CN105646069A - Multieffect biological organic granular fertilizer and preparation method thereof - Google Patents
Multieffect biological organic granular fertilizer and preparation method thereof Download PDFInfo
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- CN105646069A CN105646069A CN201511024942.4A CN201511024942A CN105646069A CN 105646069 A CN105646069 A CN 105646069A CN 201511024942 A CN201511024942 A CN 201511024942A CN 105646069 A CN105646069 A CN 105646069A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B1/00—Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
- C05B1/02—Superphosphates
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
- A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
- A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F1/00—Fertilisers made from animal corpses, or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F9/00—Fertilisers from household or town refuse
- C05F9/04—Biological compost
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Abstract
The invention relates to the field of fertilizer preparation and discloses a multieffect biological organic granular fertilizer and a preparation method thereof. The fertilizer is prepared from chicken manure, goat manure, sewage sludge, slaughter leftovers, kitchen waste, calcium superphosphate, ammonium sulfate, a composite bacterial solution, wheat bran, field rice bran, a growth promotor, aeration granules, a pesticide and a binder. The preparation method comprises the steps: (1) mixing the composite bacterial solution with the wheat bran and the field rice bran, and carrying out drying, so as to prepare a mixture; (2) mixing the chicken manure, the goat manure, the sewage sludge, the slaughter leftovers and the kitchen waste with the mixture, carrying out stirring, and then, carrying out compost fermentation; (3) carrying out baking on the fermented material, carrying out crushing and screening, proportioning the screened material with remaining ingredients, and finally, carrying out stirring, granulating and drying, thereby obtaining a finished product. The multieffect biological organic granular fertilizer disclosed by the invention is good in shape and high in fertilizer effect and has the effects of disinsection and plant growth promoting.
Description
Technical field
The present invention relates to fertilizer preparation field, particularly relate to a kind of multiple-effect biological organic granular fertilizer and its preparation method.
Background technology
Fertilizer mainly refers to the class fertilizer that natural organic matter becomes through microbial decomposition or fermentation. The main component of general fertilizer is human excrement, livestock waste etc.
But traditional organic fertilizer, when carrying out the fermentation of raw material, there will be raw material and becomes thoroughly decomposed not problem thoroughly. Causing final organic fertilizer fertility not enough, fertilizer efficiency is short.
Application number be 201010252598.5 Chinese patent disclose a kind of method that feces of livestock and poultry makes fertilizer, it is characterised in that feces of livestock and poultry, maize straw (simply pulverize), HM zymophyte are evenly stirred obtained.
The fertilizer feces of livestock and poultry of above-mentioned patent easily becomes thoroughly decomposed not thorough, causes fertility poor. This fertilizer function singleness simultaneously, does not meet the development trend of current fertilizer multifunction.
Summary of the invention
In order to solve the problems of the technologies described above, the present invention provides a kind of multiple-effect biological organic granular fertilizer and its preparation method. The multiple-effect biological organic granular fertilizer of the present invention, adopts the organic matter source of high-quality, adopts modern biotechnology fermentation engineering, add mixing microorganisms fermenting agent, under the production technique of advanced person, through the thermophilic fermentation of microorganism, fully become thoroughly decomposed, refine and become. This multiple-effect biological organic granular fertilizer grain forming is good, fertilizer efficiency height, and has the effect killing worm, Promoting plant growth.
The concrete technical scheme of the present invention is: a kind of multiple-effect biological organic granular fertilizer, comprises the raw material of following weight part:
Chicken excrement 180-220 part,
Sheep excrement 480-520 part,
Sewage sludge 140-160 part,
Butcher tankage 45-55 part,
Meal kitchen waste material 90-110 part,
Calcium superphosphate 28-32 part,
Ammonium sulfate 28-32 part,
Composite bacteria liquid 4-6 part,
Wheat bran 8-12 part,
Cylinder chaff 8-12 part,
Growth promoter 4-6 part,
Oxygenation particle 8-12 part,
Sterilant 8-12 part,
Binding agent 8-12 part.
