods 0.000 title claims abstract description 33
- 238000006243 chemical reaction Methods 0.000 claims abstract description 53
- 239000003054 catalyst Substances 0.000 claims abstract description 39
- 238000000926 separation method Methods 0.000 claims abstract description 39
- 238000001816 cooling Methods 0.000 claims abstract description 32
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 7
- 150000001336 alkenes Chemical class 0.000 claims abstract description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 29
- 239000007789 gas Substances 0.000 claims description 19
- 239000002826 coolant Substances 0.000 claims description 17
- 239000000047 product Substances 0.000 claims description 17
- 239000001294 propane Substances 0.000 claims description 14
- 238000006555 catalytic reaction Methods 0.000 claims description 13
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- 230000005587 bubbling Effects 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 3
- 239000000446 fuel Substances 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 12
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 10
- 230000007423 decrease Effects 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000011144 upstream manufacturing Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 238000010574 gas phase reaction Methods 0.000 description 3
- 238000004227 thermal cracking Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 1
- -1 aromatic alkanes Chemical class 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361903050P | 2013-11-12 | 2013-11-12 | |
| US61/903,050 | 2013-11-12 | ||
| PCT/US2014/060371 WO2015073152A1 (en) | 2013-11-12 | 2014-10-14 | Catalytic dehydrogenation process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112016009581A2 BR112016009581A2 (enExample) | 2017-08-01 |
| BR112016009581B1 true BR112016009581B1 (pt) | 2021-09-21 |
Family
ID=51842878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112016009581-2A BR112016009581B1 (pt) | 2013-11-12 | 2014-10-14 | Processo de desidrogenação catalítico |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9725382B2 (enExample) |
| EP (1) | EP3068748B1 (enExample) |
| KR (1) | KR102322348B1 (enExample) |
| CN (2) | CN105683137A (enExample) |
| AR (1) | AR098383A1 (enExample) |
| BR (1) | BR112016009581B1 (enExample) |
| CA (1) | CA2929594C (enExample) |
| MX (1) | MX367860B (enExample) |
| RU (1) | RU2665480C1 (enExample) |
| SA (1) | SA516371017B1 (enExample) |
| WO (1) | WO2015073152A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9707533B2 (en) * | 2015-12-01 | 2017-07-18 | Dow Global Technologies Llc | Fluidized catalyst stripping unit for displacing entrained gas from catalyst particles |
| US10662129B2 (en) * | 2016-01-21 | 2020-05-26 | Sabic Global Technologies B.V. | Methods for producing propylene by the dehydrogenation of propane |
| AR109884A1 (es) | 2016-11-02 | 2019-01-30 | Dow Global Technologies Llc | Métodos para diseñar reactores catalíticos fluidos ampliados |
| EP3535053B1 (en) | 2016-11-02 | 2022-07-27 | Dow Global Technologies LLC | Fluid catalytic reactors which include flow directors |
| AR111237A1 (es) | 2017-03-13 | 2019-06-19 | Dow Global Technologies Llc | Métodos y aparatos para formar olefinas ligeras por craqueo |
| AR111124A1 (es) * | 2017-03-13 | 2019-06-05 | Dow Global Technologies Llc | Métodos para fabricar olefinas ligeras a partir de corrientes de alimentación diferentes |
| AR111992A1 (es) | 2017-06-19 | 2019-09-11 | Dow Global Technologies Llc | Sistemas de reactor que comprenden el reciclado de fluidos |
| CN112074499B (zh) | 2018-03-23 | 2023-09-05 | 埃克森美孚化学专利公司 | 用于烃转化的方法和系统 |
| JP7585244B2 (ja) * | 2019-06-28 | 2024-11-18 | ダウ グローバル テクノロジーズ エルエルシー | 冷却された生成物をリサイクルされた急冷ストリームとして使用することを含む軽質オレフィンを形成するための方法 |
