CN105482375A - 一种高效阻燃的玻璃钢复合材料 - Google Patents

一种高效阻燃的玻璃钢复合材料 Download PDF

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CN105482375A
CN105482375A CN201510872642.5A CN201510872642A CN105482375A CN 105482375 A CN105482375 A CN 105482375A CN 201510872642 A CN201510872642 A CN 201510872642A CN 105482375 A CN105482375 A CN 105482375A
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parts
flame
composite material
fiber reinforced
glass fiber
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李盛明
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QINGDAO HONGYU ENVIRONMETNAL PROTECTION AIR CONDITIONING EQUIPMENT CO Ltd
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QINGDAO HONGYU ENVIRONMETNAL PROTECTION AIR CONDITIONING EQUIPMENT CO Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种高效阻燃的玻璃钢复合材料，由以下重量份数的原料组成：无碱玻璃短纤维18-24份、环氧乙烯基树脂12-17份、阻燃剂0.4-1.1份、异辛酸钴0.7-1.8份、氢氧化铝3-6份、过氧化氢9-16份、双环戊二烯0.3-0.6份、六次亚甲基四胺0.03-0.2份，所述环氧乙烯基树脂为双酚A环氧乙烯基酯树脂、酚醛环氧乙烯基酯树脂中的一种，所述阻燃剂为聚磷酰胺。本发明具有化学稳定性和强度，阻燃效果好。

Description

一种高效阻燃的玻璃钢复合材料
技术领域
本发明属于复合材料领域，具体涉及一种高效阻燃的玻璃钢复合材料。
背景技术
玻璃钢具有耐腐蚀、重量轻的特点，在各领域得到了运用，但是高分子材料的通性易燃，在使用时存在诸多火灾隐患。目前提高玻璃钢复合材料阻燃性的主要方法为添加阻燃剂，但是阻燃剂都有一定的不足，比如含卤素阻燃剂，阻燃效果好，但是在阻燃过程中易产生大量有害烟雾，卤素阻燃剂逐步被淘汰。因此，研发一种安全环保、无毒无公害的无机阻燃剂，是提高玻璃钢复合材料阻燃性能的关键。
发明内容
针对现有技术的不足，本发明提供一种高效阻燃的玻璃钢复合材料。
为解决上述技术问题，本发明采用的技术方案是，一种高效阻燃的玻璃钢复合材料，由以下重量份数的原料组成：无碱玻璃短纤维18-24份、环氧乙烯基树脂12-17份、阻燃剂0.4-1.1份、异辛酸钴0.7-1.8份、氢氧化铝3-6份、过氧化氢9-16份、双环戊二烯0.3-0.6份、六次亚甲基四胺0.03-0.2份，所述环氧乙烯基树脂为双酚A环氧乙烯基酯树脂、酚醛环氧乙烯基酯树脂中的一种，所述阻燃剂为聚磷酰胺。
本发明具有以下优点：
（1）采用无碱玻璃短纤维，化学稳定性、电绝缘性能、强度都很好；
（2）采用聚磷酰胺阻燃剂，含磷量高、含氮量多，不含卤素，热稳定性好，水溶性好，阻燃及抑烟效能好。
具体实施方式
下面结合具体实施方式对本发明做进一步的阐述。
实施例1
一种高效阻燃的玻璃钢复合材料，由以下重量份数的原料组成：无碱玻璃短纤维18份、环氧乙烯基树脂12份、阻燃剂0.4份、异辛酸钴0.7份、氢氧化铝3份、过氧化氢9份、双环戊二烯0.3份、六次亚甲基四胺0.03份，所述环氧乙烯基树脂为双酚A环氧乙烯基酯树脂，所述阻燃剂为聚磷酰胺。
实施例2
一种高效阻燃的玻璃钢复合材料，由以下重量份数的原料组成：无碱玻璃短纤维20份、环氧乙烯基树脂15份、阻燃剂0.8份、异辛酸钴1份、氢氧化铝5份、过氧化氢10份、双环戊二烯0.4份、六次亚甲基四胺0.1份，所述环氧乙烯基树脂为双酚A环氧乙烯基酯树脂，所述阻燃剂为聚磷酰胺。
实施例3
一种高效阻燃的玻璃钢复合材料，由以下重量份数的原料组成：无碱玻璃短纤维24份、环氧乙烯基树脂17份、阻燃剂1.1份、异辛酸钴1.8份、氢氧化铝6份、过氧化氢16份、双环戊二烯0.6份、六次亚甲基四胺0.2饭份，所述环氧乙烯基树脂为酚醛环氧乙烯基酯树脂，所述阻燃剂为聚磷酰胺。
上述虽然对本发明的具体实施方式进行了描述，但并非对本发明保护范围的限制，所属领域技术人员应该明白，在本发明的技术方案的基础上，本领域技术人员不需要付出创造性劳动即可做出的各种修改或变形仍在本发明的保护范围以内。

Claims (1)

1.一种高效阻燃的玻璃钢复合材料，其特征在于：由以下重量份数的原料组成：无碱玻璃短纤维18-24份、环氧乙烯基树脂12-17份、阻燃剂0.4-1.1份、异辛酸钴0.7-1.8份、氢氧化铝3-6份、过氧化氢9-16份、双环戊二烯0.3-0.6份、六次亚甲基四胺0.03-0.2份，所述环氧乙烯基树脂为双酚A环氧乙烯基酯树脂、酚醛环氧乙烯基酯树脂中的一种，所述阻燃剂为聚磷酰胺。
CN201510872642.5A 2015-12-03 2015-12-03 一种高效阻燃的玻璃钢复合材料 Pending CN105482375A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114605597A (zh) * 2022-03-28 2022-06-10 吉林重通成飞新材料股份公司 具有后固化与高表面活性的聚环戊二烯复合材料及其制备方法
CN114605770A (zh) * 2022-03-28 2022-06-10 吉林重通成飞新材料股份公司 一种新型聚环戊二烯纤维复合材料及其制备方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114605597A (zh) * 2022-03-28 2022-06-10 吉林重通成飞新材料股份公司 具有后固化与高表面活性的聚环戊二烯复合材料及其制备方法
CN114605770A (zh) * 2022-03-28 2022-06-10 吉林重通成飞新材料股份公司 一种新型聚环戊二烯纤维复合材料及其制备方法
CN114605770B (zh) * 2022-03-28 2023-05-09 吉林重通成飞新材料股份公司 一种聚环戊二烯纤维复合材料及其制备方法
CN114605597B (zh) * 2022-03-28 2023-06-02 吉林重通成飞新材料股份公司 具有后固化与高表面活性的聚环戊二烯复合材料及其制备方法

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Application publication date: 20160413