Preferably, described chicken excrement, sheep excrement, sewage sludge, butcher tankage, moisture content in meal kitchen waste material be 30wt%, and in chicken excrement, sheep excrement, soil-containing rate is being 0%;Described calcium superphosphate be powdery and soluble rate more than 93%, described ammonium sulfate is that powdery and soluble rate are more than 96%.
Preferably, described composite bacteria liquid comprises at least two kinds in subtilis bacterium liquid, bacillus thuringiensis bacterium liquid, bacillus megaterium bacterium liquid, colloid bacillus cereus bacterium liquid, lactobacillus plantarum bacterium liquid. Described growth promoter is one or more in Plant hormones regulators,gibberellins pulvis, ethrel pulvis, IDALL's receipts pulvis. Growth promoter and fertilizer together compound, when, after fertilising, growth promoter can penetrate in soil, Promoting plant growth. Described binding agent be in Xylo-Mucine, sodium alginate one or more. Select Xylo-Mucine and sodium alginate as the binding agent of fertilizer, the bonding force between each raw material can be improved when granulation on the one hand, make the fertilizer intensity height after granulation, and there is certain toughness, be not subject to external force and fragmentary; On the other hand, Xylo-Mucine and sodium alginate have less water-retaining capacity, when after fertilising, fertilizer can fast absorption moisture, thus make water absorption and swelling in fertilizer, be easy to dissolve, it is possible to rapid osmotic in soil, instant effect.
Preferably, described sterilant is be adsorbed with in Malathion, cyhalothrin, pyridaben, nicotine one or more sepiolite powder; Described method for producing insecticide is as follows: by Malathion, cyhalothrin, pyridaben, nicotine, one or more add that to dissolve obtained concentration in water be the solution of 0.1-0.3wt% to, the sepiolite then adding its 4-6 times of quality in solution carries out stirring, leave standstill, filter after get solid and namely obtain described sterilant.
Generally by normally direct to sterilant and fertilizer compound mixing granulation, the less stable of sterilant like this, and easily run off. After sterilant is first dissolved by the technical program, sepiolite is selected to draw insecticide solution. Sepiolite powder is the stone flour that a kind of inside has three-dimensional porous road, there is very strong imbibition ability and imbibition capacity, and the hold facility of solution is relatively strong, sepiolite powder is other raw material mixing granulations of fertilizer after being adsorbed by sterilant liquid, it is possible to improve the stability of sterilant. In addition sterilant can be carried out slow releasing by sepiolite, extends the actual effect of sterilant.
Preferably, described oxygenation particle is the polyurethane foam particle that load has oxygenation agent; Described oxygenation agent is one or more in urea peroxide, SPC-D, percarbonic acid calcium.
Preferably, the preparation method of described oxygenation particle is: carry out after oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, carboxymethyl cellulose, tea saponin and water being mixed stirring foaming, after foaming, the foam of rear obtained hard standing at 60-70 DEG C, dry, pulverizes foam and namely obtains described oxygenation particle; The mass ratio of wherein oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, tea saponin and water is (20-30): 40:50:1:1:2.
Oxygenation agent is added in fertilizer, after after fertilising, oxygenation agent penetrates into soil gradually, it is possible to improve the oxygen level of soil, together coordinate with growth promoter, it is possible to promote plant root growth. Oxygenation agent and urethane together are carried out foaming and pulverizes in particle again, be equivalent to oxygenation agent be carried in polyurethane foam particle, there is following benefit; Oxygenation agent has certain biocidal property, if directly mixed with the bacterial classification in fertilizer, can be suppressed by mushroom, and oxygenation agent and be dissolved in water and decompose, it is easy to after fertilising contact with water and dissolve and put oxygen, just oxygen is discharged fast in early days after causing fertilising, ageing short.After polyurethane foam compound, oxygenation agent is served coated effect by urethane, it is possible to avoid oxygenation agent directly to contact with mushroom, solves the problem that oxygenation agent suppresses fungus grown. And urethane is by being oleophilic drainage material, after fertilising, oxygenation agent is intercepted, it is possible to prevent oxygenation agent from dissolving rapidly.
In oxygenation particle preparation process, carboxymethyl cellulose plays the effect of tackiness agent, and water is as whipping agent, and tea saponin is as emulsifying agent and stablizer, and tea saponin self also has certain disinsection efficiency simultaneously, it is possible to sterilant synergy.