| US11760703B2 (en) * | 2020-03-06 | 2023-09-19 | Exxonmobil Chemical Patents Inc. | Processes for upgrading alkanes and alkyl aromatic hydrocarbons |
| CN115210201B (zh) * | 2020-03-06 | 2025-02-11 | 埃克森美孚化学专利公司 | 烷烃和烷基芳族烃的提质方法 |
| US11000832B1 (en) * | 2020-03-13 | 2021-05-11 | Uop Llc | Dehydrogenation catalyst with minimized aromatic production |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2982798A (en) * | 1958-09-08 | 1961-05-02 | Phillips Petroleum Co | Co-current flow dehydrogenation system |
| US4579716A (en) | 1983-09-06 | 1986-04-01 | Mobil Oil Corporation | Closed reactor FCC system with provisions for surge capacity |
| US5190650A (en) | 1991-06-24 | 1993-03-02 | Exxon Research And Engineering Company | Tangential solids separation transfer tunnel |
| US5254788A (en) * | 1991-09-10 | 1993-10-19 | Stone And Webster Engineering Corporation | Process for the production of olefins from light paraffins |
| US5220093A (en) * | 1992-04-03 | 1993-06-15 | Stone & Webster Engineering Corporation | Process for production of olefins from mixtures of light paraffins |
| RU2178399C1 (ru) * | 2000-12-09 | 2002-01-20 | Институт катализа им. Г.К. Борескова СО РАН | Способ каталитического дегидрирования углеводородов |
| ITMI20012709A1 (it) * | 2001-12-20 | 2003-06-20 | Snam Progetti | Composizione catalitica per la deidrogenazione di idrocarburi alchilaromatici |
| BRPI0506606B1 (pt) | 2004-02-09 | 2015-03-31 | Dow Chemical Co | Processo para desidrogenar um hidrocarboneto |
| DE102005010586A1 (de) * | 2005-03-08 | 2006-09-14 | Basf Ag | Verfahren zur Herstellung von Propen aus Propan |
| WO2013009820A1 (en) | 2011-07-13 | 2013-01-17 | Dow Global Technologies Llc | Reactivating propane dehydrogenation catalyst |
| CN102417432A (zh) * | 2011-12-16 | 2012-04-18 | 天津市泰亨气体有限公司 | 采用丁烷催化脱氢制备1,3-丁二烯的方法 |
| WO2013126210A1 (en) * | 2012-02-20 | 2013-08-29 | Dow Global Technologies Llc | Reconstituted dehydrogenation catalyst showing slowed activity loss when compared with fresh catalyst |
-
2014
- 2014-10-14 BR BR112016009581-2A patent/BR112016009581B1/pt active IP Right Grant
- 2014-10-14 MX MX2016005412A patent/MX367860B/es active IP Right Grant
- 2014-10-14 EP EP14790934.5A patent/EP3068748B1/en active Active
- 2014-10-14 CA CA2929594A patent/CA2929594C/en active Active
- 2014-10-14 US US15/034,637 patent/US9725382B2/en active Active
- 2014-10-14 CN CN201480059171.XA patent/CN105683137A/zh active Pending
- 2014-10-14 KR KR1020167013702A patent/KR102322348B1/ko active Active
- 2014-10-14 RU RU2016122616A patent/RU2665480C1/ru active
- 2014-10-14 WO PCT/US2014/060371 patent/WO2015073152A1/en not_active Ceased
- 2014-10-14 CN CN202010646524.3A patent/CN111875468A/zh active Pending
- 2014-11-11 AR ARP140104240A patent/AR098383A1/es active IP Right Grant
-
2016
- 2016-04-27 SA SA516371017A patent/SA516371017B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX2016005412A (es) | 2016-08-19 |
| CA2929594C (en) | 2021-12-07 |
| RU2016122616A (ru) | 2017-12-19 |
| WO2015073152A1 (en) | 2015-05-21 |
| EP3068748B1 (en) | 2019-07-03 |
| MX367860B (es) | 2019-09-09 |
| KR20160093001A (ko) | 2016-08-05 |
| AR098383A1 (es) | 2016-05-26 |
| CN105683137A (zh) | 2016-06-15 |
| US20160272559A1 (en) | 2016-09-22 |
| BR112016009581A2 (enExample) | 2017-08-01 |
| EP3068748A1 (en) | 2016-09-21 |
| CA2929594A1 (en) | 2015-05-21 |
| SA516371017B1 (ar) | 2017-12-05 |
| CN111875468A (zh) | 2020-11-03 |
| KR102322348B1 (ko) | 2021-11-09 |
| RU2665480C1 (ru) | 2018-08-30 |
| US9725382B2 (en) | 2017-08-08 |
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| Date | Code | Title | Description |
|---|---|---|---|
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 14/10/2014, OBSERVADAS AS CONDICOES LEGAIS. |