CN105619961A - 一种协同阻燃复合层压防火板 - Google Patents

一种协同阻燃复合层压防火板 Download PDF

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CN105619961A
CN105619961A CN201510966216.8A CN201510966216A CN105619961A CN 105619961 A CN105619961 A CN 105619961A CN 201510966216 A CN201510966216 A CN 201510966216A CN 105619961 A CN105619961 A CN 105619961A
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杨小锋
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SUZHOU CITY QIANGSEN WOOD INDUSTRY Co Ltd
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SUZHOU CITY QIANGSEN WOOD INDUSTRY Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/065—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/38—Corrosion-inhibiting agents or anti-oxidants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/05—5 or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant

Abstract

本发明公开了一种协同阻燃复合层压防火板，包括：增强层、纸板层和防火胶层；所述纸板层位于所述增强层的两侧，所述防火胶层涂覆在所述纸板层的外表面；其中，所述防火胶层由如下重量份组分制备而成：溴化环氧树脂50～80份、三聚氰胺5～10份、季戊四醇2～5份、多聚磷酸5～10份、氢氧化镁10～15份、甲基膦酸二甲酯5～10份、乙二烯三胺6～10份、抗氧剂0.5～1份。本发明一种协同阻燃复合层压防火板，通过阻燃胶层的配方设计和增强层的设计，使防火板具有优异的防火性能、结构强度和环保性能，综合性能优异，是现有防火板的优异替代品。

Description

一种协同阻燃复合层压防火板
技术领域
本发明涉及防火板领域，特别是涉及一种协同阻燃复合层压防火板。
背景技术
防火板又名耐火板，学名为热固性树脂浸渍纸高压层积板，是表面装饰用耐火建材，有丰富的表面色彩，纹路以及特殊的物流性能，广泛用于室内装饰、家具、厨柜、实验室台面、外墙等领域。防火板的品种很多，其中酚醛防火板成为人们获得性能满意、成本有竞争力的品种之一，从而具有广阔的应用前景。
但是现有酚醛树脂防火板存在如下问题：1、释放游离甲醛，对人们的健康造成威胁；2、阻燃等级低，存在火灾隐患；3、整体强度低。
发明内容
本发明主要解决的技术问题是提供一种协同阻燃复合层压防火板，能够解决现有防火板存在的上述问题。
为解决上述技术问题，本发明采用的一个技术方案是：提供一种协同阻燃复合层压防火板，包括：增强层、纸板层和防火胶层；所述纸板层位于所述增强层的两侧，所述防火胶层涂覆在所述纸板层的外表面；其中，所述防火胶层由如下重量份组分制备而成：溴化环氧树脂50～80份、三聚氰胺5～10份、季戊四醇2～5份、多聚磷酸5～10份、氢氧化镁10～15份、甲基膦酸二甲酯5～10份、乙二烯三胺6～10份、抗氧剂0.5～1份。
在本发明一个较佳实施例中，所述增强层为多层玻璃纤维层布。
在本发明一个较佳实施例中，所述玻璃纤维层布的层数为3层以上。
在本发明一个较佳实施例中，所述防火胶层的厚度为1～5mm。
本发明的有益效果是：本发明一种协同阻燃复合层压防火板，通过阻燃胶层的配方设计和增强层的设计，使防火板具有优异的防火性能、结构强度和环保性能，综合性能优异，是现有防火板的优异替代品。
附图说明
图1是本发明一种协同阻燃复合层压防火板一较佳实施例的立体结构示意图；
附图中各部件的标记如下：1.增强层，2.纸板层，3.阻燃胶层。
具体实施方式
下面对本发明的较佳实施例进行详细阐述，以使本发明的优点和特征能更易于被本领域技术人员理解，从而对本发明的保护范围做出更为清楚明确的界定。
请参阅图1，本发明实施例包括：
实施例1
一种协同阻燃复合层压防火板，包括：增强层1、纸板层2和防火胶层3；所述纸板层位于所述增强层的两侧，所述防火胶层涂覆在所述纸板层的外表面。
所述增强层1为3层以上的玻璃纤维层布，起到支撑、增强和提高抗冲击性能的作用，另外，对提高阻燃性能也有辅助作用。
所述防火胶层3的厚度为1mm，其由如下重量份组分制备而成：溴化环氧树脂50份、三聚氰胺5份、季戊四醇2份、多聚磷酸5份、氢氧化镁10份、甲基膦酸二甲酯5份、乙二烯三胺6份、抗氧剂0.5份。
实施例2
一种协同阻燃复合层压防火板，包括：增强层1、纸板层2和防火胶层3；所述纸板层位于所述增强层的两侧，所述防火胶层涂覆在所述纸板层的外表面。
所述增强层1为3层以上的玻璃纤维层布，起到支撑、增强和提高抗冲击性能的作用，另外，对提高阻燃性能也有辅助作用。
所述防火胶层3的厚度为5mm，其由如下重量份组分制备而成：溴化环氧树脂80份、三聚氰胺10份、季戊四醇5份、多聚磷酸10份、氢氧化镁15份、甲基膦酸二甲酯10份、乙二烯三胺10份、抗氧剂1份。
上述协同阻燃复合层压防火板，经测试，其性能为：冲击强度8～10kJ/m2；拉伸强度58MPa以上；氧指数大于33。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书及附图内容所作的等效结构或等效流程变换，或直接或间接运用在其他相关的技术领域，均同理包括在本发明的专利保护范围内。