Preferably, the preparation method of described polyether glycol is as follows: add in phenol after bamboo powder and xylogen being mixed, stir at 170-180 DEG C, whipping process adds sodium hydroxide solution that mass concentration is 20% in batches, by pH adjusting agent, solution is adjusted to neutrality after 1h, allows solution naturally cooling, until when solution temperature is 80 DEG C, plant polyatomic alcohol, formaldehyde is added, obtained polyether glycol after proceeding stirring reaction 2-3h to solution.
The common degradation of polyurethane cycle is very long, is unfavorable for environmental protection, and meeting spoiled soil structure, makes soil compaction, and fertility declines. The polyether glycol selecting aforesaid method to prepare is that urethane prepared by raw material so that the degradation cycle of urethane shortens greatly, and the several months just can degrade completely. The benefit of urethane capable of being fast degraded is also: along with the degraded gradually of urethane, the oxygenation agent of its load also can be discharged gradually, thus plays slow releasing function.
A preparation method for multiple-effect biological organic granular fertilizer, step is:
1), by composite bacteria liquid mix with wheat bran, cylinder chaff, mix obtained compound after being dried.
2), by chicken excrement, sheep excrement, sewage sludge, butchers tankage, carries out compost fermentation after meal kitchen waste material and above-mentioned compound mix and blend.
3), by the fermentation material after fermentation prepare burden with calcium superphosphate, growth promoter, oxygenation particle, sterilant and binding agent after oven dry, pulverizing, sub-sieve, eventually pass stirring, granulation, dry rear obtained finished product. Fermentation material is when drying, and in order to avoid effectively living bacterium because temperature is too high and dead in drying course, drying materials temperature must not higher than 60 DEG C (being generally 50 DEG C).
Preferably, described chicken excrement, sheep excrement, sewage sludge, butchers tankage, and the composting fermentation process of meal kitchen waste material is as follows: ferment at compost temperature is room temperature to 45 DEG C 1-3 days, then ferment 8-10 days at compost temperature 45-80 DEG C, finally cool secondary fermentation of becoming thoroughly decomposed and terminate.
Preferably, described chicken excrement, sheep excrement, sewage sludge, butchers tankage, meal kitchen waste material before compost fermentation through pre-treatment: by chicken excrement, sheep excrement, sewage sludge, butchers tankage, meal kitchen waste material together mixes with sodium bicarbonate, is then incubated 1-2h at 50-80 DEG C, and wherein the quality of sodium bicarbonate is chicken excrement, sheep excrement, sewage sludge, butchers tankage, the 1-3% of meal kitchen waste material total mass.
By chicken excrement, sheep excrement, sewage sludge, butchering tankage, meal kitchen waste material carries out pre-treatment before compost fermentation, after sodium bicarbonate Hybrid Heating, sodium bicarbonate decomposes release gas, so that chicken excrement, sheep excrement, sewage sludge, butchers tankage, and waste material inside, meal kitchen has a large amount of pores, structure becomes homogeneous more and loosens, air permeable effect is better, is conducive to growth, the breeding fermentation of mushroom with mushroom, it is to increase attenuation degree after mixing.
The technical scheme of the present invention has following useful effect: the multiple-effect biological organic granular fertilizer of the present invention, adopt the organic matter source of high-quality, adopt modern biotechnology fermentation engineering, add mixing microorganisms fermenting agent, under the production technique of advanced person, through the thermophilic fermentation of microorganism, fully become thoroughly decomposed, refine and become.This multiple-effect biological organic granular fertilizer grain forming is good, fertilizer efficiency height, and has the effect killing worm, Promoting plant growth.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
A kind of multiple-effect biological organic granular fertilizer, comprises the raw material of following weight part:
200 parts, chicken excrement,
500 parts, sheep excrement,
Sewage sludge 150 parts,
Butcher tankage 50 parts,
100 parts, meal kitchen waste material,
Calcium superphosphate 30 parts,
30 parts, ammonium sulfate,
Composite bacteria liquid 5 parts,
10 parts, wheat bran,
Cylinder chaff 10 parts,
5 parts, Plant hormones regulators,gibberellins pulvis,
Oxygenation particle 10 parts,
10 parts, sterilant,
Xylo-Mucine 10 parts.
In the raw material of the present embodiment,
Described chicken excrement, sheep excrement, sewage sludge, butcher tankage, moisture content in meal kitchen waste material be 30wt%, and in chicken excrement, sheep excrement, soil-containing rate is being 0%; Described calcium superphosphate be powdery and soluble rate more than 93%, described ammonium sulfate is that powdery and soluble rate are more than 96%.
Described composite bacteria liquid comprises subtilis bacterium liquid, colloid bacillus cereus bacterium liquid, lactobacillus plantarum bacterium liquid.
Described sterilant is the sepiolite powder being adsorbed with Malathion. Method for producing insecticide is as follows: Malathion adds to dissolve obtained concentration in water be the solution of 0.2wt%, the sepiolite then adding its 5 times of quality in solution carries out stirring, leave standstill, filter after get solid and namely obtain described sterilant.
Described oxygenation particle is the polyurethane foam particle that load has oxygenation agent; Described oxygenation agent is urea peroxide. The preparation method of oxygenation particle is:
The preparation of polyether glycol: add in phenol after bamboo powder and xylogen are mixed, stir at 175 DEG C, whipping process adds sodium hydroxide solution that mass concentration is 20% in batches, by pH adjusting agent, solution is adjusted to neutrality after 1h, allow solution naturally cooling, until when solution temperature is 80 DEG C, adding plant polyatomic alcohol, formaldehyde to solution, obtained polyether glycol after proceeding stirring reaction 2.5h.
Carry out after oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, carboxymethyl cellulose, tea saponin and water being mixed stirring foaming, after foaming, the foam of rear obtained hard standing at 65 DEG C, dry, pulverizes foam and namely obtains described oxygenation particle; The mass ratio of wherein oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, tea saponin and water is 25:40:50:1:1:2.
The preparation method of the multiple-effect biological organic granular fertilizer of the present embodiment, step is:
1), by composite bacteria liquid mix with wheat bran, cylinder chaff, mix obtained compound after being dried. Composite bacteria liquid is mixed with wheat bran, cylinder chaff, bacterium liquid is scattered in wheat bran, cylinder chaff as carrier, it is to increase bacterial classification survival rate.
2), by chicken excrement, sheep excrement, sewage sludge, butcher tankage, meal kitchen waste material and above-mentioned compound mix and blend after carry out compost fermentation. Fermenting process is as follows: ferment 2 days at compost temperature is room temperature to 45 DEG C, then ferments 9 days at compost temperature 45-80 DEG C, finally cools secondary fermentation of becoming thoroughly decomposed and terminates.
3), by the fermentation material after fermentation prepare burden with calcium superphosphate, growth promoter, oxygenation particle, sterilant and binding agent after oven dry, pulverizing, sub-sieve, eventually pass stirring, granulation, dry rear obtained finished product.
The finished particle diameter that the present embodiment obtains is 3.0-4.0mm, and the water content of finished product fertilizer is lower than 14%.
Embodiment 2
A kind of multiple-effect biological organic granular fertilizer, comprises the raw material of following weight part:
200 parts, chicken excrement,
500 parts, sheep excrement,
Sewage sludge 150 parts,
Butcher tankage 50 parts,
100 parts, meal kitchen waste material,
Calcium superphosphate 30 parts,
30 parts, ammonium sulfate,
Composite bacteria liquid 5 parts,
10 parts, wheat bran,
Cylinder chaff 10 parts,
5 parts, ethrel pulvis,
Oxygenation particle 10 parts,
10 parts, sterilant,
Xylo-Mucine 5 parts, sodium alginate 5 parts.
In the raw material of the present embodiment,
Described chicken excrement, sheep excrement, sewage sludge, butcher tankage, moisture content in meal kitchen waste material be 30wt%, and in chicken excrement, sheep excrement, soil-containing rate is being 0%; Described calcium superphosphate be powdery and soluble rate more than 93%, described ammonium sulfate is that powdery and soluble rate are more than 96%.