Claims (4)

1.一种协同阻燃复合层压防火板，其特征在于，包括：增强层、纸板层和防火胶层；所述纸板层位于所述增强层的两侧，所述防火胶层涂覆在所述纸板层的外表面；其中，所述防火胶层由如下重量份组分制备而成：溴化环氧树脂50～80份、三聚氰胺5～10份、季戊四醇2～5份、多聚磷酸5～10份、氢氧化镁10～15份、甲基膦酸二甲酯5～10份、乙二烯三胺6～10份、抗氧剂0.5～1份。
2.根据权利要求1所述的协同阻燃复合层压防火板，其特征在于，所述增强层为多层玻璃纤维层布。
3.根据权利要求2所述的协同阻燃复合层压防火板，其特征在于，所述玻璃纤维层布的层数为3层以上。
4.根据权利要求1所述的协同阻燃复合层压防火板，其特征在于，所述防火胶层的厚度为1～5mm。
CN201510966216.8A 2015-12-22 2015-12-22 一种协同阻燃复合层压防火板 Pending CN105619961A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106848862A (zh) * 2017-01-19 2017-06-13 厦门弘诚复合材料有限公司 一种复合阻燃纸板及其制备方法

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CN2238139Y (zh) * 1996-01-12 1996-10-23 万长富 阻燃型豪华装饰片材
CN101148936A (zh) * 2007-09-25 2008-03-26 朱金龙 带防火夹芯层金属复合板及其制造方法
US20090226710A1 (en) * 2006-03-31 2009-09-10 Rene Gabriel Erich Herbiet Magnesium hydroxide with improved compounding and viscosity performance
CN101885859A (zh) * 2009-05-11 2010-11-17 中国科学院化学研究所 阻燃微胶囊及其应用
CN103724666A (zh) * 2013-12-26 2014-04-16 辽宁工程技术大学 一种含有微胶囊包覆膨胀阻燃剂的复合阻燃剂及制备方法

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
CN2238139Y (zh) * 1996-01-12 1996-10-23 万长富 阻燃型豪华装饰片材
US20090226710A1 (en) * 2006-03-31 2009-09-10 Rene Gabriel Erich Herbiet Magnesium hydroxide with improved compounding and viscosity performance
CN101148936A (zh) * 2007-09-25 2008-03-26 朱金龙 带防火夹芯层金属复合板及其制造方法
CN101885859A (zh) * 2009-05-11 2010-11-17 中国科学院化学研究所 阻燃微胶囊及其应用
CN103724666A (zh) * 2013-12-26 2014-04-16 辽宁工程技术大学 一种含有微胶囊包覆膨胀阻燃剂的复合阻燃剂及制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106848862A (zh) * 2017-01-19 2017-06-13 厦门弘诚复合材料有限公司 一种复合阻燃纸板及其制备方法
CN106848862B (zh) * 2017-01-19 2019-07-16 厦门弘诚复合材料有限公司 一种复合阻燃纸板及其制备方法

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Application publication date: 20160601