Described composite bacteria liquid comprises bacillus thuringiensis bacterium liquid, bacillus megaterium bacterium liquid, lactobacillus plantarum bacterium liquid.
Described sterilant is the sepiolite powder being adsorbed with cyhalothrin, pyridaben. Method for producing insecticide is as follows: cyhalothrin, pyridaben add to dissolve obtained concentration in water be the solution of 0.2wt%, the sepiolite then adding its 5 times of quality in solution carries out stirring, leave standstill, filter after get solid and namely obtain described sterilant.
Described oxygenation particle is the polyurethane foam particle that load has oxygenation agent. described oxygenation agent is SPC-D. The preparation method of oxygenation particle is:
The preparation of polyether glycol: add in phenol after bamboo powder and xylogen are mixed, stir at 175 DEG C, whipping process adds sodium hydroxide solution that mass concentration is 20% in batches, by pH adjusting agent, solution is adjusted to neutrality after 1h, allow solution naturally cooling, until when solution temperature is 80 DEG C, adding plant polyatomic alcohol, formaldehyde to solution, obtained polyether glycol after proceeding stirring reaction 2.5h.
Carry out after oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, carboxymethyl cellulose, tea saponin and water being mixed stirring foaming, after foaming, the foam of rear obtained hard standing at 65 DEG C, dry, pulverizes foam and namely obtains described oxygenation particle; The mass ratio of wherein oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, tea saponin and water is 25:40:50:1:1:2.
The preparation method of the multiple-effect biological organic granular fertilizer of the present embodiment, step is:
1), by composite bacteria liquid mix with wheat bran, cylinder chaff, mix obtained compound after being dried.
2), by chicken excrement, sheep excrement, sewage sludge, butcher tankage, meal kitchen waste material together mixes with sodium bicarbonate, then at 65 DEG C, be incubated 1.5h, wherein the quality of sodium bicarbonate be chicken excrement, sheep excrement, sewage sludge, butcher tankage, the 1-3% of meal kitchen waste material total mass. Then by chicken excrement, sheep excrement, sewage sludge, butcher tankage, meal kitchen waste material and above-mentioned compound mix and blend after carry out compost fermentation. Fermenting process is as follows: ferment 2 days at compost temperature is room temperature to 45 DEG C, then ferments 9 days at compost temperature 45-80 DEG C, finally cools secondary fermentation of becoming thoroughly decomposed and terminates.
3), by the fermentation material after fermentation prepare burden with calcium superphosphate, growth promoter, oxygenation particle, sterilant and binding agent after oven dry, pulverizing, sub-sieve, eventually pass stirring, granulation, dry rear obtained finished product.
The finished particle diameter that the present embodiment obtains is 3.0-4.0mm, and the water content of finished product fertilizer is lower than 14%.
Embodiment 3
A kind of multiple-effect biological organic granular fertilizer, comprises the raw material of following weight part:
180 parts, chicken excrement,
520 parts, sheep excrement,
Sewage sludge 160 parts,
Butcher tankage 45 parts,
90 parts, meal kitchen waste material,
Calcium superphosphate 28 parts,
28 parts, ammonium sulfate,
Composite bacteria liquid 4 parts,
8 parts, wheat bran,
Cylinder chaff 8 parts,
4 parts, pulvis is received by IDALL,
Oxygenation particle 8 parts,
8 parts, sterilant,
Sodium alginate 8 parts.
In the raw material of the present embodiment,
Described chicken excrement, sheep excrement, sewage sludge, butcher tankage, moisture content in meal kitchen waste material be 30wt%, and in chicken excrement, sheep excrement, soil-containing rate is being 0%; Described calcium superphosphate be powdery and soluble rate more than 93%, described ammonium sulfate is that powdery and soluble rate are more than 96%.
Described composite bacteria liquid comprises bacillus thuringiensis bacterium liquid, lactobacillus plantarum bacterium liquid.
Described sterilant is the sepiolite powder being adsorbed with nicotine. Method for producing insecticide is as follows: nicotine adds to dissolve obtained concentration in water be the solution of 0.1wt%, the sepiolite then adding its 4 times of quality in solution carries out stirring, leave standstill, filter after get solid and namely obtain described sterilant.
Described oxygenation particle is the polyurethane foam particle that load has oxygenation agent; Described oxygenation agent is urea peroxide and SPC-D. The preparation method of oxygenation particle is:
The preparation of polyether glycol: add in phenol after bamboo powder and xylogen are mixed, stir at 170 DEG C, whipping process adds sodium hydroxide solution that mass concentration is 20% in batches, by pH adjusting agent, solution is adjusted to neutrality after 1h, allow solution naturally cooling, until when solution temperature is 80 DEG C, adding plant polyatomic alcohol, formaldehyde to solution, obtained polyether glycol after proceeding stirring reaction 2h.
Carry out after oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, carboxymethyl cellulose, tea saponin and water being mixed stirring foaming, after foaming, the foam of rear obtained hard standing at 60 DEG C, dry, pulverizes foam and namely obtains described oxygenation particle; The mass ratio of wherein oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, tea saponin and water is 20:40:50:1:1:2.
The preparation method of the multiple-effect biological organic granular fertilizer of the present embodiment, step is:
1), by composite bacteria liquid mix with wheat bran, cylinder chaff, mix obtained compound after being dried.
2), by chicken excrement, sheep excrement, sewage sludge, butcher tankage, meal kitchen waste material together mixes with sodium bicarbonate, then at 50 DEG C, be incubated 2h, wherein the quality of sodium bicarbonate be chicken excrement, sheep excrement, sewage sludge, butcher tankage, meal kitchen waste material total mass 1%. By chicken excrement, sheep excrement, sewage sludge, butcher tankage, meal kitchen waste material and above-mentioned compound mix and blend after carry out compost fermentation. Fermenting process is as follows: ferment 1 day at compost temperature is room temperature to 45 DEG C, then ferments 8 days at compost temperature 45-80 DEG C, finally cools secondary fermentation of becoming thoroughly decomposed and terminates.
3), by the fermentation material after fermentation prepare burden with calcium superphosphate, growth promoter, oxygenation particle, sterilant and binding agent after oven dry, pulverizing, sub-sieve, eventually pass stirring, granulation, dry rear obtained finished product.
The finished particle diameter that the present embodiment obtains is 3.0-4.0mm, and the water content of finished product fertilizer is lower than 14%.
Embodiment 4
A kind of multiple-effect biological organic granular fertilizer, comprises the raw material of following weight part:
220 parts, chicken excrement,
480 parts, sheep excrement,
Sewage sludge 140 parts,
Butcher tankage 55 parts,
110 parts, meal kitchen waste material,
Calcium superphosphate 28-32 part,
Ammonium sulfate 28-32 part,
Composite bacteria liquid 6 parts,
12 parts, wheat bran,
Cylinder chaff 12 parts,
3 parts, pulvis is received by 3 parts, Plant hormones regulators,gibberellins pulvis, IDALL,
Oxygenation particle 12 parts,
12 parts, sterilant,
Xylo-Mucine 6 parts, sodium alginate 6 parts.
In the raw material of the present embodiment,
Described chicken excrement, sheep excrement, sewage sludge, butcher tankage, moisture content in meal kitchen waste material be 30wt%, and in chicken excrement, sheep excrement, soil-containing rate is being 0%; Described calcium superphosphate be powdery and soluble rate more than 93%, described ammonium sulfate is that powdery and soluble rate are more than 96%.
Described composite bacteria liquid comprises subtilis bacterium liquid, lactobacillus plantarum bacterium liquid.
Described sterilant is the sepiolite powder being adsorbed with Malathion, nicotine. Method for producing insecticide is as follows: Malathion, nicotine adds to dissolve obtained concentration in water be the solution of 0.3wt%, the sepiolite then adding its 6 times of quality in solution carries out stirring, leave standstill, filter after get solid and namely obtain described sterilant.
Described oxygenation particle is the polyurethane foam particle that load has oxygenation agent; Described oxygenation agent is urea peroxide and percarbonic acid calcium. The preparation method of oxygenation particle is:
The preparation of polyether glycol: add in phenol after bamboo powder and xylogen are mixed, stir at 180 DEG C, whipping process adds sodium hydroxide solution that mass concentration is 20% in batches, by pH adjusting agent, solution is adjusted to neutrality after 1h, allow solution naturally cooling, until when solution temperature is 80 DEG C, adding plant polyatomic alcohol, formaldehyde to solution, obtained polyether glycol after proceeding stirring reaction 3h.
Carry out after oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, carboxymethyl cellulose, tea saponin and water being mixed stirring foaming, after foaming, the foam of rear obtained hard standing at 70 DEG C, dry, pulverizes foam and namely obtains described oxygenation particle; The mass ratio of wherein oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, tea saponin and water is 30:40:50:1:1:2.
The preparation method of the multiple-effect biological organic granular fertilizer of the present embodiment, step is:
1), by composite bacteria liquid mix with wheat bran, cylinder chaff, mix obtained compound after being dried.
2), by chicken excrement, sheep excrement, sewage sludge, butcher tankage, meal kitchen waste material together mixes with sodium bicarbonate, then at 80 DEG C, be incubated 1h, wherein the quality of sodium bicarbonate be chicken excrement, sheep excrement, sewage sludge, butcher tankage, meal kitchen waste material total mass 3%.
By chicken excrement, sheep excrement, sewage sludge, butcher tankage, meal kitchen waste material and above-mentioned compound mix and blend after carry out compost fermentation. Fermenting process is as follows: ferment 3 days at compost temperature is room temperature to 45 DEG C, then ferments 10 days at compost temperature 45-80 DEG C, finally cools secondary fermentation of becoming thoroughly decomposed and terminates.
3), by the fermentation material after fermentation prepare burden with calcium superphosphate, growth promoter, oxygenation particle, sterilant and binding agent after oven dry, pulverizing, sub-sieve, eventually pass stirring, granulation, dry rear obtained finished product.
The finished particle diameter that the present embodiment obtains is 3.0-4.0mm, and the water content of finished product fertilizer is lower than 14%.
Raw materials used, equipment in the present invention, unless otherwise noted, is conventional raw material, the equipment of this area; Method therefor in the present invention, unless otherwise noted, is the ordinary method of this area.
The above; it it is only the better embodiment of the present invention; not the present invention being imposed any restrictions, every any simple modification, change and equivalent transformation above embodiment done according to the technology of the present invention essence, all still belongs to the protection domain of technical solution of the present invention.
Claims (10)
1. a multiple-effect biological organic granular fertilizer, it is characterised in that: the raw material comprising following weight part:
Chicken excrement 180-220 part,
Sheep excrement 480-520 part,
Sewage sludge 140-160 part,
Butcher tankage 45-55 part,
Meal kitchen waste material 90-110 part,
Calcium superphosphate 28-32 part,
Ammonium sulfate 28-32 part,
Composite bacteria liquid 4-6 part,
Wheat bran 8-12 part,
Cylinder chaff 8-12 part,
Growth promoter 4-6 part,
Oxygenation particle 8-12 part,
Sterilant 8-12 part,
Binding agent 8-12 part.
2. multiple-effect biological organic granular fertilizer as claimed in claim 1 a kind of, it is characterised in that, described chicken excrement, sheep excrement, sewage sludge, butcher tankage, moisture content in the waste material of meal kitchen be 30wt%, and in chicken excrement, sheep excrement, soil-containing rate is being 0%; Described calcium superphosphate be powdery and soluble rate more than 93%, described ammonium sulfate is that powdery and soluble rate are more than 96%.
3. a kind of multiple-effect biological organic granular fertilizer as claimed in claim 1, it is characterized in that, described composite bacteria liquid comprises at least two kinds in subtilis bacterium liquid, bacillus thuringiensis bacterium liquid, bacillus megaterium bacterium liquid, colloid bacillus cereus bacterium liquid, lactobacillus plantarum bacterium liquid; Described growth promoter is one or more in Plant hormones regulators,gibberellins pulvis, ethrel pulvis, IDALL's receipts pulvis; Described binding agent be in Xylo-Mucine, sodium alginate one or more.
4. multiple-effect biological organic granular fertilizer as claimed in claim 1 a kind of, it is characterised in that, described sterilant is be adsorbed with in Malathion, cyhalothrin, pyridaben, nicotine one or more sepiolite powder; Described method for producing insecticide is as follows: by Malathion, cyhalothrin, pyridaben, nicotine, one or more add that to dissolve obtained concentration in water be the solution of 0.1-0.3wt% to, the sepiolite then adding its 4-6 times of quality in solution carries out stirring, leave standstill, filter after get solid and namely obtain described sterilant.
5. a kind of multiple-effect biological organic granular fertilizer as claimed in claim 1, it is characterised in that, described oxygenation particle is the polyurethane foam particle that load has oxygenation agent; Described oxygenation agent is one or more in urea peroxide, SPC-D, percarbonic acid calcium.
6. a kind of multiple-effect biological organic granular fertilizer as claimed in claim 5, it is characterized in that, the preparation method of described oxygenation particle is: carry out after oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, carboxymethyl cellulose, tea saponin and water being mixed stirring foaming, after foaming, the foam of rear obtained hard standing at 60-70 DEG C, dry, pulverizes foam and namely obtains described oxygenation particle; The mass ratio of wherein oxygenation agent, polyether glycol, isocyanic ester, triethylene diamine, tea saponin and water is (20-30): 40:50:1:1:2.
7. a kind of multiple-effect biological organic granular fertilizer as claimed in claim 6, it is characterized in that, the preparation method of described polyether glycol is as follows: add in phenol after bamboo powder and xylogen being mixed, stir at 170-180 DEG C, whipping process adds sodium hydroxide solution that mass concentration is 20% in batches, by pH adjusting agent, solution is adjusted to neutrality after 1h, allow solution naturally cooling, until when solution temperature is 80 DEG C, plant polyatomic alcohol, formaldehyde is added, obtained polyether glycol after proceeding stirring reaction 2-3h to solution.
8. the preparation method of a kind of multiple-effect biological organic granular fertilizer as described in one of claim 1-7, it is characterised in that, step is:
1), by composite bacteria liquid mix with wheat bran, cylinder chaff, mix obtained compound after being dried;
2), by chicken excrement, sheep excrement, sewage sludge, butchers tankage, carries out compost fermentation after meal kitchen waste material and above-mentioned compound mix and blend;
3), by the fermentation material after fermentation prepare burden with calcium superphosphate, growth promoter, oxygenation particle, sterilant and binding agent after oven dry, pulverizing, sub-sieve, eventually pass stirring, granulation, dry rear obtained finished product.
9. the preparation method of a kind of multiple-effect biological organic granular fertilizer as claimed in claim 8, it is characterized in that, described chicken excrement, sheep excrement, sewage sludge, butchers tankage, and the composting fermentation process of meal kitchen waste material is as follows: ferment at compost temperature is room temperature to 45 DEG C 1-3 days, then ferment 8-10 days at compost temperature 45-80 DEG C, finally cool secondary fermentation of becoming thoroughly decomposed and terminate.
10. the preparation method of a kind of multiple-effect biological organic granular fertilizer as claimed in claim 9, it is characterised in that, described chicken excrement, sheep excrement, sewage sludge, butchers tankage, meal kitchen waste material before compost fermentation through pre-treatment: by chicken excrement, sheep excrement, sewage sludge, butchering tankage, meal kitchen waste material together mixes with sodium bicarbonate, is then incubated 1-2h at 50-80 DEG C, wherein the quality of sodium bicarbonate is chicken excrement, sheep excrement, sewage sludge, butcher tankage, the 1-3% of meal kitchen waste material total mass.
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| CN106489589A (en) * | 2016-09-28 | 2017-03-15 | 博白县大红火龙果专业合作社 | A kind of fertilizer bag of Karst Mountain Areas plantation Hylocereus undatuss and preparation method thereof |
| CN113462393A (en) * | 2021-07-30 | 2021-10-01 | 昆明理工大学 | Biological drying treatment method for wet organic matters in alpine and high-altitude areas |
| CN114276175A (en) * | 2020-12-23 | 2022-04-05 | 海南博奥农业发展投资有限公司 | Preparation, application and process system of biological organic waste compound fertilizer |
| WO2023187223A1 (en) * | 2022-04-01 | 2023-10-05 | Amplicon Ab | Nicotine formulations |
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